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Oxygen electrocatalysis on ruthenium metal and its pyrochloresPrakash, Jai January 1990 (has links)
No description available.
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In Situ Spectroelectrochemical Techniques Applied to ElectrocatalysisShi, Ping 14 April 2006 (has links)
No description available.
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Fabrication of Nanoparticle Based Electrocatalytic CompositesWiaderek, Kamila Magdalena 21 November 2011 (has links)
No description available.
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Electrocatalytic and Photocatalytic CO2 Reduction by Ru-Re Bimetallic ComplexesXue, Congcong 31 August 2016 (has links)
No description available.
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Synthesis and characterization of nanocatalysts for applications in water purification and hydrogen production.Popat, Yaksh Jyotindra 12 December 2019 (has links)
The thesis focuses on synthesis and characterization of nanocatalysts for applications in wastewater treatment and hydrogen production through electrochemical water splitting. Different photocatalysts and electrocatalysts are synthesized using wet chemistry techniques as well as Pulsed Laser Deposition (PLD). The synthesized catalysts pave demonstrate excellent catalytic activity thereby paving way for their use on an industrial scale.
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Nanostructure of transition metal and metal oxide forelectrocatalysisGu, Yanjuan., 谷艳娟. January 2006 (has links)
published_or_final_version / abstract / Chemistry / Doctoral / Doctor of Philosophy
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Synthesis, characterization, and oxygen evolution reaction catalysis of nickel-rich oxidesTurner, Travis Collin 30 September 2014 (has links)
A successful transition from fossil fuels to renewable energies such as wind and solar will require the implementation of high-energy-density storage technologies. Promising energy storage technologies include lithium-ion batteries, metal-air batteries, and hydrogen production via photoelectrochemical water splitting. While these technologies differ substantially in their mode of operation, they often involve transition-metal oxides as a component. Thus, fundamental materials research on metal oxides will continue to provide much needed advances in these technologies. In this thesis, the electrochemical and electrocatalytic properties of Fe- and Mn-substituted layered LiNiO₂ materials were investigated. These materials were prepared by heating mixed nitrate precursors in O₂ atmosphere at 700-850 °C for 12 h with intermediate grindings. The products were chemically delithiated with NO₂BF₄, and the delithiated samples were annealed at moderate temperatures in order to transform them to a spinel-like phase. Samples were characterized by inductively coupled plasma analysis and Rietveld refinement of the X-ray diffraction patterns, which were found to be in reasonably close agreement regarding lithium stoichiometry. Spinel-like materials were found to possess an imperfect spinel structure when heated at lower temperatures and a significant amount of NiO impurity was formed when heated to higher temperatures. This structural disorder was manifested during electrochemical cycling -- only Mn-rich compositions showed reversible capacities at a voltage of around 4.5 V. The layered materials exhibited significant capacity loss upon cycling, and this effect was magnified with increasing Fe content. These materials were further investigated as catalysts for the oxygen evolution reaction (OER). All samples containing Mn exhibited low OER activity. In addition, delithiation degraded catalyst performance and moderate temperature annealing resulted in further degradation. Because delithiation significantly increased surface area, activities were compared to the relative to BET surface area. Li₀.₉₂Ni₀.₉Fe₀.₁O₂ exhibited significantly higher catalytic activity than Li₀.₈₉Ni₀.₇Fe₀.₃O₂. This prompted testing of Li[subscript x]Ni₁₋[subscript y]Fe[subscript y]O₂ (y = 0, 0.05, 0.1, 0.2, and 0.3) samples. It was found that a Fe content of approximately 10% resulted in the highest OER activity, with decreased activities for both larger and smaller Fe contents. These results were found to be consistent with studies of Fe substituted nickel oxides and oxyhydroxides, suggesting a similar activation mechanism. / text
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Développement de catalyseurs pour un électrolyseur alcalin H2/O2 / Catalysts for H2/O2 producer devicePătru, Alexandra 22 February 2013 (has links)
Le travail de thèse présenté dans ce mémoire, est consacré à l'étude des nouveaux matériaux d'électrodes pour l'électrolyse de l'eau en milieu alcalin. L'objectif de ces études est de développer de nouveaux électrocatalyseurs à base de métaux non nobles, capables d'améliorer les cinétiques de réactions intervenant dans la décomposition de l'eau : l'évolution de l'hydrogène (HER) et l'évolution de l'oxygène (OER). L'amélioration des performances catalytiques se traduit par une diminution des surtensions de réaction et donc de l'énergie nécessaire à la production de l'hydrogène. Pour cela, nous avons choisir de réaliser des électrodes à base de nanoparticules de nickel et de cobalt pour l'HER et de nanoparticules de cobaltites de cobalt, Co3O4, pour l'OER. La mise au point de plusieurs méthodes innovantes de formulation des électrodes (dépôt par électrophorèse « réactive » et électrodes composites à base liant organique fonctionnel) a permis la réduction des surtensions des réactions. Pour une densité de courant de 100 mA cm-2, une surtension cathodique de -286 mV est nécessaire avec les électrodes composites à base de nanoparticules de nickel, -238 mV pour une électrode en Co obtenue par électrophorèse et une surtension anodique 323 mV pour une électrode composite à base de nanoparticules de Co3O4. Une étude électrochimique approfondie de l'HER a été réalisée sur différentes morphologies de nanoparticules de nickel. / The PhD work, presented in this manuscript, is devoted to the study of new electrode materials for alkaline water electrolysis.The aim of this study is to develop new electrocatalysts based on non-noble metals. These catalysts are designed to improve the kinetics of the reactions involved in the water splitting: hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The improvement of catalytic reaction results in the decrease of the overpotentials and therefore the saving of energy needed for hydrogen production. To do that, nickel and cobalt nanoparticles were used for HER, and Co3O4 nanoparticles for OER. The development of several innovative methods for electrode formulation (deposition by electrophoresis and composites electrodes based on a functional organic binder) reduced the overpotential reactions. For a current density of 100 mA cm-2, -286 mV of cathodic overpotential is needed for composites electrodes based on nickel nanoparticles, -238 mV for a Co-based electrode made by electrophoresis and 323 mV of anodic overpotential for a Co3O4 -based composite electrode. A detailed electrochemical study was made for HER on various morphologies of nickel nanoparticles.
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Gold and gold-palladium branched nanocrystals for applications in plasmonic catalysis and electrocatalysis / Nanocristais ramificados de ouro e ouro-paládio para aplicações em catálise e eletrocatálise plasmônicaSilveira, Vitor Renato Ribeiro 28 January 2019 (has links)
The harvesting of solar light is one of the main challenges in science. The outstanding optical properties of plasmonic in the visible and near-infrared ranges due to the localized surface plasmon resonance (SPR) has emerged as a promising approach for the solar-tochemical energy conversion. Specifically, it has been demonstrated that the SPR excitation in the visible range in silver (Ag) and gold (Au) nanoparticles can drive and accelerate chemical transformations. This field, coined plasmonic catalysis, enables one to merge catalytic and optical properties in the nanoscale and use visible or near-infrared light as a sustainable energy input to accelerate molecular transformations. In the first part of this thesis. we developed Au branched nanostructures to be employed as plasmonic catalysts. In this case, we aimed at investigating the effect of the sharp tips at their surface over their plasmonic catalytic performance, as it is established that tips can concentrate higher electric field enhancements relative to rounded surfaces as a result of the lightning rod effect, which, in turn, can translate into higher plasmonic catalytic performances. Here, the plasmonic-catalytic performances were tested using the SPR mediated oxidation of paminothiophenol and benzylamine as model transformations. While the Ag and Au nanoparticles support LSPR excitation in the visible and near-infrared ranges, their catalytic properties are limited in terms of versatility. Conversely, metals that are important in catalysis, such as palladium Pd, do not support SPR excitation in the visible or near-infrared range. In the second part of this thesis, we developed multimetallic nanoparticle morphologies, composed of both Au and Pd, that enabled us to marry catalytic and plasmonic component in order to address this challenge. We focused on plasmonic core-catalytic shell structures, in which the shell displayed a branched morphology. Parameters such as shell thickness could be controlled, and structure performance relationships were established towards the methanol electro-oxidation under plasmonic excitation. / O aproveitamento da luz solar é um dos principais desafios da ciência. As excepcionais propriedades óticas plasmônicas nas regiões do visível e do infravermelho próximo, devido a ressonância plasmônica de superfície localizada (SPR), surgiram como uma abordagem promissora para conversão de energia solar em energia química. De maneira mais específica, vem sendo demonstrado que a excitação SPR na região do visível em nanopartículas de prata (Ag) e ouro (Au) podem conduzir e acelerar transformações químicas. Esse campo, chamado catálise plasmônica, permite a fusão de propriedades óticas e catalíticas na nanoescala e a utilização de luz visível ou infravermelha próxima como uma fonte de energia para acelerar transformações moleculares. Na primeira parte desta dissertação, nós desenvolvemos nanoestruturas de ouro ramificadas para serem empregadas em catálise plasmônica. Neste caso, nosso foco era investigar o efeito de pontas afiadas em sua superfície sobre seu desempenho catalítico plasmônico, visto que está bem estabelecido que pontas podem concentrar maiores intensificações de campo elétrico em relação a superfícies arredondadas como resultado do \"efeito para-raios\" o que, por sua vez, pode se traduzir em maiores desempenhos em catálise plasmônica. O desempenho da catálise plasmônica foi testado através da oxidação mediada por SPR do p-aminotiofenol e da benzilamina como reações modelo. Contudo, enquanto nanopartículas de prata e ouro apresentam excitação SPR nas regiões do visível e infravermelho próximo, suas propriedades catalíticas são limitadas em termos de versatilidade. Por outro lado, metais que são importantes em catálise, como o paládio, não apresentam excitação SPR no visível e infravermelho próximo. Por isso, na segunda parte desta dissertação, nós desenvolvemos nanopartículas multimetálicas, compostas de Au e Pd, que nos permitem unir os componentes catalíticos e plasmônicos com o objetivo de enfrentar este desafio. Nós focamos em estruturas do tipo core-shell, com núcleos plasmônicos e cascas catalíticas, na qual a casca apresenta morfologia ramificada. Paramêtros como a espessura da casca puderam ser controlados, e a relação estruturaperformance foi estabelecida através da eletro-oxidação do metanol sobre excitação plasmônica.
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Synthesis of Strained Metal Nanocrystal Architectures for Energy Conversion ElectrocatalysisSneed, Brian Thomas January 2015 (has links)
Thesis advisor: Chia-Kuang F. Tsung / Thesis advisor: Dunwei Wang / In order to understand the lattice strain effect and its relationship to size, shape, composition, and catalytic performance, novel well-defined nanocrystal archetypes were designed and synthesized by taking advantage of wet chemical, seed-mediated (mild) reduction routes developed by our lab. First, the current synthesis challenges are addressed in creating smaller monometallic shape-controlled metal nanocrystals, and novel cuboctopods via a hybrid nanoparticle stabilizer. A look at the relationship between lattice strain and morphology is then shown in a single-component system, where still new features have been observed for the first time by the traditional technique of powder x-ray diffraction. Synthesis methods for differently strained Pd surfaces are described and catalysis by these surfaces is discussed. Finally, studies of the synthesis, characterization, electrocatalytic activity, and restructuring of novel and more sophisticated strained architectures are presented: core-island-shell nanocrystals, phase-segregated nanoboxes, island nanoframeworks, and core-sandwich-shell nanoparticles. Lattice strain and composition effects were studied in carbon monoxide, small alcohol, and formic acid electrocatalytic oxidations as well as in oxygen reduction, the latter of which, governs the commercial viability of automotive fuel cells, a sustainable energy and zero-emission technology. Here it is demonstrated how a tunable thickness of Ni sandwich layers can be used to improve catalytic performance by increasing lattice strain on the Pt surface. The sandwich archetype offers a new platform for the investigation of lattice strain and could be a promising, industrially relevant, catalyst design concept, to help address the need for a more sustainable energy future. The results help paint a new picture of catalysis by metal nanocrystals; one which brings lattice strain to the forefront of the discussion, as an important parameter for further study and for use in developing higher-performing catalysts. / Thesis (PhD) — Boston College, 2015. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Chemistry.
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