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Effects of Charge-Transfer Excitons on the Photophysics of Organic SemiconductorsHestand, Nicholas James January 2017 (has links)
The field of organic electronics has received considerable attention over the past several years due to the promise of novel electronic materials that are cheap, flexible and light weight. While some devices based on organic materials have already emerged on the market (e.g. organic light emitting diodes), a deeper understanding of the excited states within the condensed phase is necessary both to improve current commercial products and to develop new materials for applications that are currently in the commercial pipeline (e.g. organic photovoltaics, wearable displays, and field effect transistors). To this end, a model for pi-conjugated molecular aggregates and crystals is developed and analyzed. The model considers two types of electronic excitations, namely Frenkel and charge-transfer excitons, both of which play a prominent role in determining the nature of the excited states within tightly-packed organic systems. The former consist of an electron-hole pair bound to the same molecule while in the later the electron and hole are located on different molecules. The model also considers the important nuclear reorganization that occurs when the system switches between electronic states. This is achieved using a Holstein-style Hamiltonian that includes linear vibronic coupling of the electronic states to the nuclear motion associated with the high frequency vinyl-stretching and ring-breathing modes. Analysis of the model reveals spectroscopic signatures of charge-transfer mediated J- and H-aggregation in systems where the photophysical properties are determined primarily by charge-transfer interactions. Importantly, such signatures are found to be sensitive to the relative phase of the intermolecular electron and hole transfer integrals, and the relative energy of the Frenkel and charge-transfer states. When the charge-transfer integrals are in phase and the energy of the charge-transfer state is higher than the Frenkel state, the system exhibits J-aggregate characteristics including a positive band curvature, a red shifted main absorption peak, and an increase in the ratio of the first two vibronic peaks relative to the monomer. On the other hand, when the charge-transfer integrals are out of phase and the energy of the charge-transfer state is higher than the Frenkel state, the system exhibits H-aggregate characteristics including a negative band curvature, a blue shifted main absorption peak, and a decrease in the ratio of the first two vibronic peaks relative to the monomer. Notably, these signatures are consistent with those exhibited by Coulombically coupled J- and H-aggregates. Additional signatures of charge-transfer J- and H-aggregation are also discovered, the most notable of which is the appearance of a second absorption band when the charge-transfer integrals are in phase and the charge-transfer and Frenkel excitons are near resonance. In such instances, the peak-to-peak spacing is found to be proportional to the sum of the electron and hole transfer integrals. Further analysis of the charge-transfer interactions within the context of an effective Frenkel exciton coupling reveals that the charge-transfer interactions interfere directly with the intermolecular Coulombic coupling. The interference can be either constructive or destructive resulting in either enhanced or suppressed J- or H- aggregate behavior relative to what is expected based on Coulombic coupling alone. Such interferences result in four new aggregate types, namely HH-, HJ-, JH-, and JJ-aggregates, where the first letter indicates the nature of the Coulombic coupling and the second indicates the nature of the charge-transfer coupling. Vibronic signatures of such aggregates are developed and provide a means by which to rapidly screen materials for certain electronic characteristics. Notably, a large total (Coulombic plus charge-transfer) exciton coupling is associated with an absorption spectrum in which the ratio of the first two vibronic peaks deviates significantly from that of the unaggregated monomer. Hence, strongly coupled, high exciton mobility aggregates can be readily distinguished from low mobility aggregates by the ratio of their first two vibronic peaks. Analysis of the spatial dependence of the intermolecular interactions reveals that all four aggregate types (HH-, HJ-, JH-, JJ-) can be achieved by enforcing the appropriate crystalline packing arrangement. Such tunability is possible due of the different length scales over which the natures of the two coupling sources interconvert from J-like to H-like; whereas the nature of the Coulombic coupling is known to be sensitive to displacements on the order of half the molecular length, the nature of the charge-transfer mediated exciton coupling is sensitive to geometric displacements of approximately a carbon-carbon bond length. It is proposed that such sensitivity should allow for fine tuning of the total excitonic coupling via modifications in the packing structure, as determined, for example, by the side chains. Several examples of the different aggregate types are provided throughout this dissertation as the model is used to probe the excited state character of several relevant conjugated organic systems. Such examples include pentacene and 7,8,15,16-tetraazaterrylene (TAT) along with several derivatives from the perylene family. / Chemistry
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Electroabsorption spectroscopy of quasi-one-dimensional organic molecular crystalsGuo, Wenge 13 March 2004 (has links) (PDF)
We have presented a thorough experimental investigation of electroabsorption spectroscopy on quasi-one-dimensional organic molecular crystals such as PTCDA and MePTCDI vapor deposited thin films to clarify the involvement of the charge-transfer exciton in the lowest excited state. By a self-built experimental setup, two kinds of electroabsorption measurements, called "perpendicular" and "parallel" measurements, were conducted at room temperature in ambient air. The crystalline texture of PTCDA and MePTCDI thin film samples are characterized by X-ray diffraction measurements. Current-voltage, capacitance-frequency and capacitance-voltage measurements are performed to clarify the electric field distribution inside organic layers. The results from electrical measurements show that only under certain conditions (electroabsorption measurements with proDC bias), the perpendicular and parallel electroabsorption meaurements can be directly compared. The electroabsorption spectra of MePTCDI and PTCDA thin films can be interpreted by neither pure Frenkel exciton nor pure charge-transfer exciton model. Essential features of electroabsorption spectra of MePTCDI and PTCDA thin films can be understood by the the mixture of Frenkel and charge-transfer exciton model. However, there is still a discrepancy in the directional properties of electroabsorption signals between experimental results and modle calculations. This small discrepancy suggests that a full interpretation of electroabsorption spectra of quasi-one-dimensional organic molecular crystals needs further experimental and theoretical investigations.
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Electroabsorption spectroscopy of quasi-one-dimensional organic molecular crystalsGuo, Wenge 16 December 2003 (has links)
We have presented a thorough experimental investigation of electroabsorption spectroscopy on quasi-one-dimensional organic molecular crystals such as PTCDA and MePTCDI vapor deposited thin films to clarify the involvement of the charge-transfer exciton in the lowest excited state. By a self-built experimental setup, two kinds of electroabsorption measurements, called "perpendicular" and "parallel" measurements, were conducted at room temperature in ambient air. The crystalline texture of PTCDA and MePTCDI thin film samples are characterized by X-ray diffraction measurements. Current-voltage, capacitance-frequency and capacitance-voltage measurements are performed to clarify the electric field distribution inside organic layers. The results from electrical measurements show that only under certain conditions (electroabsorption measurements with proDC bias), the perpendicular and parallel electroabsorption meaurements can be directly compared. The electroabsorption spectra of MePTCDI and PTCDA thin films can be interpreted by neither pure Frenkel exciton nor pure charge-transfer exciton model. Essential features of electroabsorption spectra of MePTCDI and PTCDA thin films can be understood by the the mixture of Frenkel and charge-transfer exciton model. However, there is still a discrepancy in the directional properties of electroabsorption signals between experimental results and modle calculations. This small discrepancy suggests that a full interpretation of electroabsorption spectra of quasi-one-dimensional organic molecular crystals needs further experimental and theoretical investigations.
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Oligothiophene Materials for Organic Solar Cells - Photophysics and Device Properties / Oligothiophenmoleküle für Organische Solarzellen - Photophysik und SolarzelleigenschaftenKörner, Christian 25 September 2013 (has links) (PDF)
The rapidly increasing power conversion efficiencies (PCEs) of organic solar cells (OSCs) above 10% were made possible by concerted international research activities in the last few years, aiming to understand the processes that lead to the generation of free charge carriers following photon absorption. Despite these efforts, many details are still unknown, especially how these processes can be improved already at the drawing board of molecular design. To unveil this information, dicyanovinyl end-capped oligothiophene derivatives (DCVnTs) are used as a model system in this thesis, allowing to investigate the impact of small structural changes on the molecular properties and the final solar cells.
On thin films of a methylated DCV4T derivative, the influence of the measurement temperature on the charge carrier generation process is investigated. The observed temperature activation in photoinduced absorption (PIA) measurements is attributed to an increased charge carrier mobility, increasing the distance between the charges at the donor/acceptor (D/A) interface and, thus, facilitating their final dissociation. The correlation between the activation energy and the mobility is confirmed using a DCV6T derivative with lower mobility , exhibiting a higher activation energy for charge carrier generation.
Another parameter to influence the charge carrier generation process is the molecular structure. Here, alkyl side chains with varying length are introduced and their influence on the intramolecular energy levels as well as the absorption and emission properties in pristine and blend films with the acceptor C60 are examined. The observed differences in intermolecular order (higher order for shorter side chains) and phase separation in blend layers (larger phase separation for shorter side chains) are confirmed in PIA measurements upon comparing the temperature dependence of the triplet exciton lifetimes. A proposed correlation between the side chain length and the coupling between D and A, which is crucial for efficient charge transfer, is not confirmed. The presented flat heterojunction solar cells underline this conclusion, giving similar photocurrent densities for all compounds. Differences in PCE are related to shifts of the energy levels and the morphology of the blend layer in bulk heterojunction devices.
Furthermore, the impact of the electric field on the charge carrier generation yield is investigated in a proof-of-principle study, introducing PIA measurements in transmission geometry realized using semitransparent solar cells. The recombination analysis of the photogenerated charge carriers reveals two recombination components. Trapped charge carriers or bound charge pairs at the D/A interface are proposed as an explanation for this result. The miscibility of D and A, which can be influenced by heating the substrate during layer deposition, is of crucial importance to obtain high PCEs. In this work, the unusual negative influence of the substrate temperature on DCV4T:C60 blend layers in solar cells is investigated. By using optical measurements and structure determination tools, a rearrangement of the DCV4T crystallites is found to be responsible for the reduced absorption and, therefore, photocurrent at higher substrate temperature. The proposed blend morphology at a substrate temperature of 90° C is characterized by a nearly complete demixing of the D and A phases. This investigation is of particular relevance, because it shows the microscopic origins of a behavior that is contrary to the increase of the PCE upon substrate heating usually reported in literature.
Finally, the optimization steps to achieve a record PCE of 7.7% using a DCV5T derivative as donor material are presented, including the optimization of the substrate temperature, the active layer thickness, and the transport layers. / Der rasante Anstieg des Wirkungsgrads von organischen Solarzellen über die Marke von 10% war nur durch länderübergreifende Forschungsaktivitäten während der letzten Jahre möglich. Trotz der gemeinsamen Anstrengungen, die Prozesse, die zwischen der Absorption der Photonen und der Ladungsträgererzeugung liegen, genauer zu verstehen, sind einige Fragen jedoch immer noch ungelöst, z.B. wie diese Prozesse schon auf dem Reißbrett durch die gezielte Änderung bestimmter Molekülstrukturen optimiert werden können. Um dieses Ziel zu erreichen, werden in dieser Arbeit Dicyanovinyl-substituierte Oligothiophene (DCVnTs) verwendet. Diese Materialien bieten die Möglichkeit, kleine strukturelle Änderungen vorzunehmen, deren Einfluss auf die molekularen und auf die Solarzelleneigenschaften untersucht werden soll.
Der Einfluss der Messtemperatur auf den Prozess der Ladungsträgertrennung wird hier an einer methylierten DCV4T-Verbindung in einer dünnen Schicht untersucht. Die bei photoinduzierter Absorptionsspektroskopie (PIA) beobachtete Aktivierung dieses Prozesses mit zunehmender Temperatur wird auf eine erhöhte Ladungsträgerbeweglichkeit zurückgeführt. Der dadurch erhöhte effektive Abstand der Ladungen an der Grenzfläche zwischen Donator (D) und Akzeptor (A) erleichtert die endgültige Trennung der Ladungsträger. Durch den Vergleich mit einer DCV6T-Verbindung wird der Zusammenhang zwischen der Aktivierungsenergie und der Beweglichkeit bekräftigt. Die kleinere Beweglichkeit äußert sich dabei in einer größeren Aktivierungsenergie.
Darüber hinaus kann der Ladungsträgergenerationsprozess auch von der Molekülstruktur abhängen. In dieser Arbeit wird untersucht, wie sich die Länge von Alkylseitenketten auf die Energieniveaus der Moleküle, aber auch auf die Absorptions- und Lumineszenzeigenschaften der Materialien in reinen und in Mischschichten mit dem Akzeptor C60 äußert. Die ermittelten Unterschiede bezüglich der Molekülordnung (geordneter für kürzere Seitenketten) und der Phasengrößen in Mischschichten (größere Phasen bei kürzerer Kettenlänge) werden in der Untersuchung der Temperaturabhängigkeit der Lebensdauer von Triplettexzitonen mittels PIA-Messungen bestätigt. Für Solarzellen ist von Bedeutung, ob sich die Seitenkettenlänge auf die Wechselwirkung zwischen D und A auswirkt. Der vermutete Zusammenhang wird hier nicht bestätigt. Ein ähnlicher Photostrom für alle untersuchten Verbindungen in Solarzellen mit planaren Heteroübergängen unterstreicht diese Schlussfolgerung. Unterschiede im Wirkungsgrad werden auf Änderungen der Energieniveaus und die Morphologie in Mischschichtsolarzellen zurückgeführt.
Des Weiteren wird in einer Machbarkeitsstudie der Einfluss des elektrischen Felds auf die Generationsausbeute freier Ladungsträger untersucht. Dafür werden halbtransparente Solarzellen verwendet, die es ermöglichen, PIA-Messungen in Transmissionsgeometrie durchzuführen. Als mögliche Erklärung für das Auftreten zweier Rekombinationskomponenten in der Analyse des Rekombinationsverhaltens der durch Licht erzeugten Ladungsträger werden eingefangene Ladungsträger und gebundene Ladungsträgerpaare an der D/A-Grenzfläche genannt. Das Mischverhalten von D und A kann durch ein Heizen des Substrates während des Verdampfungsprozesses eingestellt werden, was von entscheidender Bedeutung für eine weitere Steigerung des Wirkungsgrades ist. Für DCV4T:C60-Mischschichtsolarzellen wird jedoch eine Verschlechterung des Wirkungsgrads zu höheren Substrattemperaturen beobachtet. Durch optische Messungen und Methoden zur Schichtstrukturbestimmung wird dieser Effekt auf eine Umordnung der DCV4T-Kristallite für hohe Substrattemperaturen und die damit verbundene Verringerung der Absorption und damit auch des Photostroms zurückgeführt. Bei einer Substrattemperatur von 90° C sind die D- und A-Komponenten fast vollständig entmischt. Dieses Beispiel ist von besonderer Bedeutung, weil hier die Ursachen für ein Verhalten aufgezeigt werden, das entgegen den Beispielen aus der Literatur eine Abnahme des Wirkungsgrads beim Aufdampfen der aktiven Schicht auf ein geheiztes Substrat zeigt.
Schließlich werden die Optimierungsschritte dargelegt, mit denen Solarzellen mit einer DCV5T-Verbindung als Donatormaterial auf einen Rekordwirkungsgrad von 7,7% gebracht werden. Dabei wird die Substrattemperatur, die Dicke der aktiven Schicht und die Transportschichten angepasst.
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Electronic excited states in quasi- one- dimensional organic solids with strong coupling of Frenkel and charge-transfer excitonsSchmidt, Karin 03 March 2003 (has links)
This work offers a concept to predict and comprehend the electronic excited states in regular aggregates formed of quasi-one-dimensional organic materials. The tight face-to-face stacking of the molecules justifies the idealization of the crystals and clusters as weakly interacting stacks with leading effects taking place within the columnar sub-structures. Thus, the concept of the small radius exciton theory in linear molecular chains was adopted to examine the excitonic states. The excited states are composed of molecular excitations and nearest neighbor charge transfer (CT) excitations. We analyzed the structure and properties of the excited states which result from the coupling of Frenkel and CT excitons of arbitrary strength in finite chains with idealized free ends. With the help of a partially analytical approach to determine the excitonic states of mixed Frenkel CT character by introducing a complex wave vector, two main types of states can be distinguished. The majority of states are bulk states with purely imaginary wavevector. The dispersion relation of these state matches exactly the dispersion relation known from the infinite chain. The internal structure of the excitons in infinite chains is directly transferred to the bulk states in finite chains. TAMM-like surface states belong to the second class of states. Owing to the damping mediated by a a non-vanishing real part of the wavevector, the wave function of the surface states is localized at the outermost molecules. The corresponding decay length is exclusively determined by the parameterization of the coupling and is independent of the system size. It can therefore be assigned as a characteristic quantum length which plays a vital role for the understanding of system-dependent behavior of the states. The number and type of surface states occurring is predicted for any arbitrary coupling situation. The different nature of bulk and surface states leads to distinct quantum confinement effects. Two regimes are distinguished. The first regime, the case of weak confinement, is realized if the chain length is larger than the intrinsic length. Both kinds of states arrange with the system size according to their nature. Derived from the excitonic states of the infinite chain, the bulk states preserve their quasi-particle character in these large systems. Considered as a quasi-particle confined in box, they change their energy with the system size according to the particle-in-a-box picture. The surface states do not react to a change of the chain length at all, since effectively only the outermost molecules contribute to the wavefunction. The second regime holds if the states are strongly confined, i.e., the system is smaller than the intrinsic length. Both types of states give up their typical behavior and adopt similar properties. / Diese Arbeit unterbreitet ein Konzept, um elektronische Anregungszustände in Aggregaten quasi-eindimensionaler organischer Materialien vorherzusagen und zu verstehen. Die dichte Packung der Moleküle rechtfertigt die Idealisierung der Kristalle bzw. Cluster als schwach wechselwirkende Stapel, wobei die führenden Effekte innerhalb der Molekülstapel zu erwarten sind. Zur Beschreibung der exzitonischen Zustände wurde das Konzept der 'small radius'-Exzitonen in linearen Molekülketten angewandt. Die elektronischen Zustände sind dabei aus molekularen (Frenkel) und nächsten Nachbarn 'charge-transfer' (CT) Anregungen zusammengesetzt. Die Struktur und Eigenschaften der Zustände wurden für beliebige Kopplungsstärken zwischen Frenkel- und CT Anregungen in Ketten mit idealisierten freien Enden für beliebiger Längen analysiert. Der entwickelte, überwiegend analytische Zugang, welcher auf der Einführung eines komplexen Wellenvektors beruht, ermöglicht die Unterscheidung zweier grundsätzlicher Zustandstypen. Die Mehrheit der Zustände sind Volumenzustände mit rein imaginärem Wellenvektor. Die zugehörige Dispersionsrelation entspricht exakt der Dispersionsrelation der unendlichen Kette mit äquivalenten Kopplungsverhältnissen. Die interne Struktur der Exzitonen der unendlichen Kette wird auf die Volumenzustände der endlichen Kette direkt übertragen. Der zweite grundlegende Zustandstyp umfaßt Tamm-artige Oberflächenzustände. Aufgrund der durch einen nichtverschwindenden reellen Anteil des Wellenvektors hervorgerufenen Dämpfung sind die Wellenfunktionen der Oberflächenzustände an den Randmolekülen lokalisiert. Die entsprechende Dämpfungslänge ist ausschließlich durch die Parametrisierung der Kopplungen bestimmt und ist somit unabhängig von der Kettenlänge. Sie kann daher als intrinische Quantenlänge interpretiert werden, welche von essentieller Bedeutung für das Verständnis systemgrößenabhängigen Verhaltens ist. Sowohl die Anzahl als auch die Art der Oberflächenzustände kann für jede Kopplungssituation vorhergesagt werden. Die unterschiedliche Natur der Volumen- und Oberflächenzustände führt auf ausgeprägte 'Quantum confinement' Effekte. Zwei Regime sind zu unterscheiden. Im Falle des ersten Regimes, dem schwachen 'Confinement', ist die Kettenlänge größer als die intrinsische Länge. Beide Zustandarten reagieren auf eine Veränderung der Kettenlänge gemäß ihrer Natur. Aufgrund ihrer Verwandschaft mit den Bandzuständen der unendlichen Kette bewahren die Volumenzustände ihren Quasiteilchen-Charakter. Aufgefaßt als Quasiteilchen, erfahren sie in endlichen Systemen eine energetische Verschiebung gemäß dem Potentialtopf-Modell. Oberflächenzustände zeigen keine Reaktion auf veränderte Kettenlängen, da effektiv nur die Randmoleküle zur Wellenfunktion beitragen. Es findet ein Übergang zum zweiten Regime (starkes 'Confinement') statt, sobald die Kettenlänge kleiner als intrinsische Quantenlänge wird. Beide Zustandsarten geben ihr typisches Verhalten auf und werden mit abnehmender Kettenlänge zunehmend ähnlicher.
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Oligothiophene Materials for Organic Solar Cells - Photophysics and Device PropertiesKörner, Christian 18 July 2013 (has links)
The rapidly increasing power conversion efficiencies (PCEs) of organic solar cells (OSCs) above 10% were made possible by concerted international research activities in the last few years, aiming to understand the processes that lead to the generation of free charge carriers following photon absorption. Despite these efforts, many details are still unknown, especially how these processes can be improved already at the drawing board of molecular design. To unveil this information, dicyanovinyl end-capped oligothiophene derivatives (DCVnTs) are used as a model system in this thesis, allowing to investigate the impact of small structural changes on the molecular properties and the final solar cells.
On thin films of a methylated DCV4T derivative, the influence of the measurement temperature on the charge carrier generation process is investigated. The observed temperature activation in photoinduced absorption (PIA) measurements is attributed to an increased charge carrier mobility, increasing the distance between the charges at the donor/acceptor (D/A) interface and, thus, facilitating their final dissociation. The correlation between the activation energy and the mobility is confirmed using a DCV6T derivative with lower mobility , exhibiting a higher activation energy for charge carrier generation.
Another parameter to influence the charge carrier generation process is the molecular structure. Here, alkyl side chains with varying length are introduced and their influence on the intramolecular energy levels as well as the absorption and emission properties in pristine and blend films with the acceptor C60 are examined. The observed differences in intermolecular order (higher order for shorter side chains) and phase separation in blend layers (larger phase separation for shorter side chains) are confirmed in PIA measurements upon comparing the temperature dependence of the triplet exciton lifetimes. A proposed correlation between the side chain length and the coupling between D and A, which is crucial for efficient charge transfer, is not confirmed. The presented flat heterojunction solar cells underline this conclusion, giving similar photocurrent densities for all compounds. Differences in PCE are related to shifts of the energy levels and the morphology of the blend layer in bulk heterojunction devices.
Furthermore, the impact of the electric field on the charge carrier generation yield is investigated in a proof-of-principle study, introducing PIA measurements in transmission geometry realized using semitransparent solar cells. The recombination analysis of the photogenerated charge carriers reveals two recombination components. Trapped charge carriers or bound charge pairs at the D/A interface are proposed as an explanation for this result. The miscibility of D and A, which can be influenced by heating the substrate during layer deposition, is of crucial importance to obtain high PCEs. In this work, the unusual negative influence of the substrate temperature on DCV4T:C60 blend layers in solar cells is investigated. By using optical measurements and structure determination tools, a rearrangement of the DCV4T crystallites is found to be responsible for the reduced absorption and, therefore, photocurrent at higher substrate temperature. The proposed blend morphology at a substrate temperature of 90° C is characterized by a nearly complete demixing of the D and A phases. This investigation is of particular relevance, because it shows the microscopic origins of a behavior that is contrary to the increase of the PCE upon substrate heating usually reported in literature.
Finally, the optimization steps to achieve a record PCE of 7.7% using a DCV5T derivative as donor material are presented, including the optimization of the substrate temperature, the active layer thickness, and the transport layers.:Abstract - Kurzfassung
Publications
Contents
1 Introduction
2 Elementary Processes in Organic Semiconductors
2.1 Introduction
2.2 Optical Excitations in Organic Materials
2.2.1 Introduction
2.2.2 Radiative Processes: Absorption and Emission
2.2.3 Non-radiative Relaxation Processes
2.2.4 Triplet Excitons and Intersystem Crossing
2.3 Polarization Effects and Disorder
2.4 Transport Processes in Disordered Organic Materials
2.4.1 Charge Transport
2.4.1.1 The Bässler Model
2.4.1.2 Marcus Theory for Electron Transfer
2.4.1.3 Small Polaron Model
2.4.1.4 Functional Dependencies of the Charge Carrier Mobility
2.4.2 Diffusive Motion
2.4.3 Exciton Transfer Mechanisms
2.4.4 Characteristics of Exciton Diffusion
2.5 Charge Photogeneration in Pristine Materials
3 Organic Photovoltaics
3.1 General Introduction to Solar Cell Physics
3.2 Introduction to the Donor/Acceptor Heterojunction Concept
3.3 The Open-Circuit Voltage in Organic Solar Cells
3.4 Doping of Organic Semiconductors
3.5 Introduction to the p-i-n Concept
3.6 Charge Transfer Excitons in Donor/Acceptor Heterojunction Systems
3.6.1 Introduction
3.6.2 Verification of Charge Transfer Excitons in Donor/Acceptor Systems
3.7 The Process Cascade for Free Charge Carrier Generation in Donor/Acceptor
Heterojunction Systems
3.7.1 The Initial Charge Transfer Step
3.7.2 The Binding Energy of the Charge Transfer Exciton
3.7.3 \"Hot\" Charge Transfer Exciton Dissociation
3.7.4 \"Cold\" Charge Transfer Exciton Dissociation
3.7.5 Supposed Influence Factors on Charge Transfer Exciton Dissociation
3.7.6 Recombination Pathways for Charge Transfer Excitons
3.7.7 Free Charge Carrier Formation and Recombination
4 Experimental Methods
4.1 Sample Preparation
4.2 Material Characterization Methods
4.2.1 Optical Characterization
4.2.2 Cyclic Voltammetry
4.2.3 Ultraviolet Photoelectron Spectroscopy
4.2.4 Atomic Force Microscopy
4.2.5 Grazing Incidence X-Ray Diffraction
4.2.6 Organic Field-Effect Transistor
4.3 Photoinduced Absorption Spectroscopy
4.3.1 Introduction
4.3.2 Derivation of the PIA Signal
4.3.3 Recombination Dynamics
4.3.4 Intensity Dependence of the PIA Signal
4.4 Solar Cell Characterization
4.4.1 External Quantum Efficiency
4.4.2 Spectral Mismatch Correction
4.4.3 Current-Voltage Characteristics
4.4.4 Optical Device Simulations
4.4.5 Optical Device Transmission Measurements
5 The Oligothiophene Material System
5.1 Introduction
5.2 Thermal Stability
5.3 Energy Levels
5.4 Optical Properties of the Pristine Materials
5.5 The Donor/Acceptor Couple: DCVnT and C60
5.6 Solar Cell Devices
5.7 Summary
6 Temperature Dependence of Charge Carrier Generation
6.1 Introduction
6.2 Principal Introduction to the PIA Measurements
6.2.1 Interpretation of the Spectra
6.2.2 Interpretation of the Frequency Scans
6.3 Temperature Dependence of the Spectra
6.4 Discussion of the Temperature Dependent Processes in the Blend Layer
6.5 Temperature Activated Free Charge Carrier Generation
6.5.1 Evaluation of the Activation Energy for the DCV4T-Me:C60 Blend
6.5.2 Comparison to a Sexithiophene Derivative (DCV6T-Me)
6.6 Summary
7 Side Chain Investigation on Quaterthiophene Derivatives
7.1 Energy Levels
7.2 Optical Properties
7.2.1 Solution and Pristine Films
7.2.2 Mixed Films with C60
7.3 Influence of the Side Chain Length on the Intermolecular Coupling
7.3.1 PIA Spectra of Pristine and Blend Layers at 10K
7.3.2 Recombination Analysis for Pristine and Blend Films at 10K
7.4 The Influence of the Side Chain Length on the Offset Charge Carrier Generation
Rate at Low Temperature
7.5 In the High-Temperature Limit: Implications for Solar Cell Devices
7.5.1 PIA Spectra in Pristine and Blend Films at 200K
7.5.2 Recombination Analysis: Triplet Excitons and Free Charge Carriers
7.6 Solar Cells
7.6.1 Flat Heterojunction Devices
7.6.2 Bulk Heterojunction Devices
7.7 Summary
8 Electric-Field Dependent PIA Measurements on Complete Solar Cell Devices
8.1 Introduction
8.2 Semitransparent Organic Solar Cells
8.3 Photoinduced Absorption Measurements
8.4 Summary and Outlook
9 The Effect of Substrate Heating During Layer Deposition on the Performance of
DCV4T:C60 BHJ Solar Cells
9.1 Introduction
9.2 The Importance of Morphology Control for BHJ Solar Cells
9.3 The Impact of Substrate Heating on DCV4T:C60 BHJ Solar Cells
9.4 Absorption and Photoluminescence
9.5 Topographical Investigations (AFM)
9.6 X-ray Investigations
9.6.1 1D GIXRD Measurements
9.6.2 2D GIXRD Measurements
9.7 Proposed Morphological Picture and Confirmation Measurements
9.7.1 Morphology Sketch of the DCV4T:C60 Blend Layer
9.7.2 Confirmation Measurements
9.8 The Equivalence of Temperature and Time
9.9 Summary
10 Record Solar Cells Using DCV5T-Me33 as Donor Material
10.1 Introduction
10.2 The Influence of the Substrate Temperature
10.3 Determination of the Optical Constants
10.4 Stack Optimization
10.5 Summary and Outlook
11 Conclusions and Outlook
11.1 Summary of the Photophysical Investigations
11.2 Summary of Device Investigations
11.3 Future Challenges
Appendix A Detailed Description of the Experimental Setup for PIA Spectroscopy
Appendix B Determination of the Triplet Level by Differential PL Measurements
Appendix C Additional Tables and Figures
Appendix D Reproducibility of the Solar Cell Results (Statistics)
Appendix E Lists
Bibliography
Acknowledgments / Der rasante Anstieg des Wirkungsgrads von organischen Solarzellen über die Marke von 10% war nur durch länderübergreifende Forschungsaktivitäten während der letzten Jahre möglich. Trotz der gemeinsamen Anstrengungen, die Prozesse, die zwischen der Absorption der Photonen und der Ladungsträgererzeugung liegen, genauer zu verstehen, sind einige Fragen jedoch immer noch ungelöst, z.B. wie diese Prozesse schon auf dem Reißbrett durch die gezielte Änderung bestimmter Molekülstrukturen optimiert werden können. Um dieses Ziel zu erreichen, werden in dieser Arbeit Dicyanovinyl-substituierte Oligothiophene (DCVnTs) verwendet. Diese Materialien bieten die Möglichkeit, kleine strukturelle Änderungen vorzunehmen, deren Einfluss auf die molekularen und auf die Solarzelleneigenschaften untersucht werden soll.
Der Einfluss der Messtemperatur auf den Prozess der Ladungsträgertrennung wird hier an einer methylierten DCV4T-Verbindung in einer dünnen Schicht untersucht. Die bei photoinduzierter Absorptionsspektroskopie (PIA) beobachtete Aktivierung dieses Prozesses mit zunehmender Temperatur wird auf eine erhöhte Ladungsträgerbeweglichkeit zurückgeführt. Der dadurch erhöhte effektive Abstand der Ladungen an der Grenzfläche zwischen Donator (D) und Akzeptor (A) erleichtert die endgültige Trennung der Ladungsträger. Durch den Vergleich mit einer DCV6T-Verbindung wird der Zusammenhang zwischen der Aktivierungsenergie und der Beweglichkeit bekräftigt. Die kleinere Beweglichkeit äußert sich dabei in einer größeren Aktivierungsenergie.
Darüber hinaus kann der Ladungsträgergenerationsprozess auch von der Molekülstruktur abhängen. In dieser Arbeit wird untersucht, wie sich die Länge von Alkylseitenketten auf die Energieniveaus der Moleküle, aber auch auf die Absorptions- und Lumineszenzeigenschaften der Materialien in reinen und in Mischschichten mit dem Akzeptor C60 äußert. Die ermittelten Unterschiede bezüglich der Molekülordnung (geordneter für kürzere Seitenketten) und der Phasengrößen in Mischschichten (größere Phasen bei kürzerer Kettenlänge) werden in der Untersuchung der Temperaturabhängigkeit der Lebensdauer von Triplettexzitonen mittels PIA-Messungen bestätigt. Für Solarzellen ist von Bedeutung, ob sich die Seitenkettenlänge auf die Wechselwirkung zwischen D und A auswirkt. Der vermutete Zusammenhang wird hier nicht bestätigt. Ein ähnlicher Photostrom für alle untersuchten Verbindungen in Solarzellen mit planaren Heteroübergängen unterstreicht diese Schlussfolgerung. Unterschiede im Wirkungsgrad werden auf Änderungen der Energieniveaus und die Morphologie in Mischschichtsolarzellen zurückgeführt.
Des Weiteren wird in einer Machbarkeitsstudie der Einfluss des elektrischen Felds auf die Generationsausbeute freier Ladungsträger untersucht. Dafür werden halbtransparente Solarzellen verwendet, die es ermöglichen, PIA-Messungen in Transmissionsgeometrie durchzuführen. Als mögliche Erklärung für das Auftreten zweier Rekombinationskomponenten in der Analyse des Rekombinationsverhaltens der durch Licht erzeugten Ladungsträger werden eingefangene Ladungsträger und gebundene Ladungsträgerpaare an der D/A-Grenzfläche genannt. Das Mischverhalten von D und A kann durch ein Heizen des Substrates während des Verdampfungsprozesses eingestellt werden, was von entscheidender Bedeutung für eine weitere Steigerung des Wirkungsgrades ist. Für DCV4T:C60-Mischschichtsolarzellen wird jedoch eine Verschlechterung des Wirkungsgrads zu höheren Substrattemperaturen beobachtet. Durch optische Messungen und Methoden zur Schichtstrukturbestimmung wird dieser Effekt auf eine Umordnung der DCV4T-Kristallite für hohe Substrattemperaturen und die damit verbundene Verringerung der Absorption und damit auch des Photostroms zurückgeführt. Bei einer Substrattemperatur von 90° C sind die D- und A-Komponenten fast vollständig entmischt. Dieses Beispiel ist von besonderer Bedeutung, weil hier die Ursachen für ein Verhalten aufgezeigt werden, das entgegen den Beispielen aus der Literatur eine Abnahme des Wirkungsgrads beim Aufdampfen der aktiven Schicht auf ein geheiztes Substrat zeigt.
Schließlich werden die Optimierungsschritte dargelegt, mit denen Solarzellen mit einer DCV5T-Verbindung als Donatormaterial auf einen Rekordwirkungsgrad von 7,7% gebracht werden. Dabei wird die Substrattemperatur, die Dicke der aktiven Schicht und die Transportschichten angepasst.:Abstract - Kurzfassung
Publications
Contents
1 Introduction
2 Elementary Processes in Organic Semiconductors
2.1 Introduction
2.2 Optical Excitations in Organic Materials
2.2.1 Introduction
2.2.2 Radiative Processes: Absorption and Emission
2.2.3 Non-radiative Relaxation Processes
2.2.4 Triplet Excitons and Intersystem Crossing
2.3 Polarization Effects and Disorder
2.4 Transport Processes in Disordered Organic Materials
2.4.1 Charge Transport
2.4.1.1 The Bässler Model
2.4.1.2 Marcus Theory for Electron Transfer
2.4.1.3 Small Polaron Model
2.4.1.4 Functional Dependencies of the Charge Carrier Mobility
2.4.2 Diffusive Motion
2.4.3 Exciton Transfer Mechanisms
2.4.4 Characteristics of Exciton Diffusion
2.5 Charge Photogeneration in Pristine Materials
3 Organic Photovoltaics
3.1 General Introduction to Solar Cell Physics
3.2 Introduction to the Donor/Acceptor Heterojunction Concept
3.3 The Open-Circuit Voltage in Organic Solar Cells
3.4 Doping of Organic Semiconductors
3.5 Introduction to the p-i-n Concept
3.6 Charge Transfer Excitons in Donor/Acceptor Heterojunction Systems
3.6.1 Introduction
3.6.2 Verification of Charge Transfer Excitons in Donor/Acceptor Systems
3.7 The Process Cascade for Free Charge Carrier Generation in Donor/Acceptor
Heterojunction Systems
3.7.1 The Initial Charge Transfer Step
3.7.2 The Binding Energy of the Charge Transfer Exciton
3.7.3 \"Hot\" Charge Transfer Exciton Dissociation
3.7.4 \"Cold\" Charge Transfer Exciton Dissociation
3.7.5 Supposed Influence Factors on Charge Transfer Exciton Dissociation
3.7.6 Recombination Pathways for Charge Transfer Excitons
3.7.7 Free Charge Carrier Formation and Recombination
4 Experimental Methods
4.1 Sample Preparation
4.2 Material Characterization Methods
4.2.1 Optical Characterization
4.2.2 Cyclic Voltammetry
4.2.3 Ultraviolet Photoelectron Spectroscopy
4.2.4 Atomic Force Microscopy
4.2.5 Grazing Incidence X-Ray Diffraction
4.2.6 Organic Field-Effect Transistor
4.3 Photoinduced Absorption Spectroscopy
4.3.1 Introduction
4.3.2 Derivation of the PIA Signal
4.3.3 Recombination Dynamics
4.3.4 Intensity Dependence of the PIA Signal
4.4 Solar Cell Characterization
4.4.1 External Quantum Efficiency
4.4.2 Spectral Mismatch Correction
4.4.3 Current-Voltage Characteristics
4.4.4 Optical Device Simulations
4.4.5 Optical Device Transmission Measurements
5 The Oligothiophene Material System
5.1 Introduction
5.2 Thermal Stability
5.3 Energy Levels
5.4 Optical Properties of the Pristine Materials
5.5 The Donor/Acceptor Couple: DCVnT and C60
5.6 Solar Cell Devices
5.7 Summary
6 Temperature Dependence of Charge Carrier Generation
6.1 Introduction
6.2 Principal Introduction to the PIA Measurements
6.2.1 Interpretation of the Spectra
6.2.2 Interpretation of the Frequency Scans
6.3 Temperature Dependence of the Spectra
6.4 Discussion of the Temperature Dependent Processes in the Blend Layer
6.5 Temperature Activated Free Charge Carrier Generation
6.5.1 Evaluation of the Activation Energy for the DCV4T-Me:C60 Blend
6.5.2 Comparison to a Sexithiophene Derivative (DCV6T-Me)
6.6 Summary
7 Side Chain Investigation on Quaterthiophene Derivatives
7.1 Energy Levels
7.2 Optical Properties
7.2.1 Solution and Pristine Films
7.2.2 Mixed Films with C60
7.3 Influence of the Side Chain Length on the Intermolecular Coupling
7.3.1 PIA Spectra of Pristine and Blend Layers at 10K
7.3.2 Recombination Analysis for Pristine and Blend Films at 10K
7.4 The Influence of the Side Chain Length on the Offset Charge Carrier Generation
Rate at Low Temperature
7.5 In the High-Temperature Limit: Implications for Solar Cell Devices
7.5.1 PIA Spectra in Pristine and Blend Films at 200K
7.5.2 Recombination Analysis: Triplet Excitons and Free Charge Carriers
7.6 Solar Cells
7.6.1 Flat Heterojunction Devices
7.6.2 Bulk Heterojunction Devices
7.7 Summary
8 Electric-Field Dependent PIA Measurements on Complete Solar Cell Devices
8.1 Introduction
8.2 Semitransparent Organic Solar Cells
8.3 Photoinduced Absorption Measurements
8.4 Summary and Outlook
9 The Effect of Substrate Heating During Layer Deposition on the Performance of
DCV4T:C60 BHJ Solar Cells
9.1 Introduction
9.2 The Importance of Morphology Control for BHJ Solar Cells
9.3 The Impact of Substrate Heating on DCV4T:C60 BHJ Solar Cells
9.4 Absorption and Photoluminescence
9.5 Topographical Investigations (AFM)
9.6 X-ray Investigations
9.6.1 1D GIXRD Measurements
9.6.2 2D GIXRD Measurements
9.7 Proposed Morphological Picture and Confirmation Measurements
9.7.1 Morphology Sketch of the DCV4T:C60 Blend Layer
9.7.2 Confirmation Measurements
9.8 The Equivalence of Temperature and Time
9.9 Summary
10 Record Solar Cells Using DCV5T-Me33 as Donor Material
10.1 Introduction
10.2 The Influence of the Substrate Temperature
10.3 Determination of the Optical Constants
10.4 Stack Optimization
10.5 Summary and Outlook
11 Conclusions and Outlook
11.1 Summary of the Photophysical Investigations
11.2 Summary of Device Investigations
11.3 Future Challenges
Appendix A Detailed Description of the Experimental Setup for PIA Spectroscopy
Appendix B Determination of the Triplet Level by Differential PL Measurements
Appendix C Additional Tables and Figures
Appendix D Reproducibility of the Solar Cell Results (Statistics)
Appendix E Lists
Bibliography
Acknowledgments
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