Certain waxes when solidified in a strong electric field exhibit unusual electrical properties. Several days after formation there is a polarization in the direction of the field which seems to persist for an indefinite length of time. The surface that was in contact with the anode during formation first ass a negative charge and then obtains a positive charge, which under proper conditions is practically permanent. The surface that was in contact with the cathode first has a positive charge and then obtains a negative charge which is the permanent charge.

Masters of Science / Radon (222Rn) has been identified as an important factor that could result in a health hazard by studies all around the world. The health risks can be minimised by preventive measures where radon is highly concentrated as in some mines and homes. A study in the diffusion of the inert gas, will give us a better understanding of its possible pathways through soil into the air surrounding mine dumps where the radon releases can become hazardous. Measuring and modelling the radon concentrations in the mine dump soil, can help to deduce the radon flux to identify the problem areas for rehabilitation especially in the cases of gold and uranium mine tailings.

Este trabalho apresenta dois problemas distintos. No primeiro, obteve-se a característica da corrente em função da voltagem em um dielétrico sob radiação, supondo-se que só um portador seja móvel, que recombinação e injeção da carga móvel através de um eletrodo. Na interface eletrodo-dielétrico foi imposta a condição de densidade de carga constante. No outro problema foi feita uma generalização do problema transiente clássico estudado por Many e Rakavy, usando a mesma condição anterior de densidade de carga constante no eletrodo injetor. Obteve-se soluções analíticas durante o 1º tempo de trânsito e de desenvolveu soluções por computador até o 3º tempo de trânsito. As oscilações amortecidas da corrente em torno do valor estacionário, também merece alguma atenção / Two distinct problems are treated here. In the first one, the relation between current and voltage in a dielectric under radiation is obtained, assuming only carrier to be mobile, recombination and injection of the mobile charge from the electrode. We have chosen for this last boundary condition a constant charge density at the electrode-dielectric interface. The second problem treated is a generalization of the classic transcient problem studied by Many-Rakavy, using the constant charge density boundary condition. Analytic solutions were obtained during the first transit time and computed ones for larger times. Some attention was given to the damped current oscillations approaching the steady state value

Este trabalho apresenta dois problemas distintos. No primeiro, obteve-se a característica da corrente em função da voltagem em um dielétrico sob radiação, supondo-se que só um portador seja móvel, que recombinação e injeção da carga móvel através de um eletrodo. Na interface eletrodo-dielétrico foi imposta a condição de densidade de carga constante. No outro problema foi feita uma generalização do problema transiente clássico estudado por Many e Rakavy, usando a mesma condição anterior de densidade de carga constante no eletrodo injetor. Obteve-se soluções analíticas durante o 1º tempo de trânsito e de desenvolveu soluções por computador até o 3º tempo de trânsito. As oscilações amortecidas da corrente em torno do valor estacionário, também merece alguma atenção / Two distinct problems are treated here. In the first one, the relation between current and voltage in a dielectric under radiation is obtained, assuming only carrier to be mobile, recombination and injection of the mobile charge from the electrode. We have chosen for this last boundary condition a constant charge density at the electrode-dielectric interface. The second problem treated is a generalization of the classic transcient problem studied by Many-Rakavy, using the constant charge density boundary condition. Analytic solutions were obtained during the first transit time and computed ones for larger times. Some attention was given to the damped current oscillations approaching the steady state value

Issus de l'industrie de la microélectronique, les MEMS envahissent progressivement le marché avec des applications dans de nombreux domaines tels que l'aérospatiale, la médecine, l'industrie ou encore le grand public. Une des vocations de ces microstructures est de permettre le déploiement de réseaux de capteurs autonomes. Grâce à la miniaturisation, les systèmes deviennent de moins en moins consommateurs d'énergie et ceci permet de concevoir de nouvelles sources d'énergie basées sur la récupération de l'énergie ambiante (soleil, gradients de température,…). Il est par exemple possible de récupérer l'énergie des vibrations ambiantes à l'aide de systèmes piézoélectriques, électromagnétiques ou encore électrostatiques. Dans ce travail de thèse, nous nous concentrons sur l'étude de structures électrostatiques utilisant les électrets (diélectriques chargés électriquement). / Developed from the microelectronics industry, MEMS (Micro-Electro-Mechanical Systems) gradually invade the market with applications in many fields such as aerospace, medicine, industry or the general public. One of the purposes of these microstructures is to allow the deployment of autonomous sensor networks, that is to say a set of structures that can collect information from their environment, process, transmit and interact between them, without any human intervention. How to power these autonomous Microsystems? Use batteries… Unfortunately, the major flaw of batteries is their lifetimes, since it will be necessary to replace or to refill them after some months or some years. Actually, thanks to miniaturization, microsystems consume less and less energy, giving them the opportunity to harvest energy from their surrounding environment (sunlight, temperature gradients…). It is also possible to harvest energy directly from ambient vibration using piezoelectric, electromagnetic or electrostatic devices. In this mid-thesis work, we focus on the study of electrostatic structures using electret (electrically charged dielectrics). From the study of electrets to the fabrication and the optimization of electrostatic energy harvesters, we expose in this report, the results we obtained during this thesis.

Les matériaux actifs, tels que les matériaux piézoélectriques et électrostrictifs, sont couramment utilisés dans la conception de dispositifs exploitant leurs propriétés respectives. La propriété principale de ces matériaux réside dans le fort couplage entre les comportements électrique et mécanique (piézoélectricité). Dans la majorité des cas, ces matériaux sont utilisés séparément. L’utilisation combinée de ces matériaux permet la réalisation de dispositifs innovants basés sur l’effet électrostrictifs: l’apparition d’une polarisation électrique induite par une contrainte mécanique et réciproquement l’apparition d’une déformation mécanique sous l’action d’un champ électrique. Les applications « support » concernent les capteurs et les actionneurs. L’étude de ce couplage passe par la caractérisation de ces matériaux, puis par la mise en place de modèles décrivant finement leurs comportements et enfin par le développement d’outils pour la conception. L’objectif de la thèse est de remplacer le matériau céramique, rigide et à faible déformation, par un film polymère nanocomposite électroactifs, présentant des grandes déformations et forces d'actionnement sous champ électrique modéré grâce à l'incorporation dans la matrice polymère de micro et nano-objets (charge) conducteurs ou semi-conducteurs. De plus, pour des applications plus spécifiques de la récupération d’énergie, la charge du film polymère par des micro et nano-objets conducteurs sera également étudiée. Idéalement, il serait très intéressant de réaliser un matériau multifonctionnel, sensible à la fois à une stimulation mécanique (propriétés de détection et/ou de récupération d’énergie par couplage électromécanique). / In the last decades, direct energy conversion devices for medium and low grades waste heat have received significant attention due to the necessity to develop more energy efficient engineering systems. A great deal of research has in recent years been carried out on harvesting energy using piezoelectric, electrostatic, electromagnetic , and thermoelectric ,transduction, with the aim of harvesting enough energy to enable data transmission. For this purpose, piezoelectric elements have been extensively used in the past; however they present high rigidity and limited mechanical strain abilities as well as delicate manufacturing process for complex shapes, making them unsuitable in many applications. Thus, recent trends in both industrial and research fields have focused on electrostrictive polymers for electromechanical energy conversion. This interest is explained by many advantages such as high productivity, flexibility, and processability. Hence, electrostrictive polymer films are much more suitable for energy harvesting devices requiring high flexibilities, such as systems in smart textiles and mobile or autonomous devices. Electrostrictive polymers can also be obtained in many different shapes and over large surfaces. . In the last years, electrostrictive polymers have been investigated as electroactive materials for energy harvesting. However for scavenging energy a static field is necessary, since this material is isotope, there is no permanent polarization compare to piezoelectric material. A solution for avoid this problem; concern the hybridization of electrostrictive polymer with electret. Finally, the implementation of electrostrictive materials is much simpler for small-scale systems (MEMS). Hence, several studies have analyzed the energy conversion performance of electrostrictive polymers, both in terms of actuation and energy harvesting.

Há vários métodos descritos na literatura sobre a forma como os piezoeletretos ou ferroeletretos podem ser fabricados, sendo que cada uma dessas técnicas apresenta suas vantagens e desvantagens. Por exemplo, espumas de polipropileno (PP) são fáceis de serem processadas em grande escala aliada a um baixo custo de produção, entretanto, seu efeito piezoelétrico é dependente da temperatura, assim como não há um controle dos vazios internos durante sua fabricação, ocasionando uma heterogeneidade da geometria desses vazios. Por outro lado, em outros métodos as dimensões das cavidades podem ser controlada e polímeros termicamente mais estáveis podem ser utilizados, no entanto, a um maior custo de produção. Em relação aos métodos que visam a produção dos piezoeletretos, neste trabalho é apresentada uma nova técnica baseada em termo selagem e template de água para criar piezoeletretos com canais tubulares abertos. Este tipo de estrutura vazada foi inicialmente produzida pela laminação de filmes de etileno propileno fluorado (FEP) com o template de politetrafluoretileno (PTFE) entre eles, sendo o template descartado após a laminação, gerando resíduos. Com a substituição do template de PTFE pela água na etapa de produção dos novos piezoeletretos, foi possível eliminar o descarte de resíduos sólidos ao mesmo tempo em que um tratamento químico foi efetuado na superfície do filme. Pelo método desenvolvido, a estabilidade térmica do piezoeletreto foi melhorada sem a necessidade de um tratamento prévio ou posterior dos filmes, diminuindo assim o custo de produção. Outro método inovador para produção dos piezoeletretos também foi exposto neste trabalho. Essa inovação consiste na fabricação de piezoeletretos com cavidades controladas por meio da impressão de filmes de ABS. Para a impressão dos filmes uma impressora 3D de baixo custo foi utilizada. / There are several methods described in the literature on how piezoelectrets or ferroelectrets can be manufactured, each of these techniques present their advantages and disadvantages. For example, foamed polypropylene (PP) are easy to be processed on a large scale combined with a low cost of production, however, its piezoelectric effect is temperature dependent, and there is no control of internal voids during its manufacture, causing a heterogeneity of the geometry of these empty. Furthermore, in other methods the cavities dimensions can be controlled and more thermally stable polymers can be used, however, with a higher production cost. Regarding the methods for producing piezoelectrets, in this work we present a new technique based on hot sealing and water template for creating multi-layered piezoelectrets with open-tubular channels. This type of voided structure have been initially produced by laminating fluoroethylene-propylene (FEP) films with a polytetrafluorethylene (PTFE) template in between although the template was discarded after lamination, creating residual waste. With the replacement of the PTFE template by water in the production step of the new piezoelectrets, it was possible to eliminate the disposal of solid waste at the same time a chemical treatment was performed on the film surface. By the developed method, the piezoelectrets thermal stability was improved without the need for a prior or subsequent treatment of the films, reducing the production cost. Another innovative method for production of piezoelectrets was also exposed in this work. This innovation consists in manufacturing piezoelectrets with cavities controlled by printing ABS films. In order to print the films, a 3D printer was used.

Há vários métodos descritos na literatura sobre a forma como os piezoeletretos ou ferroeletretos podem ser fabricados, sendo que cada uma dessas técnicas apresenta suas vantagens e desvantagens. Por exemplo, espumas de polipropileno (PP) são fáceis de serem processadas em grande escala aliada a um baixo custo de produção, entretanto, seu efeito piezoelétrico é dependente da temperatura, assim como não há um controle dos vazios internos durante sua fabricação, ocasionando uma heterogeneidade da geometria desses vazios. Por outro lado, em outros métodos as dimensões das cavidades podem ser controlada e polímeros termicamente mais estáveis podem ser utilizados, no entanto, a um maior custo de produção. Em relação aos métodos que visam a produção dos piezoeletretos, neste trabalho é apresentada uma nova técnica baseada em termo selagem e template de água para criar piezoeletretos com canais tubulares abertos. Este tipo de estrutura vazada foi inicialmente produzida pela laminação de filmes de etileno propileno fluorado (FEP) com o template de politetrafluoretileno (PTFE) entre eles, sendo o template descartado após a laminação, gerando resíduos. Com a substituição do template de PTFE pela água na etapa de produção dos novos piezoeletretos, foi possível eliminar o descarte de resíduos sólidos ao mesmo tempo em que um tratamento químico foi efetuado na superfície do filme. Pelo método desenvolvido, a estabilidade térmica do piezoeletreto foi melhorada sem a necessidade de um tratamento prévio ou posterior dos filmes, diminuindo assim o custo de produção. Outro método inovador para produção dos piezoeletretos também foi exposto neste trabalho. Essa inovação consiste na fabricação de piezoeletretos com cavidades controladas por meio da impressão de filmes de ABS. Para a impressão dos filmes uma impressora 3D de baixo custo foi utilizada. / There are several methods described in the literature on how piezoelectrets or ferroelectrets can be manufactured, each of these techniques present their advantages and disadvantages. For example, foamed polypropylene (PP) are easy to be processed on a large scale combined with a low cost of production, however, its piezoelectric effect is temperature dependent, and there is no control of internal voids during its manufacture, causing a heterogeneity of the geometry of these empty. Furthermore, in other methods the cavities dimensions can be controlled and more thermally stable polymers can be used, however, with a higher production cost. Regarding the methods for producing piezoelectrets, in this work we present a new technique based on hot sealing and water template for creating multi-layered piezoelectrets with open-tubular channels. This type of voided structure have been initially produced by laminating fluoroethylene-propylene (FEP) films with a polytetrafluorethylene (PTFE) template in between although the template was discarded after lamination, creating residual waste. With the replacement of the PTFE template by water in the production step of the new piezoelectrets, it was possible to eliminate the disposal of solid waste at the same time a chemical treatment was performed on the film surface. By the developed method, the piezoelectrets thermal stability was improved without the need for a prior or subsequent treatment of the films, reducing the production cost. Another innovative method for production of piezoelectrets was also exposed in this work. This innovation consists in manufacturing piezoelectrets with cavities controlled by printing ABS films. In order to print the films, a 3D printer was used.

This research focuses on the evaluation of temporal and spatial variability associated with radon airborne measurements and the predictive utility of surrogate measures to estimate radon concentrations within the same environment as well as in other environments. This dissertation consists of three components. In Chapter II, "Evaluation of agreement of time-integrated basement residential radon measurements and correctness of further radon testing indicators", we investigated the temporal variability between short-term and annual residential radon measurements collected on the lowest livable level and identified housing/occupant factors that influenced each measurement as well as their differences. The false negative rate of how often the short-term test incorrectly indicated that further radon testing was unnecessary based on an annual measurement was 12 percent at the action level of 148 Bq m-3, but dropped to two percent at a 74 Bq m-3 reference level. The foundation wall material of the basement was the only significant factor to have an impact on the absolute difference between both measurements. This study has the potential to significantly influence public health policy concerning radon testing protocols, specifically the need to re-assess the EPA's current radon mitigation guidance level of 148 Bq m-3. In Chapter III, "Temporal and spatial variation associated with residential airborne radon measurements", we investigated the temporal and spatial variability between basement winter short-term and annual radon measurements performed in upper floors (i.e., non-basement) of the home and identified housing/occupant factors that influenced each measurement as well as their differences. This study found that individuals would be falsely overestimating their potential exposure to radon half the time at the EPA's action level of 148 Bq m-3 based on basement short-term tests and much more frequently (80 percent of the time) at a lower reference level of 74 Bq m-3. The presence of a sump was the only factor that was significantly associated with the absolute difference between both these measurements. This study has the potential to influence public health policy in regard to exposure surrogate measures, specifically to encourage testing of radon in living areas of the home and not relying solely on a screening measurement to estimate the concentration of radon in the entire home. In Chapter IV, "Comparative survey of outdoor, residential, and workplace radon concentrations", we investigated occupational radon concentrations in above ground workplaces in Missouri and compared them to above ground radon concentrations in nearby homes and outdoor locations and evaluated the utility of above ground annual home and outdoor concentrations to predict above ground radon concentrations at a nearby workplace. Employees at county agencies, schools, and businesses were recruited to participate in the study. Annual above ground workplace radon concentrations were found to be similar to annual radon concentrations in the upper floor of homes. Annual non-basement first floor home and outdoor radon concentrations were poor predictors of annual above ground radon concentrations at a nearby workplace. This study provides insights into the potential for above-ground radon exposures in the workplace and the potential agreement between workplace and residential radon concentrations.

An array of electret-biased frequency-selective resonant microelectromechanical system (MEMS) acoustic sensors was proposed to perform analysis of stress pulses created during an impact between two materials. This analysis allowed classification of the stiffness of the materials involved in the impact without applying post-impact signal processing. Arrays of resonant MEMS sensors provided filtering of the incident stress pulse and subsequent binning of time-domain waveforms into frequency-based spectra. Results indicated that different impact conditions and materials yielded different spectral characteristics. These characteristics, as well as the resulting sensor array responses, are discussed and applied to impact classification. Each individual sensor element in the array was biased by an in situ charged electret film. A microplasma discharge apparatus embedded within the microsensor allowed charging of the electret film after all device fabrication was complete. This enabled electret film integration using high-temperature surface micromachining processes that would typically lead to discharge of traditionally formed electret materials. This also eliminated the traditional wafer-bonding and post-fabrication assembly processes required in conventional electret integration approaches. The microplasma discharge process and resulting electret performance are discussed within the context of the MEMS acoustic sensor array.