Vid produktion av biodiesel produceras även råglycerol (10 vikt%) som biprodukt och utbudet av råglycerol har ökat över de senaste åren till följd av att biodieselproduktionen ökat. Marknadsvärdet för råglycerol är lågt, men det är en utmärkt föregångare till att producera mervärdesprodukter för exempelvis läkemedelsindustrin, kemikalieindustrin eller kosmetika. Genom att reformera glycerol till mervärdesprodukter ökar konkurrenskraftigheten för biodiesel och värdekedjans ekonomiska hållbarhet. Elektrokemisk reformering av glycerol är en lovande metod för att producera dess mervärdesprodukter, eftersom processen är justerbar och miljövänlig. En ytterligare fördel är att vätgas kan samproduceras med mervärdesprodukterna genom denna metod och energikonsumtionen för att producera vätgas genom denna metod är ungefär hälften av vad som krävs vid vattenelektrolys. Denna studie utvärderar hur masstransport påverkar selektiviteten och prestandan för elektrokemisk oxidation av glycerol, genom att utföra elektrokemiska experiment, karaktärisera processens katalysator och analysera produkter som produceras.  Den experimentella uppställningen innefattar en roterande diskelektrod med ett elektrodepositerat lager av Pd, på ett Ni-substrat, i varierande tjocklek. Elektroden undersöks i elektrolyter bestående av varierande koncentration av NaOH (1, 0.5 och 0.25 M) och 0.5 M glycerol vid 25 oC. Systemet konstrueras även som modell i Comsol Multiphysics 6.0 för att simulera experiment. Resultaten visar att masstransport av glycerol begränsar systemet genom att orsaka deaktiveringen av katalysatorn. Vid de lägre NaOH koncentrationerna begränsar även masstransport av OH- reaktionshastigheten genom att miljön omgärdande elektroden blir mindre oxidativ. Slutligen visas att reaktionsmekanismen vid alla tjocklekar av katalysatorn utgörs av två parallella reaktionsvägar. En ökande tjocklek hos katalysatorn ökar selektiviteten mot den ena reaktionsvägen framför den andra, samt ökar antal oxidationssteg som åstadkoms vid reaktionen. / Biodiesel production gives rise to 10 wt% crude glycerol as a byproduct, which is becoming increasingly available on the market owing to the increased biodiesel production over the last few years. Crude glycerol has a low market value, but it is an excellent precursor to producing value added products for the pharmaceutical industry, chemical industry or cosmetics to mention a few. By producing value added products with biodiesel derived glycerol, the ability of biodiesel to compete with fossil fuels is improved and its economical sustainability is promoted. One of the most promising methods to convert glycerol into its value added products is electrochemical reforming, as it poses high tunability and is an environmentally friendly process. Additionally, the process produces hydrogen concurrently and halves the energy consumption compared to producing hydrogen from water electrolysis. This study evaluates the impact of mass transport in the glycerol electrooxidation reaction (GEOR), as a parameter that can be used to finetune product selectivity and optimise the system performance. To do so, the study employs electrochemical experiments, catalyst characterisation and product analysis. The experimental setup consists of a rotating disk electrode (RDE) cell with electrodeposited Pd on Ni substrate at varying thicknesses, operating in 1, 0.5, 0.25 M NaOH and 0.5 M glycerol electrolyte at 25 oC. Additionally, the system is modelled in Comsol Multiphysics 6.0 which is used to perform simulations. It is found that mass transport of glycerol is limiting the system by causing the deactivation of the catalyst. At lower NaOH bulk concentrations for the thicker electrodes, the mass transport of OH- also limits the reaction rate by causing the formation of a locally less oxidative environment. Finally, it is found that all electrodes pose dual reaction mechanisms. Increasing the electrode thickness promotes one reaction mechanism over the other as well as it increases the number of oxidation steps achieved in the reaction.

The focus of the research is on the problem of ventilation on lead-melting production. The main sources of lead emissions in the refining shop are determined. The primary conditions for convective jet saving for its further removal and cleaning are defined. With COMSOL Multiphysics simulation platform the shop model is created for fluid flow analysis. The results of numerical calculation of air exchange scheme and its comparing with experimental data are shown. An own scheme of air distribution in refining shop is offered. The scheme takes into account all the requirements for saving of convective circulation, initiated by convective jets from melting pots. / Диссертация посвящена проблеме вентиляции свинцово-плавильного производства. Определены основные источники выделения аэрозолей свинца в рафинировочном цехе. Определены основные условия, и параметры сохранения конвективной струи для её дальнейшего удаления и очищения. В программе COMSOL Multiphysics® построена модель цеха для моделирования процессов течения воздуха. Представлены результаты численного моделирования организации схемы воздухообмена и их сравнение с физическим опытом. Предложена собственная схема распределения воздуха в рафинировочном цехе, в которой учитываются все требования, для сохранения естественной циркуляции, инициированной конвективными струями от котлов.

Transformers are essential for modern power distribution system. They are efficient and enable the voltages to be transformed up for transportation of electricity and back down for consumer use. The reliability of the transformer is affected by faults and fatigue of the copper. The bigger faults a transformer is subjected to, the shorter life time it will have due to damage to the winding and other parts of the transformer. This thesis investigates if it is possible to characterise the noise made from the windings during a short circuit fault or lightning strike, to see if it can be replicated and if transformers can be diagnosed with the help from the noise. Faults creates forces on the windings, these forces can be so great that the windings collide with each other and in worst case breaks. The sound sources that are interesting are the thermal expansion due to the current, the radial forces and the axial forces acting on the coil. Simulations were made in Comsol multiphysics to see how the currents and forces behaved in a winding. A simplified microphone circuit was built and tested to see if it could detect the noise made from the collisions in the coil. Two microphone types and amplifier circuits were tested to see which ones was most suited for the experiments. The microphone circuit was used to record the sound made from the coils when being compressed. An experiment with a capacitor bank sending a large current pulse through different coils and the noise made from the coil was recorded with a microphone circuit connected to an oscilloscope. The currents are recorded by a computer using the program Picoscope. The capacitor bank was charged to different voltages to get different current amplitudes. A microphone circuit was built and tested so it could detect the sound from the collision. Sound occured with a current pulse with an amplitude of 2 kA, and permanent deformation occured when the amplitude of the current pulse was 4.5 kA. The frequency content of the impact was within the audible spectrum. Possibly even higher frequencies than 20 kHz was present during the fault. The microphone had a bandwidth between 20-20000 Hz, which limits the frequencies that is picked up by the microphone. / Transformatorer är viktiga för det morderna elsystemet. Transformatorer är effektiva och tillåter spänningen att transformeras upp för transport vilket minimerar förlusterna i lendningarna och sedan ned igen för kunder. Tillförlitligheten av transformatorer blir påverkad av fel, felen kan orsaka utslitning av kopparen i lindningarna. Ju större fel som transformatorn blir utsatt för, ju kortare livstid får transformatorn på grund av skada på lindningarna eller andra delar av transformatorn. Denna avhandling undersöker om det är möjligt att karaterisera ljudet från transformator lindningar under ett kortslutningsfel eller blixtnedslag. Felströmmarna skapar krafter på lindningarna, dessa krafter kan vara så stora att lindningarna kolliderar med varandra och i värsta fall går lindningarna sönder. Några intressanta ljudkällor är termisk expansion av kopparen från strömmarna, den radiella kraften på spolen och den axiella kraften på spolen. Simuleringar gjordes i Comsol Multiphysics för att se hur strömmar och krafterna beter sig i transformator lindningarna. En mikrofonkrets byggdes och testades för att se om den kunde detektera ljudet från kollisionerna i spolen. Två olika mikrofontyper och två olika förstärkartyper testades för att se vilka som passade bäst för experimenten. Mikrofonkretsen användes för att spela in ljudet från spolarna. Experimenten gjordes med med hjälp av en kondensatorbank som genererar en strömpuls genom de olika lindningarna/spolarna och ljudet från spolarnas kompression var inspelade av mikrofonkretsen som var inkopplad till ett oscilloskop. Strömpulsen var sparad på datorn med programmet Picoscope. Kondensatorbanken var uppladdad med olika spänningar för att få strömpulser med olika amplituder. Experimenten gjordes på fyra olika spolar, en två varvs spole, en 19 varvs spole, en 40 varvs tätlindad spole och en deformerad 19 varvs spole, för att se om det var skillnad mellan kollisionerna. Ljud uppstod vid en strömpuls med amplituden 2 kA och permanent deformation uppstod vid 4.5 kA. Frekvensinnehållet från kollisionen befann sig inom det hörbara spektrumet. Det fanns möjligen frekvenser över 20 kHz, men mikrofonen hade en bandbredd mellan 20-20000 Hz vilket begränsar de upptagna frekvenserna.

<p>Complex surface structures in nature often have remarkable optical properties. By understanding the origin of these properties, such structures may be utilized in metamaterials, giving possibilities to create materials with new specific optical properties. To simplify the optical analysis of these naturally developed surface structures there is a need to assist data analysis and analytical calculations with numerical calculations.</p><p>In this work an application tool for numerical calculations of optical properties of surface structures, such as reflectances and ellipsometric angles, has been developed based on finite element methods (FEM). The data obtained from the application tool has been verified by comparison to analytical expressions in a thorough way, starting with reflection from the simplest of interfaces stepwise increasing the complexity of the surfaces.</p><p>The application tool were developed within the electromagnetic module of Comsol Multiphysics and used the script language to perform post-process calculations on the obtained electromagnetic fields. The data obtained from this application tool are given in such way that easily allows for comparison with data received from spectroscopic ellipsometry measurements.</p>

This project considers the diffusion of water molecules through a cellular medium in which the cells are modeled by square compartments placed symmetrically in a square domain. We assume the diffusion process is governed by the 2D diffusion equations and the solution is provided by implementing the Crank-Nicolson scheme. These results are verified and illustrated to agree well with the finite element method using the Comsol Multiphysics package. The model is used to compute the values of the apparent diffusion coefficient, (ADC) which is a measure that is derived from diffusion weighted MRI data and can be used to identify, e.g., regions of ischemia in the brain. With our model, it is possible to examine how the value of the apparent diffusion coefficient is affected whenever the extracellular space is varied. We observe that the average distance that the water molecules travel in a definite time is highly dependent on the geometrical properties of the cellular media. / UOIT

The thesis investigates the temperature distribution in the chip of an infrared camera caused by its read out integrated circuit. The heat from the read out circuits can cause distortions to the thermal image. Knowing the temperature gradient caused by internal heating, it will later be possible to correct the image by implementing algorithms subtracting temperature contribution from the read out integrated circuit. The simulated temperature distribution shows a temperature gradient along the edges of the matrix of active bolometers. There are also three hot spots at both the left and right edge of the matrix, caused by heat from the chip temperaturesensors and I/O pads. Heat from the chip temperature sensors also causes an uneven temperature profile in the column of reference pixels, possibly causing imperfections in the image at the levels of the sensors. Simulations of bolometer row biasing are carried out to get information about how biasing affects temperatures in neighbouring rows. The simulations show some row-to-row interference, but the thermal model suffers from having biasing heat inserted directly onto the top surface of the chip, as opposed to having heat originate from the bolometers. To get better simulation results describing the row biasing, a thermal model of the bolometers needs to be included. The results indicate a very small temperature increase in the active pixel array, with temperatures not exceeding ten millikelvin. Through comparisons with another similar simulation of the chip, there is reason to believe the simulated temperature increase is a bit low. The other simulation cannot be used to draw any conclusions about the distribution of temperature. / Examensarbetet undersöker den temperaturdistribution som uppkommer i ett chip till en IR-kamera till följd av värmeutvecklingen i dess egna utläsningskretsar. Genom att ha information om temperaturdistributionen är det möjligt att längre fram i utvecklingsprocessen skapa algoritmer som subtraherar bort chippets interna värmetillskott från den termiska bilden. Den simulerade temperaturdistributionen visar att de största temperaturgradienterna uppkommer längs den aktiva pixelmatrisens sidor. Det är även möjligt att se tre varmare områden vid både den vänstra och högra sidan av matrisen skapade av värme från chippets temperatursensorer och I/O-kretsar. Värme från temperatursensorerna påverkar även temperaturen i kolumnen med referenspixlar, vilket kan ge upphov till avvikelser i den termiska bilden i höjd med dessa temperatursensorer. Simuleringar av radvis basering av bolometrar utförs för att få information om hur bolometerbiaseringen påverkar temperaturen i angränsade rader. Simuleringarna visar att det finns störningar mellan rader, men simuleringsmodellen lider av avsaknaden av en termisk bolometermodell och tvingas applicera värme direkt på chipytan istället för att låta värme utvecklas i bolometrarna. För bättre simuleringsresultat innefattande bolometerbiasering bör en termisk bolometermodell inkluderas i simuleringen. Resultaten visar på en mycket liten temperaturökning inom den värmekänsliga aktiva pixelmatrisen, med temperaturökningar inom detta område som inte överstiger tio millikelvin. Genom jämförelser med en liknande simulering av samma chip är det inte omöjligt att dra slutsatsen att temperaturökningen är något låg. Det går inte att dra några slutsatser om temperaturens distribution genom denna jämförelse av simuleringar.

Complex surface structures in nature often have remarkable optical properties. By understanding the origin of these properties, such structures may be utilized in metamaterials, giving possibilities to create materials with new specific optical properties. To simplify the optical analysis of these naturally developed surface structures there is a need to assist data analysis and analytical calculations with numerical calculations. In this work an application tool for numerical calculations of optical properties of surface structures, such as reflectances and ellipsometric angles, has been developed based on finite element methods (FEM). The data obtained from the application tool has been verified by comparison to analytical expressions in a thorough way, starting with reflection from the simplest of interfaces stepwise increasing the complexity of the surfaces. The application tool were developed within the electromagnetic module of Comsol Multiphysics and used the script language to perform post-process calculations on the obtained electromagnetic fields. The data obtained from this application tool are given in such way that easily allows for comparison with data received from spectroscopic ellipsometry measurements.

A dust layer, especially based on high-resistivity dust, at the collecting electrodes may cause a back corona discharge in electrostatic precipitators (ESP). It can significantly reduce the ESP efficiency and as a result cause ecological damages. To study the dust layer influence inside ESPs, it is necessary to derive an adequate model of the ESP precipitation process with a dust layer at the collecting electrode. The research of the present thesis is focused on stationary studies of the precipitation process with a dust layer at the collecting electrode in ESPs. Three mathematical models are proposed as a description of the precipitation process with a dust layer at the collecting electrode. The models are based on Maxwell’s equations and the finite element method (FEM). COMSOL Multiphysics software is used for their implementation. In all models the dust layer has constant conductivity and the air region has constant ion mobility. In the first model there are no coupling conditions, which is required in mathematics, are given between the two regions. The solution found by COMSOL Multiphysics does not provide physically acceptable coupling conditions. In the second model, a continuous transition zone is introduced between the two regions so that no coupling conditions are required. With the large derivatives in the transition zone, the nonlinear solver in COMSOL Multiphysics does not converge. Finally, in the third model, the dust layer and the grounded collecting electrode are replaced with a boundary condition for the air region. The properties of the third model are investigated, and these models can be used to study the influence of the dust layer. The results of these investigations are reported and discussed.

M. Tech. Hydrogen storage modeling. / In this dissertation, a 2D dynamic simulation for a portion of metal hydride based hydrogen storage tank was performed using computational software COMSOL 4.0a Multiphysics. The software is used to simulate the diffusion and heating of hydrogen in both radial and axial directions. The model consists of a system of partial differential equations (PDE) describing two dimensional heat and mass transfer of hydrogen in a porous matrix. This work provides an important insight to the fundamental understanding of multi-physics coupling phenomena during hydrogen absorption/ desorption process. The simulation results could be applied to the on-board hydrogen storage technology, in particular for the hydrogen supply of a fuel cell for powering of a hydrogen fuel cell vehicle.

The diploma thesis deals with problems of air flow in stables. The research part is devoted to ventilation requirements in livestock breeding, fluid flow problems and the possibility of prediction of this flow through computer modeling methods. The following chapter focuses on the COMSOL Multiphysics software in which theo bject model was created. In the practical part of the diploma thesis is described model of air flow in stable object, including all partial steps necessary for it ssuccessful numerical realization. The conclusion of the thesis is devoted to comparison of obtained results with value smeasured in real breeding.