Master´s thesis deals with the utilization of lead-acid accumulators in hybrid electric vehicle regime. It describes the side effects known as PCL, generated during PSOC regime and connected with the length of the battery lifespan. One possibility how to eliminate these effects, is the use of additives in active mass of the negative electrode, in the form of glass fibres. The project provides the parametres and reactions of additive, that have lead to the improvement of battery properties. The purpose of this thesis is to verify the positive effect of the aditive on the lifespan of the lead-acid accumulator.

The main aim of this paper is to contribute to the elucidation of electrochemical processes. These processes occur in the investigated experimental lead-acid cell. For this purpose, electrochemical impedance spectroscopy was used. There are two methods of measurement presented. First one is used to measure impedance between electrodes. Second one is used to measure impedance of collector ribs inside positive or negative electrode. The results are represented by electrical equivalent circuits, whose elements are described in detail in the theoretical part.

The increasing demand for electric vehicles (EVs) has led to technological advancementsin the field of battery technology. State of charge (SOC) estimation is a vital function ofthe battery management system - the heart of EVs, and Kalman filtering is a commonmethod for SOC estimation. Due to the non uniformities in tuning and testing scenarios,quantifying performance of SOC estimation algorithms is difficult. Gathering data fordifferent operational scenarios is also cumbersome. In this thesis, SOC estimation algorithmsare developed and tested for a variety of scenarios like varying sensor noise andbias properties, varying state and parameter initializations as well as different initial celltemperatures. A validated and open-source simulation plant model is used to enable easygathering of data for different operational scenarios.The simulation results show that unscented Kalman filter performs better than extendedKalman filter in presence of hard nonlinearities and high initial uncertainties. However,both filters gave similar performance under nominal conditions implying that the choiceof estimation algorithms must depend on operational scenarios. Observability analysisalso gave valuable information to aid in selection of algorithms. The simulation plantmodel facilitated easy data collection for initial development of algorithms, which werethen tested successfully using a real dataset. Further testing using real datasets is requiredto enhance validation. / Den ¨okande efterfr°agan p°a elfordon har lett till teknologiska framsteg inom omr°adet batteriteknik.Estimering av batteriets laddningstillst°and ¨ar en essentiell funktion i batteristyrsystemet,hj¨artat i ett elfordon, och g¨ors ofta genom att till¨ampa metoden Kalmanfiltrering.P°a grund av varierande implementations och testmetodik i litteraturen ¨ar detsv°art att kvantifiera estimeringsalgoritmer. I denna avhandling utvecklas algoritmer f¨oratt estimera ett batteris laddningstillst°and. Algoritmerna testas f¨or olika former av sensorfeloch initialtillst°and, samt f¨or en rad olika temperaturer. En validerad datormodell avbatteri, sensorer och omgivning nyttjas f¨or att generera representativa data f¨or de olikaf¨orh°allandena.Simuleringsresultat visar att den s°a kallade doftl¨osa varianten av Kalmanfiltret (UKF)presterade b¨attre ¨an det utvidgade Kalmanfiltret (EKF) i fall d¨ar systembeteendet ¨ar mycketolinj¨art och d°a initialtillst°andet ¨ar os¨akert. Under normala f¨orh°allanden presterardock de b°ada algoritmerna likv¨ardigt, vilket antyder att valet av algoritm b¨or g¨oras medavseende anv¨andningsscenario. En observerbarhetsanalys av de olika filtervarianterna gavytterligare v¨ardefull information f¨or valet av algoritm. Efter utveckling av filtreringsalgoritmernai simuleringsmilj¨o utf¨ordes tester p°a faktiska m¨atdata med goda resultat. F¨or attfullst¨andig validering av algoritmerna kr¨avs emellertid mer utt¨ommande tester.

In commercial vehicles, where the driver overnights with the engine turned off whilestill consuming electricity, it is important to know how much the battery can bedischarged before reliable engine starting is at risk. The vehicle’s ability to crank theengine, i.e. startability, changes with the vehicle’s ambient temperature and thebatteries state of charge. The aim of this project is therefore to test the startability ofa commercial vehicle and its cranking system’s behaviour at different ambienttemperatures and battery state of charge. Physical startability tests were planned andperformed on a commercial vehicle at different temperatures inside a climatechamber. The results of these tests show the torque of the vehicle’s powertrainincreasing with lowering temperature while the cranking system’s performancedecreases. This decrease in the cranking system’s performance is a result of thebattery’s lowering ability to supply power at lower temperatures. / I tunga fordon, där chauffören spenderar natten med avstängd motor men fortsätteratt förbruka el, är det viktigt att veta hur mycket batterierna kan urladdas innanmotorn inte kan startas. Fordonets förmåga att starta motorn, det vill säga dessstartbarhet, ändras med omgivningstemperaturen och batteriernas laddnivå. Syftetmed projektet var därför att undersöka startbarheten på ett tungt fordon samt dessstartsystems beteende vid olika omgivningstemperaturer och laddningsnivåer påbatterierna. Under projektets gång planerades samt genomfördes provstarter meddet tunga fordonet vid olika omgivningstemperaturer i en klimatkammare.Provstarterna påvisade att släpmomentet på fordonets drivlina ökade med enfallande temperatur medan startsystemets prestanda försämrades. Startsystemetsförsämrade prestanda beror huvudsakligen på batteriernas försämrade förmåga attavge effekt vid lägre temperaturer.

Lithium-ion (Li-Ion) batteries are widely used in various applications and are viable for automotive applications. The effective management of Li-Ion batteries in battery electric vehicles (BEV) plays a crucial role in performance and range. One can achieve good performance and range by using efficient battery models in battery management systems (BMS). Hence, these battery models play an essential part in the development process of battery electric vehicles. Physics-based battery models are used for design purposes, control, or to predict battery behaviour, and these require much information about materials and reaction and mass transport properties. Model parameterization, i.e., obtaining model parameters from different experimental sets (by fitting the model to experimental data sets), can be challenging depending on model complexity and the type and quality of experimental data. Based on the idea of parameter sensitivity, certain current/voltage data sets could be chosen that theoretically has a more considerable sensitivity for a given model parameter that is of interest to extract. In this thesis work, different methods for extracting model parameters for a Nickel-Manganese-Cobalt (NMC) battery composite electrode are experimentally tested and compared. Specifically, model parameterization using \emph{optimal experiments} based on performed parameter sensitivity analysis has been benchmarked against a 1C discharge test and low rate pulse tests. The different parameter sets obtained have then been validated on a drive cycle and 2C pulse tests. Comparing the methods show some promising results for the optimal experiment design (OED) method, but consideration regarding the state of charge (SOC) dependencies, the number of parameters has to be further evaluated. / Litiumjonbatterier (Li-jon) används i olika applikationer och är ett bra alternativ förfordonsapplikationer. Den effektiva hanteringen av litiumjonbatterier i elbilar har en viktigroll för fordonens prestanda och räckvidd. Man kan nå bra prestanda och räckviddgenom att använda bra batterimodeller i batteriets övervakningssystem (BMS). Därförspelar dessa batterimodeller en viktig roll i utvecklingen av elbilar. Fysikbaseradebatterimodeller används för design, reglering eller för att prediktera beteendet hos batteriet,vilket kräver mycket information om material samt dess reaktion och andra beskaffenheter.Modellparametrisering, dvs. att införskaffa modellparametrar från olika experiment (genom attanpassa modell till experimentella data) kan vara utmanande beroende på modellkomplexitetoch typen samt kvalitén på experimentell data. Baserat på idén om parametersensitivitet kan data om ström och spänning väljas så att de teoretiskt har mer sensitivitet för engiven modellparameter som är av intresse att extrahera. I detta examensarbete testas ochjämförs olika metoder för att extrahera modellparametrar för en Nickelmangankobolt (NMC)batterielektrod. Mer specifikt, modellparametrisering genom optimala experiment baseradepå genomförd parametersesitivitetsanalys jämförts med 1C urladdningstest och låg nivåpulstest. Jämförande av metoderna visar goda resultat för OED metoden men flera parametrarmåste fortsatt utvärderas gällande laddningstatusberoenden (SOC).

Cette thèse se concentre sur la fiabilité des batteries lithium pour des applications véhicules à faible émission en CO2. Pour cela, des méthodologies de caractérisation électriques et thermiques, des protocoles et des tests de vieillissement de batteries lithium sous différents modes (cyclage actif, calendaire simple et cyclage/calendaire) ont été mis en œuvre.Une première partie de ces travaux de thèse s’attache à la modélisation et à l’estimation des états de charge et de santé de la batterie.La deuxième partie est consacrée à l’étude du vieillissement calendaire des batteries lithium utilisant la spectroscopie d’impédance comme méthode de caractérisation. Ensuite, une méthode originale pour l’évaluation de l’état santé de la batterie est proposée. Elle est basée sur l’exploitation de l’étape de charge à tension constante lors d’une recharge complète et est donc bien adaptée à une intégration au sein d’un système de gestion de batterie. L’approche introduite est validée sur des données réelles de vieillissement allant jusqu’à deux ans de test.Enfin, une étude du phénomène de régénération de la capacité suite à un vieillissement des batteries de type combiné cyclage/calendaire est menée. Cette dernière partie constitue une ouverture pour le développement de stratégies d’usage des batteries lithium en incluant leur comportement thermique. / In this thesis, we focus on the reliability of lithium batteries used for automotive applications. For this purpose, electric and thermal characterization methodologies as well as aging tests under several modes (calendar, power cycling, calendar/power cycling) are carried out.In a first part of the work, battery modeling and battery state estimation (state-of-charge and state-of-health) are considered.Then, based on periodic characterization from electrochemical impedance spectroscopy, calendar aging is investigated. Next, we proposed an original process for precise battery state-of-health determination that exploits a full recharge and mainly constant-voltage charge step which allows easily its integration within a battery management system. Our experimental results, up to two years real-life data, confirm effectiveness of our technique.Finally, we study the capacity recovery phenomenon occurring due to combined battery aging (calendar/power cycling). This final part is almost dedicated to introduce strategies for battery use presenting at the same time a thermal behavior study.

Följande studie är utförd på uppdrag av företaget Nilar som tillverkar Nickel-Metallhydridbatterier (NiMH-batterier) vid sin produktionanläggning i Gävle. Den nuvarande beräkningen av State of Charge (SoC) sker på deras Battery Management Unit (BMU) och är implementerad i Structured Text i exekveringsmiljön CODESYS. Nilar vill flytta SoC-beräkningen från BMU:n så att den kan exekveras på en Interface Control Unit (ICU). Motiveringen till detta är för att distribuera SoC-beräkningen då ett flertal ICU:er finns tillgängliga per Battery Management System (BMS) men även för att i framtiden helt byta ut CODESY. Syftet med denna studie är att migrera implementationen av SoC-algoritmen till programmeringsspråket C så att algoritmen senare kan exekveras på ICU:n. Därefter optimeras algoritmen för att sänka exekveringstiden. Studien utforskar kodstrukturella och funktionella skillnader mellan implementationerna samt metoder för att optimera SoC-algoritmen. Migreringen av algoritmen fullföljdes utan större inverkan på noggrannheten. Algoritmen optimerades genom att skapa en variant av en LU-faktorisering som var specifikt anpassad för det aktuella problemet. Optimeringen av algoritmen resulterade i en minskning på 25% av den totala exekveringstiden för algoritmen. De nya implementationerna tar markant längre tid att exekvera då batteriet befinner sig under laddning jämfört när det befinner sig under urladdning, någonting som inte kan noteras för den gamla implementationen. / The following study was carried out on the behalf of Nilar, which manufactures Nickel–metal hydride batteries at its production site in Gävle. The current State of Charge (SoC) calculation is done on their Battery Manegment Unit (BMU) and is implemented in Structured Text for the CODESYS runtime. Nilar wants to move the SoC calculation from the BMU so that its executed on a Interface Control Unit (ICU). The reasoning behind this is to distribute the SoC computation as several ICUs are available per Battery Management System (BMS) but also to remove the CODESYS dependency in the future. The purpose of this study is to migrate the implementation of the SoC-algorithm to the programming language C so that the algorithm can be executed on an ICU in the future. Furthermore this study aims to optimize the the algorithm to lower the execution time. The study explores differences in code structure and functionallity between the implementations as well as methods to optimize the SoC algorithm. The migration of the algorithm was completed without major impact on the accuracy. The algorithm was optimized by creating a variant of a LU factorization that was specifically suited to LU factorize the given problem. The optimization of the algorithm resulted in a 25% lower total execution time. The new implementations suffers from a longer total execution time when the battery is charging compared to when it’s discharging, something that’s not prevalent for the old implementation.

<p>An emerging technology in the field of transient thermal management is thermal energy storage, or TES, which enables temporary, on-demand heat rejection via storage as latent heat in a phase-change material.  Latent TES devices have enabled advances in many thermal management applications, including peak load shifting for reducing energy demand and cost of HVAC systems and providing supplemental heat rejection in transient thermal management systems.  However, the design of a transient thermal management system with integrated storage comprises many challenges which are yet to be solved.  For example, design approaches and performance metrics for determining the optimal dimensions of the TES device have only recently been studied.  Another area of active research is estimation of the internal temperature state of the device, which can be difficult to directly measure given the transient nature of the thermal storage process.  Furthermore, in contrast to the three main functions of a thermal-fluid system--heat addition, thermal transport, and heat rejection--thermal storage introduces the need for active, real-time control and automated decision making for managing the operation of the thermal storage device. </p> <p>In this thesis, I present the design process for integrating thermal energy storage into a single-phase thermal management system for rejecting transient heat loads, including design of the TES device, state estimation and control algorithm design, and validation in both simulation and experimental environments. Leveraging a reduced-order finite volume simulation model of a plate-fin TES device, I develop a design approach which involves a transient simulation-based design optimization to determine the required geometric dimensions of the device to meet transient performance objectives while maximizing power density.  The optimized TES device is integrated into a single-phase thermal-fluid testbed for experimental testing.  Using the finite volume model and feedback from thermocouples embedded in the device, I design and experimentally validate a state estimator based on the state-dependent Riccati equation approach for determining the internal temperature distribution to a high degree of accuracy.  Real-time knowledge of the internal temperature state is critical for making control decisions; to manage the operation of the TES device in the context of a transient thermal management system, I design and test, both in simulation and experimentally, a logic-based control strategy that uses fluid temperature measurements and estimates of the TES state to make real-time control decisions to meet critical thermal management objectives. Together, these advances demonstrate the potential of thermal energy storage technology as a component of thermal management systems and the feasibility of logic-based control strategies for real-time control of thermal management objectives.</p>

Redox Flow Batteries are chemical based energy storage systems that accumulate energy in liquid electrolytes. Dissolved redox active substances undergo redox reactions in an electrochemical cell and so charge and discharge a battery. Recently, the introduction of organic materials as electrolytes raised research interest. Electrolytes that operate with the bromine/bromide redox couple are interesting due to their high energy density and fast reversible kinetics. They are used in combination with several anodic chemistries (e.g. Zinc, Hydrogen, Quinone), including organic materials.Due to the corrosive and volatile nature of bromine, practical electrolytes use Bromine Complexing Agents (BCAs) in order to bind bromine in a less volatile form and deal with safety issues. These additives have a strong influence on the battery’s operation by influencing the concentration of redox active species, the cell voltage and the electrolyte conductivity. Nevertheless, very little is known about the real properties of aqueous acidic bromine electrolytes, both in pure dilution and in presence of BCAs, which influence on the electrolyte is not predictable so far. The aim of this PhD project is to provide a comprehensive understanding of the behavior of an electrolyte based on bromine and bromide, with particular reference to the one used in semi-organic flow batteries. Along this work an analysis on the performance of a AQDS-Bromine flow battery cell was executed and an extensive study on the physico-chemical behavior of the positive electrolyte was developed. A review of the flow battery technology and of the metrics and methods available for diagnostics was firstly performed as a basis to define macro characteristics,such as State of Charge (SoC) and State of Health (SoH). The cycling behavior of an AQDS-Bromine flow battery was investigated by cell tests and possible degradation mechanisms have been highlighted and explained by interpretation of electrochemical measurements. Following, a broad characterization of the bromine-based electrolyte was performed, producing extended experimental data on physico-chemical properties and a modeling framework for the prediction of the electrolyte behavior.

[pt] O planejamento da expansão da transmissão (PET) visa identificar novos reforços para a rede, permitindo uma conexão tecnicamente adequada entre demanda e geração de energia elétrica, ambas previstas para um determinado horizonte de planejamento. Um bom plano de expansão deve garantir o equilíbrio entre os custos de investimento e operação, mantendo um nível satisfatório de segurança no fornecimento de energia elétrica. Entretanto, a identificação de bons planos de expansão para o PET tem se tornado uma tarefa cada vez mais difícil. Isso se deve, principalmente, às características e dimensões dos sistemas atuais, a não linearidade e natureza combinatória do problema de otimização e às incertezas presentes nos dados. Os erros de previsão, a indisponibilidade de equipamentos e a disponibilidade dos recursos naturais são parâmetros que variam de forma aleatória e inserem um alto grau de incerteza nos sistemas elétricos, o qual aumenta proporcionalmente com o horizonte de planejamento. Uma das incertezas mais relevantes a ser gerenciada nas próximas décadas será a capacidade de geração oriunda de fontes renováveis, em particular as eólicas, devido à sua grande variabilidade. A utilização de dispositivos de armazenamento permitirá melhor aproveitamento dessas fontes e, portanto, torna-se necessário o desenvolvimento de ferramentas computacionais capazes de considerar tais dispositivos no problema PET. Esta dissertação apresenta uma nova metodologia de apoio ao problema PET inserindo armazenadores de energia elétrica para aumentar o aproveitamento de fontes renováveis no sistema. Isso, respeitando as restrições de segurança da rede, acompanhando à curva de demanda e levando em consideração as variáveis operativas destes dispositivos. A possibilidade de incluir sistemas de armazenamento de energia elétrica é avaliada através de uma análise custo-benefício. A metodologia proposta é aplicada a um sistema teste, submetido a diversas condições operativas, e os resultados obtidos são amplamente discutidos. / [en] The transmission expansion planning (TEP) aims at identifying new reinforcements for the network, allowing a technically adequate connection between demand and generation of electric energy, both foreseen for a given planning horizon. A good expansion plan must ensure a balance between investment and operating costs, while maintaining a satisfactory level of security of the electric energy supply. However, identifying good expansion plans for TEP has become an increasingly difficult task. This is mainly due to the characteristics and dimensions of the current systems, the nonlinearity and combinatorial nature of the optimization problem, and the uncertainties present in the data. Forecasting errors, equipment unavailability, and the availability of natural resources are parameters that vary in a random way and insert a high degree of uncertainty in the electrical system, which proportionally increases with the planning horizon. One of the most relevant uncertainties to be managed in the upcoming decades will be the generation capacity from renewable sources, particularly wind power, due to its great variability. Storage devices will allow better use of these sources and, therefore, it becomes necessary to develop computational tools capable of considering such devices in the TEP problem. This dissertation presents a new methodology to support the TEP problem by inserting electric energy storage to increase the use of renewable energy in the system, while respecting the security restrictions of the network, following the demand curve and taking into account the operational variables of these devices. The possibility of including electric energy storage systems is evaluated through a costbenefit analysis. The proposed methodology is applied to a test system, subject to various operating conditions, and the obtained results are widely discussed.