Masters of Science / Radon (222Rn) has been identified as an important factor that could result in a health hazard by studies all around the world. The health risks can be minimised by preventive measures where radon is highly concentrated as in some mines and homes. A study in the diffusion of the inert gas, will give us a better understanding of its possible pathways through soil into the air surrounding mine dumps where the radon releases can become hazardous. Measuring and modelling the radon concentrations in the mine dump soil, can help to deduce the radon flux to identify the problem areas for rehabilitation especially in the cases of gold and uranium mine tailings.

No description available.

As oil production increases in Alberta’s Athabasca Oil Sands Region (AOSR), optimization of tailings management processes will be integral to the successful reclamation of tailings-based environments. Syncrude Canada Ltd. has established an innovative dry-storage method for their wastes known as composite tailings (CT) that supports mine closure objectives by providing a base for terrestrial reclamation landscapes. Syncrude’s Sandhill Reclamation Fen is the first instrumented research wetland of its kind to be developed in the AOSR and it overlays a sand-capped composite tailings deposit in a retired open-pit mine site. This stratified sulfur-rich environment is highly anthropogenically altered and consists of three distinct zones: a constructed wetland, a 10m layer of sand, and 40m of CT. As oil sands tailings systems are becoming globally significant sulfur reservoirs due to their size, sulfur content, and diverse microbial communities, understanding the mechanisms behind H2S generation in novel tailings structures will help inform our understanding of sulfur-rich environments. This study is the first to characterize the sulfur biogeochemistry in each zone of the Sandhill Reclamation Fen deposit in an effort to establish the potential for microbial sulfur cycling and explore the mechanisms controlling H2S generation. Porewater ΣH2S(aq) was detected at all depths, increasing with depth from the surface of the wetland (<1.1 μM) and peaking in the sand cap (549 μM). Across all sampling trips, ΣH2S(aq) concentrations were consistently highest in the sand cap, with sampling-associated H2S gas concentrations in the wells reaching 104-180 ppm. Abundance of dissolved sulfate (0.14-6.97 mM) did not correlate to the distribution of ΣH2S, and dissolved organic carbon (21.47-127.72 mg/L) only positively correlated with the observed maxima of ΣH2S in the sand-cap. Identical sodium and chloride distributions in the sand and CT supported the model of upward migration of CT-derived porewater and fines into the sand cap. Functional metabolic enrichments established the ability of endemic microbial communities from all depths of the deposit to oxidize and reduce sulfur. Experimental microcosms demonstrated 1) the dependence of ΣH2S generation on the presence of fine particles; 2) stimulation of endemic microbial sulfur reduction through amendment with labile carbon and 3) increased generation of ΣH2S in the presence of thiosulfate over sulfate. Field and experimental results indicated that the bioaccessibility of recalcitrant organic carbon in the deposit likely controls rates of ΣH2S generation at depth. While the mechanisms relating CT-derived fines to ΣH2S in the sand cap are still unconstrained, the sand layer is clearly a bioreactive mixing-zone supporting optimal conditions for ΣH2S accumulation. These findings inform our understanding of biogeochemical sulfur cycling in novel oil sands reclamation deposits and will advise on-going optimization of tailings-based landscape management practices. / Thesis / Master of Science (MSc)

This research project investigated the high concentration of sulphate in a tailing pond at LKAB and the characteristics and behavior of sulphate minerals in different areas of the pond. The sampling of the tailings was carried out at Nine stationary sampling points. Each sample was taken from the surface to a depth of one meter except for the underflow sample which was collected from the thickener in the processing plant (fresh tailings). Stereo microscopy and SEM-EDS analysis aid in identifying mineral grains and confirming the presence of Gypsum and/or Anhydrite, along with other minerals like Pyrite, Pyrrhotite, and Chalcopyrite. The difficulty in distinguishing between Gypsum and Anhydrite under SEM was noted due to their similar crystal shapes and chemical composition. Gypsum and/or Anhydrite were identified as the main minerals responsible for the high sulphate concentration based on elemental screening, sequential extraction, and mineralogical results. Sulfide minerals like Pyrite, Chalcopyrite, and Pyrrhotite were also present but did not show any signs of weathering characteristics and therefore probably not contributed to the high sulphate concentration in the pond. The quantitative mineralogy carried out confirmed the presence of Gypsum and/or Anhydrite, Pyrite, Pyrrhotite and Chalcopyrite as identified in the mineralogical analysis. The study concludes that Gypsum and/or Anhydrite are the main contributors to the high sulphate concentration in the LKAB tailings pond.

This project aims to quantify natural gamma radiation in gold tailings disposal facilities (TDFs) relative to uranium concentration data in order to use natural gamma detection methods as alternative methods for uranium resource estimation modelling in gold tailings. Uranium migration within the New Machavie TDF was also investigated as migration affects both the grade of the TDF as a uranium resource and poses a threat to the environment. In order to determine the most appropriate radiometric testing procedure, various methods were employed for natural gamma detection, including surface natural gamma spectrometry, borehole natural gamma spectrometry and scintillometry, as well as incremental sampling. These measurements were then statistically compared to ICP-MS analyses to find the best method, and then modelled to apply volumetric resource estimation procedures. The oxidation reduction potential was also tested as uranium geochemistry is dependent on oxidation for mobilisation. Furthermore, leaching tests were employed to relate specific anions as a mode of transportation in solution. Results indicated that down-hole natural gamma spectrometry performed the best and that 2376.87 kg of uranium is present in the TDF. Migration modelling indicated that uranium is mobilised away from the oxidized top area of the TDF and that accumulation occurs in the saturated zone of the TDF under a reducing environment. Sulphate anions as the result of pyrite oxidation are primarily responsible for the mobilisation as radionuclides in New Machavie. The results of this project can be applied to the resource estimation of all uranium bearing tailings facilities prior to re-mining as a means to decrease exploration costs and to accurately model the distribution of uranium. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2014

Tailings is leftover material from mining industry and is produced in huge quantities approximately 70-99% of the ore production.  Tailings material is stored as impoundments by constructing tailings dams which are often constructed with tailings material itself. Tailings are artificial material and the mechanical behavior of tailings material upon loading is different as compared to natural soil materials. There are number of dam failures reported every year which has severe impact on inhabitants and environment nearby. Considering the failures of tailings dams and consequences there is a need to understand the tailings material in depth for safe existence of these dams. The confident dam design can assure the safe existence of tailings dams for long term as these dams are presumed to function for generations to come. The material properties in tailings dams can change during operation due to raising of new layer. Raised new layer can change stress level, which in turn may change the material properties in terms of strength, pore pressures, grain sizes etc. Today mostly tailings dam are designed by performing analysis for safety for existing and future rasings as well. These analyses are based upon a for certain factor of safety. Not very much can be done with design and analysis for tailings material if the material is not described very well. Understanding of tailings material in depth can provide help for detailed material parameters which later can be used in safety assessment for future raising and changed conditions in dam. This study presents the work carried out on tailings material from a Swedish tailings dam. The study is conducted on undisturbed and disturbed tailings material. The undisturbed tests are carried out to understand material properties as per in-situ conditions. Whereas disturbed materials are used to created different materials with different particles sizes. Initially in this study the basic properties of tailings materials are studied e.g. specific gravity, phase relationships, particle sizes, particle shapes and shear behavior on collected samples at various depths. During direct shear tests, the unexpected vertical height reductions were observed, these results are presented in this study. The comparison of strength parameters by direct shear and triaxial tests on material from various depths is also done and presented. Based on results from direct shear, triaxial and oedometer tests on uniform sized tailings material; the evaluation of primary and secondary deformations and particle breakage and effect of vertical loads is also carried out and presented. The study also includes the comparison of strength parameters for each particles size. The breakage of particles is analyzed by sieving the material after direct shear tests followed by a particle shape study. The effect of deposition on shear strength parameters is also studied by construction of samples with different angle of deposition of material. The strength parameters of uniform sized particles in triaxial tests are also evaluated and discussed.

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. Johannesburg, 2016. / Gold mining of the Witwatersrand Basin reefs has been responsible for the rise of Johannesburg as an economic centre of South Africa. While mining provided a base for business and infrastructure development for the region, it has also generated social and environmental problems for the country. Tailings storage facilities (TSFs), a common sighting around Johannesburg and across the entire basin, have been built to contain the processed waste following extraction of gold from the pyrite containing quartzite ore. When the fine grained waste is exposed to atmospheric conditions, oxidation of remnant sulphides occurs resulting in acidic, metal rich and sulphate rich plumes that enter the environment through surface and groundwater systems. This thesis sought to better understand the release, transport, dispersal and fate of metals emanating from TSFs and their remnant footprints on the Witwatersrand. These metals included aluminium, copper, chromium, iron, manganese, nickel and uranium and are known to be toxic to humans depending on their concentration and speciation. Traditionally, analytical methods have been employed in studies focussing on the characterisation of some of these processes in the region. While these studies have generally conducted quantitative assessment of the extent of pollution, little comprehensive interrogation and fingerprinting of the processes that are influential in determining the potential risk posed by metals has been done. This has largely been due to the shortcomings of analytical methods to determine these. To this end, this research has employed geochemical modelling to complement the traditional analytical methods. The approach to study the release of metals from TSFs involved assessment of the partitioning of metals within tailings and their potential release using batch and sequential extraction methods. Processes of metal release within the tailings were simulated through geochemical modelling (using the PHREEQC and Geochemist’s Workbench codes). The simulations were based on the percolation of rainwater through these layers and the changes in its chemistry along the path. The potential seepage of this plume along the path was then correlated to observed efflorescent mineral crusts that are temporary sinks for metals and are a common feature in the vicinity of the tailings and water bodies such as ponds and streams. The potential impact of the mineral crusts on the water chemistry of receiving water systems following their dissolution was assessed using forward geochemical modelling. The transport of the metals in groundwater was also studied. This involved simulations of the transition in chemistry of a plume from a TSF along an aquifer of known composition. This was based on a 1-D reactive transport model constructed using information from sequential extraction work on the aquifer rock (to identify the key minerals to consider) and site data (mainly flow rates) from previous studies. The processes occurring in the removal of metals from acid mine drainage (AMD) through a permanent sink in the form of a pump-and-treat plant in the Central Goldfield of the basin were simulated using PHREEQC. The findings from the research showed that two different plumes were produced from an abandoned TSF as a result of rainwater percolation, notably a plume produced from the dissolution of secondary salts formed in the oxidised layer and a sulphuric acid rich plume in the unoxidised layer. These differences were apparent in the geochemical composition of the mineral crusts collected on the walls of tailings dumps and from a pond into which the plumes were draining. On dissolution, mineral crusts were found to produce acidic solutions with crusts containing predominantly Fe producing pH values below 3. The simulated dissolution of various types of mineral crusts gave insight into the impact of minerals present in the smallest amount. This showed that the bulk mineralogy as determined by analytical techniques such as PXRD and remote sensing could not be used with confidence to deduce the impact of the mineral crusts on receiving water bodies. The characteristics of surface plumes released from tailings TSF were compared to other water systems in the area around Soweto, with complementary interpretation conducted using chemometric methods. From principal component analysis (PCA), surface water systems were found to form distinct groups largely influenced by mineral solubility, alkalinity and dissolved oxygen content. The 1-D reactive transport simulations involved acidic, metal and sulphate rich water ingressing the aquifer (below the TSF). Several scenarios were modelled including simulations with different dolomite contents; allowing for surface complexation and the presence of cation exchange surfaces. At a point 500 m from the water ingress in the dolomite rich aquifer, Fe and Mn were largely precipitated out (as confirmed by sequential extraction results on the aquifer rock) while the sulphate concentration was reduced by almost half. On the other hand, Ca concentrations were conservative largely because of continuous dissolution of dolomite and precipitation of gypsum along the flow path. The simulations of the high density sludge treatment plant involved forward modelling of the treatment process with the sludge responsible for the removal of trace metals from the incoming acid mine drainage. The model can be of use for cost and process optimisation at the facility. This research has had notable outputs in the form of publications; models on metal release, transport and attenuation; and models on pump-and-treat processes. These will form an important repository of information and for benchmarking any further studies related to AMD. / MT2016

No description available.

This project aims to quantify natural gamma radiation in gold tailings disposal facilities (TDFs) relative to uranium concentration data in order to use natural gamma detection methods as alternative methods for uranium resource estimation modelling in gold tailings. Uranium migration within the New Machavie TDF was also investigated as migration affects both the grade of the TDF as a uranium resource and poses a threat to the environment. In order to determine the most appropriate radiometric testing procedure, various methods were employed for natural gamma detection, including surface natural gamma spectrometry, borehole natural gamma spectrometry and scintillometry, as well as incremental sampling. These measurements were then statistically compared to ICP-MS analyses to find the best method, and then modelled to apply volumetric resource estimation procedures. The oxidation reduction potential was also tested as uranium geochemistry is dependent on oxidation for mobilisation. Furthermore, leaching tests were employed to relate specific anions as a mode of transportation in solution. Results indicated that down-hole natural gamma spectrometry performed the best and that 2376.87 kg of uranium is present in the TDF. Migration modelling indicated that uranium is mobilised away from the oxidized top area of the TDF and that accumulation occurs in the saturated zone of the TDF under a reducing environment. Sulphate anions as the result of pyrite oxidation are primarily responsible for the mobilisation as radionuclides in New Machavie. The results of this project can be applied to the resource estimation of all uranium bearing tailings facilities prior to re-mining as a means to decrease exploration costs and to accurately model the distribution of uranium. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2014

Densification of tailings slurries to mature fine tailings (MFT) is important in the oil sands industry for tailings inventory reduction, pore water recovery and tailings reclamation. The cause of methane release from the tailings pond of Shell Albian Sands (Albian) and the effects this process has on densification of Albian tailings was investigated. Citrate, added to tailings with polyacrylamide and hydrocarbon-diluent, was identified as the methanogenic substrate. Bacterial and Archaeal 16S rRNA gene sequences in Albian MFT were dominated by matches to Rhodoferax, some Clostridia and sulfate-reducing bacteria, and acetoclastic methanogens. Citrate-, diluent-, and polyacrylamide-amendments to Albian MFT did not cause a microbial shift over a 10-month laboratory incubation period. A potential pathway for microbial methane production in Albian MFT is proposed. Methane production and release from citrate-amended Albian MFT correlated to accelerated densification. Though diluent and polyacrylamide did not affect methanogenesis, they potentially affect gas bubble formation and release. / Microbiology and Biotechnology