A new theory has been proposed for stationary phase formation of chemically modified chromatographic adsorbents. This theory consists of a model in which the bonded hydrocarbon moiety, silica substrate, and their respective solvation layers all participate in stationary phase formation. Stationary phase formation was found to be dependent on three parameters: (1) Solvent strength of the mobile phase components for the bonded organic moiety and the silica substrate; (2) the type of organic moiety covalently bound to the surface; and (3) the bound moiety density or surface coverage. Binary aqueous-organic mobile phases were investigated for LiChrosorb RP-8 and RP-18. For RP-8 the solica substrate played a more important role in stationary phase formation. Whereas, for RP-18 the longer bound hydrocarbon chain dominated stationary phase formation. With different organic modifiers in the mobile phase, the modifier with the larger solvent strength for the bound hydrocarbon was selectively enriched in the stationary phase solvation layer for RP-18. Ternary mobile phase systems were also investigated for RP-18. The second modifier was found to exert a large influence on stationary phase formation. Temperature's role in stationary phase formation was studied with a ternary mobile phase of 40/45/15 methanol, water, THF with RP-18. In this specific case, changing the temperature of the system did not impact on stationary phase formation. A new type of column structure was investigated. This structure involved a totally porous silica gel as compared to a column packed with totally porous silica microparticles. These silica gel columns were characterized both thermodynamically and kinectically. Under Normal Phase chromatographic conditions the silica gel column was found to have a higher selectivity but poorer efficiency for the separation of aniline from nitrobenzene than a packed column. The silica gel can be chemically modified by silane reaction and its bonded phase characteristics were investigated. The gel also showed ion-exchange properties which were investigated using sodium nitrite.

This item was digitized as part of the Million Books Project led by Carnegie Mellon University and supported by grants from the National Science Foundation (NSF). Cornell University coordinated the participation of land-grant and agricultural libraries in providing historical agricultural information for the digitization project; the University of Arizona Libraries, the College of Agriculture and Life Sciences, and the Office of Arid Lands Studies collaborated in the selection and provision of material for the digitization project.

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A tractor mounted three-point hitch implement was developed to extract and collect subsurface trickle irrigation laterals from the soil. Power to the implement was supplied by the tractor hydraulic system to the three-point hitch and two remote hydraulic circuits. In operation, the implement loosened the soil around the lateral, extracted the tubing from the soil, wound it on a reel assembly, and then dropped the roll of tubing at the end of the row. Draft power requirements averaged 14.5 kW (19.4 hp) and hydraulic power averaged 0.56 kW (.75 hp) when the one row implement was operated at 7.2 km/h (4.5 mph). Field capacity of the one row implement averaged 0.19 ha/hr (.47 ac/hr) when operated in 100 m (328 ft) long rows.

Recent experiments with optical fibers have reached a remarkable development for optical communication spectroscopy as well as a medical technology. Hollow optical fibers are required for optical communications. The measurement of the transmission of light through fibers can provide information about the fiber quality and about the far-field energy which radiates from the fiber end. We used five flexible hollow fused quartz fibers to study laser beam propagation down the fiber axis. Five different refractive index fluids were prepared and inserted into the fiber core to measure the transmitted intensity as a function of core property. The plots of the normalized, relative transmitted intensity measured as a function of the beam insertion point show the dependence of the transmitted intensity as a function of fiber diameter and refractive index fluid.

We investigated the elastic scattering and fluorescence from laser dye solutions inside 5000, 1100, and 96.5 micron inner-diameter hollow-core capillaries. Incident 4416 A laser illumination of Coumarin 7 dye dissolved in ethanol caused fluorescence from approximately 4600 to 6000 A. This was studied over an angular range from 0° to 360°. A light scattering nephelometer coupled with a spectrometer gave intensity measurements as functions of wavelength (at fixed detection angles) and angle (at fixed wavelengths), while the illumination source, dye-filled capillary, and detector remained stationary. We saw capillary size and detection-angle dependence of the fluorescence and elastic scattering. Results show that angular variations of the elastic scattering and emitted fluorescence can be used to determine an optimum detection angle from the capillary with respect to the incident illumination direction. This work is important in the design and execution of Capillary Zone Electrophoresis (CZE) experiments.

The purpose of this thesis is to study and develop intelligent agents for the forthcoming Space Station Freedom. Relevant intelligent capabilities, which are necessary in a semi-autonomous laboratory environment, are assumed to be built into a robot. An intelligent controller based on the DEVS formalism and the event-based approach is considered for an experiment. We shall discuss multiple model representations, where each model is tailored toward a specific purpose. Considering the necessity of diagnostic capabilities, we shall discuss the possibility of hierarchical diagnostic units for the Space Station. A high-level diagnostic unit is implemented on the basis of an artificial intelligence scheme and a hierarchy of diagnosers. This thesis also discusses the need for real-time diagnostic units and real-time data acquisition. We shall consider a constraint driven diagnostic unit which utilizes the time/cost (i.e., the actual associated cost or time in inquiring information necessary for a diagnosis process) criterion in an attempt to locate the cause(s) of failures.