Abstract The effects of restoration and certain elements, nitrogen, sulphur, calcium and Misch metal, on the hot ductility of austenitic, high-alloyed austenitic and duplex stainless steels have been investigated by means of hot rolling, hot tensile, hot bending and stress relaxation tests. The results of these different testing methods indicated that hot rolling experiments using stepped specimens is the most effective way to investigate the relationship between the softening and cracking phenomena under hot rolling conditions. For as-cast, high-alloyed and duplex stainless steels with a low impurity level, the cracking tendency was observed to increase with increasing pass strain and temperature, being minimal for the small strain of 0.1. No cracking occurred in these steels when rolled in the wrought condition. It could be concluded that the cracking problems are only exhibited by the cast structure with the hot ductility of even partially recrystallised steel being perfectly adequate. However, the recrystallisation kinetics of the high-alloyed austenitic stainless steels, determined by stress relaxation and double-pass rolling tests, were found to be so slow that only partial softening can be expected to occur between roughing passes under normal rolling conditions. In the duplex steel, the restoration is fairly fast so that complete softening can occur within typical interpass times in hot rolling, while certain changes in the phase structure take place as well. Sulphur was found to be an extremely harmful element in duplex stainless steel with regard to their hot ductility so that severe cracking can take place with sulphur content above 30 ppm. However, the effect of sulphur can be eliminated by reducing its content and by calcium or Misch metal treatments that significantly increase the number and decrease the average size of the inclusions. It seems that the desulphurisation capacity of an element is the most important property for assessing its usefulness in reducing the detrimental influence of sulphur. The hot ductility of type 316L stainless steel determined by tensile tests was found to be better for nitrogen content of 0.05 wt-% than 0.02%, while in double-hit tensile tests the hot ductility values were identical. The mechanism whereby nitrogen affects hot ductility remains unclear but a retarding effect on static recrystallisation was observed.

L’objectif de ce travail est de développer une modélisation prédictive du comportement et de la rupture ductile des matériaux métalliques à anisotropies initiales et induites par l’endommagement. La thermodynamique des processus irréversibles est utilisée comme cadre pour la formulation proposée. Le modèle de comportement est élastoplastique anisotrope avec écrouissage non linéaire isotrope et cinématique en grandes déformations plastiques, avec une théorie non associée à normalité associée, basée sur des normes de contraintes quadratiques. L’endommagement ductile anisotrope est décrit par un tenseur du second ordre symétrique dont l’évolution est décrites par des relations de type Lemaitre-Desmorat. Le couplage fort comportement-endommagement est réalisé dans le cadre de l’hypothèse de l’équivalence en énergie totale où l’effet de l’endommagement sur le comportement est introduit par un tenseur « effet d’endommagement » d’ordre quatre symétrique de type Murakami. Après une caractérisation expérimentale des mécanismes physiques de l’endommagement dans l’acier AISI 316L, le modèle de comportement avec endommagement a été identifié. Une fois discrétisé et implémenté dans le code de calcul de structures ABAQUS/Explicit®, une étude paramétrique et de nombreuses simulations numériques de l’endommagement anisotrope en mise en forme de quelques structures ont été réalisées et discutées en détail / The objective of this work is to develop a predictive modeling of behavior and ductile fracture of metallic materials with initial anisotropy and induced by the ductile anisotropic damage. Thermodynamics of irreversible processes is used as a framework for the proposed formulation. The model is anisotropic elastoplastic with non-linear isotropic and kinematic hardening under large plastic strains. It is formulated in the framework of the non-associative plasticity theory with associative normality rule and based on quadratic equivalent stress. The anisotropic ductile damage is described by a symmetric second-rank tensor whose evolution is described by Lemaitre /Desmorat type relationships. The strong damage-behavior coupling is done under the assumption of total energy equivalence where the effect of the anisotropic damage is introduced by a fourth-rank symmetric damage-effect tensor of Murakami kind.After an experimental characterization of the main physical mechanisms of anisotropic damage in stainless steel AISI 316L, the behavior model with damage has been identified. Once discretized and implemented in the computer code ABAQUS / Explicit ®, a parametric study and many numerical simulations of anisotropic damage in some metal forming processes have been carried out and discussed in detail

In the light of extreme events of natural disasters (earthquakes or hurricanes) and accidents (fire or explosion), repairing and strengthening of existing concrete structures has become more common during the last decade due to the increasing knowledge and confidence in the use of composite advanced repairing materials. The past experience from real fires shows that it is exceptional for a concrete building to collapse as a result of fire and most fire-damaged concrete structures can be repaired economically rather than completely replacing or demolishing them. In this connection an experimental study was conducted to investigate the effectiveness of fibre reinforced polymer jackets for axial compressive and seismic shear performance of post-heated columns. This study also investigates the effectiveness of ferrocement laminate for the repairing of post-heated reinforced concrete columns.A total of thirty-five reinforced concrete columns were constructed and then tested after categorising them into three main groups: un-heated, post-heated and post-heated repaired. The post-heated columns were initially damaged by heating (to a uniform temperature of 500°C). The concrete cubes were also heated to various temperatures to develop the relation between compressive strength and ultrasonic pulse velocity. The residual compressive strength of the concrete cubes and reinforced concrete columns were determined by ultrasonic testing. The post-heated columns were subsequently repaired with unidirectional glass or carbon fibre reinforced polymer and ferrocement jackets. The experimental programme was divided into two parts. The columns of experimental part-1 were tested under axial compressive loading. The columns of experimental part-2 with a shear span to depth ratio of 2.5 were tested under constant axial and reversed lateral cyclic loading. The results indicated that the trend of reduction in ultrasonic pulse velocity values and in residual compressive strength of concrete was similar with increasing temperature. The reduction in residual stiffness of both post-heated square and circular columns was greater than the reduction in ultimate load. The circular sections benefited more compared to the square cross-sections with fibre reinforced polymers for improving the performance of post-heated columns in terms of compressive strength and ductility tested under axial compression. GFRP and CFRP jackets performed in an excellent way for increasing the shear capacity, lateral strength, ductility, energy dissipation and slowed the rate of strength and stiffness degradation of fire damaged reinforced concrete square and circular columns tested under combined constant axial and reversed lateral cycle loading. However, the effect of a single layer of glass or carbon fibre reinforced polymer on the axial stiffness of post-heated square and circular columns was negligible. The use of a ferrocement jacket for the repairing of post-heated square and circular columns enhanced the axial stiffness and ultimate load carrying capacity of columns significantly.

Ve všeobecnosti, poznatky o design slitin, jejich výrobě a výběru legujúcich prvků sú omezené na slitiny s jedním základním prvkem. Tento fakt ale výrazně limituje možnosti a volnost výběru prvků pro dosáhnuti speciálních vlastností a mikrostruktur. V poslední dekádě se ukázalo, že materiálová věda a inženýrství nejsou ještě zdaleka prozkoumané v důsledku objevu nové třídy materiálů nazvané vysoko entropické slitiny (HEA high entropy alloys). Jejich objev upoutal pozornost vědecké komunity. Základní koncept pro jejich design je, že namísto jednoho, nebo dvou základních prvků obsahují minimálně 5 prvků v podobných atomových koncentracích. V posledních letech se objevila skupina materiálů odvozená od HEA, nazvaná slitiny so střednou entropii (MEA medium entropy alloys). Na rozdíl od HEA ale obsahují 3, nebo 4 prvky. Táto práce je věnovaná studiu přípravy a charakterizaci HEA, MEA a jejich kompozitů s pomocí metod práškové metalurgie. V této práci byli dohromady zkoumány tři kompozice: AlCoCrFeNiTi0.5, Co1.5Ni1.5CrFeTi0.5 a CoCrNi, kompozity s kovovou matricí (MMC metal matrix composites) vyztužené částicemi B4C s CoCrNi jako matricí. Hloubková mikrostrukturní a mechanická analýza těchto materiálů byla provedena pomoví metod rastrovací a transmisní elektronové mikroskopie spojené s tahovými a ohybovými zkouškami. V průběhu celé studie se objevovaly problémy s kontaminací kyslíkem, co se projevilo vznikem značného množství oxidů v připravených materiálech. U Slitiny AlCoCrFeNiTi0.5 byla naměřena tvrdost přesahující 800 HV. Její houževnatost ale byla velice omezena. V její mikrostruktuře byly identifikovány částice in-situ TiC v důsledku přítomnosti organického, anti-aglomeračního činidla (metanolu) v mlecí misce. Tato reakce může být použita v budoucnu k přípravě MMC se záměrnou disperzí TiC. Na druhé straně, slitina CoCrNi ukázala vysoké hodnoty tažnosti (26%) a meze pevnosti přes 1000 MPa. Mikrostruktura obsahovala majoritní FCC fázi s BCC precipitáty. Tahle slitina byla z důvodu vysoké tažnosti zvolena pro přípravu kompozitu s výztuží B4C. V průběhu slinování ale došlo k reakci mezi přítomným Cr a B4C, které výsledkem byl Cr5B3 borid. Tento kompozit mel pevnost v tahu 1400 MP a extrémne jemnozrnnou strukturu. Celková tažnost ale klesla na 1.9 %. Slitina AlCoCrFeNiTi0.5, která mela strukturu složenou jen z FCC tuhého roztoku dosáhla nejlepší kombinaci mechanických vlastností s pevností přesahující 1300 MPa a dostatečnou tažností 4%. Prášková metalurgie se ukázala jako vhodná metoda pro přípravu HEA a MEA slitin a jejich kompozitů, s dobrou kombinací pevnosti a tažnosti. Tato metoda dovoluje měnit mikrostrukturní parametry připravených materiálů jednoduchou úpravou parametrů procesu.

En la presente investigación, se analiza la influencia de la irregularidad de la masa y del efecto PΔ sobre el comportamiento estructural de una edificación de 15 pisos. Se plantea el caso de una edificación regular 15 pisos, 4 casos de edificaciones con presencia de irregularidad de masa en un piso establecido y 4 casos de edificaciones irregulares con efecto PΔ. Primeramente, mediante el análisis dinámico lineal se determina la respuesta estructural en términos de derivas, fuerza cortante basal y momento. Posteriormente, se realiza el análisis estático no lineal (Push over) y se construye la curva de capacidad de la estructura. A partir de la curva de capacidad se obtienen los desplazamientos ultimo y de fluencia, y se estima la ductilidad global. Luego se procede a determinarse el desempeño sísmico para los diferentes niveles de sismo. Por último, se realiza un análisis comparativo de la respuesta estructural y el desempeño sísmico de los casos. Al analizar los momentos de las estructuras irregulares con efecto PΔ, se obtuvo una variación de hasta 5.60% con respecto a la edificación regular, de modo que se tiene mayor incremento de los momentos cuando en el análisis estructural de una estructura con irregularidad de la masa se considera el efecto PΔ. Se ha generado un incremento de la variación de la rigidez en el caso 1 cuando se considera el efecto PΔ, en la dirección x-x se obtuvo una variación de hasta 73.06 % y 77.76% en la dirección y-y. / In the present investigation, the influence of the irregularity of the mass and the PΔ effect on the structural behavior of a 15-story building is analyzed. The case of a regular 15-story building, 4 cases of buildings with the presence of mass irregularity in an established floor and 4 cases of irregular buildings with PΔ effect is presented. First, through linear dynamic analysis, the structural response is determined in terms of drifts, basal shear force and moment. Subsequently, the non-linear static analysis (Push over) is performed and the capacity curve of the structure is constructed. The ultimate and creep displacements are obtained from the capacity curve, and the overall ductility is estimated. Then, the seismic performance is determined for the different levels of earthquake. Finally, a comparative analysis of the structural response and the seismic performance of the cases is carried out. When analyzing the moments of the irregular structures with the PΔ effect, a variation of up to 5.60% was obtained with respect to the regular building, so that there is a greater increase in the moments when in the structural analysis of a structure with irregularity of the mass the PΔ effect is considered. An increase in the variation of the stiffness has been generated in case 1 when the PΔ effect is considered, in the x-x direction a variation of up to 73.06% and 77.76% in the y-y direction was obtained. / Trabajo de investigación

Un modèle phénoménologique 3D de visco-plasticité couplée avec les évolutions microstructurales et l'endommagement est proposé pour les superalliages monogranulaires base Nickel, les matériaux des aubes de turbine à haute pression de moteurs d'hélicoptères. L'anisotropie de la mise en radeaux, la croissance et la dissolution de la phase durcissante sont modélisés. Une variable tensorielle et sa loi d'évolution permettent la description de la variation de la largeur des couloirs de matrice. Ce travail s'appuie sur la décomposition en modes de Kelvin du tenseur d'élasticité. Cette décomposition conduit également à une description multi-critère mésoscopique de la visco-plasticité cubique. Une formulation en (visco-)plasticité cristalline a été également proposée. Une loi d'endommagement avec seuil de type dD/dt=... est formulée pour la modélisation du fluage tertiaire et pour la prévision de la ductilité en traction. Une expression originale du seuil d'endommagement rend compte des effets de vitesse sur l'amorçage de l'endommagement par visco-plasticité. Une étude expérimentale a été conduite sur le CMSX-4, l'alliage au centre de cette étude, parallèlement aux travaux de modélisation. Des essais de dissolution ont été réalisés afin de mesurer la variation de la fraction volumique des précipités avec la température. Les mécanismes de déformation du matériau ont été observés en fluage isotherme à 850°C et 1050°C selon les principales directions cristallines du triangle stéréographique standard et constituent une base d'identification pour le modèle, la réponse mécanique du matériau obtenue. Trois essais de traction ont été réalisés selon la direction <111>, deux à vitesse de chargement constante, le troisième à vitesse variable. Des essais cyclés thermiquement de type 150h-moteur ont été réalisées sur le banc MAATRE. Des analyses EBSD et MET ont été réalisés sur les échantillons orientés selon les directions cristallines <011>, <111> et <112> et testés à 850°C. Ces analyses ont montré que le mâclage est le principal mécanisme de déformation pour des déformations supérieures à $1-2%$ selon ces orientations cristallines en fluage à cette température et à haute contrainte (>400 MPa). Enfin, le modèle a été implanté dans le code à élément Finis ZéBuLon, sans ou avec endommagement, et des calculs de structures ont été réalisés / A 3D phenomenological model coupling viscoplasticity, microstructural evolutions and damage is proposed for Ni-based single crystal superalloys, which are widely used materials for high pressure turbine blade in helicopter engines. The anisotropy of the gamma'-rafting, the gamma'-coarsening and the dissolution of the hardening gamma' phase are modeled. A tensorial variable and its evolution law allow to describe the variation of the gamma channels. The modeling is based on the Kelvin decomposition of the elasticity tensor. This decomposition leads to a phenomenological multi-criterion description of the cubic visco-plasticity. A formulation based on the single crystal (visco-)plasticity framework is also proposed. A damage law of type dD/dt=… is introduced in order to model the tertiary creep stage and the ductility. A novel rate sensitive damage threshold is introduced in order to account for the rate sensitivity of the damage onset by visco-plasticity. An experimental study has been carried out on the CMSX-4 alloy, which is the material of main interest in this study, in parallel to the modeling work. Dissolution tests have been carried out to measure the gamma'-volume fraction variation with temperature. The deformation mechanisms of the CMSX-4 alloy have been observed by performing tensile creep tests at 1050°C and 850°C. These tests have also constituted a database for the model identification. Three tensile tests have been realized along the <111> crystal direction, two at constant strain rate and the third by varying the strain rate. Non-isothermal creep tests reproducing the 150h-type engine test have been performed on the MAATRE bench. EBSD and TEM analysis have been realized on the specimens oriented along the <011>, <011> and <112> crystal directions and crept at 850° C. These analysis have shown that micro-twinning governs the deformation along these crystal directions during creep at this temperature and at high stresses (> 400 MPa) for deformation in excess of 1-2%. Finally, the model (with and without damage) has been encoded in the ZéBuLoN Finite Element solver and structure computations have been performed.

No description available.

No description available.

Reinforced concrete buildings built prior to the enactment of modern seismic codes are often seismically deficient. These buildings may have inadequate strength and ductility to withstand strong earthquakes. Conventional retrofit techniques for such frame buildings involve adding reinforced concrete shear walls or structural bracing systems to the existing bays. These techniques can be intrusive and result in lengthy down times and expensive structural interventions. An alternative to conventional techniques is the use of high-strength prestressing strands or cables, diagonally placed as tension elements. This technique was researched and used in a limited manner after the 1985 Mexico City Earthquake. It has since been further investigated at the University of Ottawa through experimental and analytical research (Shalouf and Saatcioglu (2006), Carrière (2008), Molaei (2014)). While the use of steel strands as tension bracing elements proves to be an effective technique, the resulting stiffening effects on the frames lead to increased seismic force demands and higher based shear, as well as increased axial forces on the attached columns, potentially generating net tension, foundation uplift and excessive compression. Relatively low elongation characteristics of high-strength cables and slack caused by yielding strands and associated pinching of hysteresis curves reduce potential energy dissipation capacity. The current research aims to improve the previously observed deficiencies of the system. One of the improvements involve the use of shape memory alloys (SMA) in the middle of the cables, which reduce/eliminate residual deformations upon yielding and associated pinching of the hysteresis curves. SMA allows energy dissipation in the system while forcing the structure to recover from its inelastic deformations because of the flag-shape hysteretic characteristics of the material. The feasibility of the cable-SMA assembly as tension brace elements is illustrated through dynamic analyses of selected prototype buildings. The other improvement is the development of progressively engaging, initially loose multiple strands as tension cables. These cables are placed loosely to engage in seismic resistance at pre-determined drift levels, thereby eliminating premature increase in seismic force demands until their participation is required as the frame capacity is reached. Tests of a large-scale reinforced concrete frame, designed following the requirements of the 1965 National Building Code of Canada NRC (1965) as representative of existing older frame buildings in Canada, are conducted under simulated seismic loading to assess the effectiveness of the proposed system. The verification of the concept is extended analytically to prototype buildings and the effectiveness of the system is demonstrated for mid-rise and low-rise frame buildings.

<p> A method for tlie dynamic analysis· of planar coupled shear walls subjected to ground motions is developed herein. The method is capable of application to nonuniform coupled shear walls resting on flexible foundations. The possibility-of development of yield hinges at the ends of the connecting beams is included in the analysis . Also P-& Effect is incorporated in the stiffness of the structure. </p> <p> The method is based on the transfer matrix technique in combination with the continuum method. A step-by-step integration approach is used in solving the equation of motion. The response to a number of earthquake records are obtained. The effect of the rotational ductility factor of connecting beams is studied. </p> / Thesis / Master of Engineering (MEngr)