Vandenilio dujų tankis yra mažas ir turi absoliučiam nuliui artimą suskystėjamo temperatūrą, todėl vandenilio saugojimas yra sudėtingas uždavinys. Kai kurie, ypač metalo, elementai pasižymi savybe absorbuoti vandenilio molekules prie artimų aplinkai vidutinėms temperatūroms bei slėgiams, todėl tyrinėjamas vandenilio saugojimas ryšiuose su metalo jonais. Iš šių junginių vandenilis šalinamas pakaitinus lydinius. Norint, kad vandenilio saugojimas energetiniu požiūriu pasiteisintų, svarbu žinoti vandenilio adsorbcijos, desorbcijos ir difuzijos mechanizmus. Šiame darbe, pasitelkus analitines išraiškas, modeliuojami adsorbcijos ir paviršiaus joninės erozijos, vandenilio pasiskirstymo metalo lydinyje bei vandenilio dehidrinimo procesai. / The storage of hydrogen is an important problem. Hydrogen gas has low density and freezing point close to absolute zero. Some, specially, metal elements have feature to adsorb molecules of hydrogen at intermediate temperatures and pressures. This research deals with possibilities to store hydrogen in metals alloys. It is need external heat for these alloys dehydrogenation. An attempt to understand the processes of hydrogen adsorption, desorption and diffusion is made. Modelling results of deposition and ion irradiation, distribution of hydrogen in bulk, kinetic of dehydrogenation are presented.

In this master work the influence of calcium ions on the cadmium mobility in the sandy and clay soils was investigated. Work subject - samples of Orthieutric Fluvisol and Calcaric-Endohypogleyic Luvisol topsoils taken from arable lands in Balbieriskis distirict. Work objective - to investigate the influence of calcium ions on the cadmium adsorption-desorption processes in the model systems of different kind of soil-Cd(NO3)2-Ca(NO3)2 simulating pH, Cd2+ and Ca2+ amounts. Work methods - the investigated soil samples were agitated for 1 hour with Cd(NO3)2 and Ca(NO3)2 solutions of various concentrations. The solutions were made in the 0.03M NaNO3 for the constant ionic strength maintaining. The Cd amounts in the equilibrium solution after the adsorption were determined with atomic absorption spectrometer (AAS). The Cd desorption was investigated in the samples after adsorption using 0.05M NH4-EDTA (pH 7) solution as extractant. The Cd amount in extract was determined with AAS. Work results - results of the research showed that in the clay soil were accumulated more mobile Cd ions under the influence of Ca ions than in the sandy soil. The clay soil adsorbed for 25 % less and desorbed for 77 % more mobile Cd ions than sandy soil. When soil contamination with Cd was increased from 8 till 40 mg/kg, the Cd adsorption increased about 17 % in both alkaline (pH 8) and acidic (pH 4) medium, while in the sandy soil it decreased about 7 % at pH 8 and increased about 3 % at pH 4. The... [to full text]

Magistro darbe tiriama kadmio ir švino adsorbcijos ir desorbcijos procesai bei jų tarpusavio sąveika skirtingos granuliometrinės sudėties dirvožemiuose. Darbo objektas - du skirtingos granuliometrinės sudėties (priesmėlio ir priemolio) dirvožemiai. Darbo tikslas – ištirti kadmio ir švino adsorbcijos-desorbcijos procesus ir jų tarpusavio sąveikos poveikį jų judrumui tiriamuose dirvožemiuose. Darbo metodai – švino, kadmio, ir jų mišinių adsorbcijos dirvožemiuose procesui tirti dirvožemių ėminiai iki pusiausvyrosios būsenos buvo plakami su skirtingos koncentracijos (0, 0,25, 0,5, 1 mM) Cd (NO3)2, Pb(NO3)2 ir jų mišinių tirpalais, paruoštais 0,03M NaNO3 tirpale pastoviai joninei jėgai palaikyti. Po adsorbcijos eksperimento Cd2+ ir Pb2+ jonų koncentracijos pusiausvirajame tirpale nustatytos liepsnos atominės absorbcinės spektrometrijos metodu (AAS). Desorbcijos procesas ištirtas tuose pačiuose mėginiuose panaudojant ekstrakciją su 0,05M NH4 – EDTA (pH 7) ekstrahentu. Ekstraktuose Pb2+ ir Cd2+ jonų koncentracijos nustatytos liepsnos AAS metodu. Tyrimo rezultatai įvertinti matematiniais-statistiniais metodais naudojant Excel programą. Darbo rezultatai. Atlikus tyrimus nustatyta kad priesmėlio dirvožemis adsorbuoja (esant 1 mM (207 mg•kg-1) koncentracijai) 206,2 mg•kg-1 Pb, 109,9 mg•kg-1 Cd sausosios masės, o desorbuoja 97,7 mg•kg-1 Pb ir 61,6 mg•kg-1 Cd sausosios masės. O priemolio dirvožemis adsorbuoja esant tai pačiai koncentracijai 206,6 mg•kg-1 Pb ir 107,3 mg•kg-1 Cd s.m... [toliau žr. visą tekstą] / In this master work was investigated cadmium and lead adsorption – desorbtion processes and their interaction impact on thier imobility in soils of different texture. Work subject - two soils of different texture (loam and sandy loam). Work objective – to investigate cadmium and lead adsorption – desorbtion processes and their interaction impact on thier imobility in soils of different texture. Work methods – the investigated soil samples were agitated with Cd (NO3)2, Pb(NO3)2 solutions of different concentrations (0, 0,25, 0,5, 1 mM) as well as with solutions of thier mixtures. The solutions were prepared in the 0,03 M NaNO3 for the maintaining of constant ionic strength. After adsoption experiment, the Cd2+ and Pb2+ ionic concentrations in the equilibrium solution were determined with atomic adsorption spectrometer (AAS). The desorption was investigated in the same samples using 0,05M NH4 – EDTA (pH 7) extractant. In extracts Pb2+ and Cd2+ ionics concentrations were determinadet with AAS. Work results – after investigation observed that sandy soil absorbed 109,9 mg•kg-1 Cd and 206,2 mg•kg-1 Pb, desorbed 61,6 mg•kg-1 Cd and 97,7 mg•kg-1 Pb. And loam soil absorbed 107,3 mg•kg-1 Cd and 206,6 mg•kg-1 Pb, desorbed 57,1 mg•kg-1 Cd and 82,4 mg•kg-1 Pb. Cd in loam soil after Pb adsorption and desorption in Cd-Pb model-sistem the influence was tenuous, while the dorsorption decreased only in loam soil and only in the low concentations (unto 0,5 mM Cd-Pb). Keywords:... [to full text]