No / Abstract: Avoiding collision among contending customer premise equipments (CPEs) attempting to associate with a base station (BS), the only available solution in IEEE 802.22 standard is binary exponential random backoff process in which the contending CPEs retransmit their association requests. The number of attempts the CPEs sends their requests to the BS are fixed in IEEE 802.22 network. This paper presents a mathematical framework for helping the BS in determining at which attempt the majority of the CPEs become the part of wireless regional area network (WRAN) from a particular number of contending CPEs at a given initial contention window size.

Ever since their discovery, Carbon nanotubes (CNTs) have been renowned to be potential candidates for a variety of applications. Nevertheless, the difficulties accompanied with their dispersion and poor solubility in various solvents have hindered CNTs potential applications. As a result, studies have been developed to address the dispersion problem. The solution is in modifying the surfaces of the nanotubes covalently or non-covalently with a desired dispersant. Various materials have been employed for this purpose out of which polymers are the most common. Non-covalent functionalization of CNTs via polymer wrapping represents an attractive method to obtain a stable and homogenous CNTs dispersion. This method is able to change the surface properties of the nanotubes without destroying their intrinsic structure and preserving their properties. This thesis explores and studies the surface modification and solublization of pristine single and multiwalled carbon nanotubes via a simple solution mixing technique through non-covalent interactions of CNTs with various anionic and cationic conjugated polyelectrolytes (CPEs). The work includes studying the interaction of various poly(phenylene ethynylene) electrolytes with MWCNTs and an imidazolium functionalized poly(3-hexylthiophene) with SWCNTs. Our work here focuses on the noncovalent modifications of carbon nanotubes using novel CPEs in order to use these resulting CPE/CNT complexes in various applications. Upon modifying the CNTs with the CPEs, the resulting CPE/CNT complex has been proven to be easily dispersed in various organic and aqueous solution with excellent homogeneity and stability for several months. This complex was then used as a nanofiller and was dispersed in another polymer matrix (poly(methyl methacrylate), PMMA). The PMMA/CPE/CNT composite materials were cast or electrospun depending on their desired application. The presence of the CPE modified CNTs in the polymer matrix has been proven to enhance the composites thermal, mechanical and electrical properties compared to pristine CNTs. Various spectroscopic and microscopic techniques such as UV-vis, fluorescence, TEM, AFM and SEM were used to study and characterize the CPE/CNT complexes. Also, TGA, DSC and DMA were used to study the thermal and mechanical properties of the composite materials. Our current work represents a fundamental study on the non-covalent interactions between CNTs and CPEs on one hand and gives a real life example on the CPE/CNT application in composite materials and electronics.

The development of the IEEE 802.22 standard is aimed at providing broadband access in rural areas by effectively utilizing the unused TV band, provided no harmful interference is caused to the incumbent operation. This thesis presents the analytical framework to evaluate the number of active customer premise equipments (CPEs) in a wireless regional area network. Initial ranging is the primary process in IEEE 802.22 networks for CPEs to access the network and establish their connections with the base station (BS). A comprehensive analysis of initial ranging mechanism is provided in this work and initial ranging request success probability is derived based on the number of contended CPEs and the initial contention window size. Further, the average ranging success delay is derived for the maximum backoff stages. The collision probability is highly dependent on the size of the initial contention window and the number of contended CPEs. To keep it at a specific level, it is necessary for the BS to schedule the required size of the initial contention window to facilitate the maximum number of CPEs to establish their connections with reasonable delay. Therefore, the optimized initial window size is proposed that meets the collision probability constraint for a particular number of contended CPEs. An analytical model is also developed to estimate the ranging request collision probability depending upon the size of initial contention window and the number of contended CPEs. Moreover, this approximation provides the threshold size for contention window to start the initial ranging process in the IEEE 802.22 network.

The development of the IEEE 802.22 standard is aimed at providing broadband access in rural areas by effectively utilizing the unused TV band, provided no harmful interference is caused to the incumbent operation. This thesis presents the analytical framework to evaluate the number of active customer premise equipments (CPEs) in a wireless regional area network. Initial ranging is the primary process in IEEE 802.22 networks for CPEs to access the network and establish their connections with the base station (BS). A comprehensive analysis of initial ranging mechanism is provided in this work and initial ranging request success probability is derived based on the number of contended CPEs and the initial contention window size. Further, the average ranging success delay is derived for the maximum backoff stages. The collision probability is highly dependent on the size of the initial contention window and the number of contended CPEs. To keep it at a specific level, it is necessary for the BS to schedule the required size of the initial contention window to facilitate the maximum number of CPEs to establish their connections with reasonable delay. Therefore, the optimized initial window size is proposed that meets the collision probability constraint for a particular number of contended CPEs. An analytical model is also developed to estimate the ranging request collision probability depending upon the size of initial contention window and the number of contended CPEs. Moreover, this approximation provides the threshold size for contention window to start the initial ranging process in the IEEE 802.22 network. / Bahauddin Zakariya University Multan, Pakistan.

<p>The Materials Genome Initiative (MGI) has established guidelines to accelerate the discovery, development, and implementation of advanced materials in order to address current and future challenges. A key area of interest is the pressing need for more efficient energy storage systems to support technologies such as electric vehicles and renewable energies. In this work, we present an Integrated Computational Materials Engineering approach for the development of novel solid-state electrolyte materials. In particular, we embark on a quest to unravel the potential of ceramic garnet lithium lanthanum zirconium oxide (LLZO) for next-generation battery technologies.</p> <p>Our exploration begins with an overview of the current state of the Materials Innovation Infrastructure (MII) and our rationale behind choosing LLZO. Through the use of machine learning techniques and molecular dynamics simulations, we aim for efficient material optimization. Our findings are reinforced through experiments by using these materials as inorganic fillers in composite polymer electrolytes. Our findings demonstrate that the combined use of these complementary techniques facilitates the discovery of potential alternative solid-state electrolytes. Finally, we propose future research directions in materials science for the design of advanced materials using these integrated approaches. </p>