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Orientador: Paulo Roberto Ribeiro / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica e Instituto de Geociencias / Made available in DSpace on 2018-08-03T18:14:08Z (GMT). No. of bitstreams: 1 Nunes_JoaoOtavioLeite_M.pdf: 4170180 bytes, checksum: 7c2064f4ba67fccb4f1c209b60bf69c7 (MD5) Previous issue date: 2002 / Resumo: O controle de poço sempre foi um assunto muito importante na exploração e explotação de óleo e gás, pois envolve aspectos econômicos, de segurança de pessoas e questões ambientais. O avanço das explorações offshore, particularmente em águas profundas e ultra-profundas, tem aumentado cada vez mais a relevância do controle de kicks e prevenção de blowouts. Práticas de perfuração largamente utilizadas têm sido otimizadas e reavaliadas, então novas tecnologias têm sido desenvolvidas para tratar problemas relacionados a operações de perfuração em águas profundas, tal como uma prática de controle de poço confiável e eficiente. Este esforço é de grande importância em paises como o Brasil, que tem a maior parte da produção de óleo e gás em campos offshore, sendo que a maioria dos campos localiza-se em águas profundas e ultra-profundas. Considerando-se tal cenário, um modelo matemático foi desenvolvido para simular um kick de gás e prever a variação de pressão na linha do choke e no espaço anular de um poço, durante uma situação de controle de poço em águas profundas. Considerações sobre o efeito da geometria do poço, perdas de carga por fricção, expansão do influxo e modelagem bifásica foram implementadas. O efeito de algumas variáveis no controle de poço, tais como o pit gain, lâmina d'água, densidade e reologia do fluido de perfuração e vazão de bombeio foram estudadas / Abstract: Well control has always been a very important issue in the oi! and gas exploitation business, since it involves money savings, people safety and environment threatening. The advancement of the exploration frontiers from onshore to offshore fields, particularly, deep and ultra-deep waters, has increased even more the relevance of kick control and blowout prevention during drilling operations. Widely used drilling practices have been optimized and re-evaluated, so have new technologies been developed to handle specific issues related to deepwater drilling operations, such as reliable and efficient well control practices. This effort has great importance to some countries like Brazil, which have most part of their oil and gas production concentrated on offshore wells, about of those reserves are located in deepwaters. Regarding such scenario, a mathematical model has been developed to simulate a gas kick and predict the pressure variation in the choke line and the annular space of the well during well control situation in deepwater scenarios. Considerations regarding the effects of wellbore geometry, frictional pressure losses, influx expansion, and two-phase flow aspects have been implemented in the present model. The effects of some variables in well control, such as the pit gain, water depth, mud weight and rheology and pump flow rate have been studied. / Mestrado / Geociencias / Mestre em Ciências e Engenharia de Petróleo

This thesis examines the interaction of pre-existing and evolving salt-related topography on the temporal and spatial evolution of depositional systems in deepwater. To achieve this, the thesis integrates stratigraphic and structural analysis of 3D seismic data from the Miocene record of the salt-influenced Lower Congo Basin, Offshore Angola. Observations at multiple scales ranging from the semi-regional (&gt; 50 km) to local, kilometre-scale and covering timescales ranging from the entire Miocene (~ 18 Myr) to &gt; 2 Myr are presented. At the semi-regional scale, results from this study shows that the progressive along-strike linkage of short (&lt;10 km) fault segments and salt diapirs into through-going large scale (&gt; 30 km) faults and elongated saltwalls results in long lived diversion and/or confinement of depositional system fairways. Axial confinement of fairways occurs where structural strike is parallel to sediment input, contrasting with ponding or diversion of deposits oriented at a high angle to structural strike. The orientation of the structures remains relatively static, which in combination with the fixed sediment entry points of the fairways results in recurrence of the major styles of interaction, and long term pinning of fairways throughout the Miocene. The development of large (10's of km) "sediment shadow" zones devoid of coarse clastics downdip of diverted and or confined sediment gravity flows is also observed through the Miocene. At the intraslope basin (10's of km) and sub-basin scale ( < 10 km), the role of confinement by salt-related structures on the temporal evolution and dip-and-strike variability of Late Miocene channelised-lobe complexes in an elongate intraslope basin was also investigated. At both of these scales, the morphology of the recieving basin geometry significantly influences the dimensions, planform morphology and vertical stacking patterns of channelised-lobe complexes. A transition from thick, radial shaped lobe-complexes which are aggradationally stacked and deposited via 'fill-and-spill' of sub-basins within an intraslope basin to thinner, elongate, laterally offset and compensationally stacked channelised-lobe complexes in the intraslope basin is observed. This transition occurs as the salt-related structural template evolves and confinement changes from the sub-basin scale to the intraslope basin scale. At the depositional element scale ( < 5 km), results from this study further shed light on the critical and hitherto neglected role of salt-related topography in controlling the location of channel to lobe transition zones in deepwater depositional systems. The location of the transition zones are documented from four case studies, with the transitions spatially controlled by salt-related reduction in gradient e.g. a break in slope downflow of monoclinal structures, and/or a reduction in lateral confinement of depositional fairways downflow of segment boundaries. Overall, the result of this thesis show the significant influence which evolving saltrelated topography exerts on the stratigraphic development, geometry and sediment routing patterns on salt-influenced continental margins. In particular the study highlights how variable the interaction between evolving salt-related topography and deepwater sedimentation is at a range of temporal and spatial scales.

On April 20, 2010, the Deepwater Horizon oil platform exploded after a series of issues with the Macondo oil well, around the Louisiana coast, in the Gulf of Mexico, causing the death of 11 workers and wounding 17 others. On April 22, the rig sank into the ocean. Large quantities of oil have then poured into the Gulf waters for almost 3 months, causing the most serious oil spill in history. The event is critically examined in relation to the State-corporate crime integrated theoretical model by Michalowski and Kramer (2006), in particular using the institutional level (the relationship between politics and economics) and the operationality of control catalyst (the presence or absence of social control). The results are presented with a deductive strategy. Furthermore, part of the long-term consequences on the environment will be presented, using a deductive thematic strategy. I believe, in order to comprehend the importance of this study field and the relevance of my work, it is necessary to fully analyze the long-term consequences of the DWH (Deepwater Horizon) oil spill in the Gulf of Mexico. The analysis is developed within a case study, based on a literature review. Results show that not only the long-term consequences of the oil spill on the environment are devastating on almost all the elements studied, but that the role of the State in the accident was decisive, especially for the work culture which developed during the years, that led to the accident.

After Deepwater Horizon oil reached the Florida coast, oil was buried in Pensacola Beach (PB) sands to ~ 70 cm depth, resulting in Total Petroleum Hydrocarbon (TPH) concentrations up to ~ 2 kg per meter of beach. This study followed the decomposition of the buried oil and the factors influencing its degradation. The abundance of bacteria in oiled sand increased by 2 orders of magnitude within one week after oil burial, while diversity decreased by ~ 50%. Half-lives of aliphatic and aromatic hydrocarbons reached 25 and 22 days, respectively. Aerobic microbial oil decomposition, promoted by tidal pumping, and human cleaning activities effectively removed oil from the beach. After one year, concentrations of GC-amenable hydrocarbons at PB were similar to those in the uncontaminated reference beach at St. George Island/FL, and microbial populations that disappeared after the oil contamination had reestablished. Yet, oxihydrocarbons can be found at PB to the present day.

Human population growth and global industrial development are driving potentially irreversible anthropogenic impacts on the natural world, including altering global climate and ocean conditions and exposing oceanic environments to a wide range of pollutants. While there are numerous studies highlighting the variable effects of climate change and pollution on marine organisms independently, there are very few studies focusing on the potential interactive effects of these stressors. The deep-sea is under increasing threat from these anthropogenic stressors, especially cold-water coral (CWC) communities which contribute to nutrient and carbon cycling, as well as providing biogenic habitats, feeding grounds, and nurseries for many fishes and invertebrates. The primary goals of this dissertation are to assess the vulnerability of CWCs to independent and interacting anthropogenic stressors in their environment; including natural hydrocarbon seepage, hydrocarbon and dispersant concentrations released during an accidental oil spill (i.e. Deepwater Horizon), and the interacting effects of climate change-related factors and hydrocarbon/dispersant exposure. To address these goals, multiple stressor experiments were implemented to assess the effects of current and future conditions [(a) temp: 8C and pH: 7.9; (b) temp: 8C and pH: 7.6; (c) temp: 12C and pH: 7.9; (d) temp: 12C and pH: 7.6] and oil spill exposure (oil, dispersant, oil + dispersant combined) on coral health using the CWC Lophelia pertusa. Phenotypic response was assessed through observations of diagnostic characteristics that were combined into an average health rating at four points during exposure and recovery. Regardless of environmental condition, average health significantly declined during 24-hour exposure to dispersant alone and increased temperature resulted in a delay in recovery (72 hours) from dispersant exposure. The overall gene expression patterns varied by coral colony, but the dispersant exposure elicited the strongest response. Gene ontology (GO) enrichment analysis revealed that L. pertusa likely experienced varying stages of the cellular stress response (CSR) during exposure to oil, dispersant, and a decrease in pH. The most severe responses were associated with the dispersant exposure including GO terms related to apoptosis, the immune system, wound healing, and stress-related responses. However, the oil exposure induced an upregulation of metabolic pathways and energy transfer but a downregulation of cell growth and development, indicating that the coral nubbins could have been reallocating resources and reducing growth to maintain cellular homeostasis. The decrease in seawater pH elicited a similar response to oil through the enrichment of terms associated with a reduction in the cell cycle and development. Interestingly, the increase in temperature did not elicit a CSR that was detectable in the gene expression data. To further investigate the influence of hydrocarbon exposure on CWCs, comparisons of gene expression profiles were conducted using Callogorgia delta colonies that live in close proximity to active hydrocarbon seepage (“seep”) areas with no current active seepage (“non-seep”) at two different sites in the Gulf of Mexico. There were fewer differentially expressed genes in the “seep” versus “non-seep” comparison (n=21) than the site comparison (n=118) but both analyses revealed GO terms indicating slight alterations in natural biological housekeeping processes, as opposed to a CSR. Our results indicate that distinct stages of the CSR are induced depending on the intensity of stress. This bolsters the idea that there is a stress response shared by all corals in response to a variety of stressors. These data provide evidence that CWCs can be more negatively impacted, both on the phenotypic and molecular levels, by exposure to chemical dispersants than to hydrocarbons alone. Gaining an understanding of how these communities respond, not only to independent stressors, but the combination of these stressors, provides vital information about how CWC communities will fair in current and future conditions. / Biology

The Mississippi Alluvial Valley (MAV) was dominated by extensive lowland forests, but during the 20th century most of the MAV was converted to agricultural, aquaculture, and other human uses. These land-use changes created stopover migration and wintering habitats for waterfowl, shorebirds and other waterbird species. Before landscape modification of the MAV, shorebirds likely migrated past the MAV to wetlands along the northern Gulf of Mexico (NGoM). In 2010, the Deepwater Horizon oil spill impacted coastal marshes of the NGoM. The USDA Natural Resources Conservation Service implemented the Migratory Bird Habitat Initiative (MBHI) to provide waterbirds with wetlands inland of oil-impacted areas. My objectives were to 1) statistically model the waterbird community on wetlands in the MAV and NGoM, 2) estimate relative abundance of shorebird and other waterbirds in idled aquaculture ponds enrolled in MBHI and associated wetlands in the MAV and NGoM, and 3) collect shorebird feathers and blood for stable isotope analysis (13C/12C, 15N/14N) to assess foraging niches and potential migratory connectivity between MAV and NGoM habitats during 2012 – 2013. Consequently, autumns of these years were under a drought, extensively wet from Hurricane Isaac, and exhibited average precipitation in the post-hurricane recovery period which may have had an effect on waterbird assemblages differing by year, month, twice-monthly survey period, latitude, region, state, site, and water depth index. Latitude shifted north and water depth was narrowest when abundant wet habitat existed on the landscape in 2012. Bird abundances were greatest in 2011 and never recovered to these levels in 2012 or 2013, which may have reflected effects of drought concentrating birds on remaining wetlands in 2011 and subsequent to the hurricane. Stable isotope analysis of blood indicated spatial segregation of shorebird species. Neither blood nor feather carbon and nitrogen values revealed definitive linkage of sites between the MAV and NGoM. Shallow water habitat inland may be a limiting resource during migration for waterbirds, especially in drought years when other wetlands may have been limited. Thus, provision of wetlands (mudflat – 15 cm) by MBHI and other conservation strategies across the landscape may allow waterbirds access to needed resources during migration.

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Cold-water corals are an important component of deep-sea ecosystems as they establish structurally complex habitats that support benthic biodiversity. These communities face imminent threats from increasing anthropogenic influences in the deep sea. Following the 2010 Deepwater Horizon blowout, several spill-impacted coral communities were discovered in the deep Gulf of Mexico, and subsequent mesophotic regions, although the exact source and extent of this impact is still under investigation, as is the recovery potential of these organisms. At a minimum, impacted octocorals were exposed to flocculant material containing oil and dispersant components, and were visibly stressed. Here the impacts of oil and dispersant exposure are assessed for the octocoral genus Paramuricea. A de novo reference assembly was created to perform gene expression analyses from high-throughput sequencing data. Robust assessments of these data for P. biscaya colonies revealed the underlying expression-level effects resulting from in situ floc exposure. Short-term toxicity studies, exposing the cold-water octocorals Paramuricea type B3 and Callogorgia delta to various fractions and concentrations of oil, dispersant and oil/dispersant mixtures, were also conducted to determine overall toxicity and tease apart the various components of the synergistic exposure effects. Finally, alterations in Paramuricea B3 gene expression profiles were inspected to characterize genome-wide changes induced by each treatment and putative genes under differential regulation. The experimental results provide evidence for a relatively high toxicity of chemical dispersants as compared to oil additions alone, elucidating the implications of applying oil dispersants to future oil spills. My findings revealed signatures of cellular stress in floc-exposed corals associated with xenobiotic metabolism, immune and inflammatory responses as well as transcriptional suppression of vital cellular components like ribosomal proteins. The data also suggests poor recovery potential in our coral samples exposed to floc. In addition, promising biomarker candidates were identified from the differential expression data for use in future spill-impact monitoring. / Biology

Oil spills have long been recognized as a significant threat to wildlife. Historically, mortality estimates have served as the basis for assessing impact to natural resources. However, these mortality estimates alone neglect the more wide-spread impact of oil spills on wildlife including birds, many of which may not immediately succumb to exposure, but instead suffer sublethal injury that may negatively affect physiological homeostasis, reproduction, and long-term survival. Therefore, there is a need to improve our understanding of the risk of exposure and effect of sublethal oiling during damage assessments. In this dissertation I evaluated the extent of sublethal oil exposure in the immediate aftermath of the Deepwater Horizon spill on American oystercatchers (Haematopus palliatus), black skimmers (Rynchops niger), brown pelicans (Pelecanus occidentalis), clapper rails (Rallus crepitans), and seaside sparrows (Ammodramus maritimus) through both visual evaluation of and under the application of ultraviolet light to individual birds potentially exposed to oil. I found that there were many individual birds with modest oil exposure, demonstrating that more birds are exposed to oil than are accounted for by mortality estimates. Additionally, I developed a field-adapted technique using an in vitro method in brown pelicans that was effective in determining oxidative hematologic injury as measured by a suite of parameters including a reduction in circulating erythrocytes and hemoglobin, formation of Heinz bodies, and an increase in reticulocytes, in birds exposed to oil. I then applied this suite of parameters to individual birds affected in the aftermath of the Deepwater Horizon spill, and found that birds with modest visible or UV-detectible oil exposure suffer hematologic injury, a quantifiable adverse sublethal effect of modest oil exposure. Finally, I used an experimental approach to evaluate the pathologic effects of crude oil exposure in zebra finches (Taeniopygia guttata), evaluating the same suite of hematologic parameters as well as gross pathology, histopathology, and electron microscopy. This controlled study provided evidence that there may be significant variability in the response of birds to oil exposure that may be attributable to species-specific sensitivity and/or other factors such as the use of dispersants after oil spills. Collectively, this body of work demonstrated that many more birds are exposed to oil during spill events than are accounted for by mortality estimates alone, and that these birds can suffer quantifiable sublethal hematologic injury. The ability to accurately assess the extent of exposure and hematologic damage caused by oil spills is critical to determine the appropriate approach to management needed to offset impacts to fisheries, wildlife, habitats, and economic resources impacted by oil spills. / Doctor of Philosophy / Fossil fuels are the world's primary energy source and are an important part of everyday life. Our reliance on petroleum requires extraction, transportation, storage, and refinement of millions of gallons of crude oil each day. As an unintended consequence, some of this oil is inadvertently spilled into the environment, and these oil spills have long been recognized as a threat to wildlife. Assessing the impact of oil spills on wildlife is a major concern to industries, government, and the general public. Historically, mortality estimates have served as the basis for assessing impact to natural resources. However, these mortality estimates alone neglect the more wide-spread impact of oil spills on wildlife including birds, many of which may not immediately succumb to exposure, but instead suffer sublethal physiologic injury that negatively affects physiology, reproduction, and long-term survival. Therefore, there is a need to improve our understanding of the risk of exposure and effects of sublethal oiling during damage assessments. In this dissertation, I evaluated the extent of sublethal exposure to oil from The Deepwater Horizon spill for several species of birds through both visual evaluation of and under the application of ultraviolet light. This demonstrated that many more birds are affected by oil exposure than are accounted for by mortality estimates. Additionally, I developed a field-adapted technique in a controlled setting that is effective in determining oxidative injury to red blood cells in birds exposed to oil, and applied this approach to several species in the field during the aftermath of the Deepwater Horizon spill. Finally, I used an experimental approach to evaluate the extent of pathologic effects of Deepwater Horizon crude oil exposure in individuals under controlled dosages. The ability to accurately assess the extent of damage caused by oil spills is critical to determine the appropriate approach to management needed to offset impacts to fisheries, wildlife, habitats, and economic resources impacted by oil spills.