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Geochemical and mineralogical characterization of the Arbuckle aquifer: studying mineral reactions and its implications for CO[subscript]2 sequestrationBarker, Robinson January 1900 (has links)
Master of Science / Department of Geology / Saugata Datta / In response to increasing concerns over release of anthropogenic greenhouse gases the Arbuckle saline aquifer in south-central Kansas has been proposed as a potential site for geologic storage for CO2. Two wells (KGS 1-32 and 1-28) have been drilled to provide data for site specific determination of the storage potential of the Arbuckle. Cores from specific depths within Arbuckle (4164`-5130`) were utilized for study and flow-through experiments. Examination of formation rocks by thin section studies, SEM, XRD and CT scans was carried out to characterize the mineralogy of the core.
Dominant mineralogy throughout the formation is dolomite with large chert nodules and occasional zones with pyrite and argillaceous minerals. Carbonate-silica contacts contain extensive heterogeneity with sulfide minerals and argillaceous material in between. Extensive vugs and microfractures are common. This study focuses on three zones of interest: the Mississippian pay zone (3670`-3700`), a potential baffle in Arbuckle (4400`-4550`) and the proposed CO2 injection zone (4900`-5050`).
Drill stem tests and swabbed brine samples collected from 13 depths throughout the aquifer reveal a saline brine (~50,000-190,000 TDS) dominated by Na+, Ca2+ and Cl-. Elemental ratios of major cations with Cl- demonstrate a typical saline aquifer system. Cl/Br ratios reveal mixing between primary and secondary brines within the aquifer. Ca/Cl and Mg/Cl ratios suggest effect of dolomitization within the brines. δ18O and δ2H isotopes and Li/Cl ratios in the brine suggest the separation of upper and lower Arbuckle by a baffle zone. Swabbed waters provide Fe speciation data and reveal the importance of it in the system.
Laboratory experiments carried out at 40°C and 2100 psi using formation core plug and collected brine identify reaction pathways to be anticipated when supercritical CO2 is injected. Results showed fluctuating chemistries of elements with Ca2+, Mg2+, Na+ and Cl- increasing during the first 15 hours, while Fe, S, and SO42- decrease. For the next 15 hours a reverse trend of the same elements were observed. Alkalinity and pH show inverse relationship throughout the experiment. We conclude that dominant reactions will occur between brine, CO2 and dolomite, calcite, chert, pyrite and argillaceous minerals. There is no perceived threat to freshwater resources in Kansas due to CO2 injection.
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Perceptions of climate and environmental change in Northcentral KansasWilson, Iris E. January 1900 (has links)
Master of Arts / Department of Geography / John A. Harrington Jr / Global and regional climates have changed significantly in recent decades. One of the sectors most affected by a changing climate is agriculture. While the scientific consensus is clear that climate has changed, a declining number of Americans believe in the seriousness of “global warming”. Bridging this knowledge gap will require a more in depth understanding of public perceptions of climate change. The research reported here addressed public perceptions of climate and environmental change in north central Kansas and found that farmers are aware that climate has changed over their lifetimes. Local residents were found to be aware on ongoing environmental changes and adopting changes in land management practices that balance improving environmental conditions with the need to make a profit. More information is needed on what information sources and presentation styles would work best for the communication of updated information, both for communicating with farmers and with educators.
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Climate classification for the earth's oceanic areas using the KӦppen SystemWalterscheid, Steven K. January 1900 (has links)
Master of Arts / Department of Geography / John A. Harrington Jr / The objective of this thesis is classify climate for the Earth’s ocean areas. The classifica-tion task is accomplished in part by using monthly average sea surface temperature and precipita-tion data from 1980-2008. Coast-to-coast coverage of the needed data were obtained from the reanalysis product produced by the National Centers for Environmental Prediction and the National Center for Atmospheric Research. Köppen’s classification scheme was implemented in the ArcGIS suite of software, which was used to analyze and display all of the classified map products. Russell’s ‘climatic years’ concept was used and separate classifications were produce for each year of available data. Findings indicate that the oceans are very different from land areas when it comes to the location and extent of varying climate types. Some main findings include the idea that A, C, and E climates dominate the geography of the oceans and that there are zero continental, or D, climates. Also, the Southern Oscillation plays an important part in tropical ocean dynamics and climate, but summarizing twenty nine years of mapped patterns into a summary product removes any major effect from yearly climate system anomalies. A key finding is an argument that supports the establishment of a unique Southern Ocean surrounding Antarctica. There are polar, ET and EF, climate subtypes surrounding both the Arctic and Antarctic poles, but only the north has the well established Arctic Ocean. Oceanic E climate areas are more pronounced in the Southern Hemisphere with circumpolar rings around the Antarctic continent. Classification results support the idea of a Southern Ocean based on the spatial pattern of climate types and in view of the fact that that the climate of the Southern Ocean area is so different from the temperate, or C, climate and its subtypes. This research is important for many reasons, the primary being that climate classification helps us better understand the world around us. It is difficult to see change in the environment without first knowing what the state of the system used to be. Classification will also help depict the changes that have happened, when these shifts in climate occurred, and with that information we can better predict what the future will hold.
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Before its time? : a case study and lessons of the Yasuní-ITT initiativeDyar, Joel January 1900 (has links)
Masters in Science / Department of Landscape Architecture/Regional & Community Planning / Stephanie A. Rolley / This case study considers the lessons of Ecuador’s Yasuní-ITT initiative for future climate change policy and international conservation and development efforts. A comprehensive post-cancellation history of the initiative and background information regarding key domestic and international actors and institutions is presented in the Literature Review. Documents identified from LexisNexis and Google searches are analyzed to identify seven narratives of the initiative’s failure, which provide a basis for the suggestion of lessons. Questions regarding supply-side climate policy opportunities and challenges are explored. The initiative’s political mismanagement, design omissions and insufficient domestic political efforts, and a lack of contribution incentives are identified as the key causes of failure. The author concludes that the initiative’s supply-side model of shared sacrifices has the potential to align developed and developing country needs in support of greenhouse gas emissions reduction goals while addressing the difficulties posed by an emergent political economy of developing world resource extractivism in Ecuador and elsewhere. Future research regarding supply-side climate policies is suggested.
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Assessing plans that support urban adaptation to changing climate and extreme events across spatial scalesOmunga, Philip M. January 1900 (has links)
Doctor of Philosophy / Department of Environmental Design and Planning Program / Lee R. Skabelund / Despite the growing number of urban adaptation planning initiatives to climate change hazards, there exist significant barriers related to implementation uncertainties that hinder translation of adaptation plans into actions, resulting in a widely recognized ‘planning-implementation gap’ across scales and regions. Bridging the planning-implementation gap will require overcoming implementation uncertainties by better understanding the relationships between the primary factors driving adaptation planning initiatives and emerging adaptation options across spatial scales.
The modified Driver-Pressure-State-Impact-Response model published by Rounsevell, Dawson, and Harrison in 2010 provided a robust framework for identifying the primary factors driving adaptation planning initiatives and the emerging adaptation options related to risk of changing climate and flooding events in the urban context. Drawing on evidence from the systematic review of 121 adaptation planning case studies across North America, this research derived qualitative and quantitative data, which was subsequently analyzed using binary logistic regression to generate objective and generalizable findings.
The findings of binary logistic regression models suggest that the choice of specific adaptation options (namely enhancing adaptive capacity; management and conservation; and improving urban infrastructure, planning, and development) may be predicted based on the assessment of primary factors driving adaptation planning initiatives (namely, anticipation of economic benefits; perceived threats to management and conservation of urban natural resources; support of human and social systems; and improvement of policy and regulations) in relation to the risk of changing climate and urban flooding events. This does not imply that other primary factors (namely information and knowledge; perceived funding and economic opportunities; evidence of climate change effects; and general concerns) have no or insignificant relationships with the selection of adaptation options, only that the review did not find evidence to support such claims.
These study findings may offer useful guidance to the design and further development of planning and decision support tools that could be used for assessment of adaptation plans and selection of robust adaptation options that take account of uncertainties surrounding implementation of effective climate adaptation actions. Study findings can also inform evidence-based policy and investment decision making, especially in regions where urban adaptation plans are weak or absent.
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Envisioning 3D learning environments in environmental education: an exploration of the Konza PrairieWebb, Natalie January 1900 (has links)
Master of Landscape Architecture / Landscape Architecture/Regional and Community Planning / Howard D. Hahn / “There is an alarming gap between awareness and action on [environmental issues]”
(Sheppard, 2005). Public awareness of how to cope and change with these issues is lacking (Sheppard, 2004; Nicholson-Cole, 2005; Dockerty et al., 2005), but new visualization technologies can begin to bridge the gap through environmental education.
Environmental education focuses on the user exploring an environment, environmental
issues, problem solving and ways to mitigate these issues. While the younger generations (middle to high school students) are much more aware of current and future environmental issues than older generations, the solutions to these problems may not be so apparent. By combining the need to educate young adults about climate change, regional ecosystem climate mitigation, and ecological management for technologically driven youth, middle and high school students can better understand their environment’s impact on climate-change regulation. Through literature synthesis, documentation of existing visualization exhibits and technologies, and preliminary technology exploration, a production process, criteria, framework, and technology recommendations were established. These components informed the final storyboards, which visually organized a proposal to build a 3D learning environment focused on the Konza Prairie and its ecological management practices.
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Restorative urban design: toward a design method for mitigating human impacts on the natural environment through urban re/developmentToros, Tulu January 1900 (has links)
Doctor of Philosophy / Department of Environmental Design & Planning Program / Lee R. Skabelund / The Restorative Urban Design (RUD) calls for a new urban design and planning approach targeting environmentally responsible re/development of urbanized areas through ecologically responsive impact mitigations. If implemented in a systematic manner, such re/developments can help move urban areas toward the successful restoration of the natural environment of which they are an inseparable part.
The RUD model advocates more rigorous assessment and mitigation of urban impacts by carefully evaluating the environmental performance of urban re/developments within five primary dimensions: Atmosphere (emissions, pollutants, ozone depletion); Hydrosphere (stormwater, domestic water, wastewater); Lithosphere (land use, land cover, food and wastes); Ecology (habitat resilience, biodiversity, population and resources); and Energy (renewability, reduction and efficiency, transportation). The model relies on a scenario-comparison process in order to evaluate and optimize the performance of urban re/development projections through four critical scenarios, which are respectively: 1) Natural Baseline (NBASE); 2) Historic Progression (HPROG); 3) Trajectory Forecast (TFORE); and 4) Restorative Projection (RPROJ).
The RUD Case Study illustrates how the principles and strategies of Restorative Urban Design can be applied specifically to a typical (densely developed) urban area, namely River North District in Chicago Metropolitan Area. The case study focuses exclusively on mitigation of a single critical human impact on the natural environment: Anthropogenic CO₂ Emissions. The case study focuses on the design assumptions by which the restorative urban re/development scenarios might exceed beyond the full mitigation of emissions into the global remediation by 2040. The restorative projections illustrate that only a certain portion of emissions can be effectively mitigated onsite (5 to 55%), and that the remainder of projected emissions (45 to 95%) need to be mitigated offsite in order to achieve the necessary sequestration and storage.
The restorative research suggests that the mitigation of major human impacts on the natural environment – not only CO₂ emissions but also other major impacts – are likely to require significant urban transformations. Moving beyond the strategies of preservation and/or conservation, the restorative approach asserts that comprehensive environmental restoration is achievable if urban impacts are adequately estimated and then entirely mitigated onsite as well as offsite through a systematic process of urban re/development.
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