Polydimethylsiloxane (PDMS) mechanical properties were measured using custom-built compression test device. PDMS elastic modulus can be varied with the elastomer base to the curing agent ratio, i.e. by changing the cross-linking density. PDMS samples with different crosslink density in terms of their elastic modulus were measured. In this project the PDMS samples with the base/curing agent ratio ranging from 5:1 to 20:1 were tested. The elastic modulus varied with the amount of the crosslinker, and ranged from 0.8 MPa to 4.44 MPa. The compression device was modified by adding digital displacement gauges to measure the lateral strain of the sample, which allowed obtaining the true stress-strain data. Since the unloading behavior was different than the loading behavior of the viscoelastic PDMS, it was utilized to asses viscoelastic properties of the polymer. The thesis describes a simple method for measuring mechanical properties of soft polymeric materials.

There is a technological need for hard thin films with high elastic modulus. Silicon Carbide (SiC) fulfills such requirements with a variety of applications in high temperature and MEMS devices. A detailed study of SiC thin films mechanical properties was performed by means of nanoindentation. The report is on the comparative studies of the mechanical properties of epitaxially grown cubic (3C) single crystalline and polycrystalline SiC thin films on Si substrates. The thickness of both the Single and polycrystalline SiC samples were around 1-2 µm. Under indentation loads below 500 µ-Newton both films exhibit Elastic contact without plastic deformation. Based on the nanoindentation results polycrystalline SiC thin films have an elastic modulus and hardness of 422 plus or minus 16 GPa and 32.69 plus or minus 3.218 GPa respectively, while single crystalline SiC films elastic modulus and hardness of 410 plus or minus 3.18 Gpa and 30 plus or minus 2.8 Gpa respectively. Fracture toughness experiments were also carried out using the nanoindentation technique and values were measured to be 1.48 plus or minus 0.6 GPa for polycrystalline SiC and 1.58 plus or minus 0.5 GPa for single crystal SiC, respectively. These results show that both polycrystalline SiC thin films and single crystal SiC more or less have similar properties. Hence both single crystal and polycrystalline SiC thin films have the capability of becoming strong contenders for MEMS applications, as well as hard and protective coatings for cutting tools and coatings for MEMS devices.

This thesis describes a numerical modelling methodology to interpret dynamic fluctuations in pore-pressures to isolate the effects of loading associated with changes in total soil moisture (site water balance) alone. The methodology is required to enhance the data-interpretation and performance-assessment for potential applications of a novel piezometer-based, large-scale, geological weighing lysimeter. This interpretative methodology is based on a method of superimposing computer-based numerical analyses of independent causes of pore-pressure transients to separate the different pore-pressure responses. Finite element coupled load-deformation and seepage numerical models were used to simulate field-observed piezometric responses to water table fluctuations and loading induced by surface water balance (using meteorological data).<p> Transient pore-pressures in a deep clay-till-aquitard arising from variations in the water table within a surface-aquifer were modelled and removed from the measured pore-pressure record (corrected for earth tide and barometric effects) to isolate and identify pore-pressure fluctuations arising from loading associated with site water balance. These estimates were compared to simulated pore-pressure responses to an independently measured water balance using meteorological instrumentation. The simulations and observations of the pore-pressure responses to surface water balance were in good agreement over the dry years of a 9-year period. Some periods of significant differences did occur during wet years in which runoff, which is not accounted for in the current analyses, may have occurred.<p> The identification of pore-pressure response to total soil moisture loading using the developed numerical modelling methodology enhances the potential for the deployment of the piezometer-based geological weighing lysimeter for different applications which include real-time monitoring of site water balance and hydrological events such as precipitation and flooding. Interestingly, the disparity occurring during the wet years even suggests the potential to adapt the method to monitor runoff (net lateral flow).<p> The methodology also demonstrated the capability to accurately estimate in situ elastic and hydraulic parameters. Calibration of the model yielded equivalent properties of the aquitard (hydraulic conductivity, Kv, of 2.1E-5 m/day and specific storage, Ss, of 1.36E-5 /m) for a Skemptons B-bar coefficient of 0.91 for an assumed porosity of 0.26. Sensitivity tests also provided insight into the consolidation and pressure propagation (swelling) behaviour of the aquitard under parametric variations. The parameters obtained are consistent with range of values reported for glacial clay till soil. Therefore, this work also provides a unique case history of a method for determining, large scale, in situ material properties for geo-engineers and scientists to explore by simply using piezometric and meteorological data.

The growing cost of energy combined with the increasing energy demand has driven the need for more efficient energy use. Air-to-air energy recovery in buildings has been shown to provide substantial energy savings in many cases. A new type of air-to-air energy recovery system, known as a run-around energy exchanger (RAEE), and which has excellent potential for the retrofit market, has been proposed and numerically modelled for heat and moisture exchange by Fan et al. (2006). This thesis focuses on the material properties of semi-permeable membranes required for each RAEE exchanger core.<p>Two commercially available membranes are considered in this thesis: a spunbonded polyolefin manufactured by DuPont with the trade name Tyvek®, and a two layer polypropylene laminate material manufactured by the 3M Company with the trade name Propore.<p>The moisture transfer effectiveness of the RAEE system depends mostly on the ability of its membrane to transfer water vapour. This effectiveness is investigated by measuring the vapour diffusion resistance of Tyvek® and Propore using a dynamic moisture permeation cell (DMPC). For Tyvek®, the average vapour diffusion resistance is 440 s/m, which corresponds to an expected typical RAEE energy recovery effectiveness of 52%. For Propore, the average vapour diffusion resistance is 140 s/m, which corresponds to an RAEE effectiveness of 62% in the same exchanger system.<p>The air permeability is also measured using the DMPC with Tyvek® having a Darcy air flow resistance of 27 nm-1 and Propore having a Darcy air flow resistance of 111 nm-1. The lower air flow resistance of Tyvek® is undesirable since air transfer is undesirable in the RAEE system. <p>The liquid penetration pressure is determined using a modified standard method that resembles the geometry of a membrane in the RAEE exchanger. It is found that the Propore has a liquid penetration pressure beyond the measurement capabilities of the apparatus (276 kPa); while the Tyvek® membrane has a liquid penetration pressure of 18 kPa which agrees well with published values. <p>The elastic moduli of the membranes are required to predict the membrane deflection under typical operating pressures and to properly size a support screen. The elastic modulus is determined using two tensile standards and a bulge test. The bulge test results are used in the design since the geometry of the bulge test better represents the situation of a pressurized membrane in the RAEE. The elastic modulus of Propore is found to be 20 ± 3 MPa and the elastic modulus of Tyvek® is found to be 300 ± 45 MPa. The values are used in subsequent calculations for sizing the square screen, where it is found that a screen with square openings of 12.7 mm (0.5 in.) is required to support the membrane. <p>The degradation of Tyvek® and Propore with UVC exposure is also investigated. It is found that both materials deteriorate when exposed to UVC radiation, and that the degradation is primarily a function of the exposure time and not the exposure intensity. <p>Considering all material properties tested, it is concluded that the Propore membrane is a better membrane choice for the RAEE than the Tyvek® membrane.

The growing cost of energy combined with the increasing energy demand has driven the need for more efficient energy use. Air-to-air energy recovery in buildings has been shown to provide substantial energy savings in many cases. A new type of air-to-air energy recovery system, known as a run-around energy exchanger (RAEE), and which has excellent potential for the retrofit market, has been proposed and numerically modelled for heat and moisture exchange by Fan et al. (2006). This thesis focuses on the material properties of semi-permeable membranes required for each RAEE exchanger core.<p>Two commercially available membranes are considered in this thesis: a spunbonded polyolefin manufactured by DuPont with the trade name Tyvek®, and a two layer polypropylene laminate material manufactured by the 3M Company with the trade name Propore.<p>The moisture transfer effectiveness of the RAEE system depends mostly on the ability of its membrane to transfer water vapour. This effectiveness is investigated by measuring the vapour diffusion resistance of Tyvek® and Propore using a dynamic moisture permeation cell (DMPC). For Tyvek®, the average vapour diffusion resistance is 440 s/m, which corresponds to an expected typical RAEE energy recovery effectiveness of 52%. For Propore, the average vapour diffusion resistance is 140 s/m, which corresponds to an RAEE effectiveness of 62% in the same exchanger system.<p>The air permeability is also measured using the DMPC with Tyvek® having a Darcy air flow resistance of 27 nm-1 and Propore having a Darcy air flow resistance of 111 nm-1. The lower air flow resistance of Tyvek® is undesirable since air transfer is undesirable in the RAEE system. <p>The liquid penetration pressure is determined using a modified standard method that resembles the geometry of a membrane in the RAEE exchanger. It is found that the Propore has a liquid penetration pressure beyond the measurement capabilities of the apparatus (276 kPa); while the Tyvek® membrane has a liquid penetration pressure of 18 kPa which agrees well with published values. <p>The elastic moduli of the membranes are required to predict the membrane deflection under typical operating pressures and to properly size a support screen. The elastic modulus is determined using two tensile standards and a bulge test. The bulge test results are used in the design since the geometry of the bulge test better represents the situation of a pressurized membrane in the RAEE. The elastic modulus of Propore is found to be 20 ± 3 MPa and the elastic modulus of Tyvek® is found to be 300 ± 45 MPa. The values are used in subsequent calculations for sizing the square screen, where it is found that a screen with square openings of 12.7 mm (0.5 in.) is required to support the membrane. <p>The degradation of Tyvek® and Propore with UVC exposure is also investigated. It is found that both materials deteriorate when exposed to UVC radiation, and that the degradation is primarily a function of the exposure time and not the exposure intensity. <p>Considering all material properties tested, it is concluded that the Propore membrane is a better membrane choice for the RAEE than the Tyvek® membrane.

This thesis describes a numerical modelling methodology to interpret dynamic fluctuations in pore-pressures to isolate the effects of loading associated with changes in total soil moisture (site water balance) alone. The methodology is required to enhance the data-interpretation and performance-assessment for potential applications of a novel piezometer-based, large-scale, geological weighing lysimeter. This interpretative methodology is based on a method of superimposing computer-based numerical analyses of independent causes of pore-pressure transients to separate the different pore-pressure responses. Finite element coupled load-deformation and seepage numerical models were used to simulate field-observed piezometric responses to water table fluctuations and loading induced by surface water balance (using meteorological data).<p> Transient pore-pressures in a deep clay-till-aquitard arising from variations in the water table within a surface-aquifer were modelled and removed from the measured pore-pressure record (corrected for earth tide and barometric effects) to isolate and identify pore-pressure fluctuations arising from loading associated with site water balance. These estimates were compared to simulated pore-pressure responses to an independently measured water balance using meteorological instrumentation. The simulations and observations of the pore-pressure responses to surface water balance were in good agreement over the dry years of a 9-year period. Some periods of significant differences did occur during wet years in which runoff, which is not accounted for in the current analyses, may have occurred.<p> The identification of pore-pressure response to total soil moisture loading using the developed numerical modelling methodology enhances the potential for the deployment of the piezometer-based geological weighing lysimeter for different applications which include real-time monitoring of site water balance and hydrological events such as precipitation and flooding. Interestingly, the disparity occurring during the wet years even suggests the potential to adapt the method to monitor runoff (net lateral flow).<p> The methodology also demonstrated the capability to accurately estimate in situ elastic and hydraulic parameters. Calibration of the model yielded equivalent properties of the aquitard (hydraulic conductivity, Kv, of 2.1E-5 m/day and specific storage, Ss, of 1.36E-5 /m) for a Skemptons B-bar coefficient of 0.91 for an assumed porosity of 0.26. Sensitivity tests also provided insight into the consolidation and pressure propagation (swelling) behaviour of the aquitard under parametric variations. The parameters obtained are consistent with range of values reported for glacial clay till soil. Therefore, this work also provides a unique case history of a method for determining, large scale, in situ material properties for geo-engineers and scientists to explore by simply using piezometric and meteorological data.

Material property heterogeneity is present ubiquitously in various natural and man-made materials, such as bones, seashells, rocks, concrete, composites, and functionally graded materials. A fundamental understanding of the structure-property relationships in these material systems is crucial for the development of advanced materials with extreme properties. Well-developed homogenization schemes exist to establish such relationships in elasticity, electrostatics, magnetism, and other time- or history-independent material properties. Nevertheless, one’s understanding of the effective fracture properties of heterogeneous media is remarkably limited. The challenge here is that heterogeneous fracture, as a history-dependent process, involves complex interaction and negotiation of a discontinuity front with local heterogeneities. The determination of effective fracture properties necessitates a critical interrogation of this evolutionary process in detail. In this work, a combined experimental and modeling effort is made to examine and control fracture mechanisms in heterogeneous elastic solids. A two-phase laminated composite, which mimics the key microstructural features of many tough biological materials, is selected as a model material. In the computational part of this work, finite element analysis with cohesive zone modeling is used to model crack propagation and arrest in the laminated direction. A crack-tip-opening controlled algorithm is implemented to overcome the instability problems associated with inherently unstable crack growth. Computational results indicate that the mismatch of elastic modulus is an important factor in determining the fracture behaviors of the heterogeneous model material. Significant enhancement in the material’s effective fracture toughness can be achieved with appropriate modulus mismatch. Systematic parametric studies are also performed to investigate the effects of various material and geometrical parameters, including modulus mismatch ratio, phase volume fractions, T-stress, and cohesive zone size. Concurrently, a novel stereolithography-based additive manufacturing system is developed and used for fabricating heterogeneous test specimens with well-controlled structural and material properties. Fracture testing of each specimen is performed using the tapered double-cantilever beam (TDCB) test method. With optimized material and geometrical parameters, heterogeneous TDCB specimens are found to exhibit higher fracture toughness than their homogenous counterparts, which is in good agreement with the computational predictions. The integrative computational and experimental study presented here provides a fundamental mechanistic understanding of the fracture mechanisms in brittle heterogeneous materials and sheds light on the rational design of ultra-tough materials through patterned heterogeneities.

This thesis describes the development of a high-throughput approach towards the encapsulation of cancer cells in biopolymer microgels with tunable mechanical properties. In particular, this thesis is focused on: i) the high-throughput generation of biopolymer microgels with tunable mechanical properties ii) the measurement of the mechanical properties of the microgels, and iii) the high-throughput encapsulation of a cancer cell line within biopolymer gels. The microgels will be generated by (i) introducing in a microfluidic device two distinct streams of biopolymer solutions; (ii) mixing the streams; (iii) emulsifying the biopolymer and (iv) using thermosetting to transform the droplets in situ into microgels. By applying a compression force to the hydrogel microbead and measuring its deformation, the Young’s modulus and relaxation time of the microgel can be examined. The properties of cells were examined within the gels using various spectroscopic techniques such as absorption (UV-Vis) and fluorescence microscopy (fluorescent microscopy, confocal microscopy).

This thesis describes the development of a high-throughput approach towards the encapsulation of cancer cells in biopolymer microgels with tunable mechanical properties. In particular, this thesis is focused on: i) the high-throughput generation of biopolymer microgels with tunable mechanical properties ii) the measurement of the mechanical properties of the microgels, and iii) the high-throughput encapsulation of a cancer cell line within biopolymer gels. The microgels will be generated by (i) introducing in a microfluidic device two distinct streams of biopolymer solutions; (ii) mixing the streams; (iii) emulsifying the biopolymer and (iv) using thermosetting to transform the droplets in situ into microgels. By applying a compression force to the hydrogel microbead and measuring its deformation, the Young’s modulus and relaxation time of the microgel can be examined. The properties of cells were examined within the gels using various spectroscopic techniques such as absorption (UV-Vis) and fluorescence microscopy (fluorescent microscopy, confocal microscopy).

Osteoporosis is a disease characterized by reduced bone mass and reduced bone quality. This deterioration manifests itself in osteoporotic fractures at skeletal sites containing large proportions of cancellous bone (ie. forearm, hip, spine). Given the costs associated with these fractures, improvements in our ability to model and predict the behaviour of cancellous bone would be of great financial and social benefit to society. This thesis makes contributions in three areas within the much larger goal of developing a comprehensive model for describing the mechanical behaviour of cancellous bone. Since the accuracy of model predictions can only be as good as the test data against which it is compared, the effect of experimental artifacts introduced by specimen geometry is examined for cored samples. The apparent elastic modulus of cancellous bone is found to be relatively insensitive to specimen (or gauge) length, such that it can be reduced below the recommended 2:1 aspect ratio without introducing detectable artifact. Conversely, apparent modulus is found to be much more sensitive to specimen diameter. The role of water is also examined. Dehydration at room temperature was found to increase the apparent elastic modulus by roughly 14%. This net increase results from the competing effects of an increased tissue modulus and a decreased bone volume fraction due to shrinkage. Finally, preliminary work is presented which attempts to relate micro-CT voxel intensity and locally measured nanoindentation moduli, in order to provide an experimental basis for assigning heterogeneous material properties to finite element method (FEM) models. / Thesis (Ph.D, Mechanical and Materials Engineering) -- Queen's University, 2009-04-24 14:28:17.772