No description available.

Young children are limited in their usage of comparative adjectives and ordinal numbers, typical ways of describing ordinal relationships. However, research in a number of areas suggests the possibility of a precursor level of ordinal concept. To facilitate the search for precursor ordinal skills, ordinal ability was defined in ordinal measurement terms. Only "greater than - less than," asymmetric judgements were required. Additionally, linguistic demands were reduced by using family-role terms as size designators. Experimental manipulations included variations in scale size and in the complexity level of ordinal conceptualization. Solution strategies based on "good form" and on "pairwise comparison" were precluded by using pictures of randomly placed objects which could not be manipulated by the child. Ninety-six 3-6 year old children pointed to "Daddy," "Mommy," "Big boy/girl," "Little boy/girl," and "Baby" when shown sets of 3 to 5 circles or squares which differed only in size. Tasks were of three types: Identification, mapping labels onto a single set of objects; Coordination, mapping labels onto two identical sets of objects in which corresponding "family members" are the same size; and Transposition, mapping labels onto two separate sets in which corresponding family members are of different sizes. Data were analyzed in an Age (3), by Scale Size (3), by Complexity Level (3), by Shape (2) mixed design ANOVA, and significant main effects were obtained for all variables. Tasks became more difficult with increases in scale size, and in complexity level. Square objects were slightly more difficult than circular, and older children were more proficient than younger ones. Post hoc tests generally supported the obtained main effects. Finer grained analysis using Latent Trait procedures supported the global ANOVA results, and supported the hypothesis that the end points of a scale are easier than the central positions. Response patterns indicated that errors were size-related, and suggested transitional levels of performance. The present study demonstrates that children as young as three can demonstrate a precursor ordinal concept when the task is framed in familiar terms and is placed in a context which is meaningful for them.

Current study of separation mechanism in chromatography heavily relies on the measurement of macroscopic properties, such as retention time and peak width. This dissertation describes the vibrational spectroscopy characterization of separation processes.Raman Spectroscopic characterization of a silica-based, strong anion exchange stationary phase in concentrated aqueous solutions is presented. Spectral response of stationary phase quaternary amine is closely related to changes in interaction between counter anions and the amine functional groups as the result of anion hydration. The molecular-level information obtained will provide useful guidance for control of stationary phase selectivity.To study the effects of stationary phase pore size on separations processes, monodisperse silica particles in the sub-100 nm range are prepared and self-assembled to well-ordered, three-dimensional colloidal arrays. A modified LaMer model is proposed and demonstrated for optimization of reaction conditions that lead to uniform and spherical silica particles. This approach greatly reduces the number of training experiments required for optimization. Fast Fourier transformation of colloidal array scanning electron microscopy images indicates closely-packed hexagonal packing patterns.Using these arrays, a novel system for the measurement of molecular diffusion coefficients in nanopores is reported. This system consists of an ordered colloidal array with well-defined pore structure deposited onto an internal reflection element for in-sit collection of kinetic information by attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR). A mathematical model is established to extract diffusion coefficients from these data. A decrease of approximately eight orders of magnitude in molecular diffusion coefficients is observed for molecular transport in nanopores.Finally, by using this colloidal array-ATR-FTIR system and the corresponding mathematical models that describe absorption in the colloidal array, the distribution in the nanopores of the acetonitrile organic modifier in an aqueous mobile phase solvent system is determined. Based on the results of 50 nm colloidal arrays, pore surface properties have a strong effect on the distribution of organic molecules from bulk solution to the pores.

No description available.

This study focuses on the effect that particle properties (size, density and shape) have on fluidized bed hydrodynamics and entrainment rate. The experimental work was carried out using two Plexiglas columns having internal diameters of 0.05 m and 0.14 m respectively and a total height of 6 m from the gas distributor. The particle density was in the range 1300 to 4600 kg/m3, the Sauter mean diameter was in the range 23 to 60 um and the fines content (% < 22 um) was in the range 1 to 29 %. Particle shapes, which ranged from angular to spherical, were characterized by image analysis of SEM photographs. Air was used, as the fluidizing gas and the superficial velocity was kept constant at 0.38 m/s in the 0.05 m column. In the 0.14 m column it was varied in the range 0 to 0.8 m/s. The dense-phase voidage, bubble fraction and entrainment rate of the powders were measured at ambient conditions. In general it was found that the bubble fraction and entrainment rate increased with an increase in the superficial gas velocity. The dense phase voidage was found to increase with an increase in the fines content of the powder and it was only a weak function of the superficial gas velocity. Most importantly, it was found that angular-shaped particles had a higher dense phase voidage, a lower bubble fraction and a lower entrainment rate when compared to spherical-shaped particles having similar particle density and size. Possible reasons for the lower entrainment rate for the angular-shaped particles are given. The measured dense phase voidage, bubble fraction and entrainment flux was compared with predictions from published correlations and it was found that none of the correlations provided a good fit to the data obtained in this work and that different correlations predicted widely different entrainment rates for the same system. It is therefore recommended that literature correlations should be used with caution in the absence of experimental data. Empirical correlations for the dense phase voidage and bubble fraction are developed. / Thesis (M.Sc.Eng.)-University of KwaZulu-Natal, Durban, 2007.

The Compact Linear Collider (CUC) is a proposed electron-positron collider with a centre- of-mass energy of 0.5 to 5 TeV, optimised for a nominal centre-of-mass energy of 3 TeV, at high luminosities exceeding 1034 cm-2s-J. The high beam charges in the CUC beams make classical techniques for measuring the transverse beam size such as optical transition radiation (OTR) screens or wire scanners very difficult, which necessitates the use of non-invasive beam- size monitors. The laser-wire is a system that meets these requirements; it uses inverse Compton scattering to determine transverse beam-sizes by scanning a laser beam across the electron beam. This thesis describes how such a laser-wire system was installed and operated at PETRA-III at DESY, which uses an automated mirror to scan a Q-switched laser pulse across the electron beam and is developed from the system previously operated at PETRA-II. The measurements of key performance parameters are described and used in determining the emittance of the PETRA-III beam. The thesis includes a detailed investigation of the laser .' system as well as the collision measurements. Furthermore, simulations were carried out to design a similar system for the proposed transfer line of the CUC Drive-Beam and the necessary baseline characteristics of such a system are described.

Twin roll casting (TRC) offers a promising route for the economic production of Mg sheet, but unfortunately, it produces strip with coarse and non-uniform microstructures and severe centre line segregation. Recently, a novel magnesium strip casting process termed melt conditioned twin roll casting (MC-TRC) was developed that, compared with the conventional TRC process, emphasizes solidification control at the casting stage rather than hot rolling. This was achieved by melt conditioning under intensive forced convection prior to twin roll casting resulting in enhanced heterogeneous nucleation followed by equiaxed growth. In this study the development of TRC and MC-TRC processes and a microstructural comparison of the MC-TRC Mg-alloy strip with that of conventional TRC strip, have been investigated. Emphasis has been focused on the solidification behaviour of the intensively sheared liquid metal, and on the mechanisms for microstructural refinement and compositional uniformity in the MCTRC process. The results of the process development indicate that the MC-TRC process reduces considerably or eliminates defects such as the centre line segregation, voids and cracks at or near the strip surface that are always present in conventional TRC strip. The newly-designed homogenization treatment investigated for TRC and MC-TRC magnesium alloy strips was based on microstructural evolution obtained during heat treatment. The results of the MC-TRC strips showed a much faster recrystallization rate with finer recrystallized grains, which are due to more homogeneous and a finer grain size of the as-cast MC-TRC strips compared with the as-cast TRC strips. During down-stream processing, the effects of MC-TRC process on microstructural evolution of hot-rolled magnesium strips have been understood thoroughly by accurate control of the hot-rolling procedure during each step of strip thickness reduction. This study indicates that the MC-TRC strip requires fewer rolling steps when compared to TRC strip, thus offering reduced processing cost and carbon footprint. Mechanical properties at room temperature of MC-TRC as-cast and rolled sheets are much improved when compared with the conventional TRC as-cast and rolled sheets which can result in a higher quality of final components. The mechanical properties at elevated temperature shows for the first time that the higher elongation and lower yield strength of MC-TRC as-cast strips at a temperature close to its optimised hot-rolling temperature results in better ability for rolling and higher ductility of MC-TRC Mg strip compared with the TRC Mg strip.

A new range of multi-plankton biogeochemical models have recently been developed, designed to advance our understanding of the ocean carbon cycle to improve predictions of its future influence on climate. Synoptic measurements of the different phytoplankton communities are required to validate and ultimately improve such models. Measuring ocean colour from satellite is the only method currently available for synoptically monitoring wide-area properties of ocean ecosystems, such as phytoplankton chlorophyll biomass. Recently, a variety of bio-optical methods have been established that use satellite data to identify and differentiate between either phytoplankton functional types (PFTs) or phytoplankton size classes (PSCs). In this thesis, several of these techniques were evaluated against in situ observations (6504 samples) to determine their ability to detect dominant phytoplankton size classes (micro-, nano- and picoplankton). Results show that spectral-response, ecological and abundance-based approaches can all perform with similar accuracy. However, abundance-based approaches provide better spatial retrieval of PSCs. Based on insights into the abundance-based models, and by utilising a large pigment database, a new three-component model was developed which calculates the fractional contributions of three phytoplankton size classes (micro-, nano- and picoplankton) to the overall chlorophyll-a concentration. Using a globally representative, independent, coupled pigment and satellite dataset the model estimates fractional contributions with a mean accuracy of 9.2 % for microplankton, 17.1 % for nanoplankton and 16.1 % for picoplankton. The effect of optical depth on the model parameters was also investigated and explicitly incorporated into the model. Using the three-component model, the two-component absorption model of Sathyendranath et al. (2001) and Devred et al. (2006) was extended to three-component populations of phytoplankton, namely, pico-, nano- and microplankton. The new model infers total and size-dependent phytoplankton absorption as a function of the total chlorophyll-a concentration. A main characteristic of the model is that all the parameters that describe it have biological or optical interpretation. The three-component model performs better than the two-component model, at retrieving total phytoplankton absorption. Accounting for the contribution of pico- and nanoplankton, rather than the combination of both used in the two-component model, improved significantly the retrieval of phytoplankton absorption at low chlorophyll-a concentrations. The three-component model was applied to a decade of ocean colour observations. In the equatorial region of the Pacific and Indian Oceans, phytoplankton size class anomalies (% total chlorophyll-a) were highly correlated with indices of both the El Niño (La Niña) Southern Oscillation and the Indian Ocean Dipole. Furthermore, in these regions, micro- and nanoplankton size class anomalies were negatively correlated with anomalies of the sea surface temperature, sea surface height and stratification. Whereas, the picoplankton size class anomalies were positively correlated with these physical variables. Results from this thesis indicate that phytoplankton size class can be retrieved from Earth Observation with reasonable accuracy. It is recommended that such information can now be assimilated into multi-plankton biogeochemical models, or alternatively, verify them.

Effective monitoring and modelling of the marine environment is of importance to both the general public and the scientific community, but relies on the ability to obtain accurate measurements of suspended particle characteristics. Many instruments for measuring particles rely on optical and acoustic scattering from the particles and use this information to infer a particle size and concentration. However, assumptions such as spherical particles of a known composition are widely used, both in measurement technology and in numerical modelling. Various imaging techniques have shown great variability in the shape, size and composition of marine particles when measured within their natural environment. Subsequently, there is substantial uncertainty in the response of light scattering instruments to this diverse range of particles. In this study, a holographic camera was modified to simultaneously record in-focus images of marine particles with their forward angle scattering characteristics. This was achieved by combining both laser scattering and transmissometry with digital holography. The results from this system were compared with theoretical models of scattering from spherical particles within the intended size range of both instruments (15-500microns), with particle size information from both techniques agreeing well during these idealised conditions. The combined holographic and light scattering system was then used to investigate the response of the LISST-100 (Sequoia Scientific Inc.) to spherical particles with diameters extending beyond that intended by the instrument 250microns for type-B and 500microns for type-C derivatives), but that have been observed in-situ with imaging methods. This revealed an aliasing of single large particles into multiple smaller particles during the inversion of LISST-100 scattering into a particle size distribution. For spheres greater than the type-C instrument range, the inversion of scattering produces particle volume distributions that peak at varying sizes between 250-400microns. This key finding highlights the need for care to be taken when interpreting particle size distributions from the LISST-100 when there is potential for particles outside of its range limit. Natural particles, extracted from coastal waters, were then recorded by the combined laboratory system. These complex particles produced highly variable scattering properties which were contaminated by asymmetrical features within the azimuthal plane. This observation of strong azimuthal asymmetry is of concern for both measurements and models of optical properties that assume a symmetrical scattering function for natural particle populations. The azimuthal asymmetry in scattering contributed to additional variability in the response of the instrument in comparison to the holographic camera, which was also subjected to apparent particle break-up via segmentation during image processing. A discussion of holographic imaging and laser diffraction for characterising particles in-situ forms the final part of this thesis, which utilises data from a magnified holographic system that covers the same size range of the LISST-100. This final analysis demonstrated the need for future technology to accurately measure size distributions over a much larger range of sizes than is currently possible (e.g. &lt;2microns to 1000microns). In summary, three key factors were identified to cause an increase in the apparent number of small particles reported by the LISST-100: 1) contamination from scattering of particles larger than the intended size range of the instrument; 2) a decrease in refractive index (particle composition); 3) additional scattering from small sub-components of particle geometry. The standard holographic camera systems are capable of accurately obtaining particle size and concentration measurements that are comparable to other techniques such as the LISST-100. However, in situations where background illumination is poor, errors in the image processing routines can cause an apparent particle break-up due to incorrect binarisation. Despite this, the holographic method provides a unique and powerful mechanism that enables images of particles to be analysed within the context of their in-situ environment.

The purpose of this study was to create an understanding of how group leaders manage their worktime and what conditions the group leader needs to conduct their work assignments. The research design was a single case study that was performed on a larger corporation´s central warehouse. The data collection consisted of semi structured interviews with six group leaders. Furthermore, an inventory of the worktime was made in which the group leaders themselves estimated their worktime during a month of work. The results showed that the group leaders experienced a lack of time but that the conditions were good for leadership. Progress was promoted and the space of action was big. The time inventory showed that the group leaders’ average work were made of 52 hours. The study discusses the job description, which was too wide and should be focused more towards the group. The conclusion was that the group leaders worked reactively, more assignments should be focused towards the group. The job description needed to be better defined and the groups were too big and there were time constraints which affected the work.