Resumo: Devido a frequente demanda por aplicações de produtos fitossanitários dada pela ocorrência simultânea de pragas (insetos, doenças e planta-daninha) em uma mesma área e a procura do agricultor em otimizar recursos financeiros e operacionais na lavoura, a prática de misturas em tanque de diferentes classes de produtos fitossanitários tem sido cotidiana. Os efeitos resultantes das misturas, relativos a fatores como às formulações, às dosagens e a interação entre os produtos a serem aplicados, estão associados a compatibilidade entre as formulações e às alterações físico-química nas caldas, que podem resultar na perda de eficácia dos produtos aplicados e ainda em efeitos tóxicos para a cultura tratada e ao ambiente. Nesse cenário, o objetivo desse trabalho foi avaliar as propriedades físico-químicas de calda inseticida e identificar primórdios de perda da estabilidade de misturas com fungicidas e adjuvantes. Os tratamentos foram constituídos da combinação do inseticida tiametoxam + lambda-cialotrina com os fungicidas fluxapiroxade + piraclostrobina e clorotalonil e adjuvantes lecitina e ácido propiônico e óleo mineral. Foram realizadas avaliações de características físico-químicas das combinações, quanto ao pH, condutividade elétrica, tensão superficial e ângulo de contato resultantes das caldas preparadas. Para a avaliação dos primórdios de perda da estabilidade estoudou-se o comportamento reológico, a viscosidade, o potencial zeta, a distribuição de tamanho de partículas disper... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: Due to frequent demand for pesticide applications, imports of financial and operational resources in tillage, a practice of tank storage of different classes phytosanitary products has been daily. The effects of the mixtures are factors such as the formulations, the dosages and the interactions between the products that are applied, are associated to the compatibility between the formulations and the physical of the chemical complex in the syrups, that can cause the breakage of its products and also in toxic effects on the treated crop and the environment. In this scenario, the use of chemical-chemical syrups proved to be insidious and identitarian, impairing the stability of the mixtures with fungicides and adjuvants. The isolates were constituted by the combination of the insecticide thiamethoxam + lambda-cyhalothrin with fungicides fluxapiroxade + pyraclostrobin and chlorothalonil and lecithin and propionic and mineral acid adjuvants. The physical, chemical and enzymatic properties, such as pH, electrical conductivity, surface tension and the contact bottom of the prepared syrups were discontinued. For an evaluation of the stability results, viscosity, zeta potential, dispersion capacity and physical stability of the grouts. The combination of the thiamethoxam + lambda-cyhalothrin insecticide with the chlorothalonil fungicide and the lecithin and propionic acid adjuvants and the mineral oil interfere with the coating of the target, eliminating the surface tension of the sy... (Complete abstract click electronic access below) / Mestre

Electromagnetic compatibility remains an important topic in the design and manufacturing of printed circuit boards (PCBs). Compatibility of these devices with their surroundings is becoming increasingly difficult as a modern PCB can have hundreds or thousands of parts, operating on many layers, and all at high speed. One such part is a via and its clearance, or via hole, commonly required in multilayer circuits where vertical connections between layers are used. The via hole may be exposed to large electromagnetic fields within the PCB. Although electrically small, the via hole provides a pathway for the fields to excite the exterior, either directly or through coupling to adjacent structures. To quantify this process, the near fields and radiation of an excited via hole are analysed, and are the focus of this thesis. The near fields of the via hole are first decoupled into electric and magnetic fields of the 'static' type. In both cases a series solution for two regions, one outside, and one inside the layers is constructed. The coefficients of the terms of the series are chosen to best satisfy the boundary behaviour of the fields on the conducting surfaces and across the hole. The criteria for assessing quality of the solution is based on the least squares method (LSM). Linear equation systems for both models are derived, and as no numerical integration or discretisation is required, an efficient and robust implementation to find the near fields is developed. Transformation into the far field is then achieved through surface integration of relevant field quantities close to the via hole. The far fields are best viewed as that due to two dipoles, of the magnetic and electric type, with strength and orientation depending on how the via hole is excited. It is shown that the two dipole model is sufficient to find the radiation from a 1mm diameter via hole at a frequency up to 8 GHz. Of further interest is how the choice of via hole dimensions affects the dipole moments and the near fields solved earlier are a key to this understanding.

Web services are increasingly gaining acceptance as a framework for facilitating application-to-application interactions within and across enterprises. It is commonly accepted that a service description should include not only the interface, but also the business protocol supported by the service. The present work focuses on the formalization of the important category of protocols that include time-related constraints (called timed protocols), and the impact of time on compatibility and replaceability analysis. We formalized the following timing constraints: CInvoke constraints define time windows of availability while MInvoke constraints define expirations deadlines. We extended techniques for compatibility and replaceability analysis between timed protocols by using a semantic-preserving mapping between timed protocols and timed automata, leading to the novel class of protocol timed automata (PTA). Specifically, PTA exhibit silent transitions that cannot be removed in general, yet they are closed under complementation, making every type of compatibility or replaceability analysis decidable. Finally, we implemented our approach in the context of a larger project called ServiceMosaic, a model-driven framework for web service life-cycle management.

Darwin's theory of sexual selection explains the existence of sexual dimorphism, or within-species sex differences in shape, color, size, and behavior. In some cases, sexually dimorphic traits, especially extravagant male ornaments, seem maladaptive and thus in opposition to natural selection. The crux of Darwin's theory was that sexual selection arises from individual differences in reproductive success that result from competition for mates. In this dissertation, I investigated several aspects of sexual selection and the evolution of female mating preferences and male ornaments in the great frigatebird (Fregata minor). Frigatebirds as a group (family Fregatidae) are the most ornamented of any seabirds, and are among the most ornamented of any animal group. Their most prominent ornament is a gular (throat) pouch which becomes red in males during the breeding season, and which is inflated and displayed to females during courtship. Male courtship display also includes a warble vocalization and extension and trembling of the wings. I investigated the following issues concerning sexual selection and ornamentation in great frigatebirds: 1) the source of ornamental coloration in male great frigatebird gular pouches. I determined that this was a carotenoid-based color display; 2) the relationship of male mating success to gular pouch size and coloration. I determined that mating success was not related to the size or color of this ornament; 3) the relationship between male vocal display traits and female preferences. Again, I found no relationship between vocal display traits and female preferences, and finally, 4) the role of a major histocompatibility complex (MHC) locus in female mate choice. The MHC is a highly polymorphic multi-gene family associated with immune defense and has been proposed to play a role in mate choice. I found a significant disassortative mating pattern amongst mated pairs compared to random pairings based on MHC genotypes. In summary, I found no evidence for female mating preferences based on visual or auditory display traits associated with male ornamentation. However, I did find evidence for female mating preferences based on genetic dissimilarity at an MHC locus.

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Software evolution is a crucial activity for software organizations. A specifc type of software evolution is the integration of previously isolated systems. The need for integration is often a consequence of different organizational changes, including merging of previously separate organizations. One goal of software integration is to increase the value to users of several systems by combining their functionality, another is to reduce functionality overlap. If the systems are completely owned and controlled in-house, there is an additional advantage in rationalizing the use of internal resources by decreasing the amount of software with essentially the same purpose. Despite in-house integration being common, this topic has received little attention from researchers. This thesis contributes to an increasing understanding of the problems associated with in-house integration and provides guidelines to the more efficient utilization of the existing systems and the personnel. In the thesis, we combine two perspectives: software architecture and processes. The perspective of software architecture is used to show how compatibility analysis and development of integration alternatives can be performed rapidly at a high level of abstraction. The software process perspective has led to the identification of important characteristics and practices of the integration process. The guidelines provided in the thesis will help those performing future in-house integration to make well-founded decisions timely and efficiently. The contributions are based on several integration projects in industry, which have been studied systematically in order to collect, evaluate and generalize their experiences.

This PhD thesis addresses the threat posed to society by sources that can produce high power electromagnetic pulses (HEPM) and be used maliciously to disturb or damage electronic equipment. The vulnerability from intentional electromagnetic interference (IEMI) has increased in the recent decades due to the widespread dependence of the civil society on sensitive electronic systems and proliferation of radiation sources. As the characteristics of the disturbances associated with IEMI often have very high frequency content, the existing mitigation measures and protection components may not be adequate. It was seen that for ultra wideband (UWB) transients low voltage protection components may not work as intended, due to parasitic components that arises from the packaging of the device. The large spatial distribution of many civilian facilities and critical infra-structures (e.g., power generation, communications, train system, etc.) presents many unexpected ports for an attacker as the majority of the parts of these systems are not protected or secure. As the new European Rail Traffic Management System (ERTMS) will utilize wireless communication for communication and control of the trains the vulnerability from different radiating HPEM sources was investigated. Angles of incidence and frequencies that are a threat in a given situation are identified. Due to the possibility of unexpected ports, the propagation of differential mode ultra wideband transients in low voltage power networks, when injected into a power socket of a facility, was studied. The effects on the transient propagation from cable bends, switches and junctions were studied, both in a laboratory setup and in the network of a facility. Also, as modern electronic equipment and systems may not be tested for waveforms and disturbances other than standardized EMC tests, experiments on some common commercial-off-the-shelf (COTS) equipment were performed with non-standard test situation. It was seen that these could easily be disturbed or even permanently damaged. In addition, due to the inherent difficulties with IEMI, a new method for classifying facilities from IEMI is suggested. It is based on available terminology of accessibility (A), susceptibility (S) and consequence (C), but expands these and forms the so called IEMI/ASC-cube.

With growing demand for cardiovascular implants, improving the performance of artificial blood-contacting devices is a task that deserves close attention. Current prostheses made of fluorocarbon polymers such as expanded polytetrafluoroethylene (ePTFE) suffer from early thrombosis and require periodic replacement. A great number of attempts have already been made to improve blood compatibility of artificial surfaces, but only few of them found commercial implementation. One of the surfaces under intensive research for cardiovascular use is amorphous carbon-based coatings produced by means of the plasma-assisted deposition. However, this class of coatings can be produced using various techniques leading to a number of coatings with different properties. Carbon coatings produced in different plasmas may be of hard diamond-like type or soft graphite-like type, doping with different elements also changes the surface structure and properties. Taking this into account, the search for blood-compatible coating requires the understanding of surface composition and structure and its influence on blood-compatibility. This work attempts to advance our knowledge of this field. Here, commercial PTFE thin film was used as a working material, which composition corresponds to the composition of modern ePTFE vascular grafts and which compatibility with blood we tried to improve by deposition of nitrogenated amorphous carbon (a-CN) coatings in the plasma. Biocompatibility was assessed by a number of tests including the interaction with whole blood and various cells such as platelets, endothelial cells, neutrophils, and fibroblasts. Most of tests showed the blood compatibility of coated surface is better than that of untreated PTFE. Physico-chemical and morphological properties of coated surfaces were studied in parallel using x-ray photoemission spectroscopy (XPS), electron energy loss spectroscopy (EELS), x-ray absorption spectroscopy (XAS), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM). Some correlation between the structure of coatings and blood compatibility was inferred. It was found that at first nitrogen incorporation into amorphous carbon film stimulates blood compatibility. However, when nitrogen fraction increases over 23-25 %, no further improvement but reduction of blood compatibility was observed. Conclusion is made that for best biomedical performance, nitrogen percentage in a-CN coatings must be adjusted to the optimum value.

The scalar tensor theory of gravitation is constructed in D dimensions in all possible geometries of spacetime. In Riemannian geometry, theory of gravitation involves a spacetime metric g with a torsion-free, metric compatible connection structure. If the geometry is non-Riemannian, then the gauge theory of gravitation can be constructed with a spacetime metric g and a connection structure with torsion. In non-Riemannian theory, connections may be metric compatible or non-metric compatible. It is shown that theory of gravitation which involves non-metric compatible connection and torsion, can be rewritten in terms of torsion-free theory. It is also shown that scalar tensor theory can be reformulated in Einstein frame by applying a conformal transformation. By adding an antisymmetric axion field, the axi-dilaton theory is studied in Riemannian and non-Riemannian geometries. Motion of massive test particles is examined in all these geometries. The static, spherically symmetric and stationary, Kerr-type axially symmetric solutions of the scalar tensor and axi-dilaton theories are presented. As an application, the geodesic elliptical orbits based on a torsion-free connection and the autoparallel orbits based on a connection with a torsion, are examined in Kerr Brans-Dicke geometry. Perihelion shift of the elliptical orbit is calculated in both cases and the results are compared.

ElectroMagnetic Interferences (EMI) are emerging problems in today's high speed circuits. There are several examples that these interferences affected the circuits and systems. This work tries to reduce the abovementioned problems in synchronous systems by modifying the clock signal such that it produces less interferers. In this thesis first EMI and its sources and related definitions are studied in Chap.1 and then a theoretical background is presented in Chap.2, finally Chap.3 and Chap.4 are dedicated to circuit implementation and simulation results, respectively. A novel multi-segment clocking scheme is presented in this thesis. An analytical methods for formal verification of advantages of this clocking method is presented in Chap.2. Chap.3 and Chap.4 also are devoted to implementation, simulation and comparison of proposed clocking method versus other methods. Since proposed clocking method does not set any constraint on timing (speed of the circuit) and does not impose very high extra power consumption on the circuit, compared to the conventional clocking, this method could be used to reduce interferences in system.