abstract: Mass spectrometric analysis requires that atoms from the sample be ionized in the gas phase. Secondary ion mass spectrometry achieves this by sputtering samples with an energetic primary ion beam. Several investigations of the sputtering and ionization process have been conducted. Oxygen is commonly used in secondary ion mass spectrometry (SIMS) to increase ion yields, but also can complicate the interpretation of SIMS analyses. An 18O implant in silicon has been used to quantify the oxygen concentration at the surface of sputtered silicon in order to study the dependence on oxygen of several sputtering and depth profile phenomena. The ion yield dependence of trace elements in silicon on the surface oxygen concentration is a function of the ionization potential of the element. The ion yield is high and unaffected by oxygen for elements with low ionization potential and ranges over several orders of magnitude for elements with high ionization potential. Depth resolution in sputter profiles has been shown to be degraded by the presence of oxygen, the mechanism of this effect has been investigated using an 18O implant to quantify oxygen levels and it is shown that the process does not appear to be a consequence of surface oxide formation. Molecular ions are a source of mass interference in SIMS analysis, and multiply charged atomic ion signals might be interference-free due to the possible instability of multiply-charged molecular ions. Sputtered SiH2+, AlH2+, BeH2+, Mo22+ and Mg22+ ions have been observed and appear surprisingly stable. The formation mechanism of some of these species has been explored. / Dissertation/Thesis / Ph.D. Chemistry 2012

<p>The PANDA experiment is a part of the future FAIR accelerator facility and will study the strong interaction by detecting the reaction products from antiproton-proton annihilations in a near full solid-angle configuration. One option for the internal proton target in PANDA is frozen micro-spheres of hydrogen, so-called pellets.</p><p>Such a pellet target is interesting because of the unique characteristics it offers; the high target thickness, the small interaction volume, the minimal gas load on the vacuum system, and the possibility of tracking individual pellets. Nevertheless, it is possible to allocate the bulky equipment needed to produce the pellets at a few meters away from the beam. This way particle detectors can be located close and almost fully around the interaction point.</p><p>This thesis is devoted to the optimization of a pellet target. To perform measurements, a Pellet-Test Station was built at The Svedberg Laboratory, Uppsala. For the first time, experimental results show the pellet distribution in space and time, and in addition, the vacuum along the pellet pipes. Furthermore, dedicated measurements carried out at CELSIUS/WASA demonstrate the existence of pellet heating as a result of beam-target interactions.</p><p>In performing calculations, the potential problems with pellet heating at PANDA are outlined. Moreover, to look at the consequences for the desired physics, a reaction involving short-lived D-mesons has been used to show the advantages of pellets compared to a more spacious target.</p><p>In conclusion, these studies lead to a deeper understanding of the pellet properties, which makes it possible to suggest future improvements, such as cooling with no vibrations.</p>

The PANDA experiment is a part of the future FAIR accelerator facility and will study the strong interaction by detecting the reaction products from antiproton-proton annihilations in a near full solid-angle configuration. One option for the internal proton target in PANDA is frozen micro-spheres of hydrogen, so-called pellets. Such a pellet target is interesting because of the unique characteristics it offers; the high target thickness, the small interaction volume, the minimal gas load on the vacuum system, and the possibility of tracking individual pellets. Nevertheless, it is possible to allocate the bulky equipment needed to produce the pellets at a few meters away from the beam. This way particle detectors can be located close and almost fully around the interaction point. This thesis is devoted to the optimization of a pellet target. To perform measurements, a Pellet-Test Station was built at The Svedberg Laboratory, Uppsala. For the first time, experimental results show the pellet distribution in space and time, and in addition, the vacuum along the pellet pipes. Furthermore, dedicated measurements carried out at CELSIUS/WASA demonstrate the existence of pellet heating as a result of beam-target interactions. In performing calculations, the potential problems with pellet heating at PANDA are outlined. Moreover, to look at the consequences for the desired physics, a reaction involving short-lived D-mesons has been used to show the advantages of pellets compared to a more spacious target. In conclusion, these studies lead to a deeper understanding of the pellet properties, which makes it possible to suggest future improvements, such as cooling with no vibrations.

Cavity ring-down spectroscopy has been used over the last twenty years as a highly sensitive absorption spectroscopic technique to measure light attenuation in gases, liquids, and solid samples. An optical cavity is used as a multi-pass cell, and the decay time of the light intensity in the cavity is measured, thereby rendering the techniques insensitive to light intensity fluctuations. Optical waveguides are used to build the optical cavities presented in this work. The geometries of such waveguides permit the use of very small liquid sample volumes while retaining the advantages of cavity ring-down spectroscopy. In this thesis cavity ring-down measurements are conducted, both, in the time domain and by measuring phase-shifts of sinusoidally modulated light, and the two methods are theoretically connected using a simple mathematical model, which is then experimentally confirmed. A new laser driver, that is compatible with high powered diode lasers, has to be designed to be able to switch from time domain to frequency domain measurements. A sample path length enhancement within the optical cavity is explored with the use of liquid core waveguides. The setup was optimised with respect to the matrix liquid, the geometrical matching of waveguide geometries, and the shape of liquid core waveguide ends. Additionally, a new technique of producing concave lenses at fibre ends has been developed and the output of a general fibre lens is simulated. Finally, liquid core waveguides are incorporated into a fibre-loop ring-down spectroscopy setup to measure the attenuation of two model dyes in a sample volume of <1 µL. The setup is characterized by measuring concentrations of Allura Red AC and Congo Red from 1 µM to a limit of detection of 5 nM. The performance of the setup is compared to other absorption techniques measuring liquid samples. / Thesis (Ph.D, Chemistry) -- Queen's University, 2013-04-23 14:08:16.33