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Heat shrink tubing is used to insulate wire conductors, protect wires, and to create cable entry seals in wire harnessing industries. Performing this sensitive process manually is time consuming, the results are strongly dependent on the operator’s expertise, and the process presents safety concerns. Alternatively, automating the process minimizes the operators’ direct interaction, decreases the production cost over the long term, and improves quantitative and qualitative production indicators dramatically. This thesis introduces the automation of a heat shrink tubing prototype machine that benefits the wire harnessing industry. The prototype consists of an instrumented heat chamber on a linear positioning system, and is fitted with two heat guns. The chamber design allows for the directing of hot air from the heat guns onto the wire harness uniformly through radially-distributed channels. The linear positioning system is designed to move the heat chamber along the wire harness as the proper shrinkage temperature level is reached. Heat exposure time as a major factor in the heat shrink tubing process can be governed by controlling the linear speed of the heat chamber. A control unit manages the actuator position continuously by measuring the chamber’s speed and temperature. A model-based design approach is followed to design and test the controller, and MATLAB/Simulink is used as the simulation environment. A programmable logic controller is selected as the controller implementation platform. The control unit performance is examined and its responses follow the simulation results with adequate accuracy.

Mott insulators are a family of materials in which strong electron-electron interactions induce an unconventional insulating state in the system that would otherwise behave as an electrical conductor according to the non-interacting band theory. In particular, the nature of the Mott metal-insulator transition (MIT) has been the subject of intense research interest because it can involve a complicated interplay between magnetic and electronic properties. In some Mott systems, Mott transitions occur in the one-step process, from an antiferromagnetic insulator (AFI) to a paramagnetic metal phase (PMM), while in other Mott systems a two-step transition with an intermediate antiferromagnetic metal (AFM) phase can be observed. Since 2015, the muon spin relaxation (𝜇SR) group at Columbia University started systematic 𝜇SR studies on a series of Mott systems, including one-step transition Mott systems 𝑅𝐸NiO₃ and V₂O₃, as well as two-step transition Mott systems Ba(Co, Ni)S₂, Ni(S, Se)₂ and (La, Sr)VO₃. This dissertation first introduces the comprehensive 𝜇SR research on multiple families of Mott systems conducted by our 𝜇SR group, including 𝑅𝐸NiO₃, V₂O₃, and BaCoS₂. Then the 𝜇SR experimental findings on the Mott system NiS₂₋ₓSeₓ will be presented, which is the most extensively studied material in this thesis. The NiS₂₋ₓSeₓ system is of particular interest because there is a large region of intermediate AFM state emerging between AFI and PMM states with Se doping, making it an ideal platform to provide information on static magnetism in the AFM state and thus can help us better understand the evolution of magnetic NiS₂₋ₓSeₓ, with our key findings being: (1) The AFM state of the NiS₂₋ₓSeₓ system shows significantly random spin correlations, and the magnetic order is suppressed by a gradual reduction of the ordered moment size, with a nearly full ordered volume fraction until very close to the AFM-PMM boundary. (2) No signature of dynamic critical behavior was observed in the thermal phase transition, indicating a first-order thermal phase transition. The next part of this dissertation presents our computational simulations on the NiS₂₋ₓSeₓ system. Dipolar field simulations have shown that only the combination of easy axis randomization and Ni moment dilution in NiS₂ can lead to the internal field distribution corresponding to the observed 𝜇SR spectrum in the AFM region. Also, this picture could qualitatively explain the neutron and muon results consistently, thus reconciling the seemingly contradicting experimental results by 𝜇SR and the previous neutron scattering studies shown in the AFM region. Furthermore, we propose a percolation model that can capture both the charge and spin connections of the interpenetrating percolating spin and charge networks in the NiS₂₋ₓSeₓsystem, which raises the possibility of "compromising metallicity and magnetic order" in the two-step Mott transition evolving AFI to AFM to PMM states in NiS₂₋ₓSeₓ.

Barium Strontium Titanate (BST) was deposited on Pt/ZrO2 / SiO2/Si substrates using liquid source metal organic chemical vapor deposition. A stoichiometry series was deposited with various GrII/Ti ratios (0.658 to 1.022) and a temperature series was deposited at 550 to 700°C. The thin films were characterized using transmission electron microscopy. Both series of samples contained cubic perovskite BST and an amorphous phase. The grain size increased and the volume fraction of amorphous phase decreased with increasing deposition temperature. The electrical and microstructural properties improved as the GrII/Ti ratio approached 1 and deteriorated beyond 1. This research demonstrates that BST thin films are a strong candidate for future MOS transistor gate insulator applications.

The overall reliability of a power transformer depends to a great extent on the sound operation of the bushings thereof. In view of its overwhelming advantages, resin impregnated paper (RIP) is acquiring prominence over conventional oil impregnated paper (OIP) in transformer bushings. The main advantages of RIP bushings are low dielectric loss and capability of positioning them at any desired angle over the transformer. The RIP structure, being an all-solid system, is completely free from oil phase. The temperature rise in RIP bushings under normal operating conditions is seen to be a difficult parameter to control in view of the limited options for effective cooling. The degradation of dry-type insulation such as RIP is often due to thermal and electrical stresses. The long time performance thereof, depends strongly, on the maximum operating temperature. In order to be able to predict the regional temperature, it is necessary to consider the thermal and electrical parameters of insulation in question; and to identify and solve the governing equations under the relevant boundary conditions. Electrical failure of insulation is known to be an extremal random process wherein nominally identical specimens of equipment insulation, at constant stress fails at inordinately different times. In order to be able to estimate the life of power equipment like transformer bushing, it is necessary to run long duration ageing experiments under accelerated stresses, to acquire and analyze insulation specific failure data. The present work is an attempt to provide reliability and life estimation of High Voltage RIP bushing insulation. The literature survey carried out in this view indicate that investigation on thermal and electric field distribution and the models for failure under combined stress and analysis of the data so as to be able to estimate the possible life of RIP bushing is scanty. Having these aspects in focus, the scope of the present work is defined as: (i) Mapping of the temperature and electric field distribution in the body of 400kV RIP bushing (ii) Deduction of parameters of the probabilistic models for the failure under electrical and thermal ageing (iii) Estimation of life based on diagnostic testing using PD With this in view, the temperature distribution in the body of a 400kV RIP bushing is studied considering the heat generation both in central conductor and that in the insulation. Presence of multiple materials with non-confirming interfaces makes analytical solution rather difficult and hence numerical approach is adopted. In the present work, vertex-centered Finite Volume Method (FVM) is employed for both thermal and electrical analysis. The electric stress distribution is accurately evaluated considering both the non-zero conductivity of the RIP material and the presence of capacitive grading foils. These analysis has clearly shown that Stress grading foils uniforms the stress across the major portion of the bushing insulation Enhancement of the electric conductivity by the temperature is not found to be affective in changing the electric field distribution The temperature distribution is shown to have a maxima near the flange due to the influence of top oil temperature of the transformer Heat generated in the dielectric due to the prevailing electric stress is shown to be insignificant. This ruled out the possibility of thermal runaway and hence the dielectric temperature is within the safe working limits for the bushing considered. The deduction of physical models governing insulation failure depends on the nature of stress. In this work, the insulation failure at constant accelerated stress has been considered and the estimation of life is computed based on inverse power law coupled with Arrhenius law. A high degree of scatter is generic to the experimental data forming the ingredients to develop the models. In view of this, the concept of a random process is invoked. Probabilistic models for the failure of RIP bushing under synergy are adopted and an attempt is made to estimate the life. The well known Weibull distribution and probability plotting of life data is used in this endeavor. The maximum likelihood estimation is used to determine the scale and shape parameters of the Weibull distribution. In the diagnosis of the extent of degradation of insulation due to PD, under long duration electric stress, a non-conventional voltage application method called the classical stepped stress method is adopted. In this technique, the voltage is applied in pre-determined steps over predetermined duration of time. The magnitude of voltage steps is carefully computed based on Miners law and the end-of-life is computed using inverse power law. In summary, this thesis work has contributed to the thermal and electrical degradation of resin impregnated paper insulation for high voltage transformer bushing. The thermal and electrical field distributions computed in the body of bushing clearly shown that these stresses are well within the limit, thereby ruling out the possibility of a thermal runaway. Comparing the estimates of the most probable life of RIP, based on several methods appears to show that any of the method can be adopted. However, as matter of caution and safety, the lowest among them can be taken as a reasonable estimate.

Thesis (MSc)--University of Stellenbosch, 2007. / ENGLISH ABSTRACT: Silicone rubber, particularly poly(dimethylsiloxane) (PDMS), has been increasingly used in the manufacture of outdoor high voltage insulators in the recent years. PDMS offers several advantages that make it suitable for outdoor use, such as low weight, a hydrophobic surface, stability, and excellent performance in heavily polluted environments. PDMS surfaces can, however, become progressively hydrophilic due to surface oxidation caused by corona discharge, UV radiation and acid rain. In this study, PDMS samples of controlled formulations as well as six commercial insulator materials four PDMS based and two ethylene propylene diene monomer (EPDM) based were exposed to various accelerated weathering conditions for various periods of time in order to track changes in the material over time. The ageing regimes developed and used to simulate the potential surface degradation that may occur during in-service usage included needle corona and French corona ageing, thermal ageing, UV-B irradiation (up to 8000 hours) and acid rain (up to 200 days). Both the chemical and physical changes in the materials were monitored using a wide range of analytical techniques, including: static contact angle measurements (SCA), optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), gas chromatography (GC), gas chromatography/mass spectroscopy (GC/MS), size-exclusion chromatography (SEC), Fourier-transform infrared photoacoustic spectroscopy (FTIR-PAS) and slow positron beam techniques (PAS). A low molecular weight (LMW) uncrosslinked PDMS model compound was used to further study the chemical effects of corona exposure on PDMS materials. PDMS showed far better performance than EPDM, in terms of resistance to the various ageing regimes and “hydrophobicity recovery”. / AFRIKAANSE OPSOMMING: Silikoonrubber, spesifiek polidimetielsiloksaan (PDMS), is gedurende die afgelope paar jaar toenemend gebruik in die vervaardiging van buitelughoogspanningisolators. PDMS het baie voordele vir gebruik in elektriese isolators soos ‘n laer massa, ʼn hidrofobiese oppervlak, stabiliteit en uitstekende werking in hoogsbesoedelde omgewings. Die hidrofobiese oppervlakte kan egter gelydelik hidrofilies word weens oppervlakoksidasie as gevolg van korona-ontlading, UV-bestraling en suurreën. In hierdie studie is PDMS monsters van verskillende samestellings sowel as ses kommersiële isolators (vier PDMS en twee etileenpropileenrubber (EPDM)) blootgestel aan verskillende versnelde weersomstandighede vir verskillende periodes om die veranderinge in die materiale te monitor. Die verskillende materiale is gerangskik volgens hulle werking oor ‘n periode van tyd. Dit het ook ‘n geleentheid gebied om die eienskappe van die verskillende samestellings te bestudeer. Die tegnieke wat ontwikkel is om die moontlike oppervlakdegradasie te simuleer, het naald-korona, “French” korona, UVB-bestraling (tot 8000 uur) en suurreën (tot 200 dae) ingesluit. Beide die chemiese en die fisiese veranderinge in die materiale is gemonitor met behulp van verskeie tegnieke soos statiese kontakhoekbepaling, optiese mikroskopie, skandeerelektronmikroskopie, energieverspreidingsspektroskopie, gaschromatografie, grootte-uitsluitingschromatografie, foto-akoestiese Fouriertransforminfrarooi (PASFTIR) en stadige-positronspektroskopie (PAS). ʼn Lae molekulêre massa PDMS modelverbinding is gebruik om die chemiese effek van korona te bestudeer. Die PDMS materiale het baie beter vertoon teenoor die EPDM materiale in terme van hulle herstel van hidrofobisiteit.

Thesis (PhD)--University of Stellenbosch, 2002. / ENGLISH ABSTRACT: The main aim of this research programme was to compare the relative performance of different insulator materials used in South Africa when subjected to a severe marine pollution environment. A test programme and procedure, test facility and instrumentation were established. Some novel instrumentation and monitoring equipment were developed and built specifically for this research programme, supported by data analysing software programs. In order to compare material performance only, all non-material design variables between the test insulators had to be removed (e.g. creepage distance, connecting length, inter-shed spacing, profile, etc.). To achieve this some of the test insulators had to be specially manufactured. Leakage current, electrical discharge activity, climatic and environmental data was collected successfully over a one-year test period, starting with new test insulators. The peak and energy values of the leakage current were identified as the two main parameters needed to describe the leakage current activity on the test insulators. A correlation was found between the climatic and environmental data and the leakage current data, and it was found that the leakage current can be determined successfully from some of the climatic and environmental parameters monitored by using multiple regression techniques. Surface conductivity and energy were found to be the best parameters to show the maximum and continuous interaction of the insulator material surface with the electrolytic pollution layer. A natural ageing and pollution test procedure was developed, which has become a South African standard and is gaining international acceptance. A model and hypothesis are proposed to describe the electrical discharge activity that takes place on the test insulators and explain the difference in leakage current performance of the various materials. Keywords: Insulator, Pollution, High Voltage, Leakage current, Material performance. / AFRIKAANSE OPSOMMING: Die hoofdoel van hierdie navorsingsprogram was om die relatiewe prestasie van verskillende isolatormateriale wat in Suid-Afrika gebruik word te vergelyk in 'n swaar besoedelde marine omgewing. 'n Toetsprogram en prosedure, toets fasiliteit en instrumentasie is gevestig. 'n Paar nuwe instrumente en moniteer toerusting is ontwikkel en gebou spesifiek vir hierdie navorsingsprogram, gesteun deur data analise sagteware programme. Ten einde slegs materiaalprestasie te vergelyk, moes alle nie-materiaal ontwerpsveranderlikes tussen die toetsisolators verwyder word (bv. kruipafstand, konnekteer lengte, tussen-skerm spasiëring, profiel, ens.). Om dit reg te kry moes sommige van die toetsisolators spesiaal vervaardig word. Lekstroom, elektriese ontladingsaktiwiteit, klimaat en omgewingsdata is suksesvol versameloor 'n een-jaar toetsperiode, beginnende met nuwe toets isolators. Die piek en energie waardes van die lekstroom is identifiseer as die twee hoof parameters wat nodig is om die lekstroomaktiwiteit op die toetsisolators te beskryf. 'n Korrelasie is gevind tussen die klimaat- en omgewingsdata en die lekstroom data, en dit is gevind dat die lekstroom data suksesvol bepaal kan word van sekere van die klimaat- en omgewingsparameters wat gemoniteer is deur veelvoudige regressie tegnieke te gebruik. Oppervlakskonduktiwiteit en energie is gevind die beste parameters te wees om die maksimum en kontinue interaksie van die isolatormateriaaloppervlak met die elektrolitiese besoedelingslaag aan te toon. 'n Natuurlike veroudering en besoedeling toetsprosedure is ontwikkel, wat 'n Suid-Afrikaanse standaard geword het en besig is om internastionale aanvaarding te wen. 'n Model en hipotese word voorgestelom die elektriese ontladingsaktiwiteit wat op die toetsisolators plaasvind te beskryf en om die verskil in lekstroomprestasie van die verskeie materiale te verduidelik. S/eufelwoorde: Isolator, Besoedeling, Hoog Spanning, Leek stroom, Materiaal prestasie.

Thesis (PhD)--University of Stellenbosch, 2002. / ENGLISH ABSTRACT: The main aim of this research programme was to compare the relative performance of different insulator materials used in South Africa when subjected to a severe marine pollution environment. A test programme and procedure, test facility and instrumentation were established. Some novel instrumentation and monitoring equipment were developed and built specifically for this research programme, supported by data analysing software programs. In order to compare material performance only, all non-material design variables between the test insulators had to be removed (e.g. creepage distance, connecting length, inter-shed spacing, profile, etc.). To achieve this some of the test insulators had to be specially manufactured. Leakage current, electrical discharge activity, climatic and environmental data was collected successfully over a one-year test period, starting with new test insulators. The peak and energy values of the leakage current were identified as the two main parameters needed to describe the leakage current activity on the test insulators. A correlation was found between the climatic and environmental data and the leakage current data, and it was found that the leakage current can be determined successfully from some of the climatic and environmental parameters monitored by using multiple regression techniques. Surface conductivity and energy were found to be the best parameters to show the maximum and continuous interaction of the insulator material surface with the electrolytic pollution layer. A natural ageing and pollution test procedure was developed, which has become a South African standard and is gaining international acceptance. A model and hypothesis are proposed to describe the electrical discharge activity that takes place on the test insulators and explain the difference in leakage current performance of the various materials. Keywords: Insulator, Pollution, High Voltage, Leakage current, Material performance. / AFRIKAANSE OPSOMMING: Die hoofdoel van hierdie navorsingsprogram was om die relatiewe prestasie van verskillende isolatormateriale wat in Suid-Afrika gebruik word te vergelyk in 'n swaar besoedelde marine omgewing. 'n Toetsprogram en prosedure, toets fasiliteit en instrumentasie is gevestig. 'n Paar nuwe instrumente en moniteer toerusting is ontwikkel en gebou spesifiek vir hierdie navorsingsprogram, gesteun deur data analise sagteware programme. Ten einde slegs materiaalprestasie te vergelyk, moes alle nie-materiaal ontwerpsveranderlikes tussen die toetsisolators verwyder word (bv. kruipafstand, konnekteer lengte, tussen-skerm spasiëring, profiel, ens.). Om dit reg te kry moes sommige van die toetsisolators spesiaal vervaardig word. Lekstroom, elektriese ontladingsaktiwiteit, klimaat en omgewingsdata is suksesvol versameloor 'n een-jaar toetsperiode, beginnende met nuwe toets isolators. Die piek en energie waardes van die lekstroom is identifiseer as die twee hoof parameters wat nodig is om die lekstroomaktiwiteit op die toetsisolators te beskryf. 'n Korrelasie is gevind tussen die klimaat- en omgewingsdata en die lekstroom data, en dit is gevind dat die lekstroom data suksesvol bepaal kan word van sekere van die klimaat- en omgewingsparameters wat gemoniteer is deur veelvoudige regressie tegnieke te gebruik. Oppervlakskonduktiwiteit en energie is gevind die beste parameters te wees om die maksimum en kontinue interaksie van die isolatormateriaaloppervlak met die elektrolitiese besoedelingslaag aan te toon. 'n Natuurlike veroudering en besoedeling toetsprosedure is ontwikkel, wat 'n Suid-Afrikaanse standaard geword het en besig is om internastionale aanvaarding te wen. 'n Model en hipotese word voorgestelom die elektriese ontladingsaktiwiteit wat op die toetsisolators plaasvind te beskryf en om die verskil in lekstroomprestasie van die verskeie materiale te verduidelik. S/eufelwoorde: Isolator, Besoedeling, Hoog Spanning, Leek stroom, Materiaal prestasie.

Memoire (M. Sc. A.)-- Universite du Quebec a Chicoutimi, 1984. / Bibliographie: f. 109-114. Document électronique également accessible en format PDF. CaQCU