This essay presents a study of retention of idioms delving into a pedagogical approach by presenting them to a group of lower secondary students. The study also explores students’ memory retention whilst concurrently investigating if certain types of idioms are retained to a greater extent than others. For the sake of assessing memory retention in relation to these various types of idiomatic transparency, the selected idioms have been divided into three separate categories; transparent, semi-transparent and opaque depending on their literal and figurative meaning. This essay argues that opaque idioms are retained to a lesser extent in memory due to their non-transparent metaphorical meaning. In fact, the most striking finding is that idioms pertaining to the opaque category are indeed more difficult for students to learn and are also forgotten the fastest. Previous research has put emphasis on the complex structure of idioms and opinions seem divided regarding to what extent the teaching of idioms should be implemented together with other vocabulary items in a classroom setting. On the other hand, the same research emphasizes the great value of idioms; potentially expanding student vocabulary and making the English language more nuanced and native-like.

Das erweiterte Abstract beinhaltet die Abschnitte 'Leaders and their incentives to behave non-compliantly', 'the relevance of gender for leader's compliance', die dazu durchgeführte Studie sowie deren Auswertung. / The extended abstract consists of two clauses 'leaders and their incentives to behave non-compliantly', 'the relevance of gender for leader's compliance', as well as the related experimental study and it's conclusion.

[EN] Climate change is one of the short term threats for the humanity because it can affect seriously to the environment and, consequently, to vegetal and animal life. If it is not stopped in next years, maybe this effect will be irreversible. Climate change is produced by anthropogenic emissions of Greenhouse Gas to Earth's atmosphere. Vapour compression systems are one of the main contributors to this phenomenon. Among them, commercial refrigeration applications, through HFC usage, can be highlighted. Since 1990s, developed countries supermarkets are using refrigerants (mainly R134a, R404A and R507A) with great impact (high GWP values) on the climate change due to leakages, especially from parallel compressor rack DX systems. Recently, some regulations and directives have been approved to limit GWP values of HFC used in most extended refrigeration and air conditioning applications, directly affecting to commercial refrigeration. In this thesis, some low-GWP alternatives to replace the most commonly used HFC refrigerants in commercial refrigeration are evaluated, taking into account the limitations imposed by these regulations. To carry out this evaluation, the current status of parallel compressor rack refrigeration systems and their fluids has been reviewed. Then, the different low-GWP options to replace R134a and R404A have been studied. HFOs and their mixtures with HFC have been highlighted as the most promising drop-in or retrofit alternatives. Thus, R1234yf, R1234ze(E) and R450A were proposed to replace R134a and R448A to substitute R404A. The theoretical performance of the different low-GWP alternative fluids, as an overview of their potential use, has been studied at typical parallel compressor rack refrigeration operating conditions using the basic thermodynamic vapour compression cycle. Given the good theoretical performance of these refrigerants, they have been tested in a vapour compression test bench. From the experimental results it is depicted that R1234yf and R1234ze(E) are not acceptable as drop-in or light retrofit refrigerants from an energetic point of view. These fluids, when used in R134a systems, require system modifications (more severe in the case of R1234ze(E)) to achieve acceptable energy efficiency values. Moreover, due to the large refrigerant charge in PCRRS, both HFOs could present problems relating to security. Thus, while R450A presents a GWP value of 547, it appears as the best option to replace R134a due to the similar energy efficiency and properties. Its experimental mass flow rate and cooling capacity are slightly lower than R134a, but the final COP is approximately the same. The best R450A results when compared to R134a are obtained at higher CRs. Although can obtain better efficiency results in new systems, with a minor TXV adjustment R448A shows very high performance when it is used in R404A systems. Despite R448A lower cooling capacity than that R404A, this HFC/HFO mixture can achieve great CO2 equivalent emission reductions and it is recommended as lower-GWP replacement for R404A. / [ES] El cambio climático es una amenaza para la humanidad ya que puede afectar seriamente al medio ambiente y, en consecuencia, a la vida animal y vegetal. Si en los próximos años no se actúa para detenerlo, tal vez este efecto sea irreversible. Entre otros factores, el incremento de la temperatura global es producido por las emisiones antropogénicas de gases de efecto invernadero a la atmósfera. La refrigeración comercial, basada en sistemas de compresión de vapor, contribuye de forma relevante a este fenómeno a través del uso de fluidos sintéticos como refrigerantes y del consumo de energía eléctrica procedente de combustibles fósiles. Desde la última década del siglo XX, los supermercados de países desarrollados utilizan HFCs como fluidos de trabajo, principalmente R134a, R404A y R507A. Estos gases, de alto potencial de calentamiento atmosférico (PCA), contribuyen al cambio climático al fugarse accidentalmente de los sistemas de refrigeración, destacando las centrales de compresores en paralelo conectadas a sistemas de expansión directa. El valor máximo de PCA de los HFCs utilizados en aplicaciones de refrigeración y aire acondicionado va a ser controlado por normativas comunitarias, afectando directamente a los fluidos usados comúnmente en refrigeración comercial. Esta tesis evalúa diferentes alternativas de bajo PCA para sustituir los refrigerantes HFC más utilizados en refrigeración comercial, teniendo en cuenta las limitaciones impuestas por las normativas actuales. Para llevar a cabo dicho estudio, se revisa el estado actual de los sistemas de centrales de compresores en paralelo y sus fluidos. A continuación, se analizan las diferentes opciones de bajo PCA para sustituir al R134a y R404A. Al destacar los HFOs y sus mezclas con HFCs como alternativas para realizar un reemplazo con pocas modificaciones del sistema (propiedades similares); R1234yf, R1234ze(E) y R450A son propuestos para sustituir al R134a y R448A para R404A. El rendimiento teórico de los diferentes fluidos alternativos de bajo PCA, para obtener una visión general del potencial de su uso, se estudia simulando las condiciones operativas típicas de las centrales de compresores en paralelo, usando el ciclo termodinámico de compresión de vapor básico. Dado el buen rendimiento mostrado por estos refrigerantes, son ensayados en un banco de pruebas de compresión de vapor. De los resultados experimentales se observa que R1234yf y R1234ze(E) no son aceptables desde un punto de vista energético como sustitutivos directos o con menores modificaciones. Dichos fluidos, cuando son utilizados en sistemas de R134a, requieren modificaciones del sistema (más severas en el caso del R1234ze(E)) para alcanzar valores aceptables de eficiencia energética. Por otra parte, debido a la gran carga necesaria en PCRRS, ambos HFOs podrían presentar problemas en cuanto a la seguridad. Así, mientras que el R450A presenta un valor de PCA de 547, aparece como la mejor opción para sustituir al R134a debido a una eficiencia energética y propiedades similares. El caudal másico y la capacidad frigorífica del R450A son ligeramente inferiores en comparación con las del R134a, pero por otra parte, el COP resultante es aproximadamente el mismo. Los mejores resultados obtenidos para R450A son obtenidas a altas tasas de compresión. Aunque puede ser obtenida una eficiencia energética más alta en sistemas de nuevo diseño, con sólo un ajuste menor de la válvula de expansión termostática, el R448A muestra valores muy altos de rendimiento en sistemas utilizados con R404A. A pesar de que la capacidad frigorífica del R448A es menor que la del R404A, esta mezcla de HFC y HFO puede dar lugar a grandes reducciones de emisiones de CO2 equivalentes, siendo así recomendado como reemplazo del R404A con menor PCA. / [CA] El canvi climàtic és una amenaça per a la humanitat ja que pot afectar seriosament el medi ambient i, en conseqüència, la vida animal i vegetal. Si en els propers anys no s'actua per aturar-lo, potser aquest efecte siga irreversible. Entre altres factors, l'increment de la temperatura global és produït per les emissions antropogèniques de gasos d'efecte hivernacle a l'atmosfera. La refrigeració comercial, basada en sistemes de compressió de vapor, contribueix de manera rellevant a aquest fenomen per l'ús de fluids sintètics com refrigerants i pel consum d'energia elèctrica procedent de combustibles fòssils. Des de l'última dècada del segle XX, els supermercats dels països desenvolupats utilitzen HFCs com fluids de treball, principalment R134a, R404A i R507A. Aquests gasos, d'alt potencial d'escalfament atmosfèric (PCA en castellà), contribueixen al canvi climàtic quan s'escapen accidentalment dels sistemes de refrigeració. D'aquest tipus de sistemes destaquen com a grans emissors de diòxid de carboni les centrals de compressors en paral·lel connectades a sistemes d'expansió directa. El valor màxim de PCA dels HFCs utilitzats en aplicacions de refrigeració i aire condicionat serà controlat per normatives comunitàries, cosa que afectarà directament els fluids utilitzats a la gran majoria de sistemes de refrigeració comercial. Aquesta tesi avalua diferents alternatives de baix PCA per substituir els refrigerants HFC més utilitzats en refrigeració comercial sense oblidar les limitacions imposades per les normatives actuals. Per dur a terme aquest estudi, es revisa l'estat actual dels sistemes de centrals de compressors en paral·lel i els seus fluids. A continuació, s'analitzen les diferents opcions de baix PCA per substituir l'R134a i l'R404A. Els HFOs i les seves mescles amb HFCs com alternatives destaquen per permetre una substitució amb poques modificacions del sistema (propietats similars); R1234yf, R1234ze(E) i R450A són proposats per substituir l'R134a i R448A per l'R404A. Per obtenir una visió general del potencial de l'ús dels diferents fluids alternatius de baix PCA, s'estudia el seu rendiment teòric mitjançant una simulació de les condicions operatives típiques de les centrals de compressors en paral·lel. Per a aquesta simulació s'empra el cicle termodinàmic de compressió de vapor bàsic. Com a conseqüència del bon rendiment mostrat per aquests refrigerants, són assajats en un banc de proves de compressió de vapor. Dels resultats experimentals s'observa que R1234yf i R1234ze(E) no són acceptables des d'un punt de vista energètic com a substitutius directes o amb menors modificacions. Aquests fluids, quan són utilitzats en sistemes de R134a, requereixen modificacions del sistema (més severes en el cas de l'R1234ze(E)) per assolir valors acceptables d'eficiència energètica. D'altra banda, a causa de la gran càrrega necessària en PCRRS, tots dos HFOs podrien presentar problemes en temes de seguretat. Així, mentre que el R450A presenta un valor de PCA de 547, apareix com la millor opció per substituir l'R134a a causa de una eficiència energètica i propietats similars. El cabal màssic i la capacitat frigorífica de l'R450A són lleugerament inferiors en comparació amb les de l'R134a, però d'altra banda, el COP resultant és aproximadament el mateix. Els millors resultats de l'R450A són obtinguts a altes taxes de compressió. Tot i que pot ser obtinguda una eficiència energètica més alta en sistemes de nou disseny, amb només un ajust menor de la vàlvula d'expansió termostàtica, l'R448A mostra valors molt alts de rendiment en sistemes utilitzats amb R404A. Encara que la capacitat frigorífica de l'R448A és menor que la de l'R404A, aquesta barreja de HFCs i HFO pot aconseguir grans reduccions d'emissions de CO2 equivalents, i es per tant es recomanada com a reemplaçament amb menor PCA de l'R404A. / Mota Babiloni, A. (2016). ANALYSIS OF LOW GLOBAL WARMING POTENTIAL FLUORIDE WORKING FLUIDS IN VAPOUR COMPRESSION SYSTEMS. EXPERIMENTAL EVALUATION OF COMMERCIAL REFRIGERATION ALTERNATIVES [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/62680 / TESIS / Premios Extraordinarios de tesis doctorales

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Spillways are hydraulic structures that allow dams to release and convey surplus water or flood from the reservoir to the downstream channel. The spillway is a safety structure that prevents the overtopping of the dam. Many dam failure disasters were due to the inadequate capacity of the spillway, which fully illustrates the prominence of spillway design. According to the control structure, spillways can be divided into gated and ungated type. The gated spillway provides better control of the managed water level and reduces the elevation of the top of the dam. Researchers have mostly used experimental models to investigate these two types of spillways in previous literature. In the past few years, following the rapid development of numerical simulation technology, there have been more studies on the numerical modeling of spillways. However, most of the literature was about ungated spillways and most of it considered the case of low head ratios, while the case with gates, especially the case of vertical plane gates, was less investigated. In this study, the hydraulic characteristics, such as velocity, pressure, and discharge coefficient, of the ungated and gated ogee spillways are investigated by means of physical and numerical models for the case of low and high head ratios. The study covered head ratios varying from 1.4 to 4.6 and the relative gate-openings varying from 0.5 to 2. The second main objective of this study was to evaluate the performance of the numerical model to simulate gated and ungated spillways. It mainly employed 2DV OpenFOAM to simulate three turbulence models (realizable k-ε, RNG k-ε, k-ω SST), and the results were compared and calibrated with the experimental results from the physical model tests performed by the author to verify the performance of the numerical model. This study aims to demonstrate that the numerical model can be used as a complementary tool to the physical model to measure the hydraulic performance of ogee spillways.

Syfte: Målsättningen med studien är att hos friska kvinnor utvärdera om intensiv tuggning leder till en proprioceptiv allodyni i massetermuskulaturen. Följande hypoteser testades i studien: 30 minuters intensivt tuggande leder till (1) ökad trötthet och smärta, (2) sänkt smärttröskel, (3) ökad vibrotaktil känslighet (4) samt träningsvärk i massetermuskulaturen bilateralt. Material och Metod: 16 friska kvinnor (medelålder 25.8 ± 5.0 år) deltog i studien som bestod av två 60-minuters sessioner med 24-timmars uppföljning. Vid ena sessionen tuggade försökspersonerna på ett grekiskt tuggummi (Masticha Chios) i 5-minuters intervaller under 30 minuter, och vilade vid den andra sessionen. En vibrameter användes för att mäta vibrationströskel, upplevd vibrationsintensitet och upplevd vibrationsobehag. Upplevd trötthet och upplevd smärtintensitet värderades enligt en visuell analog skala 0-100 mm (VAS skala). Smärttröskeln mättes med en algometer som applicerades på massetermuskelns fäste. Två vägs variansanalys användes för att testa utfallsvariabler för upprepade mätningar och Dunnett’s posthoc-test. Resultat: En signifikant skillnad kunde ses mellan tuggning och icke tuggning för vibrationströskeln (P < 0.001); upplevda tröttheten (P < 0.001); smärttröskeln (P < 0.01); upplevda vibrationsobehaget (P < 0.05). Inga signifikanta skillnader observerades för upplevd smärta och upplevd vibrationsobehag. Däremot kunde en signifikant ökning ses över tid för vibrationströskeln och den upplevda tröttheten. Konklusion: Våra fynd indikerar att det ej finns något samband mellan intensiv tuggning och träningsvärk i massetermuskulaturen. Däremot resulterade tuggningen i ökad muskeltrötthet och vibrationsobehag, samt signifikant högre trösklar för smärta och vibration under försökets gång. Proprioceptiv allodyni kunde ej påvisas. / Aims: To evaluate if intense chewing leads to proprioceptive allodynia in the masseter muscle, and test if (1) pain and fatigue are increased after intense chewing, (2) pressure pain thresholds are decreased after intense chewing, (3) vibration thresholds are increased after intense chewing, (5) intense vibrations exacerbate pain after intense chewing. Materials and Methods: 16 healthy female volunteers (mean age 25.8 ± 5 years) participated in two 60-minute sessions, each with 24-hour follow-ups. In the first session, the subjects were instructed to chew on a viscous chewing gum (Masticha Chios). In the other session the participant were assigned a control task where no chewing was performed. Perceived intensity of vibration and perceived discomfort were assessed with a Vibrameter® on a 0-50-100 visual analog scale (VAS). Two 0-100 mm visual analog scales measured pain intensity and perceived fatigue. The pain threshold was measured with an electronic algometer. These variables were measured to assess delayed onset muscle soreness. All measurements were made on the masseter muscles. Two-way analysis of variance for repeated measures and Dunnett’s post hoc test was used to test for significant alterations in the outcome variables. Results: Significant differences were observed between chewing and no-activity for vibration threshold (P<0.001); perceived fatigue (P<0.001); pain threshold (P<0.01) and vibration discomfort (P<0.05). No significant differences were seen for perceived pain and perceived intensity of vibration. A significant increase over time could only be observed for vibration threshold (P<0.01) and perceived fatigue (P<0.05). Conclusion: Our findings suggest that there is no relation between intense chewing and delayed onset muscle soreness in the masseter muscles. Intense chewing evoked moderate levels of fatigue and discomfort, and a hypoalgesia to mechanical stimulation, and reduced vibrotactile sensitivity.

Helical heating coils are widely used in most conventional electric stoves for many years, these heating coils can reach 600-700°C, which is higher than the ignition point of oil and grease (about 400°C), leading to many fires. Pioneering Technology Inc. has developed a Safe-T Element plate to address such problem. The Safe-T Element plate is manufactured from Gray Cast Iron. However, these plates deform during its use. This study was carried out to investigate the current Safe-T Element design, both experimentally and numerically, in order to determine the root causes behind the deformation problem of the plate, and to suggest changes to the existing design in order to limit its distortion to acceptable targets. A chemical analysis was carried out to establish the type of material of the Safe-T Element plate. Chemical analysis showed that the material of the plate is cast iron. The microstructure of the plate was tested in order to examine its type and homogeneity. Tensile testing was carried to establish the grade of the material, and to calculate the value of its young's modulus and yield strength. Tensile testing indicated that the material of the Safe-T Element plate is close to Gray Cast Iron Class 40. Differential scanning calorimetry testing was carried out to investigate thermal stability of the plate material. This test indicated that material is thermally stable. Thermal cycling testing indicated that the root cause of the deformation problem is elastic thermal buckling. Temperature uniformity tests were carried out. More than 100°C temperature variation in the radial direction was observed. To address the distortion of the plate, an optimum geometry has been suggested based on the findings of the numerical investigation by removing the outer ring from the original design of the plate. / Thesis / Master of Applied Science (MASc)

This thesis contains the details of an experimental study on the local void fraction measurements in large-diameter vertical pipes using optical fiber probes. The experiments were conducted in vertical transparent acrylic pipe of a 20-cm diameter. An experimental test facility used for performing of experiments, was designed as a low-pressure air-water loop, which can operate in either a natural circulation mode or a forced circulation mode. Radial void fraction profiles were measured using an optical fiber probe. An average cross-sectional void fraction was calculated by integration of the data obtained by the optical fiber probe. The average void fraction was also calculated using two-phase pressure-drop measurements . The results were compared and the resulting good accuracy of the optical fiber probe was determined. The flow regime results were plotted in terms of superficial gas and liquid velocities using flow regime maps of several researchers. Absence of the slug flow regime in large-diameter pipes was observed during the experiments. The data were correlated using the drift-flux model. A near unity distribution parameter showed that nearly uniform radial distribution of the void fraction dominates in two-phase flow through large-diameter vertical pipes. / Thesis / Master of Engineering (ME)

The present research is conducted to investigate the behaviour of elliptical tube columns filled with self-compacting concrete (SCC). In total, ten specimens, including two empty columns, were tested to failure. The main parameters investigated were the length and the sections of the columns, and the concrete compressive strength. Artificial Neural Network (ANN) model was developed to predict the compressive strength of SCC using a comprehensive database collected from different previous studies. The database was used to train and test the developed ANN. Moreover, parallel to the experimental works, a three dimensional nonlinear finite element (FE) model using ABAQUS software was developed to predict the behaviour of SCC elliptical tube columns. The proposed ABAQUS model was verified against the current experimental results. The experimental results indicated that the failure modes of the SCC filled elliptical steel tube columns having large slenderness ratios were dominated by global buckling. Moreover, the composite columns possessed higher critical axial compressive capacities compared with their hollow section companions due to the composite interaction. However, due to the large slenderness ratio of the test specimens, the change of compressive strength of concrete core did not show significant effect on the critical axial compressive capacity of concrete filled columns although the axial compressive capacity increased with the concrete grade increase. The comparisons between the axial compressive load capacities obtained from experimental study and those predicted using simple methods provided in Eurocode 4 for concrete-filled steel rectangular tube columns showed a reasonable agreement. The proposed three dimensional FE model accurately predicted the failure modes, the load capacity and the load-deflection response of the columns tested. The experimental results, analysis and comparisons presented in this thesis clearly support the application of self-compacting concrete filled elliptical steel tube columns in construction engineering practice.

No / Axially loaded rubber blocks of long, thin rectangular and circular cross section whose ends are bonded to rigid plates are studied. Closed-form expressions, which satisfy exactly the governing equations and conditions based upon the classical theory of elasticity, are derived for the total axial deflection and stress distribution using a superposition approach. The corresponding relations are presented for readily calculating the apparent Young's modulus, Ea, the modified modulus, E'a, and the deformed lateral profiles of the blocks. From these, improved approximate elementary expressions for evaluating Ea and E'a are deduced. These estimates, and the precisely found values, agree for large values of the shape factor S, with those previously suggested, but also fit the experimental data more closely for small values of S. Confirmation is provided that the assumption of a parabolic lateral profile is invalid for small values of S.