The integrity of groundwater sources is constantly threatened by contaminant plumes generated by accidental gasoline leakages and leachates escaping landfills. These plumes are of concern due to their proven toxicity to living organisms. Aromatic and chlorinated hydrocarbons, volatile fatty acids, phenols, and ammonia have been found in these leachates. In addition, benzene, toluene, and xylenes (BTX) are major components of gasoline. The lack of oxygen in groundwater makes anaerobic bioremediation desired for the treatment of groundwater contaminated with BTX and chlorinated solvents. With the objective of finding microorganisms capable of BTX and cis-dichloroethylene (cis-DCE) degradation under anaerobic conditions for their use in permeable reactive barriers, different inocula were tested in batch experiments. Toluene was rapidly degraded by several inocula in the presence of alternative electron acceptors. Benzene and m-xylene were eliminated by few of the inocula tested after incubation periods ranging from 244 to 716 days. cis-DCE was highly recalcitrant as no degradation was observed over 440 days. Biological processes have been successfully applied for the treatment of landfill leachates as well. In an effort to provide an effective and economical alternative, an anaerobic-aerobic system was evaluated using a synthetic media simulating the organic and ammonia content of real leachates. The removal of the organic content reached 98% in an upflow anaerobic sludge blanket reactor, and resulted in the formation of methane. During the aerobic process, in an innovative down-flow sponge reactor, ammonia was highly transformed to nitrite and nitrate. Complete nitrification was eventually achieved.The capacity of current wastewater treatment plants for removing nanoparticles has been questioned during the last years. Nanoparticles have been incorporated into numerous applications and their presence in wastewater seems to be inevitable. A laboratory-scale secondary treatment system was set-in to study the behavior of cerium and aluminum oxide nanoparticles during wastewater treatment. The nanoparticles were highly removed, suggesting that secondary treatment is suitable for their elimination. The removal of these nanoparticles was influenced by the pH and organic content of the wastewater. Aluminum nanoparticles proved to be toxic; however the performance of the system for eliminating the organic content was recovered over time.

The main contents of campus sewage are BOD and inorganic nutrients. Conventional secondary treatment processes can remove BOD efficiently, whereas the inorganic nutrients remain mostly left. Therefore, the effluents may cause eutrophication to the receiving water bodies. Using constructed wetland treatment system to reduce nutrients become more and more popular recently. Vertical flow type subsurface process is particularly efficient in nitrogen transformations. In this research we studied the nitrogen transformation dynamics by using different types vertical flow constructed wetland system with various natural materials as the media to treat the secondary effluents from a campus sewage treatment plant. Six self designed experiment columns with broken concrete blocks, oyster shells, different sizes of marble granules, and river sands were used for this study as vertical flow constructed wetland systems. The methods of operation included batch type, continuous flow with filled water and trickling filter type, which were tested by controlling the influent flows into those six test columns. The efficiencies of various combinations in treatments and their mechanisms were discussed in the study. The experimental results showed that the best ammonium nitrogen removal efficiency was measured equal to 46.6% in batch type operations, while the continuous flow with filled water type operation showed the best performance by using concrete blocks as the media (42.8%). However, the best ammonium nitrogen removal rate in the trickling operation was found in the column with media of 3 mm marble granules (91.1%). The medium of river sand obtained the best phosphorous removal rate by using a batch flow operation. Vegetating presented only minor contributions in the column with medium of smaller grain size materials. The optimum C/N ratios for denitification tests are 3.5 and 3 by using the media of concrete and oyster, respectively.

The aim of this Master Thesis was to calculate and visualize performance indicators for the secondary treatment step in municipal wastewater treatment plants. Performance indicators are a valuable tool to communicate process conditions and energy efficiency to both management teams and operators of the plant. Performance indicators should be as few as possible, clearly defined, easily measurable, verifiable and easy to understand. Performance indicators have been calculated based on data from existing wastewater treatment plants and qualified estimates when insufficient data was available. These performance indicators were then evaluated and narrowed down to a few key indicators, related to process performance and energy usage. Performance indicators for the secondary treatment step were calculated for four municipal wastewater treatment plants operating three different process configurations of the activated-sludge technology; Sternö wastewater treatment plant (Sweden) using a conventional activated-sludge technology, Ronneby wastewater treatment plant (Sweden) using a ring-shaped activated-sludge technology called oxidation ditch, Headingley wastewater treatment plant (Canada) and Kimmswick wastewater treatment plant (USA), both of which use sequencing batch reactor (SBR) activated-sludge technology. Literature reviews, interviews and process data formed the basis of the Master Thesis. The secondary treatment was studied in all the wastewater treatment plants. Performance indicators were calculated, to the extent it was possible, for this step in the treatment process. The results showed that all the wastewater treatments plants, studied in this master thesis, were well below regulatory requirements of effluent concentrations of organic matter and nutrients. This gap between legislated requirements and performance provides an opportunity for improving energy efficiency and maintaining discharge requirements. The removal of organic matter was consistently high at all wastewater treatment plants studied but the removal of nitrogen was slightly lower during the colder months. The results further showed that the discharge of nitrogen from wastewater treatment plants is the largest stress on the recipient. Data regarding the energy usage was almost nonexistent and energy for aeration was therefore calculated when possible since it is aeration that accounts for the largest fraction of energy usage in a wastewater treatment plant. Sternö wastewater-treatment plant proved to be more energy efficient than Rustorp wastewater treatment plant.

abstract: The application of microalgal biofilms in wastewater treatment has great advantages such as abolishing the need for energy intensive aerators and recovering nutrients as energy, thus reducing the energy requirement of wastewater treatment several-fold. A 162 cm2 algal biofilm reactor with good wastewater treatment performance and a regular harvesting procedure was studied at lab scale to gain an understanding of effectual parameters such as hydraulic retention time (HRT; 2.6 and 1.3 hrs), liquid level (LL; 0.5 and 1.0 cm), and solids retention time (SRT; 3 and 1.5 wks). A revised synthetic wastewater “Syntho 3.7” was used as a surrogate of domestic primary effluent for nutrient concentration consistency in the feed lines. In the base case (2.6 hr HRT, 0.5 cm LL, and 3 wk SRT), percent removals of 69 ± 2 for total nitrogen (TN), 54 ± 21 for total phosphorous (TP), and 60 ± 7 for chemical oxygen demand (COD) were achieved and 4.0 ± 1.6 g/m2/d dry biomass was produced. A diffusion limitation was encountered when increasing the liquid level, while the potential to further decrease the HRT remains. Nonlinear growth kinetics was observed in comparing SRT variations, and promoting autotrophic growth seems possible. Future work will look towards producing a mathematical model and further testing the aptness of this system for large-scale implementation. / Dissertation/Thesis / Masters Thesis Chemical Engineering 2016

The Mid-Neolithic site of Ajvide on the Baltic Island of Gotland comprises the burials of 89 individuals within 85 separate burial contexts (Österholm 2008). Some of these individuals were detected with absent skeletal elements, such as the cranium, which have been believed to be represented by the considerable number of dispersed human bone fragments discovered from the site (Burenhult 2002: 33, see also Lundén 2012). These occurrences were initially proposed to be caused by agricultural ploughing, which however has not been done on the fields of Ajvide with the modern machinery of the late 20th century (Burenhult 2002: 31). It was hence the intention of this study to investigate the alternative motives behind these phenomena, by reviewing the statistics between these skeletal materials. The correspondence was additionally analysed with some other selected variables on the available data from these burial contexts. Based on the attained results, it was concluded that the human skeletal remains from the disturbed burials were likely intentionally retrieved to be used in the different ritual activities of the PWC populations on Gotland. / Den mellanneolitiska Ajvidelokalen på Gotland omfattar 85 begravningar av totalt 89 individer (Österholm 2008, Burenhult 2002). Vissa av individerna påträffades utan specifika skelettelement, såsom kraniet. Dessa individer har använts som representanter för tolkningen av den markanta kvantiteten av spridda mänskliga benfragment, som hittats via arkeologiska utgrävningar på lokalen (Burenhult 2002: 33, se även Lundén 2012 och Wallin 2015). Till en början ansågs jordbruksplogningen vara ansvarig för detta fenomen, dock har inga plöjningar utförts med moderna maskiner, eller sedan 1900-talet (Burenhult 2002: 31). Därmed, var syftet med studie att undersöka alternativa tolkningar bakom dessa fenomen. Studien är på analyser av de två olika grupperna med skelettmaterial, som inkluderats i en statistisk modell. Dessutom utfördes en korrespondensanalys mellan andra särskilt utvalda variabler från varje gravkontext. Studien har konkluderat, att de mänskliga skelettresterna från de förstörda begravningarna, hämtades sannolikt avsiktligen för olika rituella aktiviteter som praktiserades av den mellanneolitiska befolkningen på Gotland.