Metal halide perovskite semiconductors offers bright future for optoelectronic applications due to their excellent optical and electrical properties and their low-cost solution-based facile fabrication. The most of the perovskite application are based on the defective polycrystalline films and they offer inadequate moisture/thermal chemical stability. Therefore, this dissertation is dedicated to find new strategies to deploy the single-crystal perovskites to photovoltaics and new methods to reduce the moisture/thermal instability of inorganic perovskite light-emitters. In first part of this dissertation, we aimed to reveal the potential of the single crystal in photovoltaics. Single-crystal semiconductors can outperforms their polycrystalline forms in terms of photovoltaic performance due to their better structural quality and less electronic traps. However, the most efficient perovskite solar cells are based on polycrystalline films. While single crystals can perform beyond the limits of polycrystalline films, their synthesis and device integration are complex. Therefore, we aimed to create new synthetic methods to unveil the potential of the single-crystal perovskites in photovoltaics. We developed new strategies leading the perovskite single crystals to go beyond 20% power conversion efficiency in Chapter 2. Also fundamental limits of the perovskite single crystals are investigated in Chapter 3 by fabricating single crystal cells with varying thicknesses, and the electron diffusion length is calculated to be 520 μm. In Chapter 4, we propose surface modification and compositional engineering techniques to bring the perovskite single crystal photovoltaic one step beyond of the previous point by reaching 21.9% and 22.8% efficiencies, respectively. In the second part of this dissertation (Chapter 5), a novel synthetic method is offered to achieve highly stable light-emitting perovskite-related materials since the fast degradation of perovskites in the presence of water and moisture is a challenge for perovskite-based technologies and hinders the material’s potential. We demonstrated that these a direct transformation of 3D CsPbBr3 films to CsPb2Br5 exhibiting excellent stability against humidity and heat while keeping the high photoluminescence quantum yield. We believe the strategies offered in this dissertation will open an avenue in photovoltaic and light emitting applications, and can be utilized in new optoelectronic applications in future.

No description available.

No description available.

No description available.

In this research we study the effect of adding a single diffraction grating on top of a solar cell. We simulated the square diffraction grating, as well as triangular diffraction grating. The single square grating showed more favorable results, achieved 330% power improvement compared to 270% power improvement in the single triangular grating case. We simulated a triangle/triangle (top-bottom) and triangular/rectangular (top-bottom) grating cases. The Triangular grating achieved higher light absorption compared to rectangular grating. The best top grating was around 200nm grating period. We realized solar cell efficiency improvement about 42.4% for the triangular rectangular (top-bottom) grating. We studied the light transmitted power in a silicon solar cell using double diffraction triangular nano-grating. We simulated the solar cell behavior as it absorbs sunlight through its structure in various cases, results showed 270% increase of the weighted transmitted power when the top grating period (At) varies from 300nm to 800nm, and the bottom grating period (Ab) is at 500nm. We finally studied the effect of changing the location of the diffraction gratings with respect to the solar cell. We were able to increase the light efficiency by 120%. The study showed that the power absorbed by the solar cell is not sensitive to the grating location.

<p> A technology to produce low cost solar cells was transferred to a microelectronics institution. Appropriate processing equipment was obtained and modifications to the procedure were performed which would permit the manufacture of 100-200, 3 inch diameter silicon solar cells per day. </p> / Thesis / Master of Engineering (ME)

No description available.

No description available.

No description available.

No description available.