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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Exploration of Biological Treatment Systems for the Removal of Persistent Landfill Leachate Contaminants and Nanoparticles

Gomez-Rivera, Francisco January 2011 (has links)
The integrity of groundwater sources is constantly threatened by contaminant plumes generated by accidental gasoline leakages and leachates escaping landfills. These plumes are of concern due to their proven toxicity to living organisms. Aromatic and chlorinated hydrocarbons, volatile fatty acids, phenols, and ammonia have been found in these leachates. In addition, benzene, toluene, and xylenes (BTX) are major components of gasoline. The lack of oxygen in groundwater makes anaerobic bioremediation desired for the treatment of groundwater contaminated with BTX and chlorinated solvents. With the objective of finding microorganisms capable of BTX and cis-dichloroethylene (cis-DCE) degradation under anaerobic conditions for their use in permeable reactive barriers, different inocula were tested in batch experiments. Toluene was rapidly degraded by several inocula in the presence of alternative electron acceptors. Benzene and m-xylene were eliminated by few of the inocula tested after incubation periods ranging from 244 to 716 days. cis-DCE was highly recalcitrant as no degradation was observed over 440 days. Biological processes have been successfully applied for the treatment of landfill leachates as well. In an effort to provide an effective and economical alternative, an anaerobic-aerobic system was evaluated using a synthetic media simulating the organic and ammonia content of real leachates. The removal of the organic content reached 98% in an upflow anaerobic sludge blanket reactor, and resulted in the formation of methane. During the aerobic process, in an innovative down-flow sponge reactor, ammonia was highly transformed to nitrite and nitrate. Complete nitrification was eventually achieved.The capacity of current wastewater treatment plants for removing nanoparticles has been questioned during the last years. Nanoparticles have been incorporated into numerous applications and their presence in wastewater seems to be inevitable. A laboratory-scale secondary treatment system was set-in to study the behavior of cerium and aluminum oxide nanoparticles during wastewater treatment. The nanoparticles were highly removed, suggesting that secondary treatment is suitable for their elimination. The removal of these nanoparticles was influenced by the pH and organic content of the wastewater. Aluminum nanoparticles proved to be toxic; however the performance of the system for eliminating the organic content was recovered over time.
2

Innovative Biological Destruction of Hazardous Chlorinated and Brominated Volatile Disinfection By-products using Bio Trickling Filters

Mezgebe, Bineyam January 2017 (has links)
No description available.
3

Degradação anaeróbia de formaldeído em reator operado em bateladas seqüênciais contendo biomassa imobilizada / Anaerobic degradation of formaldehyde in sequencing batch reactor containing immobilized biomass

Pereira, Noemi da Silveira 27 July 2007 (has links)
Resíduos de formaldeído são descarregados de diversas formas no ambiente, resultantes de muitos processos industriais, e de seu uso como conservantes. A pesquisa por tecnologias adequadas para o tratamento de formaldeído aponta processos físico-químicos e biológicos, com atenção especial para os processos anaeróbios por constituírem sistemas compactos e de baixo consumo energético. No entanto, algumas lacunas presentes na pesquisa sobre tratamento anaeróbio de formaldeído e alguns pontos de discordância devem ser esclarecidos. Em muitos casos, esses resíduos são descartados de forma intermitente, motivando a opção por processos em batelada. Nesse contexto, o presente estudo avaliou a degradação de formaldeído em reator anaeróbio operado em bateladas seqüenciais, contendo biomassa imobilizada em espuma de poliuretano. O desempenho do reator foi monitorado para várias concentrações afluentes de formaldeído, variando de 31,6 a 1104,4 mg/L. Os resultados obtidos indicaram excelente estabilidade do reator e eficiência de remoção de formaldeído acima de 99%. Entretanto foi constatado acúmulo de matéria orgânica no efluente devido à presença de ácidos orgânicos, principalmente acético e propiônico. Essa constatação levanta um questionamento importante sobre a rota anaeróbia de degradação do formaldeído, que pode diferir substancialmente do que foi registrado na literatura. Os ácidos gerados não foram degradados pela biomassa exposta ao formaldeído, contudo poderiam ser facilmente removidos com a utilização de um reator em série com inoculo adaptado à remoção de ácidos orgânicos. / Formaldehyde residues are discharged into the environment in several different ways, as a result of several industrial processes, as well as its use as a preservative. Research for suitable technologies for treatment of formaldehyde points to physical-chemical and biological processes, with special attention to anaerobic processes, once they represent compact systems with low energy requirements. Nevertheless, some blank spaces still remaining in the research regarding anaerobic treatment of formaldehyde must be filled, and some points of disagreement must be clarified. In several cases, formaldehyde residues are discharged intermittently, favoring the choice of batch processes. In this context, the present study evaluated the degradation of formaldehyde in an anaerobic sequencing batch reactor, containing biomass immobilized in polyurethane foam matrices. Reactor performance was monitored for different influent formaldehyde concentrations, ranging from 31.6 to 1104.4 mg/L. Results obtained indicate excellent reactor stability and efficiency in formaldehyde removal above 99%. However, accumulation of organic matter was observed in the effluent, due to presence of non-degraded organic acids, especially acetic and propionic. This observation poses an important question regarding the anaerobic route of formaldehyde degradation, which might differ substantially from that reported in literature. The degradation of the generated products could occur in another reactor in serie containing biomass adapted to organic acids removal.
4

Avaliação do antagonismo do efeito do sódio sobre o tratamento de água residuária de Charqueada com elevada salinidade em reator anaeróbio de manta de lodo (UASB) / Evaluation of antagonism on the effect of sodium in wastewater treatment of \"Charqueada\" with high salinity using anaerobic sludge blanket reactor (UASB)

Olmo, Larissa Nogueira 10 June 2005 (has links)
As águas residuárias provenientes da indústria do charque são conhecidas por apresentarem elevado teor de cloreto de sódio, aliado a grandes concentrações de matéria orgânica proveniente do sangue liberado ao longo do processo industrial. Esse tipo de água residuária apresenta potencial para degradação biológica, contudo, o cloreto de sódio, em concentração elevada, pode inibir a atividade dos microrganismos e, em alguns casos, levar sistemas biológicos à falência. No presente trabalho, foi avaliada a viabilidade de degradação anaeróbia de efluente sintético de Charqueada contendo elevado teor de cloreto de sódio, em reator anaeróbio tipo UASB (Upflow Anaerobic Sludge Blanket), em escala de laboratório. Foram utilizados 4 reatores, alimentados com água residuária sintética com características similares à água residuária de Charqueada. O reator 1 foi utilizado como controle, o reator 2 recebeu NaCl e os demais (3 e 4) foram operados na presença de NaCl acrescidos de: betaína e potássio com cálcio, respectivamente. Os compostos citados são conhecidos como antagonizantes, por possuirem capacidade de minimizar o efeito inibitório do sódio sobre o processo de digestão anaeróbia. Os reatores foram inoculados com lodo de reator UASB e submetidos à concentração de 5000 mg/L de matéria orgânica, como DQO. A carga orgânica aplicada foi de 5 Kg/m3.d e os reatores não suportaram tal carga. Reiniciou-se a operação com aumento progressivo da DQO de 500 a 2000 mg/L resultando em cargas orgânicas de 0,5 a 2,0 Kg/m3.d, respectivamente. Após estabilização dos reatores, iniciou-se a fase de introdução de cloreto de sódio (1.500 a 13.500 mg/L) e antagonizantes com aumento progressivo a cada fase. Na presença ou ausência de antagonizantes, os reatores 2, 3 e 4 não tiveram o desempenho alterado até a concentração de NaCl de 6000 mg/L. Na presença de 9000 mg/L de NaCl, a betaína se mostrou pouco efetiva como soluto compatível no reator 3 e os antagonizantes do reator 4, potássio e cálcio, apresentaram efeitos estimulatórios. As morfologias encontradas ao longo do experimento foram cocos, víbrios, bacilos, sarcinas, além de morfologias semelhantes a Methanosarcina sp. e Methanosaeta sp. O aumento da concentração de cloreto de sódio provocou a redição da população de Arqueas. / Wastewaters from the charque industry (salted and dried meat) are known for their high levels of sodium chloride, allied to high organic concentrations originary from blood which is disposed along the industrial process. That kind of wastewater presents good potential for biological degradation (relationship DBO/DQO aproximately 0,5). However, the high concentration of sodium chloride can inhibit microorganisms activity and in some cases, take the biological systems to failure. The present work studied the viability of anaerobic degradation of synthetic charqueada wastewater, containing high salinity, in reactor UASB, at laboratory scale. Four reactors were used. Reactor 1 was used as control, reactor 2 received just NaCl and the two others (3 and 4) were operated in the presence of NaCl in increased with betaine and potassium with calcium, respectively. The mentioned compounds are known to be antagonists, for they possess capacity to minimize the inhibitory effect of sodium in the anaerobic digestion process. The reactors were inoculated with UASB sludge and the operation began with concentration from 5000 mg/L of organic matter, expressed as DQO. The organic load applied from 5,0 Kg/m3.d and the reactors did not support such load. The operation was restarted with progressive increase of 500 to 2000 mg/L of DQO, resulting in organic load from 0,5 to 2,0 Kg/m3.d, respectively. After reactors stabilization, the phase of introduction of NaCl (1500 to 13500 mg/L) and antagonists was started, with the progressive increase of sodium chloride and antagonists. In presence or absence of antagonists, reactors 2, 3 and 4 did not present performance alterations until the concentration of NaCl of 6000 mg/L was reached. When NaCl concentrations were from 9000 to 13500 mg/L, betaine was shown to have small effects in the reactor 3 and the antagonists of reactor 4, potassium and calcium, presented stimulant effects. The morphologies found along the experiment were: coconuts, víbrios, bacilli, sarcinas, besides morphologies similar to the Methanosarcina sp. and Methanosaeta sp. When concentrations of sodium chloride were increased the population of Arqueas were reduced.
5

Caracterização microbiana e degradação de detergente de uso doméstico em reator anaeróbio de leito fluidificado / Microbial characterization and degradation of household detergent in anaerobic fluidized bed reactor

Carosia, Mariana Fronja 25 March 2011 (has links)
A presente pesquisa teve como objetivo avaliar a remoção de alquilbenzeno sulfonado linear (LAS), presente na composição do detergente em pó doméstico e caracterizar os microrganismos do domínio Bacteria do reator anaeróbio de leito fluidificado. Para tal foi utilizado um reator anaeróbio de leito fluidificado contendo areia como material suporte contendo biofilme maduro. O reator foi operado com TDH de 15 horas. A alimentação consistiu em substrato sintético, com etanol e extrato de levedura, como co-substratos, e detergente em pó comercial. O reator foi operado em 7 etapas diferentes: (I) circuito fechado para adaptação do biofilme maduro a nova água residuária, (II) sistema aberto e a alimentação com substrato sintético, (III) acréscimo de solução redutora de sulfeto de sódio, (IV) nova imobilização e adaptação da biomassa em sistema fechado, (V) circuito aberto e variação da concentração de co-substratos na alimentação em função da estabilização e aumento da eficiência de remoção de DQO, (VI) estabilização da remoção de matéria orgânica,(VII) adição de detergente em pó comercial. Os seguintes parâmetros físico-químicos foram monitorados: pH, alcalinidade, ácidos voláteis, sulfato, sulfeto, DQO, sólidos suspensos totais e concentração de LAS afluente e efluente. Remoção de 48% de LAS foi verificada após 231 dias de operação. A presença do surfactante não alterou significativamente a remoção de DQO, cujos valores foram 87,2 ± 5,4% e 85,8 ± 4,9%, antes e depois da adição de LAS, respectivamente. Por meio do balanço de massa verificou-se que 42,4% do LAS adicionado no reator foram removidos por degradação biológica, 0,9% ficaram adsorvidos na biomassa e 4,5% adsorvido na biomassa efluente. Clones relacionados aos Filos Proteobacteria, Synergistetes e Fusobacteria foram obtidos, tanto em amostras do material suporte, quanto do separador de fases do reator, sendo que o Filo Verrucomicrobia foi obtido, somente, em amostras do copo do reator. Os filos Bacteroidetes e Firmicutes foram verificados somente em amostras da areia. / The present research intends to evaluate the removal of linear alkylbenzene sulphonate (LAS), a component present in the manufacturing of domestic detergent powder and characterize the microorganisms of Bacteria domain of the anaerobic fluidized bed reactor. In this case, an anaerobic fluidized bed reactor was employed, with sand containing mature biofilm as support material. The reactor was operated with a 15 hour HRT. Feeding consisted of synthetic substrate and commercial detergent powder, with ethanol and yeast extract as co-substrates. The reactor was operated in 7 different steps: (I) the circuit was kept closed for adaptation of mature biofilm to the new wastewater, (II) the system was opened and food was provided, consisting only of synthetic substrate, (III) a reducing solution of sodium sulfide was added, (IV) the system was closed for new immobilization and biomass adaptation, (V) the circuit was opened and the concentration of co-substrates of food was altered according to the stabilization and the increase of COD removal efficiency, (VI) there was stabilization of organic matter removal, (VII) commercial detergent powder was added. The following physicochemical parameters were monitored: pH, alkalinity, volatile acids, sulphate, sulphide, COD, total suspended solids and LAS concentration. The removal of 48% of LAS was observed after 231 days of operation. The presence of surfactant did not significantly affect COD removal: its values before and after LAS addition were 87.2 ± 5.4% and 85.8 ± 4.9%, respectively. The mass balance showed that 42.4% of the LAS added to the reactor was removed by biological degradation, 0.9% was adsorbed in the biomass and 4.5% was adsorbed in the effluent biomass. Clones belonging to the Phyla Proteobacteria, Synergistetes and Fusobacteria were obtained, both in the samples in the support material and in the samples in the reactor phases separator. Phylum Verrucomicrobia was found only in samples in the reactor phases separator. Phyla Bacteroidetes and Firmicutes were found only in samples of sand.
6

Atividade metanogênica e comunidade microbiana envolvidas na degradação de metilamina / Methanogenic activity and microbial community involved in the degradation of methylamine

Vich, Daniele Vital 25 August 2006 (has links)
A metilamina ('CH IND.3'NH IND.2') é um composto orgânico usado na produção de inseticidas, herbicidas, fungicidas, surfactantes, combustíveis fósseis, explosivos, produtos farmacêuticos, químicos fotográficos, tintas, tecidos, solventes, borrachas e anti-corrosivos. Estudos sobre tratamento de águas residuárias contendo metilamina são escassos e se restringem aos trabalhos envolvendo pesticidas carbamatados. Visando contribuir com os estudos acerca da degradação anaeróbia da metilamina, esta pesquisa estudou a comunidade microbiana e a atividade metanogênica específica em reatores anaeróbios em batelada, inoculados com lodo granular oriundo de reator UASB usado no tratamento de água residuária de abatedouro de aves, sob diferentes condições nutricionais: controle – sem metilamina, 5 mM, 10 mM, 20 mM, 30 mM, 50 mM, 75 mM e 90 mM de metilamina. Os reatores foram incubados sob temperatura de 30°C e agitação de 150 rpm. Desses reatores foram obtidas amostras para a determinação da atividade metanogênica específica (AME), sólidos suspensos voláteis (SVT), nitrogênio amoniacal e exames microscópicos. Ao final do experimento, foram realizados exames da biomassa por meio da técnica do número mais provável (NMP) e análise da diversidade microbiana por PCR/DGGE e seqüenciamento. O aumento da AME foi proporcional ao aumento das concentrações de metilamina, com inibição de produção de metano apenas nos reatores alimentados com 90 mM de metilamina. Os reatores alimentados com 50 mM e 75 mM de metilamina apresentaram os melhores resultados, com valores médios de AME de 0,0804 mmol 'CH IND.4'/g SVT.h e 0,0825 mmol 'CH IND.4'/g SVT.h respectivamente. Nos exames microscópicos foi verificado semelhança de morfologias microbianas em todas as concentrações de metilamina estudadas. Os organismos presentes nos reatores foram Methanosarcina sp., Methanosaeta sp., bacilos, coco-bacilos, filamentos e cocos. Em relação à análise de DGGE, não houve variação significativa nos padrões de bandas, tanto para o domínio Archaea quanto para o domínio Bacteria. Com os resultados da técnica de número mais provável (NMP) observou-se a predominância de arquéias metanogênicas dentre as bactérias anaeróbias totais. / The methylamine ('CH IND.3'NH IND.2') is an organic compound used in the production of insecticides, herbicides, fungicides, surfactants, fossil fuels, explosives, pharmaceuticals, photographic chemicals, paints, textiles, dyes, rubber and anticorrosive chemicals. Some studies about the treatment of wastewater containing methylamine are scarce and limited to works involving carbamate pesticides. This research aimed to study the anaerobic degradation of methylamine, the microbial community and the specific methanogenic activity in anaerobic battled reactors. The reactors were inoculated with granular sludge from a UASB reactor treating poultry wastes. Different nutritional conditions were adopted in the operation of the reactors: control (without methylamine), 5 mM, 10 mM, 20 mM, 30 mM, 50 mM, 75 mM and 90 mM of methylamine. The reactors were incubated under standard conditions: 30ºC and 150 rpm. Samples had been removed from the reactors to determine the specific methanogenic activity, the concentration of volatile suspended solids and ammoniacal nitrogen and the microscopic analysis. At the end of the experiment, the biomass was studied by the most probable number (MPN) technique and by the microbial diversity analysis with PCR and DGGE techniques. The increase of the specific methanogenic activity was proportional to the increase of methylamine concentration. The methane production was inhibited only in the reactor that was fed with 90 mM of methylamine. The reactors that were fed with 50 mM and 75 mM of methylamine showed the best results, with medium values of specific methanogenic activity equal to 0,0804 mmol 'CH IND.4'/g SVT.h and 0,0825 mmol 'CH IND.4'/g SVT.h, respectively. The microscopic analysis showed similarity between the microbial morphologies in all of the reactors. The observed microorganisms were Methanosarcina sp., Methanosaeta sp., rods, cocci and filaments. The DGGE analysis did not show significant variation in the standard profile of the Archaea and Bacteria domains. The results of the MPN technique revealed the predominance of the methanogenic archaea among the total anaerobic bacteria.
7

Formulation and Biodegradation Relationships in Thermoplastic Starch Blends

Melissa Russo Unknown Date (has links)
No description available.
8

Caracterização microbiana e degradação de detergente de uso doméstico em reator anaeróbio de leito fluidificado / Microbial characterization and degradation of household detergent in anaerobic fluidized bed reactor

Mariana Fronja Carosia 25 March 2011 (has links)
A presente pesquisa teve como objetivo avaliar a remoção de alquilbenzeno sulfonado linear (LAS), presente na composição do detergente em pó doméstico e caracterizar os microrganismos do domínio Bacteria do reator anaeróbio de leito fluidificado. Para tal foi utilizado um reator anaeróbio de leito fluidificado contendo areia como material suporte contendo biofilme maduro. O reator foi operado com TDH de 15 horas. A alimentação consistiu em substrato sintético, com etanol e extrato de levedura, como co-substratos, e detergente em pó comercial. O reator foi operado em 7 etapas diferentes: (I) circuito fechado para adaptação do biofilme maduro a nova água residuária, (II) sistema aberto e a alimentação com substrato sintético, (III) acréscimo de solução redutora de sulfeto de sódio, (IV) nova imobilização e adaptação da biomassa em sistema fechado, (V) circuito aberto e variação da concentração de co-substratos na alimentação em função da estabilização e aumento da eficiência de remoção de DQO, (VI) estabilização da remoção de matéria orgânica,(VII) adição de detergente em pó comercial. Os seguintes parâmetros físico-químicos foram monitorados: pH, alcalinidade, ácidos voláteis, sulfato, sulfeto, DQO, sólidos suspensos totais e concentração de LAS afluente e efluente. Remoção de 48% de LAS foi verificada após 231 dias de operação. A presença do surfactante não alterou significativamente a remoção de DQO, cujos valores foram 87,2 ± 5,4% e 85,8 ± 4,9%, antes e depois da adição de LAS, respectivamente. Por meio do balanço de massa verificou-se que 42,4% do LAS adicionado no reator foram removidos por degradação biológica, 0,9% ficaram adsorvidos na biomassa e 4,5% adsorvido na biomassa efluente. Clones relacionados aos Filos Proteobacteria, Synergistetes e Fusobacteria foram obtidos, tanto em amostras do material suporte, quanto do separador de fases do reator, sendo que o Filo Verrucomicrobia foi obtido, somente, em amostras do copo do reator. Os filos Bacteroidetes e Firmicutes foram verificados somente em amostras da areia. / The present research intends to evaluate the removal of linear alkylbenzene sulphonate (LAS), a component present in the manufacturing of domestic detergent powder and characterize the microorganisms of Bacteria domain of the anaerobic fluidized bed reactor. In this case, an anaerobic fluidized bed reactor was employed, with sand containing mature biofilm as support material. The reactor was operated with a 15 hour HRT. Feeding consisted of synthetic substrate and commercial detergent powder, with ethanol and yeast extract as co-substrates. The reactor was operated in 7 different steps: (I) the circuit was kept closed for adaptation of mature biofilm to the new wastewater, (II) the system was opened and food was provided, consisting only of synthetic substrate, (III) a reducing solution of sodium sulfide was added, (IV) the system was closed for new immobilization and biomass adaptation, (V) the circuit was opened and the concentration of co-substrates of food was altered according to the stabilization and the increase of COD removal efficiency, (VI) there was stabilization of organic matter removal, (VII) commercial detergent powder was added. The following physicochemical parameters were monitored: pH, alkalinity, volatile acids, sulphate, sulphide, COD, total suspended solids and LAS concentration. The removal of 48% of LAS was observed after 231 days of operation. The presence of surfactant did not significantly affect COD removal: its values before and after LAS addition were 87.2 ± 5.4% and 85.8 ± 4.9%, respectively. The mass balance showed that 42.4% of the LAS added to the reactor was removed by biological degradation, 0.9% was adsorbed in the biomass and 4.5% was adsorbed in the effluent biomass. Clones belonging to the Phyla Proteobacteria, Synergistetes and Fusobacteria were obtained, both in the samples in the support material and in the samples in the reactor phases separator. Phylum Verrucomicrobia was found only in samples in the reactor phases separator. Phyla Bacteroidetes and Firmicutes were found only in samples of sand.
9

Atividade metanogênica e comunidade microbiana envolvidas na degradação de metilamina / Methanogenic activity and microbial community involved in the degradation of methylamine

Daniele Vital Vich 25 August 2006 (has links)
A metilamina ('CH IND.3'NH IND.2') é um composto orgânico usado na produção de inseticidas, herbicidas, fungicidas, surfactantes, combustíveis fósseis, explosivos, produtos farmacêuticos, químicos fotográficos, tintas, tecidos, solventes, borrachas e anti-corrosivos. Estudos sobre tratamento de águas residuárias contendo metilamina são escassos e se restringem aos trabalhos envolvendo pesticidas carbamatados. Visando contribuir com os estudos acerca da degradação anaeróbia da metilamina, esta pesquisa estudou a comunidade microbiana e a atividade metanogênica específica em reatores anaeróbios em batelada, inoculados com lodo granular oriundo de reator UASB usado no tratamento de água residuária de abatedouro de aves, sob diferentes condições nutricionais: controle – sem metilamina, 5 mM, 10 mM, 20 mM, 30 mM, 50 mM, 75 mM e 90 mM de metilamina. Os reatores foram incubados sob temperatura de 30°C e agitação de 150 rpm. Desses reatores foram obtidas amostras para a determinação da atividade metanogênica específica (AME), sólidos suspensos voláteis (SVT), nitrogênio amoniacal e exames microscópicos. Ao final do experimento, foram realizados exames da biomassa por meio da técnica do número mais provável (NMP) e análise da diversidade microbiana por PCR/DGGE e seqüenciamento. O aumento da AME foi proporcional ao aumento das concentrações de metilamina, com inibição de produção de metano apenas nos reatores alimentados com 90 mM de metilamina. Os reatores alimentados com 50 mM e 75 mM de metilamina apresentaram os melhores resultados, com valores médios de AME de 0,0804 mmol 'CH IND.4'/g SVT.h e 0,0825 mmol 'CH IND.4'/g SVT.h respectivamente. Nos exames microscópicos foi verificado semelhança de morfologias microbianas em todas as concentrações de metilamina estudadas. Os organismos presentes nos reatores foram Methanosarcina sp., Methanosaeta sp., bacilos, coco-bacilos, filamentos e cocos. Em relação à análise de DGGE, não houve variação significativa nos padrões de bandas, tanto para o domínio Archaea quanto para o domínio Bacteria. Com os resultados da técnica de número mais provável (NMP) observou-se a predominância de arquéias metanogênicas dentre as bactérias anaeróbias totais. / The methylamine ('CH IND.3'NH IND.2') is an organic compound used in the production of insecticides, herbicides, fungicides, surfactants, fossil fuels, explosives, pharmaceuticals, photographic chemicals, paints, textiles, dyes, rubber and anticorrosive chemicals. Some studies about the treatment of wastewater containing methylamine are scarce and limited to works involving carbamate pesticides. This research aimed to study the anaerobic degradation of methylamine, the microbial community and the specific methanogenic activity in anaerobic battled reactors. The reactors were inoculated with granular sludge from a UASB reactor treating poultry wastes. Different nutritional conditions were adopted in the operation of the reactors: control (without methylamine), 5 mM, 10 mM, 20 mM, 30 mM, 50 mM, 75 mM and 90 mM of methylamine. The reactors were incubated under standard conditions: 30ºC and 150 rpm. Samples had been removed from the reactors to determine the specific methanogenic activity, the concentration of volatile suspended solids and ammoniacal nitrogen and the microscopic analysis. At the end of the experiment, the biomass was studied by the most probable number (MPN) technique and by the microbial diversity analysis with PCR and DGGE techniques. The increase of the specific methanogenic activity was proportional to the increase of methylamine concentration. The methane production was inhibited only in the reactor that was fed with 90 mM of methylamine. The reactors that were fed with 50 mM and 75 mM of methylamine showed the best results, with medium values of specific methanogenic activity equal to 0,0804 mmol 'CH IND.4'/g SVT.h and 0,0825 mmol 'CH IND.4'/g SVT.h, respectively. The microscopic analysis showed similarity between the microbial morphologies in all of the reactors. The observed microorganisms were Methanosarcina sp., Methanosaeta sp., rods, cocci and filaments. The DGGE analysis did not show significant variation in the standard profile of the Archaea and Bacteria domains. The results of the MPN technique revealed the predominance of the methanogenic archaea among the total anaerobic bacteria.
10

Degradação anaeróbia de formaldeído em reator operado em bateladas seqüênciais contendo biomassa imobilizada / Anaerobic degradation of formaldehyde in sequencing batch reactor containing immobilized biomass

Noemi da Silveira Pereira 27 July 2007 (has links)
Resíduos de formaldeído são descarregados de diversas formas no ambiente, resultantes de muitos processos industriais, e de seu uso como conservantes. A pesquisa por tecnologias adequadas para o tratamento de formaldeído aponta processos físico-químicos e biológicos, com atenção especial para os processos anaeróbios por constituírem sistemas compactos e de baixo consumo energético. No entanto, algumas lacunas presentes na pesquisa sobre tratamento anaeróbio de formaldeído e alguns pontos de discordância devem ser esclarecidos. Em muitos casos, esses resíduos são descartados de forma intermitente, motivando a opção por processos em batelada. Nesse contexto, o presente estudo avaliou a degradação de formaldeído em reator anaeróbio operado em bateladas seqüenciais, contendo biomassa imobilizada em espuma de poliuretano. O desempenho do reator foi monitorado para várias concentrações afluentes de formaldeído, variando de 31,6 a 1104,4 mg/L. Os resultados obtidos indicaram excelente estabilidade do reator e eficiência de remoção de formaldeído acima de 99%. Entretanto foi constatado acúmulo de matéria orgânica no efluente devido à presença de ácidos orgânicos, principalmente acético e propiônico. Essa constatação levanta um questionamento importante sobre a rota anaeróbia de degradação do formaldeído, que pode diferir substancialmente do que foi registrado na literatura. Os ácidos gerados não foram degradados pela biomassa exposta ao formaldeído, contudo poderiam ser facilmente removidos com a utilização de um reator em série com inoculo adaptado à remoção de ácidos orgânicos. / Formaldehyde residues are discharged into the environment in several different ways, as a result of several industrial processes, as well as its use as a preservative. Research for suitable technologies for treatment of formaldehyde points to physical-chemical and biological processes, with special attention to anaerobic processes, once they represent compact systems with low energy requirements. Nevertheless, some blank spaces still remaining in the research regarding anaerobic treatment of formaldehyde must be filled, and some points of disagreement must be clarified. In several cases, formaldehyde residues are discharged intermittently, favoring the choice of batch processes. In this context, the present study evaluated the degradation of formaldehyde in an anaerobic sequencing batch reactor, containing biomass immobilized in polyurethane foam matrices. Reactor performance was monitored for different influent formaldehyde concentrations, ranging from 31.6 to 1104.4 mg/L. Results obtained indicate excellent reactor stability and efficiency in formaldehyde removal above 99%. However, accumulation of organic matter was observed in the effluent, due to presence of non-degraded organic acids, especially acetic and propionic. This observation poses an important question regarding the anaerobic route of formaldehyde degradation, which might differ substantially from that reported in literature. The degradation of the generated products could occur in another reactor in serie containing biomass adapted to organic acids removal.

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