We investigate chaotic ionization of highly excited hydrogen atom in crossed electric and magnetic fields (Rydberg atom) and intra-molecular relaxation in planar carbonyl sulfide (OCS) molecule. The underlying theoretical framework of our studies is dynamical systems theory and periodic orbit theory. These theories offer formulae to compute expectation values of observables in chaotic systems with best accuracy available in given circumstances, however they require to have a good control and reliable numerical tools to compute unstable periodic orbits. We have developed such methods of computation and partitioning of the phase space of hydrogen atom in crossed at right angles electric and magnetic fields, represented by a two degree of freedom (dof) Hamiltonian system. We discuss extensions to a 3-dof setting by developing the methodology to compute unstable invariant tori, and applying it to the planar OCS, represented by a 3-dof Hamiltonian. We find such tori important in explaining anomalous relaxation rates in chemical reactions. Their potential application in Transition State Theory is discussed.

With the rapid development of optical communications and the increasing amount of data exchanged, it has become utterly important to provide effective ar- chitectures to protect sensitive data. The use of chaotic optoelectronic devices has already demonstrated great potential in terms of additional computational security at the physical layer of the optical network. However, the determination of the security level and the lack of a multi-user framework are two hurdles which have prevented their deployment on a large scale. In this thesis, we propose to address these two issues. First, we investigate the security of a widely used chaotic generator, the external cavity semiconductor laser (ECSL). This is a time-delay system known for providing complex and high-dimensional chaos, but with a low level of security regarding the identification of its most critical parameter, the time delay. We perform a detailed analysis of the influence of the ECSL parameters to devise how higher levels of security can be achieved and provide a physical interpretation of their origin. Second, we devise new architectures to multiplex optical chaotic signals and realize multi-user communications at high bit rates. We propose two different approaches exploiting known chaotic optoelectronic devices. The first one uses mutually cou- pled ECSL and extends typical chaos-based encryption strategies, such as chaos-shift keying (CSK) and chaos modulation (CMo). The second one uses an electro-optical oscillator (EOO) with multiple delayed feedback loops and aims first at transpos- ing coded-division multiple access (CDMA) and then at developing novel strategies of encryption and decryption, when the time-delays of each feedback loop are time- dependent.

When statistical assumptions do not hold and coherent structures are present in spatially extended systems such as fluid flows, flame fronts and field theories, a dynamical description of turbulent phenomena becomes necessary. In the dynamical systems approach, theory of turbulence for a given system, with given boundary conditions, is given by (a) the geometry of its infinite-dimensional state space and (b) the associated measure, that is, the likelihood that asymptotic dynamics visits a given state space region. In this thesis this vision is pursued in the context of Kuramoto-Sivashinsky system, one of the simplest physically interesting spatially extended nonlinear systems. With periodic boundary conditions, continuous translational symmetry endows state space with additional structure that often dictates the type of observed solutions. At the same time, the notion of recurrence becomes relative: asymptotic dynamics visits the neighborhood of any equivalent, translated point, infinitely often. Identification of points related by the symmetry group action, termed symmetry reduction, although conceptually simple as the group action is linear, is hard to implement in practice, yet it leads to dramatic simplification of dynamics. Here we propose a scheme, based on the method of moving frames of Cartan, to efficiently project solutions of high-dimensional truncations of partial differential equations computed in the original space to a reduced state space. The procedure simplifies the visualization of high-dimensional flows and provides new insight into the role the unstable manifolds of equilibria and traveling waves play in organizing Kuramoto-Sivashinsky flow. This in turn elucidates the mechanism that creates unstable modulated traveling waves (periodic orbits in reduced space) that provide a skeleton of the dynamics. The compact description of dynamics thus achieved sets the stage for reduction of the dynamics to mappings between a set of Poincare sections.

Thesis (MPhil)--University of Stellenbosch, 2007. / ENGLISH ABSTRACT: Many variations of Systems Development Life Cycle models have evolved over the last fifty years of systems engineering and software science, yet not enough knowledge is available to better understand these as Complex Adaptive Systems by studying chaos and complexity theories. The primary application domain of the thesis is focused on the development of electronic hardware and software products. There is a great need for innovation to reach all corners of the development ecosystem; however a large cognitive distance exists between the concept of systematic product development and that of value creation. Instruments are needed to aid process agility, for defusing imminent problems as they mount, and for making effective decisions to sustain maximum productivity. Many of these objectives are neglected in systems development practices. As with so many management fads, it appears that no single one of these models lived up to all of the expectations and in many cases ended up being recipes for disaster. The statistics available on failed projects are concerning but has not stopped the scientific and engineering communities from trying over, and over again, to make progress. The goal of the thesis is therefore to identify the most viable model that supports the sustainability of systems development team performance. The research draws insights from extant literature, by applying a knowledge management theory based analysis on the various models with specific attention given to complexity theory. The dominant metric discovered is to measure the Value Velocity of a Systems Development Team. This metric is determined by two independent variables, being Value Created and Delivery Delay. Complex Adaptive Systems simply requires a guiding vision and a carefully selected set of generative rules for increasing and sustaining the Value Velocity. / AFRIKAANSE OPSOMMING: Menige variasies van stelselsontwikkelingsmodelle het ontwikkel oor die afgelope vyftig jaar in stelselsingenieurswese en sagtewarewetenskap, en steeds is daar nie genoegsame kennis beskikbaar om beter begrip te kry oor hoe hierdie stelsels as Komplekse Aanpassende Sisteme bestudeer kan word nie, ten einde die bestuur daarvan te verbeter. Die primêre toepassingsgebied in die tesis is gespits op die ontwikkeling van rekenaarhardeware en - sagteware. Die behoefte vir innovasie moet al die fasette van die ontwikkelingsekosisteem bereik. Die bewusheidsgaping tussen sistemiese produkontwikkeling en waardeskepping, is te wyd. Instumentasie word benodig om te help met ratsheid in prosesuitvoering, om dreigende probleme te ontlont, en effektief besluitneming toe te pas, en sodoende produktiwiteit op ‘n maksimum vlak te hou. Hierdie doelwitte word tot ’n meerdere mate in die huidige praktyk verontagsaam. Net soos somige bestuursadvies oneffektief is, blyk dit dat daar nog steeds geen stelselsmodelle is wat alle verwagtinge bevredig nie. In baie gevalle eindig die toepassing daarvan in waan en mislukking. Die statistiek beskikbaar op mislukte projekte is onrusbarend, tog het dit nie vooruitgang gekelder nie, en die behoefte na verbetering bestaan steeds. Die doelwit van die tesis is dus om die mees lewensvatbare model wat die voortbestaan van stelselsontwikkelingsgroepe sal kan handhaaf, uit te sonder. Die navorsing neem insigte uit hedendagse literatuur en is gebasseer op ’n analiese van verskeide kennisbestuursteorieё teenoor die bestaande stelselsontwikkelingsmodelle. Die fokus is meer spesifiek toegespits op kompleksiteitsteorie. Die hoofmaatstaaf is om die Waardesnelheid van ’n stelselsontwikkelingspan te bepaal. Hierdie maatstaaf word gepyl deur twee onafhanklike veranderlikes, naamlik die Waarde Geskep en die Afleweringsvertraging. Ten slotte, vereis Kompleks Aanpassende Sisteme slegs die aanwesigheid van 'n leidende visie tesame met 'n goeddeurdagte stel ontwikkelingsreëls, wat aanleiding sal gee tot die verhoging en behoud van die Waardesnelheid.

Thesis (MSc (Computer Science))-- University of Stellenbosch, 2001. / ENGLISH ABSTRACT: This thesis explores the use of neural networks for predicting difficult, real-world time series. We first establish and demonstrate methods for characterising, modelling and predicting well-known systems. The real-world system we explore is seismic event data obtained from a South African gold mine. We show that this data is chaotic. After preprocessing the raw data, we show that neural networks are able to predict seismic activity reasonably well. / AFRIKAANSE OPSOMMING: Hierdie tesis ondersoek die gebruik van neurale netwerke om komplekse, werklik bestaande tydreekse te voorspel. Ter aanvang noem en demonstreer ons metodes vir die karakterisering, modelering en voorspelling van bekende stelsels. Ons gaan dan voort en ondersoek seismiese gebeurlikheidsdata afkomstig van ’n Suid-Afrikaanse goudmyn. Ons wys dat die data chaoties van aard is. Nadat ons die rou data verwerk, wys ons dat neurale netwerke die tydreekse redelik goed kan voorspel. / Integrated Seismic Systems International

Submitted by Helmut Patrocinio (hell.kenn@gmail.com) on 2017-12-01T23:43:39Z No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Heloisa_Onias_Dissertacao_2012.pdf: 9805428 bytes, checksum: 00e0f3bac6584320107351966c70da69 (MD5) / Approved for entry into archive by Ismael Pereira (ismael@neuro.ufrn.br) on 2017-12-04T12:33:01Z (GMT) No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Heloisa_Onias_Dissertacao_2012.pdf: 9805428 bytes, checksum: 00e0f3bac6584320107351966c70da69 (MD5) / Made available in DSpace on 2017-12-04T12:33:37Z (GMT). No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Heloisa_Onias_Dissertacao_2012.pdf: 9805428 bytes, checksum: 00e0f3bac6584320107351966c70da69 (MD5) Previous issue date: 2012-08 / O circuito RLD, formado por um resistor, um indutor e um diodo em s?rie, apresenta uma din?mica muito rica quando for?ado por uma tens?o externa harm?nica e vem sendo estudado h? d?cadas. Contudo, ainda existem t?picos em din?mica n?o-linear sendo estudados com variantes deste circuito. Varreduras nos par?metros de controle podem fazer com que esse sistema oscile eletronicamente entre regi?es peri?dicas e regi?es ca?ticas. O diodo ? o elemento n?o linear respons?vel pelo surgimento do caos. Utilizando um modelo de capacit?ncia n?o linear para descrever o comportamento do diodo, podemos escrever as equa??es para esse sistema e estudar a sua din?mica numericamente. Nosso principal objetivo foi o estudo de expoentes cr?ticos complexos em bifurca??es din?micas. Para isso, realizamos um estudo num?rico do circuito RLD for?ado senoidalmente utilizando como par?metros de controle a frequ?ncia e a amplitude da tens?o de entrada. Constru?mos, a partir das s?ries temporais da corrente total e da tens?o no diodo, diagramas de bifurca??o com diferentes cortes estrobosc?picos, que apresentam cascata de dobramento de per?odo, janelas peri?dicas e transi??o intermitente. Tamb?m realizamos estudos num?ricos do comportamento da m?dia na regi?o de transi??o caos-peri?dico na busca de encontrar um expoente cr?tico caracter?stico e oscilas??es na m?dia, elementos que j? foram observados no mapa log?stico. N?o foram poss?veis observar numericamente as oscila??es, mas observamos um decaimento exponencial com expoente cr?tico de aproximadamente 0,5. Montamos um sistema de controle, aquisi??o e tratamento de dados experimentais no qual ? poss?vel a realiza??o remota de experimentos simult?neos com dois circuitos diferentes. Obtivemos diagramas de bifurca??es experimentais nos quais observamos que o sistema apresentahisterese e alta sensibilidade ?s condi??es do experimento como, por exemplo, o passo de varredura do par?metro de controle. / The RLD circuit, formed by a resistor, an inductor and a diode in series, displays a very rich dynamics when forced by an external harmonic voltage, and it has being studied for decades. However, there are some topics in nonlinear dynamics that are still studied with variants of this circuit nowadays. Changes in the control parameters may cause electronic oscillations between regular and chaotic regions.The diode is the nonlinear element responsible for the appearance of chaos. Using a nonlinear capacitance model to describe the behavior of the diode, we can write the equations for this system and study its dynamics numerically. Our main objective was the study of critical exponents in complex dynamic bifurcations. For that, we did a numerical study of the RLD circuit forced sinusoidally using as control parameters the amplitude of the input voltage and the frequency. We made, from the time series obtained, bifurcation diagrams with different stroboscopic cuts, which have cascade of period-doubling, periodic windows and intermittent transition. We also did numerical studies of the average behavior in the periodic-chaos transition region searching for characteristic critical exponent and oscilas??es on average, elements that have been observed in the logistic map. It was not possible to observe the oscillations numerically, but we observed an exponential decay with critical exponent of approximately 0.5. We set up a system able to control, acquire and process experimental data making it possible to perform remote simultaneous experiments with two different circuits. We have obtained experimental diagrams bifurcations in which we observe that the system has hysteresis and high sensitivity to the conditions of the experiment such as the step of scanning the control parameter.

Para qualquer sistema observado, físico ou qualquer outro, geralmente se deseja fazer predições para sua evolução futura. Algumas vezes, muito pouco é conhecido sobre o sistema. Se uma série temporal é a única fonte de informação no sistema, predições de valores futuros da série requer uma modelagem da lei da dinâmica do sistema, talvez não linear. Um interesse em particular são as capacidades de previsão do modelo global para análises de séries temporais. Isso pode ser um procedimento muito complexo e computacionalmente muito alto. Nesta dissertação, nos concetraremos em um determinado caso: Em algumas situações, a única informação que se tem sobre o sistema é uma série sequencial de dados (ou série temporal). Supondo que, por detrás de tais dados, exista uma dinâmica de baixa dimensionalidade, existem técnicas para a reconstrução desta dinâmica.O que se busca é desenvolver novas técnicas para poder melhorar o poder de previsão das técnicas já existentes, através da programação computacional em Maple e C/C++.

Para qualquer sistema observado, físico ou qualquer outro, geralmente se deseja fazer predições para sua evolução futura. Algumas vezes, muito pouco é conhecido sobre o sistema. Se uma série temporal é a única fonte de informação no sistema, predições de valores futuros da série requer uma modelagem da lei da dinâmica do sistema, talvez não linear. Um interesse em particular são as capacidades de previsão do modelo global para análises de séries temporais. Isso pode ser um procedimento muito complexo e computacionalmente muito alto. Nesta dissertação, nos concetraremos em um determinado caso: Em algumas situações, a única informação que se tem sobre o sistema é uma série sequencial de dados (ou série temporal). Supondo que, por detrás de tais dados, exista uma dinâmica de baixa dimensionalidade, existem técnicas para a reconstrução desta dinâmica.O que se busca é desenvolver novas técnicas para poder melhorar o poder de previsão das técnicas já existentes, através da programação computacional em Maple e C/C++.

Orientadores: Jose Manoel Balthazar, Helder Anibal Hermini / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-08-05T09:56:56Z (GMT). No. of bitstreams: 1 Bolla_MairaRosine_M.pdf: 1168474 bytes, checksum: 0fac8753156d18f561b1aeef6a8a6210 (MD5) Previous issue date: 2005 / Resumo: Este trabalho consiste de duas partes, na primeira faremos o estudo da dinâmica de uma espaçonave de dupla rotação axial, modelada por um sistema mecânico simples, constituído de um rotor desbalanceado atachado num suporte elástico e governado por uma fonte de energia não-ideal. Na segunda parte formularemos todas as equações diferenciais não-lineares que governam os movimentos não-lineares de uma viga com movimentos de curvatura e arfagem no espaço. A formulação é baseada num princípio variacional que leva em conta todas as não linearidades devido à deformação e efeitos de gradiente de gravidade. As não-linearidades devidas às deformações aparecem devido aos efeitos geométricos, que consiste dos termos não-lineares de curvatura e inércia. Equações expandidas que governam os movimentos perturbados não-lineares ao redor de um equilíbrio são também desenvolvidas para o caso em que a viga está em órbita circular. Tais equações são adaptadas para uma análise de perturbação do movimento, e não-linearidades até ordem cúbica são representadas por um parâmetro. Também é analisado o acoplamento não-linear da resposta de arfagem-curvatura de uma viga livre-livre em uma órbita circular, quando a viga está sujeita a uma excitação externa periódica. As não-linearidades presentes nas equações diferenciais do movimento são devidas às deformações da viga (isto é, não-lineridades de curvatura e de inércia) e também devido ao momento de gradiente de gravidade. Métodos de perturbações são usados para analisar o movimento. Vários movimentos de ressonância exibidos pelo sistema são analisados em detalhe, nomeados, ressonâncias harmônicas quando a freqüência de excitação externa, O, está próxima da freqüência natural de flexão ou do movimento de arfagem, e a ressonância super-harmônica quando O está próxima da metade da freqüência natural do movimento de arfagem. As últimas duas ressonâncias estão associadas com excitações de baixa freqüência / Abstract: This work concerns of two parts, in the first we will make the study of the dynamics of dual-spin-spacecraft modeled by a simple mechanical system consisting of an unbalanced rotor attached to an elastic support and driven by non-ideal source. In the second part we will formulate the complete nonlinear differential equations governing the nonlinear motions of a beam able to undergo bending and pitching in space. The formulation is based on a variational principle and accounts for all the nonlinearities due to deformation and gravity gradient effects. The nonlinearities due to deformation arise due to geometric effects, which consist of nonlinear curvature and nonlinear inertia terms. Expanded equations governing the nonlinear perturbed motions about an equilibrium are also developed for the case when the beam is in circular orbit. Such equations are suited for a perturbation analysis of the motion, and nonlinearities up to cubic order in a bookkeeping parameter are retained in them. The coupled nonlinear pitch-bending response of a free-free beam in a circular orbit, when the beam is subjected to a periodic external excitation, is analysed too. The nonlinearities present in the differential equations of motion are due to deformations of the beam (i. e. curvature and inertia nonlinearities) and to the gravity-gradient moments. Perturbation methods are used to analyse the motion. Several resonant motions exhibited by the system are analysed in detail, namely, harmonic resonances when the frequency of the external excitations, O, is either near the natural frequency of the flexural or of the pitch motion, and a superharmonic resonance when O is near one half of the natural frequency for the pitch motion. The latter two resonances are associated with very low excitation frequencies / Mestrado / Mecanica dos Sólidos e Projeto Mecanico / Mestre em Engenharia Mecânica

Orientadores: Jose Manoel Balthazar, João Mauricio Rosario / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-08-05T10:03:06Z (GMT). No. of bitstreams: 1 Cassiano_Jeferson_D.pdf: 8294948 bytes, checksum: b7318ea3e310db82a9fd5af926a9cb2a (MD5) Previous issue date: 2005 / Resumo: Este trabalho tem como objetivo a determinação analítica da ocorrência de um tipo de caos (irregularidade) determinístico denominado Caos Homoclínico em algumas aplicações da Ciência da Engenharia como, por exemplo, a Robótica e a Teoria de Controle (Controle de Bifurcações e Caótico). Para isto, faz-se uso da chamada Teoria de Poincaré - Mel¿nikov que fornece uma forma analítica para a determinação do tipo de comportamento do sistema (regular ou irregular) / Abstract: This work make the analytical determination of the occurrence of a type of deterministic chaos (irregularity) called Homoclinic Chaos in some applications of the Science of Engineering and mechanics as, for example, the Robotics and the Theory of Control (Chaotic Control of Bifurcations so on). For that purpose, the Theory of Poincaré - Mel¿nikov is used that supplies an analytical form for the determination of the type of the system behavior of the system (regular or irregular) / Doutorado / Mecanica dos Sólidos e Projeto Mecanico / Doutor em Engenharia Mecânica