The regulated control of pollutants is essential to maintaining good air quality in urban areas. A major concern is the formation of tropospheric ozone, which can be especially harmful to those with lung conditions and has been linked to the occurrence of asthma. Ozone is formed through reactions of oxidized volatile organic compounds with nitrogen oxides, and the accurate modeling of the process is necessary for smart and effective regulations. Ambient measurements are important to understanding the mechanisms involved in tropospheric chemistry. This dissertation describes the characterization of a novel instrument for the ambient measurement of dinitrogen pentoxide, N2O5, and the results of several field studies. This is an important intermediate in the major nighttime loss pathway of nitrogen oxides. The understanding of this process requires correct modeling formation, as any nitrogen oxides not removed at night will result in increased ozone formation at sunrise. Calibration studies have been performed in order to quantify the loss of reactive species within the instrument, and the sampling flow and N2O5 detection have been well characterized. The results of the laboratory measurements are presented. Results are presented from the SHARP Field Study in Houston, TX in the spring of 2009. N2O5 measurements are compared to measurements of other species, including nitric acid and nitryl chloride, which were performed by other research groups. Mixing ratios exceeding 300 ppt were observed following ozone exceedance days, and a dependence of the concentration on both wind speed and direction was noticed. There was a strong correlation determined between N2O5 with HNO3 and ClNO2 indicating both a fast heterogeneous hydrolysis and N2O5 as the primary source of the species. Observed atmospheric lifetimes for N2O5 were short, ranging from several seconds to several minutes. We have also investigated the presence of N2O5 in College Station, TX. Low mixing ratios peaking at approximately 20 ppt were observed, with longer atmospheric lifetimes of up to several hours. The role of biogenic emissions in the NO3-N2O5 equilibrium is discussed.

In this thesis, we used the E-Beam lithography to fabricate a device of coupled microdisk-ring laser on the sample which was grown by molecular beam epitaxy (MBE), and analyzed the coupled effect of the device. The active layer was composed of six compressively strained InGaAs quantum dots (QDs) that were designed to support gain at 1200nm. Under the active layer, we replaced sacrificial layer by distributed bragg reflector (DBR). The purpose of the DBR was used like a mirror to reflect the particular wavelength which located at DBR¡¦s stop band, so the energy would be confined in the active layer. The device was composed of a microdisk and a ring. The diameter of the microdisk was 3£gm, and the width of the ring is 250nm. The microdisk was placed in the ring, and the gap of both was 100nm. After design, we simulated whether the device could generate coupled modes by Finite-Difference Time-Domain (FDTD). In experiment, we used the E-Beam lithography to define negative pattern on the sample which is spread with the PMMA. We also used the thermal evaporation to evaporate the metal, and lift the metal to form our pattern. Finally, we used the dry etching to transform the pattern to the epitaxial layer, and then the device was completed. In measurement, we used the micro-PL to measure our device, and got a successful result. The result showed our device generated eight resonant modes. The measured result matched the simulation result. Through simulation, the device generated three coupled modes, 1173.8nm, 1206nm, and 1214nm. We expect that the device will be used to generate terahertz source in the future.

In this thesis, with external cavity semiconductor laser, a high lateral resolution thickness measurement is proposed and demonstrated. The approach is typical an intra-cavity measurement of focused cell thickness by wavelength tuning of an external cavity laser diode. In addition, using blue light of 406nm as laser diode, higher lateral resolution is also observed. Using the proposed thickness method, the lateral resolution and longitudinal resolution have been demonstrated with 20£gm and 0.15£gm, respectively. We also discuss the feasibility of £gm scaled lateral resolution through improvement of laser diode, such as M^2~1.

In this thesis, we fabricate the quantum dots (QDs) micro-pillar of metal-coated by E-beam lithography, and analyze the optical and electrical properties of micro-pillar cavity devices. For the sample materials, we use S-K mode to grow 3-layer In0.75Ga0.25As QDs structures sandwiched by up and down Al0.5Ga0.5As cladding layer on GaAs substrate by molecular-beam epitaxy (MBE). 40nm GaAs spacer layers with 2nm p-modulation doping in the central barrier are adopted in this study. The micro-pillar with diameter of 2 m, metal coated on top (p-type) and down (n-type) facet are designed. The good reflectivities of metal contacts provide more energy extraction inside the cavity. We expect the device lasing while the current injection. First, we design the morphology and size of patterns by AutoCAD software. Then, we use e-beam lithography with proper exposure condition to define the patterns, and thermal evaporation to deposit metals. The superfluous metal is lifted off and the defined area metal is served as dry etching mask to transfer the pattern to the dielectric layer and epi-layer. Finally, we use SiO2 layer to prevent current leakage, and the p-n contact on each facet to complete the devices. Micro-pillar samples with/without metal coated are analyzed by micro-PL system. The emission wavelength of 1282nm and the calculated Q-value of 100 are obtained for the sample with metal coated, an increase of 500%. From the EL measurement results, the device of micro-pillar samples with metal coated generate three peaks, 1149nm, 1221nm and 1291nm. Besides, it can efficiently improve the emission intensities. The measured result matched the simulation result.

In this study, we fabricated an electrically wavelength-tunable resonant-cavity light emitting diode (RCLED). It was achieved by the combination of an AlGaInAs quantum well structure with an intra-cavity liquid crystal material. In the phase modulator layer, we used nematic liquid crystal (NLC) and cholesteric liquid crystal (CLC), respectively, comparing their difference in the infrared-spectrum. When inserting NLC, the anisotropic properties of liquid crystal enable continuous tuning of mode emission along the extraordinary direction and provide a 58 nm tuning range. The optical characteristics of this device are polarization dependent. On the contrary, the CLC-based device is polarization independent because any polarization of incident light experiences the same averaged refractive index. However, the phase difference of CLC is less than NLC, only a 41 nm tuning range of this sample. We also simulated and discussed experimental results of NLC-based RCLED. The optical pumping of the active region is realized by a CW laser at 1064 nm wavelength and observed at room temperature.

Several species of small, cavity-nesting owls occur in the Sierra Nevada, including in areas impacted by human activities. The owls typically use standing dead trees (snags) for nest sites. Although descriptive studies exist regarding habitats associations around nest and roost sites, few studies have examined habitat associations at larger spatial scales or relative to certain snag characteristics (e.g., density, decay class). To improve our understanding of the habitat associations of these owls, I compared habitat characteristics at 2 spatial scales around areas of owl detection and non-detection. I also examined distances between conspecifics and heterospecifics to determine if clustering of conspecifics or avoidance of predators occurred. I conducted owl broadcast surveys and snag sampling during the spring and summer of 2006 and 2007 in the Lake Tahoe Basin of central Sierra Nevada. I measured additional habitat variables (e.g., vegetation cover, distance to roadways) from pre-existing geographical information system layers. I used stepwise logistic regression to ascertain which variables were influential in predicting owl occurrence. The northern saw-whet owl (Aegolius acadicus) was the only species detected in sufficient numbers for statistical analysis, with a detection probability of 0.25. I detected saw-whets in a wide range of conditions and it appeared that few factors influenced their distribution in the basin. Areas dominated by white fir, however, were correlated with the absence of saw-whets at both the macrohabitat and microhabitat scales. White fir-dominated areas tend to occur on the west side of the basin and it is possible white fir was acting as a proxy for other factors not measured in this study, such as microclimate conditions or prey availability. I was also more likely to find a saw-whet within 1000 m of another saw-whet than within 1000 m of a non-use point, indicating clustering of conspecifics in the basin. While it appears saw-whet needs are being met in the basin, restoration projects are ongoing to decrease both the number of snags and relative abundance of white fir. Continued monitoring of the species is essential to understand potential effects of restoration activities. Suggestions are provided for appropriate timing and effort of future surveys.

Development of effective pollution control strategies for urban areas requires accurate predictive models. The ability of models to correctly characterize the atmospheric chemistry, meteorology, and deposition rely on accurate data measurements, both as input and verification of output. Therefore, the measurement techniques must be sensitive, accurate, and capable of resolving the spatial and temporal variations of key chemical species. The application of a sensitive in situ optical absorption technique, known as cavity ring-down spectroscopy, will be introduced for simultaneously measuring the nitrate radical and dinitrogen pentoxide. The cavity ring-down spectrometer was initially designed and constructed based on the experiments by Steven Brown and Akkihebal Ravishankara at the National Oceanic and Atmospheric Administration. The instrument design has since undergone many revisions before attaining the current instrumentation system. Laboratory observations provide verification of accurate N2O5 and NO3 detection with measurements of the nitrate radical absorption spectrum centered at 662 nm, effective chemical zeroing with nitric oxide, and efficient thermal decomposition of N2O5. Field observations at a local park provided further confirmation of the instruments capability in measuring N2O5 and NO3. However, detection limits were too high to detect ambient NO3. Effective and frequent zeroing can easily improve upon the sensitivity of the instrument. Determination of the source of the polluted air masses detected during these studies was unknown since the typical southerly winds from Houston were not observed. Since deployment in the field, instrumentation modifications and laboratory measurements are underway for preparation of the SOOT campaign in Houston, Texas starting April 15, 2009. Current modifications include automation of the titration with a solenoid valve and an automated filter changer. Wall losses and filter transmission for NO3 and N2O5 will be determined through laboratory measurements in coincidence with and ion-drift chemical ionization mass spectrometer prior to the SOOT project. Potential modifications to improve upon the instrument are suggested for future endeavors.

A superconducting microwave cavity has been designed to test advanced materials for use in the accelerating structures contained within linear colliders. The electromagnetic design of this cavity produces surface magnetic fields on the sample wafer exceeding the critical limit of Niobium. The ability of this cavity to push up to 4 times the critical field provides, for the first time, a short sample method to reproducibly test these thin films to their ultimate limit. In order for this Wafer Test cavity to function appropriately, the large sapphire at the heart of the cavity must have specific inherent qualities. A second cavity was constructed to test these parameters: dielectric constant, loss tangent, and heat capacity. Several tests were performed and consistent values were obtained. The consequences of these measurements were then applied to the Wafer Cavity, and its performance was evaluated for different power inputs. The Q_0 of the cavity could be as low as 10^7 because of the sapphire heating, therefore removing the ability to measure nano-resistances. However, with additional measurements in a less complex environment, such as the Wafer Test Cavity, the Q_0 could be higher than 10^9.

The cavity quantum electrodynamics has been applied to investigate the strong coupling interaction dynamics process between the microcavity field and the atom. The high quality cavity is a key to the realization of cavity quantum electrodynamics. Photonic crystal nanocavities are with small mode volumes and large quality factors. Lights are confined within the nanocavity. They can be used for cavity QED experiments of Fabry-Perot cavity. We have provided a realization of a quantum entanglement method for quantum information processing. In this paper, we discuss the entanglement swapping in the strong coupling process between two level atoms interacting with the photonic crystal microcavities fields of coherent states. We investigate the atomic level population and the entanglement degree of the system. We have found that the atomic maximal entangled state can be transformed into the photonic crystal microcavity maximal coherent entangled state cavity field, whereas the photonic crystal microcavity maximal coherent entangled state cavity field can be transformed into the atomic maximal entangled state.

The width of an ultra high-power laser diode is greater than 50 £gm and more than 20 times of low-power laser diode.The core diameter of Erbium Doped Fiber Amplifier fiber (EDFA) is 4~6 £gm and it is a single-mode fiber (SMF).However¡Athe ultra high-power laser diode is multi-mode laser. Therefore¡Athe mismatch between high-power laser and SMF resulting in low coupling efficiency. We improve coupling efficiency by using a wedge-shaped graded-index fiber (GIF) tip spliced to a SMF then fused a fiber bragg grating (FBG) to form an external cavity laser. The GIF is a focusing action like a graded-index fiber. From near-field pattern (NFP)¡Awe find the best GIF length is 400 £gm. The coupling efficiency between ultra high-power laser diode and wedge-shape lensed fiber is only 5% .