Two suites of intermediate-felsic plutonic rocks were recovered by dredges RD63 and RD64 (R/V KK81-06-26) from the northern wall of the Mariana trench near Guam, which is located in the southern part of the Izu-Bonin-Mariana (IBM) island arc system. The locations of the dredges are significant as the area contains volcanic rocks (forearc basalts and boninites) that have been pivotal in explaining processes that occur when one lithospheric plate initially begins to subduct beneath another. The plutonic rocks have been classified based on petrologic and geochemical analyses, which provides insight to their origin and evolution in context of the surrounding Mariana trench. Based on whole rock geochemistry, these rocks (SiO2: 49-78 wt%) have island arc trace element signatures (Ba, Sr, Rb enrichment, Nb-Ta negative anomalies, U/Th enrichment), consistent with the adjacent IBM volcanics. Depletion of rare earth elements (REEs) relative to primitive mantle and excess Zr and Hf compared to the middle REEs indicate that the source of the plutonic rocks is similar to boninites and transitional boninites. Early IBM volcanic rocks define isotopic fields (Sr, Pb, Nd and Hf-isotopes) that represent different aspects of the subduction process (e.g., sediment influence, mantle provenance). The southern Mariana plutonic rocks overlap these fields, but show a clear distinction between RD63 and RD64. Modeling of the REEs, Zr and Hf shows that the plutonic suites formed via melting of boninite crust or by crystallization from a boninite-like magma rather than other sources that are found in the IBM system. The data presented support the hypothesis that the plutonic rocks from RD63 and RD64 are products of subduction initiation and are likely pieces of middle crust in the forearc exposed at the surface by faulting and serpentine mudvolcanoes. Their existence shows that intermediate-felsic crust may form very early in the history of an intra-oceanic island arc system. Plutonic rocks with similar formation histories may exist in obducted suprasubduction zone ophiolites and would be evidence that felsic-intermediate forearc plutonics are eventually accreted to the continents.

<p dir="ltr">To better predict volcanic behavior, we must understand the processes that occur in the underlying magma reservoirs. This thesis contains three chapters that work together to better understand processes that occur in sub-volcanic reservoirs. Chapter 2 is a study of an ancient, coupled volcanic-plutonic system to determine the link between the volcanic and plutonic parts of the system. The IXL-Job Canyon magmatic system is an ~28-29 Ma system, which shows a rapid transition between eruption of tuffs and lava flows to construction of an upper-crustal pluton, via incremental emplacement. The system experienced an eruptive hiatus during and after pluton construction, until the eruption of a newly identified, younger, rhyolitic tuff. This work suggests that the absence of volcanic activity at the surface does not mean that the underlying magmatic plumbing system is also inactive. Chapter 3 compiles existing U-Pb zircon ID-TIMS data for upper-crustal, silicic magmatic systems, to determine the size and frequency of magmatic increments that accumulate to build up these systems. A Monte Carlo-based model is used to investigate the underlying distributions of the increment size and time between increments, and results in sizes and inter-event times that follow an exponential distribution. This work helps guide how we can try to introduce broadly generalizable complexities into thermal models of such systems. Chapter 4 focuses on organic interferences, a common issue that impacts the speed and quality of U-Pb and Pb-Pb data collected on TIMS instruments. We share two techniques used at the Purdue Radiogenic Isotope Geology Lab to first reduce and then avoid any residual organic interferences. These techniques help shorten analytical times, increasing throughput, and provide a means to reduce uncertainties on our measurements, since the presence of organic interferences can bias and increase the uncertainties on U-Pb dates.</p>

This study examines the emerging notion of learning partnerships. As the study of such partnerships is a nascent research field, no single definition has yet emerged in the literature. However, within an uncertain and rapidly changing global context, two strategic initiatives have been identified which will support individuals, communities and organisations in their transition to a knowledge-based economy whilst building capacity for change and renewal. These two strategies are fostering learning communities/regions/towns and developing learning partnerships between multiple stakeholders. The term "learning partnership" has appeared in a wide variety of literatures including those of adult learning, management, social science and education. Working papers and emerging case reports identify a diversity of applications and a range of operational models or configurations that link multiple stakeholders. Learning partnerships have been associated with vocational education and training, innovation and research, lifelong learning, organisational learning and knowledge cultivation. These literatures reveal a paucity of Australian research to explain how multiple stakeholders form and develop these configurations, particularly in the Queensland context. The purpose of this study is to build deeper understanding of the meaning of a learning partnership in the Australian and (more precisely) the Queensland context. A working definition of a learning partnership, adopted as the basis for the research, indicates a strategy designed to foster continuous learning, collaboration, innovation and renewal in response to the demands of the knowledge-based economy and knowledge and learning societies. The research focuses on organisational arrangements in order for the researcher to gain deeper understanding from the key stakeholders in their work environments. Three diverse situations were selected for detailed exploration of their issues, relationships, activities, processes and working knowledge. With a view to contributing to emerging theory, an organisational case study methodology was adopted to identify and explore the nature of the relationships and issues confronting the key stakeholders in three Queensland-based learning partnerships. An interpretive theoretical framework draws on the social theory of symbolic interactionism and the "systems thinking" of General Systems Theory. An interpretivist perspective influenced the case study research strategy and guided data collection, analysis and reporting. Within the case studies, data collection methods included observations, informal meetings, synergetic focus groups, semi-structured interviews, diary notes, researcher memos and documents. From these multiple data sources, the researcher was able to assemble three case files. The inductive process for within-case analysis for the case reports, and later, cross-case analysis, integrated as a form of constant comparison technique, was used as a basis for presenting findings. These findings are reported as three separate "in progress" models to address three interrelated research questions. The case reports explain complex and interconnected organisational arrangements - evolving, adapting and responding to internal and external tensions. While there is considerable activity which could be regarded as representing learning partnerships, there is no cohesive policy framework to support such partnerships, and much ambiguity, "muddy" definitions and unclear terminology. It appears that a "new breed" of knowledge-worker is emerging - linking, networking, interacting, exchanging - to work across organisational intersections. The study shows that like "herding cats", co-ordinating and managing the inter relationships at the organisational intersection take time, resources, vision, processes for interaction, individual willingness and "in-kind" support. Whilst there is opportunity for linking disparate groups to cross-fertilise ideas, working knowledge, and information, and there is the potential to cultivate a knowledge and learning ecosystem (a fertile compost heap for knowledge generation and an innovative learning system) - "intellectual horsepower" - such configurations may also derail, realign or stagnate. It is individual stakeholders who form the relationships, interact, share ideas, and build networks, and it is the individual who maintains the relationships, engages in the process and learns from the experience. Therein lies a paradox between the strength of diversity of the collective (synergies) and their weakness as the relationships may be compromised by a single individual who withdraws or transfers. Drawing on a computing analogy, this could be akin to "corruption" in a system which may not be sufficiently robust to tolerate ambiguity, or a system that is too inflexible to survive threats while maintaining the momentum to adapt and renew. On the basis of this research it would appear that a more robust or resilient paradigm is emerging with interconnected, blurred boundaries and much "talking and thinking" about more sustainable futures. The study identifies these as indicative of wider social and economic changes. The thesis proposes three conceptual models as particularly useful in interpreting these "shifting systems and shifting paradigms": the concentric, the centripetal, and the plutonic.

Made available in DSpace on 2015-03-13T17:08:39Z (GMT). No. of bitstreams: 1 LuizGSD_ate_cap6.pdf: 3498562 bytes, checksum: 2d2d95d878c0320cd578c1fd98d02cfe (MD5) Previous issue date: 2006-08-31 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / The of Serrinha plutonic suite, northeastern portion of the Borborema Province (NE Brazil), is characterized by a voluminous and diversified magmatism of Neoproterozoic age, intrusive in the Archean to Paleoproterozoic gneissic-migmatitic basement of the S?o Jos? de Campestre massif. Field relations and petrographic and geochemical data allowed us to individualize different lithologic types among this plutonic suite, which is represented by intermediate to mafic enclaves, porphyritic diorites, porphyritic granitoids, porphyritic granodiorites, microporphyritic granites and dykes/sheets of microgranite. The intermediate-to-mafic enclaves occur associated with porphyritic granitoids, showing mixture textures. The porphyrytic diorites occur as isolated bodies, generally associated with intermediate-to-mafic enclaves and locally as enclaves within porphyritic granites. The granodiorites represent mixing between an intermediate to mafic magma with an acidic one. The micropophyritic granites occur as isolated small bodies, generally deformed, while the microgranite dykes/sheets crosscut all the previous granitoids. A U-Pb zircon age of 576 + 3 Ma was obtained for the Serrinha granite. This age is interpreted as age of the peak of the regional ductile deformational event (D3) and of the associated the E-W Rio Jacu shear zone, which control the emplacement of the Neoproterozoic syntectonic plutons. The porphyrytic granitoids show monzogranitic composition, transitional between peraluminous and metaluminous types, typically of the high potassium subalkaline-calc-alkaline series. The intermediate-to-mafic enclaves present vary from quartz diorite to tonalite/granodiorite, with metaluminous, shoshonitic affinity. The diorites are generally quartz-monzodiorite in composition, with metaluminous, subalkaline affinity. They display coarse-grained, inequigranular, porphyrytic texture, with predominance of plagioclase phenocrystals immersed in a matrix composed of biotite and pyroxenes. The microporphyrytic granites are essentially monzogranites of fine- to medium-grained texture, whereas microgranite dikes/sheets varying from monzogranites to syenogranites, with fine to media texture, equigranular. The diversified magmatism occurring at a relatively small surface associated with shear zones, suggests lithospheric dimensions for such structures, with magma extractions from different depths within the lower crust and upper mantle. The geological, geochemical and geochronological characteristics of the Serrinha plutonic suite suggest a pos-collisional geodynamic context for the Neoproterozoic magmatism. Thermobarometric data show emplacement conditions in the range 5-6 kbar (AlTamphibole) and 730-740?C (plagioclase-amphibole) for the porphyrytic granitoids (Serrinha body) and the intermediate-to-mafic enclaves / A su?te plut?nica da regi?o de Serrinha, localizada no extremo nordeste da Prov?ncia Borborema (NE do Brasil), caracteriza-se por um volumoso e diversificado magmatismo de idade neoproteroz?ica, intrusivo no substrato gn?issico-migmat?tico, de idade arqueana a paleoproteroz?ica, do Maci?o S?o Jos? de Campestre. Rela??es de campo, dados petrogr?ficos e geoqu?micos permitiram individualizar os diferentes tipos litol?gicos desta su?te plut?nica, que s?o representados por encraves intermedi?rios a m?ficos, rochas dior?ticas porfir?ticas, granit?ides porfir?ticos, granodioritos porfir?ticos, granitos microporfir?ticos e diques/sheets microgran?ticos. Os encraves intermedi?rios a m?ficos ocorrem, principalmente, associados aos granit?ides porfir?ticos, exibindo fei??es de mistura. Os dioritos porfir?ticos ocorrem como corpos isolados, associados com encraves intermedi?rios a m?ficos, e localmente como encraves nos granitos porfir?ticos. Os granodioritos representam um f?cies t?pico de mistura entre um magma intermedi?rio a m?fico, dior?tico, e outro ?cido, granitico. Os granitos microporfir?ticos apresentam-se como pequenos corpos isolados, geralmente deformados. Os diques e sheets microgran?ticos s?o tardios na seq??ncia magm?tica da ?rea estudada, com rela??es intrusivas nas demais unidades magm?ticas. Uma idada U-Pb em zirc?o de 576 + 3 Ma foi obtida para o Granito Serrinha, que ocorre controlado por uma zona de cisalhamento de dire??o geral E-W (Zona de Cisalhamento Rio Jacu). Tendo em vista o car?ter sintect?nico desse pl?ton, essa idade marca a sua coloca??o e o pico da deforma??o D3 associada. Este evento ? respons?vel pela atual arquitetura estrutural da ?rea mapeada, com gera??o da tect?nica ranscorrente/distensional impressa nas zonas de cisalhamento que controlam o alojamento dos pl?tons neoproteroz?icos. Os granit?ides porfir?ticos apresentam composi??o predominantemente monzogran?tica, apresentando caracter?sticas transicionais entre peraluminosos e metaluminosos, tipicamente de afinidade subalcalina - c?lcio-alcalina de alto K. Os encraves intermedi?rios a m?ficos variam de quartzo dioritos a tonalitos/granodioritos, com textura faner?tica fina a m?dia. S?o rochas metaluminosas de afinidade shoshon?tica. As rochas dior?ticas porfir?ticas s?o principalmente quartzo monzodioritos, com textura inequigranular porfir?tica, com predom?nio de fenocristais de plagiocl?sio imersos numa matriz composta por biotita e pirox?nios. S?o rochas metaluminosas, de afinidade subalcalina m?fica. Os granitos microporfir?ticos s?o essencialmente monzogranitos de textura fina a m?dia, inequigranular, e os diques e sheetsmicrogran?ticos apresentam composi??o variando de monzogranitos a sienogranitos, com textura fina, equigranular. Apesar da pouca quantidade de dados, essas rochas apresentam caracter?sticas de afinidade geoqu?mica com a s?rie c?lcio-alcalina de alto K. O diversificado magmatismo ocorrendo em uma superf?cie relativamente pequena, associado a zonas de cisalhamento, apontam dimens?es litosf?ricas para essas estruturas, com extra??o de magmas a partir de diferentes n?veis da crosta e do manto superior. As caracter?sticas geol?gicas, geoqu?micas e geocronol?gicas da su?te plut?nica Neoproteroz?ica da regi?o de Serrinha sugerem um contexto geodin?mico p?s-colisional para a coloca??o dos corpos estudados ao final da orog?nese Neoproteroz?ica. Dados termobarom?tricos apontam condi??es P-T da ordem de 5-6 kbar (AlT-anfib?lio) e 730-740?C (plagiocl?sio-anfib?lio) para a coloca??o dos granit?ides porfir?ticos e encraves intermedi?rios a m?ficos associados

Isolated granitic rock bodies (granites, granodiorites, quartz monzonites) in the vicinity of Benson in southeastern Arizona were studied to trace the behavior of rock weathering. Thin sections of fresh granites were examined to characterize the original mineralogy which consisted mainly of quartz, feldspars, and micas. The weathering products show up on the granites as grus and soil profiles as well as down slope in the basin deposits. X -ray diffraction studies of the < 2 micrometers fraction of the weathering products proved illite, smectite, illite-smectite mixed layer, and kaolinite to be the dominant clays; quartz and feldspar also persisted into this size fraction. Silt sized material produced similar results. The quartz monzonite of Texas Canyon afforded a special study of the initial weathering stages of feldspars and micas. In the < 2 micrometers fraction obtained from granitic material placed in an ultra sonic bath, the feldspars weathered to a Na-montmorillinite while biotite weathered to vermiculite.

Mid-ocean ridge hydrothermal systems are known to extend to deep levels of the oceanic crust, including the plutonic section, but little is known about the timing and nature of fluid-rock interactions at these levels. To investigate the temporal and spatial characteristics of hydrothermal alteration in the lower crust, this study investigates a suite of hydrothermally altered (<5 to >20% hydrous alteration) gabbroic rocks recovered from the Hess Deep Rift, where 1.2 Ma fast-spreading East Pacific Rise crust is well-exposed. These samples were altered to amphibole-dominated assemblages with chlorite-rich samples occurring in a restricted region of the field area. Hornfels, indicative of reheated, previously altered rocks, are clustered in the central part of the field area. The entire sample suite has elevated 87Sr/86Sr (mean: 0.70257±0.00007 (2σ), n=16) with respect to fresh rock (0.7024). Bulk rock 87Sr/86Sr is strongly correlated with percentage of hydrous alteration and weakly correlated with bulk rock Sr content. The distribution of Sr in igneous and metamorphic minerals suggests that greenshist-facies alteration assemblages (chlorite, actinolitic amphibole, albitic plagioclase) lose Sr to the fluid while amphibolite-facies secondary assemblages (secondary hornblende, anorthitic plagioclase) take up Sr. The temperature-dependent mobilization of Sr in hydrothermal systems has implications for the 87Sr/86Sr and ultimately fluid/rock ratio calculations based on the assessed 87Sr/86Sr systematics. Considering Sr behaviour, minimum fluid/rock ratios of ~1 were calculated for the plutonic section. Due to the large uncertainty regarding fluid Sr composition at depth and the sensitivity of fluid/rock ratio calculations on this parameter, a model combining the sheeted dike complex and the plutonic section to one hydrothermal system is introduced, yielding a fluid/rock ratio of 0.5. This value may be more realistic since the fluid composition entering and exiting the sheeted dike complex is better constrained. The regional distribution of hornfelsed material with elevated 87Sr/86Sr suggests that fluid ingress into the upper plutonics at Hess Deep occurred on-axis in a dynamic interface of a vertically migrating axial magma chamber (AMC) and the base of the hydrothermal system. / Graduate

The geological history of the Early Palaeozoic in eastern Australia is not known precisely. The eastern margin of the outcropping Precambrian Craton 'Tasman Line' is poorly understood. The Thomson Orogen, which underlies much of eastern Queensland, lies to the east of the Tasman Line. Basement to the Tasman Orogenic Zone is poorly understood, but knowledge of this basement is critical to our understanding to the processes that formed the eastern margin of the Precambrian craton. The Lolworth-Ravenswood Province lies to the east of the Tasman Line in northeast Queensland. A study of basement terranes in the Lolworth-Ravenswood Province will therefore provide some insights as to the nature of crust beneath this area, and therefore to the basement to the Thomson Orogen. The Fat Hen Creek Complex comprises para-authchthonous bodies of granitoid within middle to upper amphibolite facies metamorphic rocks. Data contained herein demonstrate that the composition and geochemistry of the granitoid are compatible with the generation of the granitoid by partial anatexis of the metamorphic rocks that are part of the Cape River Metamorphics. Temperature and pressure of anatexis is determined to be between 800-850OC and 5-9kb. Under these conditions, experimental data indicate that meta-pelite and meta-greywacke will produce between 5-10% melt coexisting with biotite, cordierite, garnet and plagioclase. The mineralogy of the granitoid bodies in the Fat Hen Creek Complex is consistent with partial anatexis of meta-greywacke at these temperatures and pressures. 5-10% melt is generally insufficient to allow efficient separation of melt and restite. The granitoids of the Fat Hen Creek Complex are interpreted as being a closed system with melt generated during high-grade metamorphism not separating from the residium. U/Pb dating of zircon from the Fat Hen Creek Complex indicate two distinct periods of zircon growth. The older episode occurred during the Late Cambrian to Early Ordovician. A second episode is dated as Middle Ordovician. This younger age coincides with the onset of regional compression, and may be related to exhumation of a mid-crustal layer during thrusting. The Lolworth Batholith is one of three granite batholiths in the Lolworth-Ravenswood Province. It comprises mainly muscovite-biotite granite, with smaller areas of hornblende-biotite granite to granodiorite. Sills and dykes of muscovite and garnet-muscovite leucogranite extensively intrude both of these types. The hornblende-biotite granite to granodiorite is metaluminous, with petrographic and geochemical characteristics similar to the adjacent Ravenswood Batholith. U-Pb SHRIMP ages also overlap with those from the Ravenswood Batholith. ENd(tc) values of ~-3 suggest a significant crustal contribution in the magma. Zircon populations determined using the SHRIMP suggest some inheritance from a Neoproterozoic source. The two-mica granites make up over 80% of the batholith and show little variation throughout. Aluminium Saturation indices range dominantly from 1-1.1, in keeping with the muscovite-bearing nature of the granites. U-Pb ages are significantly younger than the hornblende-biotite granitoids. ENd(tc) is ~-10, suggesting a greater role for crustal material in these granites than in the hornblende-bearing varieties. Previously, these granites were interpreted as S-types, mainly on the basis of the presence of muscovite. Low Na/Ca and Na greater than K are both considered as indicators of source compositions and both are characteristic of a mafic igneous rather than a meta-sedimentary source. Anatexis of mafic igneous rocks at temperatures less than~1000OC are found experimentally to produce peraluminous melts similar to those which produced the two-mica granites. The third major rock-type in the Lolworth Batholith is muscovite leucogranite, which occurs as sills and dykes intruding older granites and basement. The age of the leucogranite was not determined, but it has sharp contacts with the two-mica granite suggesting that the latter had cooled prior to intrusion of the former. The leucogranite is strongly peraluminous and is deemed to have been derived from anatexis of a supra-crustal (meta-sedimentary) source. The batholith is therefore deemed to comprise three different elements. The hornblende-biotite granitoids are the western extension of the adjacent Ravenswood Batholith. The two-mica granite and muscovite leucogranite are derived from different sources, but may be part of the same crustal anatexis event. During the Early Palaeozoic, the Lolworth-Ravenswood Province saw the intrusion of three granite batholiths into a basement of Late Neoproterozoic to Cambrian meta-sedimentary rocks. Also, Late Cambrian to Early Ordovician and Middle Ordovician high-grade metamorphism accompanied by partial anatexis is recorded at several sites across northeast Queensland. Although this metamorphism is restricted to these sites, they are widespread across the area suggestive of a widespread metamorphic event at these times. Similar metamorphism is recorded in the Arunta Inlier in Central Australia increasing the possible extent of this event. The geochemistry, isotopic characteristics and zircon populations of granites in the Lolworth-Ravenswood Province are used to characterise their source rocks; and thus the basement to the Province. Precambrian basement is indicated to underlie the entire province. However, the source rocks for the eastern part of the Province (Ravenswood and into the Lolworth Batholiths) are different to source rocks for the western part of the Province. Georgetown-type crust extends eastwards from the outcropping area, extending under the western Lolworth-Ravenswood Province. Late Mesoproterozoic rocks are recorded from the Cape River area adjacent to the Lolworth Batholith. They are also indicated as source-rocks for granites in the Ravenswood Batholith. Rocks of this age are characteristic of Grenvillian-age mobile belts in the United States. Their presence in north Qeensland has implications for the breakup of Rodinia, the Mesoproterozoic-age super continent that broke up during the Neoproterozoic.

A quartz diorite intrusion of probable early Tertiary age that crops out over at least 6 square miles in the Palo Verde Ranch area in Pinal County, Arizona was mapped as a distinct intrusion. The quartz diorite intrudes an area comprising Pinal Schist, Oracle granite, andesitic flows, granoaplite, and dike rocks including both pegmatite and diabase. Two major physical features, the Owl Head Buttes and Chief Buttes volcanic areas, both remnants of an extensive early Tertiary series of flows of intermediate composition that covered the area, now remain as lava-capped buttes above the pediment. Weak but persistent fracture-controlled copper mineralization is found in the quartz diorite and the Pinal Schist at or near their mutual contacts in the form of chrysocolla, malachite, black copper oxides, chalcocite, chalcopyrite, and bornite, in decreasing order. Pyrite is rare. Alteration related to northeast and northwest-trending fractures increases in intensity from the common propylitic to argillic to the northeast toward the San Juan claims area. A barely discernible increase in copper sulfides mirrors the alteration zoning, although geochemical sampling showed background copper in the quartz diorite to be more uniform away from fractures.

Use of Re-Os systematics in sulfides from the Bagdad porphyry Cu-Mo deposit provide information on the timing of mineralization and the source of the ore -forming elements. Analyzed samples of pyrite, chalcopyrite and molybdenite mainly from the quartz monzonite and porphyritic quartz monzonite units are characterized by a moderate to strong potassic alteration (secondary biotite and K- feldspar). Rhenium concentrations in molybdenite are between 330 and 730 ppm. Two molybdenite samples from the quartz monzonite and porphyritic quartz monzonite provide a Re-Os isotope age of 71.7 ± 0.3 Ma. A third sample from a molybdenite vein in Precambrian rocks yields an age of 75.8 ± 0.4 Ma. These molybdenite ages support previous suggestions of two mineralization episodes in the Bagdad deposit. An early event at 76 Ma and a later episode at 72 Ma. Pyrite Os and Re concentrations range between 0.008-0.016 and 3.9-6.8 ppb, respectively. Chalcopyrite contains a wide range of Os (6 to 91 ppt) and Re (1.7 to 69 ppb) concentrations and variable ¹⁸⁷Os/¹⁸⁸Os ratios that range between 0.13 to 22.27. This variability in the chalcopyrite data may be attributed to different copper sources, one of them the Proterozoic volcanic massive sulfides in the district, or to alteration and remobilization of Re and Os. Analyses from two pyrite samples yield an eight point isochron with an age of 77 ± 15 Ma and an initial ¹⁸⁷Os/¹⁸⁸Os ratio of 2.12. This pyrite Re-Os isochron age is in good agreement with the molybdenite ages. We interpret the highly radiogenic initial 1870s/188Os as an indication that the source of Os and, by inference, the ore-forming elements for the Bagdad deposit, was mainly the crust. This conclusion agrees with previous Pb and Nd isotope studies and supports the notion that a significant part of the metals and magmas have a crustal source.