This study encompasses various aspects of corrosion in chloride molten salt environments, employing electrochemical techniques and a forced convection loop. It explores corrosion thermodynamic properties, electrochemical corrosion kinetics, and flow-induced dynamic corrosion. The study developed a novel electrochemical method for measuring thermodynamic properties of corrosion products and develops a new analysis theory for potentiodynamic polarization data obtained from cathodic diffusion-controlled reactions. Additionally, the design and operation experience of a forced convection chloride molten salt loop is shared. Particularly, the study presents novel findings on the turbulent flow-induced corrosion phenomenon and mechanism of Fe-based alloys in Mg-based chloride molten salt. These outcomes provide valuable insights into the corrosion mechanisms and flow-induced corrosion of Fe-based alloys in chloride molten salt. The results and experiences shared in this paper have implications for the successful implementation of molten salt as an advanced heat transfer fluid and thermal energy storage material in high-temperature applications, benefiting the nuclear and concentrating solar communities. / Doctor of Philosophy / This study explores the corrosion behavior of materials chloride molten salt, which is used in advanced energy systems. By using advanced techniques, the researchers investigated how these materials react and corrode in different conditions. They developed new methods to measure the properties of the corrosion products and analyzed how different factors affect the corrosion process. Additionally, they shared their experiences in building and operating a flow loop to simulate these conditions. The study discovered interesting phenomena, such as how the flow of molten salt can cause corrosion in certain types of metals. These findings provide important insights for improving the use of molten salt as a heat transfer fluid and energy storage material in advanced energy technologies.

No / An experimental configuration that combines the powerful capabilities of a short-term shearing apparatus with simultaneous optical and X-ray scattering techniques is demonstrated, connecting the earliest events that occur during shear-induced crystallization of a polymer melt with the subsequent kinetics and morphology development. Oriented precursors are at the heart of the great effects that flow can produce on polymer crystallization (strongly enhanced kinetics and formation of highly oriented crystallites), and their creation is highly dependent on material properties and the level of stress applied. The sensitivity of rheo-optics enables the detection of these dilute shear-induced precursors as they form during flow, before X-ray techniques are able to reveal them. Then, as crystallization occurs from these precursors, X-ray scattering allows detailed quantification of the characteristics and kinetics of growth of the crystallites nucleated by the flow-induced precursors. This simultaneous combination of techniques allows unambiguous correlation between the early events that occur during shear and the evolution of crystallization after flow has stopped, eliminating uncertainties that result from the extreme sensitivity of flow-induced crystallization to small changes in the imposed stress and the material. Experimental data on a bimodal blend of isotactic polypropylenes are presented.

<p> Two phase flow induced vibrations is a field that has many inherent modelling difficulties, making research in the area challenging. In order to study the problem more closely, a two phase flow loop using Freon 11 had been designed and commissioned at McMaster University. The initial design required some modifications to make the loop as "user friendly" as possible. The final result meets this desired capability. </p> <p> The loop was designed so that research into vibrations in tube bundles could be carried out. A test section had been designed to facilitate this task. However, this design also required modifications. Additionally, new vibration monitoring instrumentation making use of light was developed to avoid the detrimental effects of Freon 11. The introduction of these items has resulted in a complete facility for the purpose of studying two phase flow induced vibrations. Preliminary experiments revealed a problem relating to tube tuning. Generally, the results are promising and some interesting new phenomena were observed as well. </p> / Thesis / Master of Engineering (ME)

The fundamental nature of the flow oscillations which are generated by two opposing planar jets is investigated. Particular attention is given to the underlying mechanism which sustains the oscillations over a wide range of flow parameters. The jet columns are observed to undergo large lateral deflection oscillations once in each direction per cycle, in an asymmetric manner. Extensive characterization of the jet oscillations over a wide range of flow parameters is established, including both the aeroacoustic response, as well as the unique flow features which are synchronized with the oscillations. The impingement region and circulation regions in each quadrant of the flow field are shown to play essential roles in sustaining the oscillations, as the pressurization of the impingement region causes the jets to initially deflect away from the centerline, while the low-pressure regions which form in the circulation zones drive the jet columns back towards, and ultimately across, the centerline. A number of interesting observations are made regarding the oscillation characteristics, including a dependence of the oscillation frequency on the jet aspect ratio, which helps explain much of the discrepancy in the Strouhal numbers reported in the literature to date. Furthermore, the nature of the sound-source field is investigated including the directionality of the various frequency components which are radiated. Unique mitigation strategies of the opposing planar jet oscillations are also explored by attempting to disrupt the circulation regions through the use of splitter plates. The oscillations are weakened considerably as the development and convection of the circulation zones is impeded. Preventing the circulation flow from interacting with the jet exit region drastically increases the effectiveness of the splitter plates, as even short splitter plates are shown to completely eliminate the oscillations. This demonstrates a very effective mitigation strategy of the opposing planar jet oscillator which is ideal for a variety of practical applications. One of the main challenges of the current investigation into the opposing planar jet oscillator is the extent to which the detailed time-varying pressure field can be resolved. Since it is not possible to experimentally detail the time-varying pressure field of the opposing planar jets, a novel PIV-based pressure field mapping technique is developed and benchmarked. A separate apparatus consisting of a planar jet impinging on a v-shaped plate is utilized to benchmark the proposed technique. This technique effectively resolves the features of the time-varying pressure field which are synchronized with the flow oscillations and helps circumvent many of the challenges which existing PIV pressure field mapping techniques face. It also provides a valuable tool for researchers to simultaneously determine the kinematic and dynamic aspects of various flow phenomena in a variety of fields, especially those in the area of aeroacoustics and fluid-structure-interaction. / Thesis / Doctor of Philosophy (PhD)

Excessive water flow velocities can contribute to rapid failures of copper premise plumbing systems. This is the first fundamental study to scientifically isolate mechanistic impacts from distinct flow induced failure mechanisms that include concentration cell corrosion, cavitation, particle/bubble impingement and high velocity impingement. Concentration cell effects resulting from exposing different copper surfaces to different flow regimes created a strong electrochemical cell that caused rapid corrosion that persisted for periods lasting from hours to days in certain waters. Free chlorine appeared to inhibit this effect in a range of waters. Under typical water chemistries the resulting non-uniform attack diminished, presumably due to formation of a protective scale or rust layer. Consequently, concentration cell corrosion would not be a major contributor to damage from high flow rates in the range of fresh waters investigated. In experiments using an ultrasonic processor, implosion of vaporous cavitation bubbles against a copper surface caused dramatic pitting, considerable copper weight loss, and, in some cases, the development of pinhole leaks. Changes in water chemistry and the existence of a pre-existing protective scale layer had nearly no mitigating effects on copper cavitation damage. An exponential relationship was found between the initial copper pipe wall thickness and the time necessary to cause a leak via vaporous cavitation. On the basis of this relationship, a Type M tube would be expected to last 23 and 3000 times less than a Type K and L tube, respectively, when facing continual cavitation attack. However, it was not possible to re-create cavitation damage in any practical circumstance that was tested in copper pipes, even though it is strongly believed that cavitation can play a practical role in service failures. On the basis of the above results, it was hypothesized that brief intervals of cavitation could remove protective scale from portions of the copper pipe surface exposed to high turbulence. In this case, even if minimal damage from cavitation occurred directly, it could allow concentration cell corrosion to become a significant contributor to non-uniform corrosion damage. On the basis of preliminary testing, it appears that this idea has considerable merit. A combination of brief cavitation and waters that create strong concentration cell effects is expected to cause serious damage to copper pipe. These potential synergies are deserving of additional research. In experiments testing the effect of high velocity jets (17.5 ft/sec) impinging against submerged copper plates perpendicularly and longitudinally, plates in heated sea water were aggressively gouged and penetrated. It is believed that the copper plate damage resulted from a combination of mechanisms including concentration cell corrosion, cavitation implosion, and high velocity impingement. Impingement of sand on the surface of copper tube created very little damage. This was surprising given prior reports in the literature. / Master of Science

There is a need to investigate and improve upon existing methods to predict response of sensors due to flow-induced vibrations in a pipe flow. The aim was to develop a tool which would enable an engineer to quickly evaluate the suitability of a particular design for a certain pipe flow application, without sacrificing fidelity. The primary methods, found in guides published by the American Society of Mechanical Engineers (ASME), of simple response prediction of sensors were found to be lacking in several key areas, which prompted development of the tool described herein. A particular limitation of the existing guidelines deals with complex stochastic stationary and non-stationary modeling and required much further study, therefore providing direction for the second portion of this body of work. A tool for response prediction of fluid-induced vibrations of sensors was developed which allowed for analysis of low aspect ratio sensors. Results from the tool were compared to experimental lift and drag data, recorded for a range of flow velocities. The model was found to perform well over the majority of the velocity range showing superiority in prediction of response as compared to ASME guidelines. The tool was then applied to a design problem given by an industrial partner, showing several of their designs to be inadequate for the proposed flow regime. This immediate identification of unsuitable designs no doubt saved significant time in the product development process. Work to investigate stochastic modeling in structural dynamics was undertaken to understand the reasons for the limitations found in fluid-structure interaction models. A particular weakness, non-stationary forcing, was found to be the most lacking in terms of use in the design stage of structures. A method was developed using the Karhunen Loeve expansion as its base to close the gap between prohibitively simple (stationary only) models and those which require too much computation time. Models were developed from SDOF through continuous systems and shown to perform well at each stage. Further work is needed in this area to bring this work full circle such that the lessons learned can improve design level turbulent response calculations. / Ph. D.

Mufflers and silencers are commonly used to attenuate noise sources such as internal combustion engines and HVAC systems. Typically, these environments contain mean flow that can affect the acoustic properties of the muffler components and may produce flow generated noise. To characterize the muffler performance, common metrics such as insertion and transmission loss and noise reduction are used in industry. Though transmission loss without flow is often measured and is a relatively simple bench top experiment and useful for model validation purposes, mean flow can significantly affect the muffler performance. There are a few existing and commercial transmission loss rigs that incorporate flow into the measurement procedure. These rigs are useful for model verification including flow but do not predict how the muffler will perform in the system since the source, termination, and pipe lengths significantly impact performance. In this research, the development of an insertion loss test rig is detailed. This testing strategy has the advantage of being simpler, quantifying the self-generated noise due to flow, and taking into account the effect of tailpipe length and a realistic termination. However, the test does not include the actual source and is not as useful for model validation. An electric blower produces the flow and a silencer quiets the flow. Loudspeakers are positioned just downstream of the flow silencer and they are used as the sound source. The low frequency source is a subwoofer installed in a cylindrical enclosure that includes a conical transition from speaker to pipe. Special care is taken to reduce any flow generated noise. Qualification of the system is detailed by comparing the measured transmission loss, noise reduction, and insertion loss to one-dimensional plane wave models. The results demonstrate that the developed rig should be useful as a muffler evaluation tool after a prototype has been constructed. The rig can also be used for transmission loss and noise reduction determination which will prove beneficial for laboratory testing.

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The goal of this project was to develop a wind generator that utilizes the collective oscillating motion of multiple piezoelectric devices. These devices would be an alternative to rotating turbine designs for low power generation, for use in applications such as remote power generation. A series of inexpensive devices were developed that harvested energy from vortex shedding, both as independent and cooperative devices. The behavior of single devices was studied, but more interestingly, the way that multiple devices arranged together can increase power output was studied. It was shown that individual devices could harvest more energy if they were placed as specific positions relative to the vortices shed by devices upstream. Through investigating the behavior of these devices, fundamental principles of the phenomenon of vortex induced vibrations were explored. Methods were developed to measure the amplitude and frequency of these vibrations in a wind tunnel, through high speed video and correlations that were found between oscillation and power output from the piezoelectric transducers. Similarly, vortex induced vibrations were explored in an approximation of a two dimensional system in a flowing soap film.