While there are exemplary studies on the relationships between social networks and media such as television and the Internet, less is known about the social network consequences of mobile phone use during life-stage transitions. This study investigates the roles that mobile phones play in supporting the relationships of young people as they transition to and through their first-year of university in Toronto, Canada. Focussing on information practices during a transition that tests the resilience of support networks, this study queried the extent to which mobile phones play a role in keeping relationships intact, enabling students to maintain a sense of social cohesion and belonging. Data were collected from November 2007 to September 2008 through a longitudinal research design. Socio-technical concepts and network analysis techniques were applied to analyze the ways in which mobile communication is embedded in the everyday social life of young people aged 17-34. Set within the culturally-specific context of urban Canada, the data provided substantial evidence that mobile phones foster social cohesion within intimate relations but provide a more tenuous platform from which to nurture new relationships. First-year undergraduates have integrated the mobile phone into the way they engage with their social networks to a considerable degree, with commuter students experiencing additional tensions in negotiating relationships from home and on-campus. Findings showed that mobile phones were the devices of choice to mitigate feelings of loneliness, with deleterious consequences for the development of new relationships. Furthermore, the mobile phone was a key contributor to a rising sense of empowerment and autonomy for young adults as they negotiated identity transformations during their rite of passage into adulthood. Issues of trust and reciprocity in forming new relationships were mediated through a continuum of social media of which the mobile phone was the most intimate. Evidence of continuous access to social networks has broader implications for how mechanisms for coping with being alone and disconnection are acquired in this generation. Finally, observations of ritualistic interaction practices involving mobile phones may be theorized as small-scale evidence of larger societal shifts from collective constructs of community to that of networked individuals.

Magnetic shape memory alloys (MSMAs) are a class of active materials that de- form under magnetic and mechanical loading conditions. This work is concerned with the modeling of MSMAs constitutive responses. The hysteretic magneto-mechanical responses of such materials are governed by two major mechanisms which are variant reorientation and field induced phase transformation (FIPT). The most widely used material for variant reorientation is Ni2 MnGa which can produce up to 6% magnetic field induced strain (MFIS) under 5 MPa actuation stress. The major drawback of this material is a low blocking stress, which is overcome in the NiMnCoIn material system through FIPT. This magnetic alloy can exhibit 5% MFIS under 125 MPa actuation stress. The focus of this work is to capture the key magneto-thermo-mechanical responses of such mechanisms through phenomenological modeling. In this work a detailed thermodynamic framework for the electromagnetic interaction within a continuum solid is presented. A Gibbs free energy function is postulated after identifying the external and internal state variables. Material symmetry restrictions are imposed on the Gibbs free energy and on the evolution equations of the internal state variables. Discrete symmetry is considered for single crystals whereas continuous symmetry is considered for polycrystalline materials. The constitutive equations are derived in a thermodynamically consistent way. A specific form of Gibbs free energy for FIPT is proposed and the explicit form of the constitutive equations is derived from the generalized formulation. The model is calibrated from experimental data and different predictions of magneto-thermo-mechanical loading conditions are presented. The generalized constitutive equations are then reduced to capture variant reorientation. A coupled magneto-mechanical boundary value problem (BVP) is solved that accounts for variant reorientation to investigate the influence of the demagnetization effect on the magnetic field and the effect of Maxwell stress on the Cauchy stress. The BVP, which mimics a real experiment, provides a methodology to correlate the difference between the externally measured magnetic data and internal magnetic field of the specimen due to the demagnetization effect. The numerical results show that localization zones appear inside the material between a certain ranges of applied magnetic field. Stability analysis is performed for variant reorientation to analyze these numerical observations. Detailed numerical and analytical analysis is presented to investigate these localization zones. Magnetostatic stability analysis reveals that the MSMA material system becomes unstable when localizations appear due to non-linear magnetization response. Coupled magneto-mechanical stability analysis shows that magnetically induced localization creates stress-localizations in the unstable zones. A parametric study is performed to show the constraints on material parameters for stable and unstable material responses.

In an automotive crash event, hot stamped, die quenched martensitic structural components have been shown to provide excellent intrusion resistance. These alloys exhibit only limited ductility, however, which may limit the overall impact performance of the component. The introduction of lower strength and more ductile “tailored” properties within some regions of a hot stamped component has the potential to improve impact performance. One approach being applied to achieving such tailored properties is through locally controlling the cooling rate within the stamping die. The primary motivation for the current work is to understand the role of cooling rate on the as-quenched mechanical response of tailored hot stampings, which has required characterization of the high strain rate mechanical behaviour of tailored hot stamped boron steel. The effect of cooling rate and resulting microstructure on the as-quenched mechanical behavior of USIBOR® 1500P boron steel at strain rates between 10-3 and 103 s-1 was investigated. Specimens quenched at rates above the critical cooling rate (~27 °C/s) exhibited a fully martensitic microstructure with a UTS of ~1,450 MPa. Sub-critical cooling rates, in the range 14°C/s to 50 °C/s, resulted in as-quenched microstructures ranging between bainitic to martensitic, respectively. Tension tests revealed that predominantly bainitic material conditions (14 °C/s cooling rate) exhibited a lower UTS of 816 MPa compared to 1,447 MPa for the fully martensitic material condition (50 °C/s cooling rate) with a corresponding increase in elongation from 0.10 to 0.15 for the bainitic condition. The reduction in area was 70% for the bainitic material condition and 58% for the martensitic material conditions which implied that a tailored region consisting of bainite may be a desirable candidate for implementation within a hot stamped component. The strain rate sensitivity was shown to be moderate for all of the as-quenched material conditions and the measured flow stress curves were used to develop a strain rate sensitive constitutive model, the “Tailored Crash Model (TCM)”. The TCM accurately reproduced the measured flow stress curves as a function of effective plastic strain, strain rate and Vickers hardness (or area fraction of martensite and bainite). The effect of deformation during quenching and the associated shift in the CCT diagram on the subsequent constitutive response was also examined for this material. Specimens were simultaneously quenched and deformed at various cooling rates to achieve a range of as-quenched microstructures that included ferrite in addition to martensite and bainite. Tensile tests conducted on these specimens at strain rates ranging from 0.003 s-1 to ~80 s-1 revealed that the presence of ferrite resulted in an increase in uniform elongation and n-value which increased overall energy absorption for a given hardness level. The strain rate sensitivity was shown to be moderate for all of the as-quenched material conditions and the TCM constitutive model was extended to account for the presence of ferrite. This extended constitutive model, the “Tailored Crash Model II (TCM II)”, has been shown to predict flow stress as a function of effective plastic strain, strain rate and area fraction of martensite, bainite and ferrite. As a validation exercise, uniaxial tension test simulations of specimens extracted from the transition zone of a hot stamped lab-scale B-pillar with tailored properties [1] were performed. The measured hardness distribution along the gauge length of the tensile specimens was used as input for the TCM constitutive model to define the element constitutive response used in the finite element (FE) models. The measured stress versus strain response and strain distribution during loading (measured using digital image correlation) was in excellent agreement with the FE models and thus validated the TCM constitutive model developed in this work. Validation of the TCM II version of the model is left for future work.

While there are exemplary studies on the relationships between social networks and media such as television and the Internet, less is known about the social network consequences of mobile phone use during life-stage transitions. This study investigates the roles that mobile phones play in supporting the relationships of young people as they transition to and through their first-year of university in Toronto, Canada. Focussing on information practices during a transition that tests the resilience of support networks, this study queried the extent to which mobile phones play a role in keeping relationships intact, enabling students to maintain a sense of social cohesion and belonging. Data were collected from November 2007 to September 2008 through a longitudinal research design. Socio-technical concepts and network analysis techniques were applied to analyze the ways in which mobile communication is embedded in the everyday social life of young people aged 17-34. Set within the culturally-specific context of urban Canada, the data provided substantial evidence that mobile phones foster social cohesion within intimate relations but provide a more tenuous platform from which to nurture new relationships. First-year undergraduates have integrated the mobile phone into the way they engage with their social networks to a considerable degree, with commuter students experiencing additional tensions in negotiating relationships from home and on-campus. Findings showed that mobile phones were the devices of choice to mitigate feelings of loneliness, with deleterious consequences for the development of new relationships. Furthermore, the mobile phone was a key contributor to a rising sense of empowerment and autonomy for young adults as they negotiated identity transformations during their rite of passage into adulthood. Issues of trust and reciprocity in forming new relationships were mediated through a continuum of social media of which the mobile phone was the most intimate. Evidence of continuous access to social networks has broader implications for how mechanisms for coping with being alone and disconnection are acquired in this generation. Finally, observations of ritualistic interaction practices involving mobile phones may be theorized as small-scale evidence of larger societal shifts from collective constructs of community to that of networked individuals.

No description available.

As explosive blasts continue to cause casualties in both civil and military environments, there is a need for increased understanding of the mechanisms of blast trauma at the organ level and a need for a more detailed predictive methodology. A fundamental understanding of blast injury will lead to the development of improved protective equipment and ultimately reduce the severity of injury. Models capable of predicting injury to varied blast loading will also reduce the emphasis on animal blast testing. To provide some historical context, this research was begun shortly after the U.S. led invasion of Iraq, and came to a close while there continues to be daily loss of life from blast injuries in the Middle East, as well as continued threats of terrorism throughout the world. In addition to industrial accidents, it is clear that blast injury is far more than just a military concern. Simplified finite element models of the human and sheep thoraces were created in order to provide practical and flexible models for the prediction of primary blast injury in simple and complex blast environments, and subsequently for the development of improved protective equipment. The models were created based on actual human and sheep geometries and published material properties. The fluid-structure interaction of the models compared well with experimental blast studies carried out during the course of the research, as shown by comparing actual and predicted overpressures in the free field and at the thorax. By comparing the models to published experimental data from simple blasts, trends in the results were verified and peak lung pressure was proposed as a trauma criterion. Local extent of injury in the lung is correlated to the peak pressure measured in each finite element, categorized as no injury (< 60 kPa), trace (60-100 kPa), slight (100-140 kPa), moderate (140-240 kPa) and severe (> 240 kPa). The calculation of the mean value of the peak lung pressures of all of the finite elements allows for an overall estimate of the injury level, with 35 kPa predicting threshold damage, 129 kPa for one percent lethality, and 186 kPa for fifty percent lethality. The simple blast results also compared well to the predictions of two previously validated mathematical models. Variation of predicted injury within a given loading severity was 15%, which is comparable to the model by Stuhmiller that had a variation of 20%. The model by Axelsson had very little variation (1.4%), but the differences between levels of severity were quite small, and often difficult to decipher. In addition to predicting consistent levels of injury, the finite element models were able to provide insight into the trauma mechanism, map the extent of injury through the lungs, and validate a local injury criterion. The models were then applied to predict injury under complex blast loading by subjecting the human finite element torso to a threshold level blast while located at varying distances from a wall or a corner. The results compared well to the validated mathematical models, showing a sharp increase in injury severity as the model approached the reflecting surface. When directly against the wall, the mean of the peak lung pressure values was 57 kPa, and in the corner, the mean value reached 69 kPa. Although these values did not reach the level representing one percent lethality, they do represent a significant increase in injury above threshold as a direct result of the surrounding geometry. Once again, the finite element models correctly showed injury trends and lung injury patterns reported in experiments. The models predicted the level of injury and were able to predict the time varying pattern of injury, which is something existing models cannot do. Having designed the models from physical principals, and having validated the models against published results, they can now be used in the continued development of protective equipment. Acknowledging that this model was the first iteration, the author believes that improvements in material properties, mesh refinement, and the investigation of other possible parameters for the prediction of injury will lead to substantial advances in the understanding of primary blast injury.

As explosive blasts continue to cause casualties in both civil and military environments, there is a need for increased understanding of the mechanisms of blast trauma at the organ level and a need for a more detailed predictive methodology. A fundamental understanding of blast injury will lead to the development of improved protective equipment and ultimately reduce the severity of injury. Models capable of predicting injury to varied blast loading will also reduce the emphasis on animal blast testing. To provide some historical context, this research was begun shortly after the U.S. led invasion of Iraq, and came to a close while there continues to be daily loss of life from blast injuries in the Middle East, as well as continued threats of terrorism throughout the world. In addition to industrial accidents, it is clear that blast injury is far more than just a military concern. Simplified finite element models of the human and sheep thoraces were created in order to provide practical and flexible models for the prediction of primary blast injury in simple and complex blast environments, and subsequently for the development of improved protective equipment. The models were created based on actual human and sheep geometries and published material properties. The fluid-structure interaction of the models compared well with experimental blast studies carried out during the course of the research, as shown by comparing actual and predicted overpressures in the free field and at the thorax. By comparing the models to published experimental data from simple blasts, trends in the results were verified and peak lung pressure was proposed as a trauma criterion. Local extent of injury in the lung is correlated to the peak pressure measured in each finite element, categorized as no injury (< 60 kPa), trace (60-100 kPa), slight (100-140 kPa), moderate (140-240 kPa) and severe (> 240 kPa). The calculation of the mean value of the peak lung pressures of all of the finite elements allows for an overall estimate of the injury level, with 35 kPa predicting threshold damage, 129 kPa for one percent lethality, and 186 kPa for fifty percent lethality. The simple blast results also compared well to the predictions of two previously validated mathematical models. Variation of predicted injury within a given loading severity was 15%, which is comparable to the model by Stuhmiller that had a variation of 20%. The model by Axelsson had very little variation (1.4%), but the differences between levels of severity were quite small, and often difficult to decipher. In addition to predicting consistent levels of injury, the finite element models were able to provide insight into the trauma mechanism, map the extent of injury through the lungs, and validate a local injury criterion. The models were then applied to predict injury under complex blast loading by subjecting the human finite element torso to a threshold level blast while located at varying distances from a wall or a corner. The results compared well to the validated mathematical models, showing a sharp increase in injury severity as the model approached the reflecting surface. When directly against the wall, the mean of the peak lung pressure values was 57 kPa, and in the corner, the mean value reached 69 kPa. Although these values did not reach the level representing one percent lethality, they do represent a significant increase in injury above threshold as a direct result of the surrounding geometry. Once again, the finite element models correctly showed injury trends and lung injury patterns reported in experiments. The models predicted the level of injury and were able to predict the time varying pattern of injury, which is something existing models cannot do. Having designed the models from physical principals, and having validated the models against published results, they can now be used in the continued development of protective equipment. Acknowledging that this model was the first iteration, the author believes that improvements in material properties, mesh refinement, and the investigation of other possible parameters for the prediction of injury will lead to substantial advances in the understanding of primary blast injury.

This work focuses on the thermomechanical characterization and constitutive model calibration of shape memory polymers (SMPs). These polymers have the ability to recover seemingly permanent large deformations under the appropriate thermomechanical load path. In this work, a contribution is made to both existing experimental and modeling efforts. First, an experimental investigation is conducted which subjects SMPs to a thermomechanical load path that includes varying the value of applied deformations and temperature rates. Specifically, SMPs are deformed to tensile extensions of 10% to 100% at temperature rates varying from 1 degree C /min to 5 degree C/min, and the complete shape recovery profile is captured. The results from this experimental investigation show that the SMP in question can recover approximately 95% of the value of the applied deformation, independent of the temperature rate during the test. The data obtained in the experimental investigation are then used to calibrate, in one-dimension, two constitutive models which have been developed to describe and predict the material response of SMPs. The models include a model in terms of general deformation gradients, thus making it capable of handling large deformations. In addition, the data are used to calibrate a linearized version of the constitutive model for small deformations. The material properties required for calibrating the constitutive models are derived from portions of the experimental results, and the model is then used to predict the shape memory effect for an SMP undergoing various levels of deformation. The model predictions are shown to match well with the experimental data.

Polymer nanocomposites refer to a broad range of composite materials with polymer acting as the matrix and any material which has at least one dimension in the order of 1 ~ 100 nanometer acting as the filler. Due to unprecedented improvement observed in properties of the nanocomposites, research interest in this area has grown exponentially in recent years. In designing better nano-composites for advanced technological applications some of the major challenges are: understanding the structure-property relationships, interaction and integrity of the two components at the interface, the role of nanofillers in enhancing the properties of the resulting material. In our work, we have utilized first principle calculations, atomistic simulations, coarse-grained modeling and constitutive equations to develop structureproperty relationships for an amorphous aromatic piezoelectric polyimide substituted with nitrile dipole, carbon nanotubes and resulting nanocomposites. We have studied in detail structure-property relationships for carbon nanotubes and (? ?CN)APB/ODPA polyimide. We have developed chemically sound coarse-grained model based on atomic level simulations of the piezoelectric polyimide to address the larger length and time scale phenomena. The challenge of coarse grain model for these polymers is to reproduce electrical properties in addition to the structure and energetics; our model is the first to successfully achieve this goal. We have compared and analyzed atomistic scale simulation results on the nanocomposite with those predicted from micromechanics analysis. Notably, we have investigated the time dependent response of these highly complex polymers, to our best knowledge this is the first of its kind. In particular we have studied the thermal, mechanical and dielectric properties of the polyimide, nanotube and their nanocomposites through multi-scale modeling technique. We expect the results obtained and understanding gained through modeling and simulations may be used in guiding development of new nanocomposites for various advanced future applications. In conclusion we have developed a computational paradigm to rationally develop next generation nano-materials.

Constitutive rhetoric theory posits that community identity is rhetorically created. There are various approaches to constitutive rhetoric, though most rhetoricians have chosen to focus on the works of Maurice Charland and Michael McGee, whose approaches focus on audience so much that often the rhetor has no agency. This project blends their ideas with those of James Boyd White to create works of criticism that highlight an increased amount of agency for the rhetor. As examples, I have chosen four case studies from the year 1954: the Brown v. Board decision, the Army-McCarthy hearing (specifically McCarthy's heated exchange with Joe Welch), the addition of "under God" to the Pledge of Allegiance, and the first article in the first dated issue of Playboy. Each chapter is designed to provide an example of what a constitutive analysis in the style of White would look like. The project begins with a description of the theories and analyses, including constitutive rhetoric, postmodernism, and textual analysis. The Brown v. Board analysis begins with a brief history of the case, moves to a rhetorical analysis, and then connects the analysis to ideas of constitutive rhetoric. The McCarthy sections examines the "Have you no sense of decency?" exchange between Welch and McCarthy. It begins with a brief explanation of McCarthy's reputation, and then utilizes an understanding of conspiracy rhetoric in the rhetorical analysis in order to explain McCarthy's constitutive efforts. The Pledge of Allegiance analysis provides a brief a summary of the Congressional arguments made to add the words "under God" to the Pledge of Allegiance, then provides a textual analysis of the Pledge (with the addition), emphasizing the power of those words, especially given the epideictic nature of the Pledge. The Playboy research focuses on the first 1954 article, which directly addresses the question of American identity. The article is contextualized with Hugh Hefner's self-proclaimed Philosophy of Playboy. Finally, all of these case studies are tied together again with further explanations of constitutive rhetoric, showing that White's understanding of constitutive rhetoric can be used to bolster Charland and McGee's in order to give agency to the rhetor.