The shear strength of the concrete-rock interface is an important parameter in sliding stability analyses of concrete dams founded on rock and depends, in addition to the normal stress state, on the bonding conditions of the interface; concrete-rock interfaces can be either unbonded, partially bonded or fully bonded. In the Swedish guidelines for dam safety all dam-foundation contacts are treated as unbonded. This has the benefit of eliminating all uncertainties related to the cohesive strength of bonded contacts but it might also lead to unnecessary strengthening of dams. Other national guidelines deal with the uncertainties related to cohesion by applying higher safety factors, mainly determined based on previous experience, when both cohesion and friction are taken into account. The main objective of this project is to study if and how cohesion can be included when evaluating the shear strength of bonded or partially bonded interfaces. To accomplish this, uncertainties associated with cohesion are identified and their influence on the assessed stability is investigated. The results show that the influence on the assessed sliding stability is strongly dependent on the magnitude of the involved uncertainties that might vary significantly for different dams. It is thus questionable if one safety factor applicable for all dams can be established for use in deterministic analyses. Taking into account cohesion when reliability methods are used is somewhat less complicated because of the possibility of directly incorporating the uncertainties in the analysis. The main challenge in such cases is the quantification of the involved uncertainties due to lack of proper data and, in some cases, knowledge. In this thesis, a framework for quantification of parameter uncertainty is suggested and the model error due to brittle failure in combination with spatial variation in cohesion is analysed. Areas that require more research to further refine the analysis are also identified. / Skjuvhållfastheten i betong-berggränssnittet är en avgörande faktor vid glidstabilitetsutvärderingar av befintliga betongdammar grundlagda på berg och beror dels på normalspänningsfördelningen och dels på kontaktytans status med avseende på vidhäftning, vilken kan delas in i tre separata fall; då vidhäftning existerar och kohesion medräknas (intakt), då vidhäftning aldrig funnits eller förlorats (bruten), samt en kombination av föregående (delvis intakt). I RIDAS, de svenska riktlinjerna för dammsäkerhet, behandlas alla berg-betonggränssnitt som brutna. Detta förhållningssätt har fördelen att det utelämnar all osäkerhet förknippad med intakta kontaktytors kohesion men det kan också resultera i icke nödvändiga förstärkningar av dammar. I andra nationella riktlinjer för dammsäkerhet beaktas osäkerheterna förknippade med kohesion genom att högre säkerhetsfaktorer, i huvudsak bestämda baserat på erfarenhet, tillämpas då både kohesion och friktion används vid beräkning av kontaktytans skjuvhållfasthet. Det övergripande syftet med detta doktorandprojekt är att studera om och hur kohesion kan medräknas vid stabilitetsutvärderingar av befintliga betongdammar med helt eller delvis intakta betong-berggränssnitt. För att uppnå detta, identifieras osäkerheter förknippande med kohesionen och deras inverkan på den bedömda glidstabiliteten utvärderas. Resultaten från projektet visar att osäkerheternas inverkan på den uppskattade glidstabiliteten är starkt beroende av osäkerheternas storlek, vilken varierar för olika dammar. Det är således tveksamt om en säkerhetsfaktor giltig för alla dammar kan bestämmas för användning i deterministiska stabilitetsanalyser. När sannolikhetsbaserade metoder används kan osäkerheterna införlivas direkt i analysen. Kvantifieringen av osäkerheterna förknippade med ett specifikt fall utgör då den huvudsakliga utmaningen. I denna avhandling presenteras ett ramverk för att uppskatta de statistiska parametrarna hos de ingående variablerna. Dessutom studeras modellosäkerheten förknippad med intakta gränssnitts spröda brott i kombination med kohesionens rumsliga variation i detalj. Områden som fordrar ytterligare forskning i syfte att förbättra analysen identifieras också. / <p>QC 20160411</p>

published_or_final_version / Civil Engineering / Master / Master of Philosophy

O propósito deste estudo foi o de avaliar a influência do sistema adesivo e do envelhecimento na resistência adesiva da interface dentina humana-resina composta. Cento e sessenta terceiros molares extraídos tiveram suas raízes removidas e as coroas seccionadas no sentido mésio-distal. As faces vestibulares foram incluídas em anel de PVC/resina acrílica e divididas em quatro grupos correspondentes aos quatro sistemas adesivos testados: um sistema adesivo de condicionamento total, como controle, Adper Single Bond 2 (ASB 2) (3M ESPE); um sistema adesivo autocondicionante de passo único, Adper Easy One (AEO) (3M ESPE); e dois sistemas adesivos autocondicionantes de dois passos, P90 System Adhesive (P90SA) (3M ESPE), e Clearfill SE Bond (CSEB) (Kuraray). Cada grupo foi dividido em quatro subgrupos correspondentes aos quatro tipos de envelhecimentos artificiais utilizados: termociclagem com 500, 10.000 e 30.000 ciclos e estocagem em água destilada a 37ºC por um ano e, após este período, termociclagem com 500 ciclos. Desta maneira, formou-se 16 subgrupos: ASB2.1, ASB2.2, ASB2.3, ASB2.4; AEO.1, AEO.2, AEO.3, AEO.4; P90SA.1, P90SA.2, P90SA.3, P90SA.4; CSEB.1, CSEB.2, CSEB.3, CSEB.4. Após o envelhecimento artificial padronizado foi realizado o teste de resistência ao cisalhamento ISO TR 11405, usando uma máquina universal de testes EMIC-2000, regulada a 0,5mm/minuto e célula de carga de 200 Kgf. Os resultados foram submetidos à análise estatística de variância (Testes ANOVA, Tukey e Scheffé). Houve diferença estatística significante (p<0,01) para dois fatores de variação (adesivo e envelhecimento) e a interação adesivo x envelhecimento (p<0,01) não apresentou diferença estatística significante. O adesivo Adper Single Bond 2, apresentou maiores valores, enquanto que, o P90 System Adhesive, os menores valores de resistência adesiva ao cisalhamento em relação aos demais sistemas adesivos. A termociclagem de 500 ciclos e a estocagem em água a 37ºC por um ano, seguida de 500 ciclos térmicos apresentaram os mais elevados valores de resistência adesiva, sem diferenças estatísticas significantes, assim com a termociclagem de 10.000 e 30.000 ciclos apresentaram os valores mais baixos. Baseado nestes achados pode-se concluir o sistema adesivo e o envelhecimento influenciaram a resistência ao cisalhamento da interface dentina humanaresina composta. / The purpose of this study was to evaluate the influence of the adhesive system and aging on the bond strength of human dentin-composite resin interface. One hundred and sixty extracted third molars had their crowns removed and the roots sectioned mesiodistally. The buccal faces were included ring PVC/acrylic resin and they were divided into four groups corresponding to the four tested adhesive systems tested. A total etch adhesive system, as controls, Adper Single Bond 2 (ASB 2) (3M ESPE), an all-in-one self-etching adhesive system, Adper Easy One (AEO) (3M ESPE) and two two steps self-etching adhesive systems, P90 System Adhesive (P90SA) (3M ESPE), and Clearfill SE Bond (CSEB) (Kuraray). Each group was divided into four subgroups corresponding to four types of used artificial aging: thermocycling with 500, 10,000 and 30,000 cycles and storage in distilled water at 37°C for one year and after this period, thermocycling with 500 cycles. Thus was formed 16 subgroups: ASB2.1, ASB2.2, ASB2.3, ASB2.4; AEO.1, AEO.2, AEO.3, AEO.4; P90SA.1, P90SA.2, P90SA.3, P90SA.4; CSEB.1, CSEB.2, CSEB.3, CSEB.4. After accelerated aging test was standardized shear bond strength ISO TR 11405, using a universal testing machine (EMIC-2000) set at 0.5 mm/minute and a load cell of 200 kgf. The results were subjected to statistical analysis of variance (ANOVA, Tukey and Scheffe). There was a statistically significant difference (p<0.01) for two factors of variation (adhesive and aging) and not for the interaction adhesive x aging (p<0.01). The adhesive Adper Single Bond 2 showed higher values of shear bond strength, whereas the P90 System Adhesive showed the lowest values of shear bond strength compared to other adhesive systems. The thermocycling regimen of 500 cycles and storage in water at 37°C for one year, followed by 500 thermal cycles showed the highest bond strength values, no statistically significant differences, as well as thermocycling of 10,000 and 30,000 cycles showed the lowest values. Based on these findings it can be concluded the adhesive system and aging affected the shear bond strength of human dentin-composite resin interface.

During the past decades there has been an increase in the use of geosynthetics in construction due to their versatility in providing a wide array of functions such as reinforcement, containment, separation, filtration and drainage. Often, geosynthetics are used in conjunction with other geosynthetics to accomplish these functions. However, geosynthetics create possible planes of weakness which can lead to failures. Textured geomembranes are widely used within landfill and mining industries due to their containment and shear strength properties, however, there are subjected to a wide array of loads and environments which are potentially hazardous, as such is of utmost importance to retain their integrity in order to avoid ecological disasters. The challenge is to understand how geomembranes resist damage, wear and which of these factors control the development of wear on textured geomembranes. Digital imaging techniques have been used in order to develop a protocol that describes the quantification of wear on textured structured geomembranes. Direct shear tests were performed to induce wear on the geomembrane textures (asperities) to analyse the wear mechanisms and study the factors that induce wear on the asperities. The research showed that normal stress and shear displacement have a major role in the development of wear on interfaces. However, the geometrical characteristics of the geomembrane asperities control the amount of wear the geomembrane can sustain without significant shear strength loss. These outcomes help to better understand the behaviour of interfaces which have as component geomembranes, leading to more robust designs. This study also proposed new asperity texture shapes by using Rapid Prototyping (RP) techniques, such as Selective Laser Sintering and Fused Filament Fabrication. Using RP techniques to create new textures for the geomembrane, could allow the creation of textures which have increased shear strength thresholds and better withstand wear, allowing for more advanced and economical designs.

The objective of this thesis is to determine the relative shear strengths of halloysite, kaolinite, synthetic mixtures, and local soils, to investigate the influence of halloysite content on the shear strength of kaolinite, and to explore the possibility that the strength properties of soil clays might be controlled by the relative content of their component minerals.

Scientists have been well aware of the complexity of Martian and lunar regoliths. There are vast unexplored areas on both, the Moon and Mars, as well as uncertainties in our understanding of the physicochemical properties of their regoliths. Lunar and Martian regoliths differ from terrestrial soils in that they appear granular, but are expected to contain some cohesion. As such, cohesion in regolith poses challenges for future space operations, more specifically for landing, settlement, and mobility purposes. The ability to induce prescribed levels of cohesion in regolith simulants and reliably measure it would allow scientists to evaluate space technology limitations under different operational scenarios on Earth prior to a mission. Therefore, the objectives of this research were to (1) develop methods to induce prescribed levels of cohesion in dry granular media, and (2) evaluate accessible and reliable testing methods to measure cohesion. We developed and evaluated several methods to induce cohesion in two types of dry sand, F-75 silica sand and generic play sand. The methods to induce cohesion included play sand mixed with sugar-water, polymeric sand, and nanocellulose fibers, as well as F-75 sand mixed with polydimethylsiloxane, polyvinyl acetate, crystalline silica, agar, zero-valent iron, adhesive spray, and sand surface modification using a plasma gun. Each method was assessed for advantages and disadvantages, and laboratory specimens produced using the most promising methods were tested at different compositions and densities to measure cohesion. The laboratory methods used to measure the cohesion included direct shear test, simple direct shear test, and vertical cut test. The results from these tests were then compared to tensile strength tests, using a split box test. In addition, these tests were also performed on lunar simulants JSC-1A and GRC-3 at different densities. The direct shear apparatus was available, but the other three devices were fabricated as part of this work. Based on the research results, simple methods to potentially induce low levels of cohesion in dry granular media are suggested along with suitability of laboratory methods to measure the added cohesion.

Approximately 80% of pharmaceutical products and the ingredients required for their manufacture are in powder form. The solid dosage form (tablets and capsules) is manufactured by either dry-blending of fine powder ingredients or combining the ingredients in a wet granulation step, followed by drying. Arching, ratholing, caking, segregation and flooding are some of the commonly encountered flow problems in the handling of fine powders. These problems lead to losses worth thousands of dollars at production scale. Poor powder flowability is a consequence of the combined effects of many variables, including improper equipment design, particle size, size distribution, shape, moisture content and surface texture. In the present work, a systematic study has been performed to determine the relationship between the flowability of fine powders and their physical properties of mean size and size distribution, density and shape.<p> Flowability studies were done on six different powders: the NutraSweet® Brand sweetener (aspartame), Respitose ML001, Alpha-D-Lactose monohydrate, the pharmaceutical binder Methocel (R) F50 Premium Hydroxypropyl methylcellulose- HPMC, a placebo pharmaceutical granulate, and common pastry flour. Scanning electron microscopy (SEM) and stereomicroscopy were used for particle shape and size analysis. Particle size distribution was determined using the laser light scattering technique. Powder flowability was measured using shear strength, angle of repose, and tapped-to-bulk density measurements. A novel method of measuring the dynamic angle of repose using electrical capacitance tomography (ECT) was developed. <p> Analysis of the images from microscopy revealed that the particles of aspartame and HPMC powders were elongated, the particles of ML001, pastry flour and lactose monohydrate powders were irregular, and the particles of placebo granulate were nearly spherical. Particle size was found to be the most reliable indicator of powder flowability, with decreasing particle size corresponding to lower flowability; however other parameters such as particle elongation and irregularity, were also found to have an influence on powder flowability. Although HPMC and pastry flour had similar particle sizes, they exhibited differences in flowability. This can be explained by the greater irregularity of the flour particles. Particle irregularity may cause mechanical interlocking between the particles, thus reducing powder flowability. ECT was found to be a promising non-intrusive tool for the measurement of the dynamic angle of repose. Unlike other methods for the measurement of dynamic angle of repose, the results obtained from ECT were not influenced by the effect of end caps. The present technique could be used by pharmaceutical industries in process analytical technology (PAT) for the detection and elimination of potential flow problems early in the manufacturing process.

Approximately 80% of pharmaceutical products and the ingredients required for their manufacture are in powder form. The solid dosage form (tablets and capsules) is manufactured by either dry-blending of fine powder ingredients or combining the ingredients in a wet granulation step, followed by drying. Arching, ratholing, caking, segregation and flooding are some of the commonly encountered flow problems in the handling of fine powders. These problems lead to losses worth thousands of dollars at production scale. Poor powder flowability is a consequence of the combined effects of many variables, including improper equipment design, particle size, size distribution, shape, moisture content and surface texture. In the present work, a systematic study has been performed to determine the relationship between the flowability of fine powders and their physical properties of mean size and size distribution, density and shape.<p> Flowability studies were done on six different powders: the NutraSweet® Brand sweetener (aspartame), Respitose ML001, Alpha-D-Lactose monohydrate, the pharmaceutical binder Methocel (R) F50 Premium Hydroxypropyl methylcellulose- HPMC, a placebo pharmaceutical granulate, and common pastry flour. Scanning electron microscopy (SEM) and stereomicroscopy were used for particle shape and size analysis. Particle size distribution was determined using the laser light scattering technique. Powder flowability was measured using shear strength, angle of repose, and tapped-to-bulk density measurements. A novel method of measuring the dynamic angle of repose using electrical capacitance tomography (ECT) was developed. <p> Analysis of the images from microscopy revealed that the particles of aspartame and HPMC powders were elongated, the particles of ML001, pastry flour and lactose monohydrate powders were irregular, and the particles of placebo granulate were nearly spherical. Particle size was found to be the most reliable indicator of powder flowability, with decreasing particle size corresponding to lower flowability; however other parameters such as particle elongation and irregularity, were also found to have an influence on powder flowability. Although HPMC and pastry flour had similar particle sizes, they exhibited differences in flowability. This can be explained by the greater irregularity of the flour particles. Particle irregularity may cause mechanical interlocking between the particles, thus reducing powder flowability. ECT was found to be a promising non-intrusive tool for the measurement of the dynamic angle of repose. Unlike other methods for the measurement of dynamic angle of repose, the results obtained from ECT were not influenced by the effect of end caps. The present technique could be used by pharmaceutical industries in process analytical technology (PAT) for the detection and elimination of potential flow problems early in the manufacturing process.

The mechanical characterization of the interfacial shear strength (IFSS) of carbon nanotube (CNT) coated carbon fibers and the interlaminar fracture toughness of woven fabric carbon fiber/epoxy composites toughened with CNT/epoxy interleave films is presented. The deposition of multiwalled carbon nanotubes (MWCNT) onto the surface of carbon fibers through thermal chemical vapor deposition (CVD) was used in an effort to produce a graded, multifunctional interphase region used to improve the interfacial strength between the matrix and the reinforcing fiber. Characterization of the IFSS was performed using the single-fiber fragmentation test. It is shown that the application of a MWCNT coating improves the interfacial shear strength between the coated fiber and matrix when compared with uncoated fibers. The effect of CNT/epoxy thin interleave films on the Mode I interlaminar fracture toughness of woven fabric carbon/epoxy composites is examined using the double-cantilever beam (DCB) test. Initiation fracture toughness, represented by critical strain energy release rate (GIC), is shown to improve over standard un-toughened composites using amine-functionalized CNT/epoxy thin films. Propagation fracture toughness is shown to remain unaffected using amine-functionalized CNT/epoxy thin films with respect to standard un-toughened composites.

A novel room temperature bonding method is used to package the micro-component. The bonding method utilizes metal microcap to package the micro-component under room temperature status, which not only can provide micro-component mechanical support also can prevent micro-component from contamination. The bonding condition under room temperature is the most conventional method can not achieve, which characteristic is the most significant effect factor to drive the wafer-level packaging process to improve in today. Utilizing ASTM standard, which was used as a macroscopic standard to evaluate and analyze the bonding shear strength relationship between the ASTM standard specimen and the metal microcap. The carrier wafer has been oxidized before photolithography process; the diameter of cavity and the contact area between the metal microcap and glass substrate were controlled by the photomask design and the accuracy of the photoresist exposure. The passivation treatment was developed to separate the microcap from the carrier wafer more easily. In this thesis, the metal microcap was fabricated by using electroforming process, which can control the thickness of metal microcap. The advantages of microcap are superior to the thin film poly-silicon made by the surface micromachining technique on the quality and mechanical properties. A glass is used as substrate of the metal microcap, and its transparent characteristic is a feature how we perform UV curing process. The adhesive can be cured under room temperature and the results exhibit the adhesive has excellent bonding strength. SEM is used to analyze the passivation result, the increasing rate of electroforming thickness. The shear stress-strain relationship between the metal microcap and the ASTM standard specimen is also discussed and analyzed in this thesis.