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Frothers are used in flotation to aid generation of small bubbles, but little is known about the mechanisms that take place in the flotation machine to produce such an effect. Coalescence prevention is the common explanation, although the exact mechanism is obscure and almost no attention has been paid to a frother effect on bubble break-up, the other possible mechanism. This thesis presents a technique to study the effect of frothers on bubble coalescence at the generation stage (at a capillary tube) and a technique to study the effect of frothers on bubble coalescence and break-up in a turbulent field. The first technique is based on the sound bubbles emit when they form and coalesce. The sound signal was linked to bubble formation and coalescence events using high-speed cinematography. The technique has a resolution capable of detecting coalescence events that occur within 1-2 ms. The second technique allows discriminating between coalescence and break-up and is based on the exposure of a mono-size distribution of bubbles to a turbulent field generated by a three-bladed axial flow impeller. Analysis of bubble size distributions after contact with the turbulent field gives the coalescence and break-up fraction. The results show frothers reduce coalescence and alter the bubble size distribution of bubbles generated by break-up. / In the course of high-speed imaging an effect of frother on bubble shape and motion after formation was detected. Analysis of this forms the third major component of the work. A dependence of velocity on bubble aspect ratio is shown, which is in line with recent literature.

This thesis is concerned with very high energy γ-ray observations of blazars observable from the southern hemisphere. The data presented were obtained using the recently deployed University of Durham Mark 6 high sensitivity Čerenkov telescope. Chapters 1 and 2 are introductory; the subjects of γ-ray astronomy, extensive air showers, Čerenkov light production, the development of the atmospheric Čerenkov technique and the current status of TeV astronomy are discussed. Chapter 3 introduces the telescopes operated by the University of Durham. The Mark 6 telescope, designed to have a low threshold energy and a high resolution imaging system, is discussed in detail. Chapter 4 presents the calibration and analysis techniques routinely applied to data obtained with the Mark 6 telescope. The chapter concludes with a set of moment parameter selections designed to reject a significant fraction of the cosmic ray cascades, while retaining the majority of γ-rays cascades. These selections have resulted in a 5σ detection of PSR 1706-44. Chapter 5 discusses active galactic nuclei and in particular blazars. Topics included are recent high energy observations; the differences between the radio/X-ray selected BL Lacs and flat spectrum radio quasars; the infrared background; high energy flux variability and γ-ray production mechanisms within these objects. The chapter concludes with a list of possible very high energy γ-ray emitting blazars observable with the Mark 6 Čerenkov telescope. Chapter 6 presents the results from four of these very high-energy γ-ray blazar candidates; PKS 0548-322, PKS 1514-24, PKS 2005-489 and PKS 2155-304. There is no evidence for γ-ray emission from these sources, either in the form of a steady flux or variable activity. Three sigma integral flux upper limits above 300 GeV are produced for these objects and the implications of these observations are discussed. The conclusions are presented in Chapter 7 as well as ideas for future work.

The Waipara – Kowai groundwater allocation zones (referred to as zones) are located 50 kilometers north of Christchurch. Land use in the Waipara zone has evolved from dry land farming towards horticultural and irrigated pastoral farming, and as such the demand for groundwater resources has increased significantly. Recent 14C age dating has shown that deep wells tap >1000 years old water, raising concerns about possible resource mining. The Kowai groundwater allocation zone has had minimal regional hydrogeological investigations and previously little is known about the groundwater resources here. The Waipara – Kowai groundwater allocation zones are located near obliquely convergent plate margin and the Porters Pass Fault System. Recent (early Quaternary) deformation has been noted by workers along margins and associated with emerging structures within basins. These emerging faults and folds within the basin are acting as hydrological barriers, hindering the passage of groundwater within the basin. A geomorphic map was constructed for this study based on existing soils maps, limited field soil surveys and morphometric analysis. Nine geomorphic surfaces are described, with inferred ages of modern to >73 ka. The geomorphic investigation revealed that the Kowai groundwater allocation zone surface is stepped, with increasing thickness of loess up gradient on the downlands. Near the coast there is intercalated terrestrial and marine sediments, to the west overlying the Kowai Formation are small alluvial fans. In the Waipara Basin the Waipara fan dominates the central portion of the basin, with smaller fluvial and alluvial fans building out from the margins. Groundwater recharge was investigated using chemical, isotopic, water level observations and a simple water balance. It was found that in the Kowai zone the major recharge sources were the rainfall, losses from the rivers and streams. The southern region of the Waipara zone is recharged by rainfall with small contributions from the Kowai River (North Branch). In the South region of the Waipara Basin groundwater recharge is derived from rainfall and losses from streams. The groundwater systems are conceptualized as being topographically driven, with slope – basin floors interactions being an important source of groundwater recharge.

Among the many and varied fields of present day chemistry, that of optical activity occupies a not unimportant position. The rotatory powers of the alkali and ammonium salts of d-sec-βoctyl hydrogen phthalate have been studied in alcoholic and aqueous solution. The rotations of the salts were found to be in the order H > Li > NH4 > Na > K > Rb. It has been concluded that the variation of the molecular rotation of the salts with concentration may be explained by assuming changes in the degree of dissociation of the electrolytes and a deforming influence of the cations on the optically active anions. The effect of the addition of inorganic salts of various valence types to 0.2 M aqueous solutions of d-sec-β-octyl sodium phthalate has been investigated. The series for the depressive influence of the alkali and ammonium chlorides on the rotatory power of the optically active electrolyte is Cs+> Rb+> K+> Na+> NH4+> Li+. The corresponding series for the divalent chlorides is Ba++> Sr++> Ca++> Mg++. It is concluded that the observed effects may be attributed mainly to a deforming influence of the positive ion on the optically active negative ion, the explanation involving a consideration of the ionic radii. It is worthy of comment that the above results have been obtained by use of a carboxylic acid containing no hydroxyl group.

This thesis explores semi-active structural control methods for mitigating damage during seismic events. Semi-active devices offer the adaptability of active devices in conjunction with low power requirements and thus the reliability of passive devices. A number of structural applications utilising semi-active resetable devices in structural control are described and analysed. A distinguishing feature of this research is the novel design of a large-scale resetable device developed, manufactured and extensively tested. This design dramatically extends the capabilities of resetable devices by readily manipulating the device response to the structural demands and specific structural control requirements. In particular, the unique ability to use these devices to reshape or sculpt structural hysteretic behaviour offers significant new opportunities in semi-active structural control. The results indicate improvements in structural performance during seismic events is gained by approaches to structural control and enhanced damping methods that challenge conventional methods. Using an array of performance metrics the overall structural performance is examined without the typically narrow focus found in other studies. Suites of earthquake ground motion records are utilised to avoid bias to any particular type of motion and statistical analysis of the performance over these suites indicates the overall efficacy of the resetable devices in each case considered. A model that accurately captures all the device dynamics is developed, which can be used for a variety of device types and designs. In addition, the testing capabilities of structural control methods is enhanced by the development of a high speed, real-time hybrid test procedure providing a link between pure simulation and full-scale testing to increase confidence before investing in large experiments. Finally, the resetable devices are extended to improve the response force to size ratio, which additionally increases the force-displacement manipulation ability. Large-scale shake table experiments validate the findings of the analytical results. Very close correlation between analytical and experimental results including overall trends and numerical values verifies the analytical methods used and increases confidence in continuing research in this area. Furthermore, these large-scale experiments confirm the efficacy and accuracy of the the device model developed, leading to highly accurate quantitative prediction of the overall structural system response. Overall, this research presents a methodology for designing, testing and applying resetable devices in structural control. The devices developed in this research and the extensive modelling and testing dramatically extend the understanding and scope of these devices. Guidelines developed for these large-scale resetable device designs including a validated dynamic model brings the application of resetable devices closer to real structural control applications.

This thesis investigates the possibility of controlling the response of a general multi-degree of freedom structure to a relatively distant blast load using passive and semi-active devices. A relatively distant blast is one that applies significant momentum to the structure, but does not destroy the face of the structure. Three multi-storey structures, and one single-storey structure, are modelled using non-linear finite elements with structural columns discretised into multiple elements to accurately capture the effects of higher order modes that are typically excited in such blast load responses. The single-storey model structure is subjected to blast loads of varying duration, magnitude and shape, and the critical aspects of the response are investigated over a range of structural periods in the form of blast load response spectra. The optimal device arrangements are found to be those that reduce the first peak of the structural displacement and thus also reduce the subsequent free vibration of the structure. For a given blast load, various passive and semi-active devices, as well as device architectures, are investigated. The optimal device architecture was found to be one that spanned approximately two-thirds the height of the structure. Depending on what damage parameters are considered critical for a given structure, different devices and arrangements are appropriate. The main factors in choosing a semi-active device and its control architecture, or arrangement, are the tradeoffs between permanent deflection, free vibration, base shear and device capacity limitations. Overall, the results present a first analysis on the effectiveness of semi-active devices and the unique force-displacement properties they offer for mitigating non-catastrophic blast loads.