In real conditions, a great majority of machine and elements and parts are subjected to cyclic deformation. There is no possibility to improve their quality, to increase their reliability and durability without good knowledge of working condition and materials feature. During cyclic loading, stresses can overpass proportionality limits. It causes residual stresses which reduce durability of elements to limited number of loading cycles. Such a loading is called low cycle loading. Usually it happens in small volumes of material, concentration zones, welded joints so on. In this work, main cyclic elastic plastic characterestics of materials are presented and explained. It also contains experimental and analytical methods of estimation that characteristics and detail research of experimental cyclic stress strain curve approximation methods.

It is impossible to improve the quality of the machines, to increase their reliability and lifetime if the working conditions and the properties of the material are not analyzed. We must know the type of the material (hardening, softening or cyclically stabile), what is chosen for the constructions in low cycle loading, because strain and stress change during the exploitation and depend on this type. If we know the type of the material, we can determine the possibility of its application in concrete exploitation conditions. Real working conditions of the most constructions are close to loading with limited strain (hard straining), because elastic and plastic deformation is met in the zones of crack and stress concentration, that are surrounded with elastically deformed material. The low cycle loading curves parameters A, and are used for the computation of elastic plastic strain curves. These parameters are obtained from the soft low cycle loading results in many cases. The other possible ways for the determination of parameters A, and are shown in this work. The most investigated materials had the initial instability in the interval . For more objective evaluation of stress strain curves parameters A, and , all values of width of hysteresis loop up to semicycle were rejected as insignificant in comparison with the rest lifetime in cycles range . The parameter for the evaluation of hardening (softening) intensity was determined, when the values of... [to full text]

Tai stačiakampio skerspjūvio strypo ciklinio tampriai plastinio grynojo lenkimo tyrimas. Nustatant mašinų ir įrengimų patikimumą, dažniausiai atliekamas atskirų jų elementų ir mazgų statinio ir ciklinio stiprumo įvertinimas. Statinis stiprumas – tai detalių ir įrengimų elementų sugebėjimas priešintis statinėms, lėtai kintančioms arba visai nekintančioms laike apkrovoms. Statinėmis apkrovomis dažniausiai veikiamos korpusinės, tvirtinimo detalės. Jei mechanizmai eksplotuojami aukštesnių temperatūrų salygomis, dažnai įvertinamas detalių atsparumas ilgalaikėms statinėms apkrovoms (valkšnumo ir relaksacijos reiškiniai). / This work presents analytical research of ractangular cross-section bar under cyclic elastic plastic (low-cycle) pure bending. The simple power relation of stress strain response in the region of plastic deformation is used in both – static and cyclic loading analysis.

The automotive industry is adopting lightweight materials to improve emissions and fuel economy. Magnesium (Mg) alloys are the lightest of engineering metals, but work is required to assess their structural strength, especially for spot-welded applications. In the present research, fatigue behavior of magnesium spot-welds was characterized and compared with steel and aluminum spot-welds. A fatigue model was proposed to predict the failure location and crack initiation life in magnesium structures. The material under investigation, AZ31B-H24 Mg alloy, and its spot-welds were characterized from microstructural and mechanical perspectives. Microstructure and hardness of the base metal (BM) and different regions in the spot-welds were studied. Under cyclic loading, the BM had an asymmetric hysteresis loop. Cyclic behavior of magnesium spot-welds was measured using different specimen configurations, and the effect of geometrical factors on fatigue life was evaluated. A constitutive model was developed to model the asymmetric hardening behavior of wrought magnesium alloys under cyclic loading. An algorithm for numerical implementation of the proposed model was developed. The numerical formulation was programmed into a user material subroutine to run with the commercial finite element software Abaqus/Standard. The proposed model was verified by solving two problems with available solutions. A number of available fatigue models, as well as a new model proposed in this research were assessed by predicting fatigue life of magnesium spot-welds. The new model used a strain energy damage parameter. All models were evaluated by comparing the predicted and experimental fatigue lives for different Mg spot-welded specimens. The effect of considering the asymmetric hardening behavior of wrought magnesium alloys on the accuracy of the fatigue life prediction was not significant for the available experimental data. This was attributed to the limited experimental data on spot-welded specimens. The proposed material model and fatigue damage parameter were verified by simulating a real-life structure manufactured and fatigue tested by the US Automotive Materials Partnership. The results obtained from the proposed asymmetric model were compared with available symmetric simulation results and experimental data. The asymmetric material model along with the proposed damage parameter resulted in more accurate prediction of fatigue failure location and life.

I examined the influence of cyclic feeding regime on fillet yield and quality and their genetic architecture in rainbow trout (Oncorhynchus mykiss). Two lots of half-sib families produced in September and December were exposed to periods of reduced ration followed by increased ration. Fish fed cyclically reduced rations weighed less and had smaller fillets and body proportions relative to controls. They also had less estimated muscle and visceral lipid but also more proportional visceral mass. Lots and families within lots differed significantly for the majority of traits. Genotypic analysis with 23 microsatellite markers spanning 19 linkage groups detected QTL for all traits over multiple linkage groups that were not necessarily consistent between feeding regime and parental lot. Linkage groups RT-9 and 29 had the largest QTL effects for fillet composition traits and overall body size across the greatest number of parents sampled.

Polycarbonates are found in a variety of common products in daily life due to their favorable mechanical and electrical properties. In addition, they are widely used in biomedical areas due to their stability and biological inertness. Therefore, the production of polycarbonates became an important industrial process in the past decades. However, the current industrial process usually requires toxic phosgene gas as a starting material. Thus, the environmentally benign route by using metal catalyzed couplings of epoxides and CO_(2) to produce polycarbonates has received attention from researchers. In this dissertation, metal catalyzed CO_(2)/cyclic ether copolymerization, depolymerization of polycarbonates, and the equilibria between polycarbonate and corresponding six-membered cyclic carbonate will be investigated. First, the Co(III) catalyzed copolymerizations of CO_(2) and various epoxides with electron-withdrawing substituents to afford polycarbonates are examined. Comparative kinetic studies were performed via in situ infrared measurements as a function of temperature to assess the activation barriers for the production of cyclic carbonate versus copolymer involving electronically different epoxides: styrene oxide, epichlorohydrin, and propylene oxide. Thermodynamically stable cyclic carbonate byproducts are produced during the course of the reaction from the degradations of propagating polymer chains. The depolymerization reactions of several polycarbonates produced from the completely alternating copolymerization of styrene oxide, epichlorohydrin, propylene oxide, cyclohexene oxide, indene oxide, and cyclopentene oxide with carbon dioxide have been investigated. Various reaction pathways can be found under different reaction conditions, including process involving chain-end backbiting and radical intermediates. Temperature-dependent kinetic studies have provided energy of activation barriers for cyclic carbonate formation. In addition, the generated monomeric materials from the degradation of select polycarbonates show the possibility of chemical recycling of plastic waste. For the copolymers made from CO_(2) and oxetane derivatives, this study focuses on the influence of steric hindrance in the 3-position of the monomer oxetane. The (salen)CrCl/onium salt catalyzed coupling reactions of these oxetane derivatives and carbon dioxide are reported. Depolymerizations of copolymers to their corresponding cyclic carbonates were also studied. In addition, several six-membered cyclic carbonates were synthesized to examine their equilibria between monomeric cyclic carbonates and their corresponding polycarbonates.

No description available.

No description available.

No description available.

Nucleoside polyphosphates and their conjugates, such as nucleoside triphosphates, nucleoside tetraphosphates, sugar nucleotides, dinucleoside pyro- and higher order polyphosphates, 2’,3’-cyclic nucleoside monophosphates, and 2´-deoxynucleoside-5´-tetraphosphates in which a fluorescent label is attached to the terminal phosphate have many biological roles and have been developed into drugs. However, their synthesis remains a challenge. Several novel and efficient approaches to the synthesis of nucleoside polyphosphates and their conjugates were developed. In the first approach dinucleoside polyphosphates (NpnN’s where n = 2-4) are prepared via in situ trifluoroacetate protection and imidazolium activation of nucleoside 5’-monophosphates. This methodology was also used to prepare a substrate-intermediate analog of the reaction catalyzed by cytidine triphosphate synthase (CTPS) a recognized target for the development of antineoplastic, antiviral and antiprotozoal agents. The second approach uses sulfonylimidazolium salts as key reagents for generating highly reactive nucleotide donors. The procedure is rapid, produces a wide variety of nucleoside polyphosphates and their conjugates in high yield, does not require protection and subsequent deprotection of the nucleotide donors or acceptors and can be used to activate nucleoside mono-, di-, and triphosphates and a wide variety of acceptors. Finally an entirely new approach to the synthesis of nucleoside tetraphosphates (Np4’s), dinucleoside pentaphosphates (Np5N’s) and nucleoside tetraphosphates in which a fluorescent dye is attached to the terminal phosphate is described employing an activated form of cyclic trimetaphosphate as a novel phosphorylating agent. Attempts to prepare nucleoside triphosphates by subjecting unprotected ribonucleosides and 2’-deoxyribonucleosides to activated cyclic trimetaphosphate failed. Instead nucleoside 2’,3’-cyclic phosphates were obtained in good yield with the ribonucleoside substrates. This represents a new and convenient approach to the synthesis of this class of compounds.