In this study a three-dimensional mathematical model is developed to simulate the flow field and mass transfer in a PEM fuel cell. In the model, the effects of the different flow channel structures in heterogeneous composite carbon fiber bipolar plates and traditional hard surface bipolar plates on the performance are studied. The results show that, the cell performance with the heterogeneous composite carbon fiber bipolar plates have better performance than that with the traditional hard surface bipolar plates, whether in the parallel flow channel structures or the serpentine flow channel structures. The reason is that, the heterogeneous composite carbon fiber ribs are porous material, so it allows the reactants and products transport uniformly even in the rib zone. This greatly improved the mass transfer and the gases distribution in the fuel cell. With the traditional bipolar plates, the reactants can only enter the reaction zone from the side of carbon cloth under ribs, so that the performance in this area under rib is relatively poor. In the simulation of the flow channel structures, we detect that, due to the single inlet serpentine flow channel have stronger convective effects that forced reactants to flow through the whole reaction zones, so it has better performance at high current density than in the singles inlet parallel flow channel. In addition, the results also show that, higher fuel stoichiometric number and operated pressure and properly humidified at anode will all improve the performance of the fuel cell.

Applications involving high electrical conduction require complex components that are difficult to be manufactured by conventional processes. Laser sintering (LS) is an additive manufacturing technique that overcomes these drawbacks by offering design flexibility. This study focuses upon optimizing the process of laser sintering to manufacture functional prototypes of components used in high electrical conduction applications. Specifically, components for two systems – high current sliding electrical contacts and fuel cells – were designed, manufactured and tested. C-asperity rails were made by LS and tested in a high current sliding electrical setup. Corrugated flow field plates were created by LS and their performance in a direct methanol fuel cell (DMFC) was tested. This is the first experimental attempt at using laser sintering for manufacturing such complex components for use in high electrical conduction applications. The second part of this study involves optimization the laser sintering process. Towards this, efforts were made to improve the green strength of parts made by LS. Particle size of graphite/ phenolic resin and addition of nylon/11 and wax were tested for their effect upon green strength. Of these, significant improvement of green strength was observed by altering the particle size of the graphite/ phenolic resin system. New methods of improving green strength by employing fast cure phenolic resins with carbon fiber additions were successfully demonstrated. This study also identified a binder system and process parameters for indirect LS of stainless steel –for bipolar plate compression/ injection mold tooling. All the experimental results of this study lead us to believe that laser sintering can be developed as a robust and efficient process for the manufacture of specialized components used in advanced electrical conduction systems. / text

Polymer electrolyte membrane fuel cells (PEMFCs) have the potential to play a major role as energy generators for transportation and portable applications. One of the current barriers to their commercialization is the cost of the components and manufacturing, specifically the bipolar plates. One approach to preparing PEMFCs for commercialization is to develop new bipolar plate materials, related to mass production of fuel cells. Thermoplastic/carbon filler composites with low filler loading have a major advantage in that they can be produced by a conventional low-cost injection molding technique. In addition, the materials used are inexpensive, easy to shape, and lightweight. An optimal bipolar plate must possess high surface and bulk electronic conductivity, sufficient mechanical integrity, low permeability, and corrosion resistance. However, it is difficult to achieve high electrical conductivity from a low-cost thermoplastic composite with low conductive filler loading. Concerns over electrical conductivity improvement and the injection processability of composites have brought forth the idea of producing a polypropylene/three-carbon-filler composite for bipolar plate application. The thesis addresses the development of synergistic effects of filler combinations, investigating composite conductive materials and using composite bipolar plate testing in PEMFCs. One significant effect of conductive network formation is the synergetic effects of different carbon filler sizes, shapes, and multiple filler ratios on the electrical conductivity of bipolar plate materials. A polypropylene resin combined with low-cost conductive fillers (graphite, conductive carbon black, and carbon fibers with 55 wt% of filler loading) compose the main composite for all investigations in this research. Numerous composite formulations, based on single-, two-, and three-filler systems, have been created to investigate the characteristics and synergistic effects of multiple fillers on composite conductivity. Electrical conductivity measurements corresponding to PEMFC performance and processing characteristics were investigated. Experimental work also involved other ex-situ testing for the physical requirements of commercial bipolar plates. All combinations of fillers were found to have a significant synergistic effect that increased the composite electrical conductivity. Carbon black was found to have the highest influence on the increase of electrical conductivity compared to the other fillers. The use of conjugated conducting polymers such as polypyrrole (PPy) to help the composite blends gain desirable conductivities was also studied. Electrical conductivity was significantly improved conductivity by enriching the conducting paths on the interfaces between fillers and the PP matrix with PPy. The conductive network was found to have a linkage of carbon fibers following the respective size distributions of fibers. The combination of Fortafil and Asbury carbon fiber mixture ameliorated the structure of conductive paths, especially in the through-plane direction. However, using small fibers such as carbon nanofibers did not significantly improve in electrical conductivity. The useful characteristics of an individual filler and filler supportive functions were combined to create a novel formula that significantly improved electrical conductivity. Other properties, such as mechanical and rheological ones, demonstrate the potential to use the composites in bipolar plate applications. This research contributes a direction for further improvement of marketable thermoplastic bipolar plate composite materials.

Neste trabalho foram analisados diferentes parâmetros geométricos para canais de fluxo em células a combustível tipo PEMFC e sua influência no desempenho do sistema, utilizando a fluidodinâmica computacional. Na análise dos modelos matemáticos, verificou-se que o modelo de aglomerado inundado descreve com maior fidelidade o comportamento de células a combustível, enquanto as equações de Butler-Volmer não consideram as perdas por transporte de massa. Foram avaliadas as seções transversais retangular, trapezoidal e em degrau. O modelo com canais de seção retangular apresentou desempenho elétrico ligeiramente superior, porém os canais com seção trapezoidal propiciam um melhor gerenciamento de água. Em todos os aspectos estudados, os canais com seção em degrau se comportaram de forma análoga aos canais com seção trapezoidal, porém sua construção é menos complexa. Também foram analisadas as configurações serpentina e interdigitada em células de 5 cm², e sua influência na uniformidade da densidade de corrente. Não foram observadas diferenças significativas quanto à eficiência elétrica entre células com as duas configurações. A configuração interdigitada propiciou distribuição mais uniforme de geração de corrente, pois os reagentes são fornecidos em alta concentração por uma maior área da célula. Assim, esta configuração é preferível para aumento de escala. / In this work, different geometric parameters for PEMFC flow channels and their influence in cell performance were analyzed using computational fluid dynamics. At first, two mathematical models, the flooded agglomerate model and the Butler-Volmer equations, were compared. It was verified that the equations do not consider mass-transfer losses, while the agglomerate model describes the system more accurately. In a second analysis, rectangular, trapezoidal and step-shaped cross-sections were evaluated. The model with rectangular channels showed a slightly higher electrical performance; however, trapezoidal channels provided better water management. Cells with step-shaped cross-sections were found to be superior to those with trapezoidal channels, due to lower constructive complexity, even though their performance was similar to that of trapezoidal cross-sections in every aspect. Further studies analyzed serpentine and interdigitated channel patterns in 5 cm² cells and their influence in current density uniformity. Again, electrical performance was very similar for both patterns. However, the interdigitated pattern provided more spatial uniformity in current generation, because concentrated reactants are supplied to a wider area of the cell. Thus, this pattern is preferable for fuel cell scaling-up.

The goal of this work was to evaluate the electrochemical properties of TiZrNbTa thin films deposited by magnetron sputtering using an industrial physical vapor deposition system. Samples were deposited on both Si(001) and 316L stainless steel. The samples deposited on Si(001) were either crystalline (bcc reflections) or amorphous, depending on the sputtering parameters. The crystalline films were composed of thin films with two different layers. The upper layer was nanocolumnar composed of elongated nanocolumns, while the lower was dense. The amorphous films had only one nanocolumnar layer and higher porosity. Polarization curves revealed that all samples had low corrosion current densities, in the order of 10-8 A/cm2. The samples showed an extended passive region up to 3.0 V vs Ag/AgCl due to the growth of a passivating oxide. The surface of the samples consisted of Nb2O5, ZrO2, TiO2 and Ta2O5. The chronoamperometry tests showed current oscillations, related to a break-down and reformation of the passive film. Electrochemical impedance spectroscopy revealed that all samples behaved similarly in all three electrolytes, and the simulated electrical circuits were indicating no corrosion reactions. A decrease in capacitance values after polarization was observed and was related to the formed surface oxide. Samples deposited on 316L stainless steel showed a passive regime for a shorter potential window, probably related to surface defects of the films. Heat treatments at 400 and 800 Celsius for 20 hours could not trigger the phase transformation from single bcc to hcp or dual bcc, as predicted by the Thermo-Calc software.

Polymer electrolyte membrane fuel cells (PEMFCs) have emerged as a strong and promising candidate to replace internal combustion engines (ICE) due their high efficiency, high power density and near-zero hazardous emissions. However, their commercialization waits for solutions to bring about significant cost-reductions and significant durability for given power densities. Bipolar plate (BPP) with its multi-faceted functions is one of the essential components of the PEMFC stacks. Stainless steel alloys are considered promising materials of choice for bipolar plate (BPP) applications in polymer electrolyte membrane fuel cells (PEMFC) due to their relatively low cost and commercial availability in thin sheets. Stainless steel materials build a protective passive metal oxide layer on their surface against corrosion attack. This passive layer does not demonstrate good electrical conductivity and increases interfacial electric contact resistance (ICR) between BPP and gas diffusion layer GDL in PEMFC. Lower ICR values are desired to reduce parasitic power losses and increase current density in order to improve efficiency and power density of PEMFC. This study aimed to bring about a broader understanding of manufacturing effects on the BPP contact resistance. In first stage, BPP samples manufactured with stamping and hydroforming under different process conditions were tested for their electrical contact resistance characteristics to reveal the effect of manufacturing type and conditions. As a general conclusion, stamped BPPs showed higher contact conductivity than the hydroformed BPPs. Moreover, pressure in hydroforming and geometry had significant effects on the contact resistance behavior of BPPs. Short term corrosion exposure was found to decrease the contact resistance of bipolar plates. Results also indicated that contact resistance values of uncoated stainless steel BPPs are significantly higher than the respective target set by U.S. Department of Energy. Proper coating or surface treatments were found to be necessary to satisfy the requirements. In the second stage, physical vapor deposition technique was used to coat bipolar plates with CrN, TiN and ZrN coatings at 0.1, 0.5 and 1 μm coating thicknesses. Effects of different coatings and coating thickness parameters were studied as manufactured BPPs. Interfacial contact resistance tests indicated that CrN coating increased the contact resistance of the samples. 1 µm TiN coated samples showed the best performance in terms of low ICR; however, ICR increased dramatically after short term exposure to corrosion under PEMFC working conditions. ZrN coating also improved conductivity of the SS316L BPP samples. It was found that the effect of coating material and coating thickness was significant whereas the manufacturing method and BPP channel size slightly affected the ICR of the metallic BPP samples. Finally, effect of process sequence on coated BPPs was investigated. In terms of ICR, BPP samples which were coated prior to forming exhibited similar or even better performance than coated after forming samples. Thus, continuous coating of unformed stripes, then, applying forming process seemed to be favorable and worth further investigation in the quest of making cost effective BPPs for mass production of PEMFC.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: In a move towards cleaner and more sustainable energy systems, hydrogen as an energy carrier and hydrogen fuel cells as energy converters are receiving increasing global attention. Considering the vital role that platinum plays in the operation of hydrogen fuels cells, South Africa stands to gain enormously as the world’s leading platinum group metals supplier. Therefore, in order to benefit across the whole value chain, it is imperative to develop the capability to manufacture hydrogen fuel cell stacks locally. This project addresses this imperative, in part, by building a framework to evaluate the manufacturing performance of one of the more costly components of the hydrogen fuel cell stack. More specifically, this project builds a cost evaluation model (or cost model) for the manufacture of bipolar plates using micro milling. In essence, the model characterises manufacturing cost (and time) as a function of relevant inputs. The model endeavours to be flexible in accommodating relevant contributing cost drivers such as tool life and manufacturing time. Moreover, the model lays the groundwork, from a micro milling perspective, for a comparison of different manufacturing methods for bipolar plates. The approach taken in building the cost model is a fundamental one, owing to the lack of historical cost data for this particular process. As such, manufacturing knowledge and experimentation are used to build the cost model in a structured way. The process followed in building the cost model begins with the formulation of the cost components by reviewing relevant examples from literature. Thereafter, two main cost drivers are comprehensively addressed. Tool life is characterised experimentally as a function of cutting parameters and manufacturing time is characterised as a function of relevant inputs. The work is then synthesized into a coherent cost model. Following the completion of the cost model, analysis is done to find the near-optimal combination of machine cutting parameters. Further, analysis is done to quantify the sensitivity of manufacturing cost to design changes and production volumes. This attempts to demonstrate how typical managerial issues can be addressed using the cost model format. The value of this work must be seen in terms of its practical contribution. That is, its contribution to the development of the capability to manufacture hydrogen fuel cells locally. By understanding the effect of relevant input factors on manufacturing cost, ‘upstream’ design and development activities can be integrated with ‘downstream’ manufacturing activities. Therefore, this project supports the development of manufacturing capability by providing a mechanism to control cost throughout the process. / AFRIKAANSE OPSOMMING: In die soeke na skoner, meer volhoubare energie bronne word die fokus op waterstof, as energie draer, en waterstof brandstofselle, as energie omskakelaars, al meer verskerp. Deur die sleutelrol van platinum in die werking van waterstof brandstofselle in ag te neem, word Suid-Afrika, as die wêreld se grootste platinum verskaffer, in `n uitstekende posisie geplaas om voordeel te trek uit hierdie geleentheid. Om dus as land voordeel te trek uit die proses in geheel, is dit van kardinale belang om die vermoë te ontwikkel om waterstof brandstofsel stapels op eie bodem te vervaardig. Hierdie projek adresseer gedeeltelik hierdie noodsaaklikheid, deur `n raamwerk te bou wat die vervaardigingsoptrede van een van die meer duursame komponente van die waterstof brandstofsel stapel evalueer. Meer spesifiek, bou hierdie projek `n koste evaluerings model (of koste model) vir die vervaardiging van bipolêre plate deur die gebruik van mikro-masjienering. In wese kenmerk hierdie model vervaardigings kostes (en tyd) as `n funksie van relevante insette. Hierdie model poog om buigsaam te wees met die in ag neming van relevante bydraende kostedrywers soos buitelleeftyd en vervaardigingstyd. Daarbenewens lê hierdie model die grondwerk, vanuit `n mikro masjienerings oogpunt, vir die vergelyking van verskillende vervaardingings metodes vir bipolêre plate. Die benadering wat gevolg word in die bou van die koste model is fundamenteel as gevolg van die gebrek van historiese data vir hierdie spesifieke proses. As sodanig word vervaardigings kennis en eksperimentering gebruik om die koste model in `n gestruktueerde wyse te bou. Die proses gevolg in die bou van die koste model begin met die formulering van die koste komponente deur die hersiening van relevante voorbeelde vanuit die literatuur. Daarna word twee hoof koste drywers deeglik geadresseer. Buitelleeftyd word ekperimenteel gekenmerk as funksie van masjieneringsparameters en vervaardigingstyd word gekenmerk as `n funksie van relevante insette. Die werk word dan gesintetiseer in `n samehangende koste model. Wat volg op die voltooiing van die koste model is `n analise om die optimale kombinasie masjieneringsparameters te vind. Daaropvolgens word analises gedoen om die sensitiwiteit van vervaardigingskoste onderworpe aan ontwerpsveranderings en produksie volumes te kwantisfiseer. Dit poog om te demostreer hoe tipiese bestuursproblem geadresseer kan word deur die koste model formaat te gebruik. Die waarde van hierdie werk moet in die lig van die praktiese bydrae daarvan gesien word, menende, die bydrae tot die ontwikkeling van die vermoë om waterstof brandstofselle in Suid-Afrika te vervaardig. Deur die effek van relevante inset faktore op vervaardigingskoste te verstaan, kan ‘stroom-op’ ontwerp en ontwikkelings aktiwiteite geïntegreer word met ‘stroom-af’ vervaardigings aktiwiteite. Dus, hierdie projek ondersteun die ontwikkeling van vervaardigingsvermoëns deur `n meganisme te voorsien om kostes oor die omvang van die proses te beheer.

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In the last couple of years there has been a great need for finding alternative, cleaner burning fuel sources. This search has led to the development of various hydrogen technologies. The reason for this is that when burnt, hydrogen gas only forms water and oxygen as products. One of the methods used in the production of hydrogen gas is that of the electrolysis of sulphur dioxide which is facilitated by a sulphur dioxide depolarized electrolyzer. The electrolysis of sulphur dioxide has the advantage of requiring lower cell voltages in the electrolysis process when compared to the electrolysis of water. This type of electrolyzer unfortunately suffers from low hydrogen gas production volumes. It was thought that by linearly increasing the reactions active area of the electrolyzer, the production volumes can be increased. A linearly upscaled 100cm2 cell was designed by using computer aided design software, such as SolidWorks, Cambridge Engineering Selector, EES and ANSYS. The cell was then constructed and tested to determine the effects of linearly upscaling. The results of the 100cm2 cell were compared to the results of a similar 25cm2 cell and results obtained from the literature. The 100cm2 cell exhibited very poor performance when compared to the other cells. The 100cm2 cell showed lower hydrogen production volumes at higher energy inputs than the 25cm2 cell and an 86cm2 stack assembly. It was concluded that creating stack assemblies with cells with smaller active areas would be much more efficient than linearly upscaling the active area of the cells. / Thesis (M.Ing. (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2012.

In the last couple of years there has been a great need for finding alternative, cleaner burning fuel sources. This search has led to the development of various hydrogen technologies. The reason for this is that when burnt, hydrogen gas only forms water and oxygen as products. One of the methods used in the production of hydrogen gas is that of the electrolysis of sulphur dioxide which is facilitated by a sulphur dioxide depolarized electrolyzer. The electrolysis of sulphur dioxide has the advantage of requiring lower cell voltages in the electrolysis process when compared to the electrolysis of water. This type of electrolyzer unfortunately suffers from low hydrogen gas production volumes. It was thought that by linearly increasing the reactions active area of the electrolyzer, the production volumes can be increased. A linearly upscaled 100cm2 cell was designed by using computer aided design software, such as SolidWorks, Cambridge Engineering Selector, EES and ANSYS. The cell was then constructed and tested to determine the effects of linearly upscaling. The results of the 100cm2 cell were compared to the results of a similar 25cm2 cell and results obtained from the literature. The 100cm2 cell exhibited very poor performance when compared to the other cells. The 100cm2 cell showed lower hydrogen production volumes at higher energy inputs than the 25cm2 cell and an 86cm2 stack assembly. It was concluded that creating stack assemblies with cells with smaller active areas would be much more efficient than linearly upscaling the active area of the cells. / Thesis (M.Ing. (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2012.