Four different kinds of filter-materials with reactive surfaces have been studied concerning their capacity to absorb heavy metals in leachate from a municipal waste deposit. The heavy metals studied were: lead, cadmium, copper, mercury, chromium, nickel and zinc. The leachate contains high levels of dissolved organic carbon (DOC) and has a high pH-value along with a high buffer capacity. These characteristics of the leachate make it difficult to remove pollutants and require efficient filters. The filters that were examined in the report are blast-furnace slag with CaO, sand covered with iron oxides, olivine and nepheline. The experiment was carried out in two sets, starting with batch experiments followed by a column study. The objective of the batch experiments was to find out how variations in pH affected the sorption capacity of the materials. The interval used during the test was from pH 5 to pH 10. The computer program VisualMinteq was used to evaluate the dominating sorption processes when the materials interacted with the solutions. Two different kinds of solutions were used in the batch experiment. One of them was the leachate, to which known concentrations of heavy metals were added (about 1 μM) and the other consisted of sodium nitrate, a solution without organic compounds, which was used as a reference. The sodium nitrate solution was also spiked with the same concentration of heavy metals as the leachate. The results from the batch experiment showed that the sorption of heavy metals was lowered if the DOC level was high. No relation between pH and sorption ability could be found for the leachate, but for some metals in the sodium solution a higher pH improved the removal of heavy metals. The two materials that showed best results in the batch experiment were the blast-furnace slag and the sand with iron oxides. These materials were used in the column study. The olivine material was somewhat better than the nepheline in the batch experiment. Four columns were used in the column study, two for each material. Leachate with heavy metals was pumped into the columns with a specific flow rate; at first a low flow rate was used and when half the experiment time had passed the flow rate was increased. The flow rates used were 0.12 m/24 h and 0.62 m/24 h. The outcome of the column experiment showed that the slag had the highest ability to adsorb metals. The metal sorption was over 60 percent for lead, cadmium and zinc, where the highest sorption was obtained for lead. No affects were noticed when the flow rate was increased. / I detta examensarbete har fyra olika reaktiva filtermaterials kapaciteter att ur deponilakvatten avskilja tungmetallerna bly, kadmium, koppar, kvicksilver, krom, nickel och zink testats. Deponilakvatten är ett avloppsvatten med höga halter organiskt material (DOC), högt pH och en hög buffertkapacitet. Dess sammansättning ställer stora krav på ett filter och närvaron av ligander påverkar sorptionprocesserna. Filtren som ingått i studien är kalciumoxiddopad masugnsslagg, järnoxidtäckt sand, olivin och nefelin. Försöken utfördes i två delar, med inledande skakförsök och därefter kolonnförsök. I båda försöken användes lakvatten med en extra tillsats av tungmetaller. I skakförsöken användes även natriumnitrat; ett referensvatten utan organiska ligander, även det spikat med tungmetaller. I skakförsöken studerades avskiljningens pH-beroende för de olika filtren, med ett pH-intervall på ca 5 – 10. Därefter modellerades resultaten i jämviktsprogrammet VisualMinteq för att fastställa vilka processer som styr avskiljningen. Skakförsöken och kolonnförsöken utfördes båda i klimatrum vid 8 ºC, för att efterlikna markens naturliga temperatur. Resultaten från skakförsöken visade att masugnsslagg och järnoxidsand gav bäst avskiljning för de flesta tungmetaller. Olivin och nefelin var sämre metallsorbenter, där olivin uppvisade något bättre resultat än nefelin. Inget tydligt pH-beroende för lakvattnet kunde utläsas, men för natriumnitratlösningen gav en pH-höjning en ökad sorption för vissa metaller. Den kemiska jämviktsmodelleringen visade att den dominerande processen i filtermaterialen var sorption på filterytorna. De två filtermaterialen som visade bäst resultat i skakförsöken (slagg och järnoxid) studerades vidare i kolonnförsök, där ett bestämt lakvattenflöde pumpades genom kolonner packade med materialen. Två olika flödeshastigheter testades (0,12 m/dygn och 0,62 m/dygn) och sorptionen av metaller analyserades. Slaggen uppvisade högst avskiljningskapacitet av de studerade filtren. De metaller som sorberades bäst var bly, kadmium och zink (över 60 % avskiljning), där den högsta sorptionen erhölls för bly. Gemensamt för både skak- och kolonnförsöken var att sorptionen försvårades då halten organiskt material (DOC) ökade, vilket beror på att DOC konkurrerar med de reaktiva ytorna på filtren om att binda den fria metalljonen. Ingen minskande avskiljningseffekt av en flödesökning kunde utläsas.

An excessive input of nutrients to lakes and other water bodies has created a problem with eutrophication in Sweden. Untreated, or partially treated, domestic sewage is a major source for discharge of phosphorus (P), which is the nutrient most frequently responsible for eutrophication of most fresh waters and the Baltic Sea. The waste water can be cleaned by filter materials, which have a high P-retention ability and which after saturation may be used as fertilizers. Four potentially suitable filter materials were tested in batch- and column experiments in this study. In the batch experiments, the following materials were shaken with waste water in time series ranging from 5 seconds to 60 minutes: coarse (1-4 mm) and fine (0-2 mm) Polonite® (heated bedrock from Poland); Filtralite® (light expanded clay aggregates with limestone added before burning); water cooled blast furnace slag (BF-slag) and BF-slag mixed with 10% burned limestone. In the column experiment, the phosphorus sorption capacity in BF-slag and BF-slag mixed with burned limestone was observed under saturated and unsaturated flow conditions for 10 weeks. The waste water used in both experiments originated from the full scale testing site at Ångersjön in Sweden. After the column experiment was ended, the filter materials were investigated with XRD (X-ray diffraction) and SEM (scanning electron microscope) in order to figure out which chemical reactions that had taken place. The results from the batch experiments show that fine Polonite® and BF-slag mixed with limestone have the fastest P sorption capacity. Already after 5 seconds of shaking the materials showed effective retention of P. The coarse Polonite®, Filtralite® and BF-slag showed similar sorption capacities, although the coarse Polonite® tended to be somewhat inferior. The column studies showed that the materials used in the columns had a sorption capacity of 98 % or more. The XRD and SEM indicated that an amorphous calcium-P-compound was created in the filter material. / I Sverige är reningen av fosfor i vatten från enskilda avlopp ofta bristfällig, vilket bland annat kan leda till övergödning av sjöar, hav och vattendrag. Sedan några år tillbaka har olika filtermaterial med speciella reaktiva egenskaper, som bland annat avskiljer fosfor från avloppsvatten, undersökts. Tanken med filtermaterialen är att de efter mättnad med näringsämnen ska kunnas användas som jordförbättringsmedel. I denna rapport har några olika filtermaterial, lämpade för fosforavskiljning, undersökts genom skak- och kolonnförsök. I skakförsök, där skaktiderna varierade mellan 5 sekunder och 60 minuter, testades Polonite®, Filtralite®, Hyttsand och Hyttsand blandad med 10 % bränd kalk. Polonite® är en upphettad form av bergarten opoka varav två olika kornstorleksfraktioner (0-2 mm och 1-4 mm) användes. Filtralite® och Hyttsand är antropogena filtermaterial. Filtralite® tillverkas i Norge och består av kalkhaltiga kulor av expanderad lera (Leca®). Hyttsand framställs genom vattenkylning av masugnsslagg som bildas vid framställningen av råjärn vid stålverket i Oxelösund. I kolonnförsöken, som utfördes under 10 veckor, studerades Hyttsand och Hyttsand blandad med 10 % bränd kalk under omättade och mättade flödesförhållanden. I samtliga experiment användes avloppsvatten från reningsverket vid Ångersjön, där Filtralite® och Hyttsand testas i fullskala. Efter kolonnförsöken avslutats undersöktes filtermaterialen med XRD (röntgendiffraktion) och SEM (svepelektron mikroskop) för att utreda vilka mekanismer som medverkat vid avskiljningen av fosfor. Resultaten från skakförsöken visade att finkornig Polonite® och Hyttsand blandad med kalk avskiljer fosfor effektivt redan efter skakning i 5 sekunder. Grovkornig Polonite, ren Hyttsand och Filtralite® sorberade fosfor tämligen likartat, även om den grovkorniga Poloniten® tenderade att vara aningen sämre än de övriga. Resultaten från kolonnförsöken visade att fosfor kunde avskiljas till över 98 % i alla kolonner och att det bildats amorfa fosfatföreningar, främst med kalcium, under den 2,5 månader långa experimentperioden.

Den negativa miljöpåverkan från förbrukning av fossila bränslen ökar kravet på förnyelsebara energikällor. Biobränsle är ett speciellt lovande alternativ. Detta projekt vill visa på möjligheten att använda gas från biobränsleförgasning som förbränns utan synliga flammor i glassmältugnar. Med bättre teknik är det möjligt både att upprätthålla produktionen och reducera kväveoxidutsläppen med ekonomiska fördelar. Biobränslena bidrar inte till växthuseffekten. En del av hela projektet är de experiment som utfördes den 1 juni 2004 vid Kosta glasbruk. Experimenten tog 7 timmar och 50 minuter. Den viktigaste uppgiften i detta examensarbete är att utvärdera mass- och energibalanserna på den medströms fastbäddsförgasare som användes vid experimenten. / The negative environmental impact of the consumption of fossil fuels has led to an increased claim for a wider use of renewable energy sources. Biomass appears as a particularly promising option. This project demonstrates the possibility to heat glass furnaces with gas from biofuel gasification combusted without visible flames. By better technique you can both retain production and reduce nitrogenoxide emissions with economical benefit. The biofuel doesn’t contribute to the greenhouse effect. A part of the whole project is the experiments performed on June 1st 2004 in Kosta glass- factory, total 7 hours and 50 minutes. A major effort of this diploma work is to evaluate mass and energy balances of the down – draft fixed bed gasifier used in the experiments.

Voltage (lighting) flicker is mainly caused by the electric arc furnaces (EAF) facility supplied by the medium and high voltage power network. In addition to that, because of the increase of wind power generation in both quantity and capacity, intermittent power output of wind turbines under wind speed variation could also cause voltage flickers that affect the performance of lighting and electronics devices in the neighboring feeder buses. Successful voltage flicker prediction and propagation estimation would help both utility and customers in dealing with the problem. This dissertation presents a nonlinear model for the short term prediction of voltage flicker due to EAF operations. In this study, synchronized voltage flicker measurement was conducted at several EAF facilities to understand the stochastic behavior of voltage flicker. The electric loading condition during EAF melting process shows a long term qualitative behavior of a dynamic system and illustrates a special structure of a fractal system. With the fractal structure identification, the behavior hidden behind the voltage flicker time series measurement could be grasped. Using a phase space reconstruction technique and Lyapunov exponent (LE) of state trajectory in the phase space, based on actual voltage flicker measurements, it is proved that the voltage flicker time series is chaos. By using LE, three formulations are adopted to build the prediction models and illustrate the feasibility of short term EAF voltage flicker prediction. Currently, some Asian countries are using the Japanese £GV10 flicker voltage standard. Due to the adoption of IEC standard by IEEE and European countries, a rational conversion of flicker planning limits between different standards would help utilities consider revising or changing their voltage flicker standards and planning limits. Statistical analyses of Pst and £GV10 measurement are conducted in this study. Under different EAF types and operation conditions, reasonable conversion factors between Pst and £GV10 standards are derived, and the flicker transfer factor between different voltage levels of the power supply system are presented.

During the three decades, the torsional impact on turbine-generator sets due to power system disturbances has been extensively discussed in many research works. However, most of them are focused on the fatigue damage of turbine shafts due to large-signal disturbances. For example, network faults occur. Obviously, the torsional effect subject to small-signal disturbances has not received much attention. In fact, although the small disturbances would not immediately damage the turbine mechanism, the cumulative long-term damaging effects may not be negligible under certain circumstances. Many operating conditions in power systems may lead to small disturbances on blades; for examples, shedding loads, switching transmission line, resetting control system parameters, and harmonics etc. Nevertheless, others only cause short-term or transient non-resonant disturbances occasionally except the power system subharmonics which could results in electro-mechanical resonance. Therefore, two types of subharmonics in power systems are proposed so as to investigate the toque impact and long-term fatigue life expenditure in turbine shafts and blades. Firstly, from the steady-state disturbance viewpoint, the long-term cumulative fatigue estimation based on the three-year project of the GE Co. shows that there are potential damages for both the shafts and the blades of the nearby generators caused by the subharmonic excitations of the HVDC link. The fatigue life sensitivity works are also carried out to provide the recommendations for the safety operation. The optimal damper type and disposition scheme for depressing the resonant torque and prolonging the turbine lifetime is consequently motivated, which is based on participation factor of linear systems with the electromechanical analogy. The effectiveness of this scheme on suppressing vibration torque arising from network faults is also satisfying. In addition, the authors propose the new electromechanical supersynchronous resonance phenomenon for the turbine-generators near the inverter station owing to asymmetric line faults near the rectifier station. Secondly, the dramatic real and reactive power consumption during the melting period of an electrical arc furnace load. The voltage flicker pollution is mainly caused by the reactive power fluctuation while the stochastic subsynchronous oscillation in turbine mechanism is excited by the electromagnetic torque of the subsynchronous frequency which is induced by the real power fluctuation. Such a small stress imposed on the low-pressure long turbine blade combined with its evitable corrosive environment contributing to the corrosion fatigue effect. Although the voltage flicker severity at the point of common coupling is still within the limit, the blade may have been damaged from the long-term corrosion fatigue life expenditure estimation. In other words, the conventional voltage flicker limit established to make human-eye comfortable might not protect the blade from damaging risk. The long-term influence resulted from the electric arc furnace loads cannot always be neglected. It is necessary to take care of the blade material intensity and operating environment. If there is the potential of blade damage, one has to strengthen the output capacity at the power plant or separate the peak load durations among the steel plants to limit the over-fluctuation real power of the generator.

The electric arc furnace steelmakers produce steel across wide ranging sizes and different quality levels. The method of using electric arc for melting is an important process to produce steel from iron or scraps. The diversity of products and markets makes the steelmakers to operate within a large number of constraints of limited enterprise resources, so the electric arc furnace manufacturing system faces problems to integrate the enterprise resource planning system with the manufacturing execution system. The international automation society has come out a solution with an international standard, also known as ISA-95 aimed to help manufacturing industries such as electric arc furnace steelmakers, for the integration of enterprises and control systems. However, ISA-95 only emphasizes on the integration of enterprises and control systems, but does not provide a whole picture of the entire system. This research utilizes the tool of system architecture to develop the architecture-oriented electric arc furnace manufacturing system model, abbreviated as AOEAFMSM, to illustrate coherently the structure view and the behavior view of the electric arc furnace manufacturing system. Furthermore, AOEAFFMSM is able to fully describe many other views of the electric arc furnace manufacturing system. This capability satisfies everybody¡¦s need for capturing different views of the system. Consequentially, AOEAFFMSM simplifies the software development and reduces many communication difficulties among system developers and customers. In modeling the electric arc furnace manufacturing system model, AOEAFFMSM is superior to ISA-95.

<p>The thermodynamic conditions for the behaviour of silicon in the lower part of the blast furnace have been the focus of the thesis. More specifically, the influences of temperature, carbon activity, total gas pressure and Fe reoxidation on silicon have been studied.</p><p>Calculations show that an increased temperature gives higher equilibrium ratio between silicon in hot metal and slag. Furthermore, laboratory reduction studies shows that the carbon activity in the cohesive zone increase with an increased reduction time. Increased carbon activity will increase the equilibrium silicon content in liquid metal.</p><p>Equilibrium calculations based on tapped hot metal and slag shows that the equilibrium silicon content of the liquid metal phase is higher than measured at tapping. Around the raceway area the equilibrium silicon content is very high. The high equilibrium silicon content makes it important to differ between the conditions under operation and the conditions of samples taken out of the blast furnace before studied. The equilibrium silicon content is strongly correlated to the CO gas partial pressure. Often this partial pressure is changed during sampling and cooling of samples. At tapping the equilibrium partial pressure of CO has been calculated to higher values than the total gas pressure inside the blast furnace.</p><p>Metal droplets found in tapped slags are probably formed by reduction of FeO. In the periphery part of the lower part of the blast furnace, it is believed that mainly FeO oxidises silicon in hot metal. It is not expected that the metal droplets in the slag is formed if FeO oxidises dissolved silicon. Instead, the iron droplets may form at reactions with gas, coke carbon or coal powder carbon. Around some droplets increased magnesium content has been found. This may be due to reactions with gaseous magnesium that, according to thermodynamic conditions, is easy to form. It has been reported that much FeO may be formed in the raceway area. The metal droplets may indicate how much FeO that reacts with other components than liquid iron. The iron found in metal droplets in the slag corresponds to between 0.02 and 0.2 wt-% FeO in the slag.</p>

<p>This study has focused on determining the heat flows in a production blast furnace hearth. This part of the blast furnace is exposed to high temperatures. In order to increase the campaign length of the lining an improved knowledge of heat flows are necessary. Thus, it has been studied both experimentally and numerically by heat transfer modeling. Measurements of outer surface temperatures in the lower part of a production blast furnace were carried out. In the experimental study, relations were established between lining temperatures and outer surface temperatures. These relations were used as boundary conditions in a mathematical model, in which the temperature profiles in the hearth lining are calculated. The predictions show that the corner between the wall and the bottom is the most sensitive part of the hearth. Furthermore, the predictions show that no studied part of the lining had an inner temperature higher than the critical temperature 1150°C, where the iron melt can be in contact with the lining.</p>

<p>Den negativa miljöpåverkan från förbrukning av fossila bränslen ökar kravet på förnyelsebara energikällor. Biobränsle är ett speciellt lovande alternativ. Detta projekt vill visa på möjligheten att använda gas från biobränsleförgasning som förbränns utan synliga flammor i glassmältugnar. Med bättre teknik är det möjligt både att upprätthålla produktionen och reducera kväveoxidutsläppen med ekonomiska fördelar. Biobränslena bidrar inte till växthuseffekten. En del av hela projektet är de experiment som utfördes den 1 juni 2004 vid Kosta glasbruk. Experimenten tog 7 timmar och 50 minuter. Den viktigaste uppgiften i detta examensarbete är att utvärdera mass- och energibalanserna på den medströms fastbäddsförgasare som användes vid experimenten.</p> / <p>The negative environmental impact of the consumption of fossil fuels has led to an increased claim for a wider use of renewable energy sources. Biomass appears as a particularly promising option. This project demonstrates the possibility to heat glass furnaces with gas from biofuel gasification combusted without visible flames. By better technique you can both retain production and reduce nitrogenoxide emissions with economical benefit. The biofuel doesn’t contribute to the greenhouse effect. A part of the whole project is the experiments performed on June 1st 2004 in Kosta glass- factory, total 7 hours and 50 minutes. A major effort of this diploma work is to evaluate mass and energy balances of the down – draft fixed bed gasifier used in the experiments.</p>

Artefacts relating to tin smelting from tin mills or 'blowing houses' in Devon and Cornwall, plus material from smelting sites that cover a range of dates from the Bronze Age through to the 19th Century, were examined: these include metallic tin, furnace linings, ore samples and slag. Analysis of tin slags from over forty sites was carried out, to determine microstructure and chemical composition. Techniques employed included optical and scanning electron microscopy, X-ray fluorescence and ICP mass spectrometry. Analysis indicates that slag appearance and composition are heavily influenced by local geology. Composition, particularly iron content, is shown to have a strong effect on slag melting point and viscosity, and the implications for the purity of metal produced are discussed. Bringing together the evidence provided by slag chemistry, documentary sources and smelting remains in the archaeological record, changes in tin smelting technology through time, and the consequences thereof, are considered.