The focus of this thesis is the development of Resistive Plate Chambers (RPCs) with ceramic electrodes. The use of ceramic composites, Si3N4/SiC, opens the way for the application of RPCs in harsh radiation environments. Future Experiments like the Compressed Baryonic Matter (CBM) at the Facility for Antiproton and Ion Research (FAIR) in Darmstadt will need new RPCs with high rate capabilities and high radiation tolerance. Ceramic composites are specially suited for this purpose due to their resistance to radiation and chemical contamination. The bulk resistivity of these ceramics is in the range 10^7 - 10^13 Ohm cm. The bulk resistivity of the electrodes is the main factor determining the rate capabilities of a RPC, therefore a specifific measuring station and a measurement protocol has been set for these measurements. The dependence of the bulk resistivity on the difffferent steps of the manufacturing process has been studied. Other electrical parameters like the relaxation time, the relative permittivity and the tangent loss have also been investigated. Simulation codes for the investigation of RPC functionality was developed using the gas detectors simulation framework GARFIELD++. The parameters of the two mixtures used in RPC operation have been extracted. Furthermore, theoretical predictions on time resolution and effi ciency have been calculated and compared with experimental results. Two ceramic materials have been used to assemble RPCs. Si3N4/SiC and Al2O3 with a thin (nm thick) chromium layer deposited over it. Several prototypes have been assembled with active areas of 5x 5 cm^2, 10x 10 cm^2 and 20 x20 cm^2. The number of gaps ranges from two to six. The gas gap widths were 250 micro meter and 300 micrometer. As separator material mylar foils, fifishing line and high-resistive ceramics have been used. Different detector architectures have been built and their effffect on RPC performance analysed. The RPCs developed at HZDR and ITEP (Moscow) were systematically tested in electron and proton beams and with cosmic radiation over the course of three years. The performance of the RPCs was extracted from the measured data. The main parameters like time resolution, effi ciency, rate capabilities, cluster size, detector currents and avalanche charge were obtained and compared with other RPC systems in the world. A comparison with phenomenological models was performed.

Metal organic frameworks (MOFs) and metal oxide-MOF composites were investigated for adsorption and oxidation of carbon monoxide. Metal oxides were successfully included in MOFs via both impregnation and encapsulation. UiO-66, a zirconium-based MOF, was impregnated with magnesium or cobalt oxide. Cobalt oxide in UiO-66 increases the room temperature CO capacity and shows increased adsorption at 65°C due to strong cobalt-CO interactions. Titania and magnetic nanoparticles were encapsulated in HKUST-1, a copper-based MOF. Including titania in HKUST-1 lowers the CO oxidation onset temperature by over 100°C compared with HKUST-1, and the composite reaches complete conversion by 250°C. HKUST-1 with magnetic nanoparticles shows enhanced structural stability and increased room temperature adsorption of CO and hexane. MOF-74, an isostructural family with coordinatively unsaturated metal centers of cobalt, magnesium, nickel, or zinc, was investigated for the metal center’s impact on stability and adsorption. Pre-treatment conditions to optimize accessibility were found that maximize solvent removal while retaining structural integrity. The impact of air exposure on equilibrium CO capacity was investigated, and these predictions were compared to dynamic conditions, separating CO from nitrogen or air at room temperature. The cobalt analog loses only 25% of its CO capacity with air exposure, retaining higher capacity than the other analogs under ideal conditions. Unlike cobalt, the magnesium analog does not follow the predicted trends with air exposure, having higher dynamic capacities with pre-exposed samples. Under all dynamic conditions, the nickel analog oxidized a portion of the carbon monoxide feed.

Increased interest in the field of sensor technology stems from the availability of an inexpensive and robust sensor to detect and quantify the presence of a specific gas. Bulk p-CuO/n-ZnO heterocontact based gas sensors have been shown to exhibit the necessary sensitivity and selectivity characteristics, however, low interfacial CuO/ZnO contact area and poor CuO/ZnO connectivity limits their effective use as gas sensors. The phase equilibria between CuO and ZnO exhibits limited solubility. By exploiting this concept, a CuO/ZnO mixed solution is formed by combining CuO and ZnO precursors using wet chemical (sol-gel) techniques. Thin films fabricated using this mixed solution exhibit a unique CuO/ZnO microstructure such that ZnO grains are surrounded by a network of CuO grains. This is highly beneficial in gas sensing applications since the CuO/ZnO heterostructure interfacial area is considerably increased and is expected to enhance sensing characteristics. This work builds on previous research by Dandeneau et al. (Thin film chemical sensors based on p-CuO/n-ZnO heterocontacts, Thin Solid Films, 2008). CuO/ZnO mixed solution thin films are fabricated using the sol-gel technique and subsequently characterized. X-ray diffraction (XRD) data confirms the phase separation between ZnO and CuO grains. Scanning electron microscopy (SEM) as well as energy dispersive spectroscopy (EDS) reveal a network of ZnO grains amidst a matrix of CuO grains. Optical and electrical characterization provide material parameters used to construct an energy band diagram for the CuO/ZnO heterostructure. Aluminum interdigitated electrodes (IDEs) are patterned on the thin film and gas sensing characteristics in the presence of oxygen and hydrogen are investigated. Optimization of the electrode geometry is explored with the aim of increasing the sensitivity of the sensor in the presence of hydrogen gas. / Graduation date: 2010

Le collisionneur linéaire international (ILC) est prévu pour être le prochain grand projet de la physique des hautes énergies. ILC est proposé avec deux détecteurs, International Large Detector (ILD), et Silicon Detector (SID). Cette thèse s’est déroulée dans le cadre de l'ILD. L'un des principaux composants du détecteur ILD est la chambre à projection temporelle (TPC). Cette thèse se concentre sur le développement de la lecture de la TPC, basée sur l'intégration des détecteurs de gaz Micro-pattern (Micromegas) et de puces CMOS pixels ("Timepix"). Ce nouveau type de dispositif est appelé "Ingrid". Les exigences principales pour "Ingrid" sont d’atteindre la sensibilité aux électrons uniques et d’obtenir une très haute résolution spatiale (~ 30 µm). Avec une TPC, on reconstruit les traces en utilisant le profil 2D des charges sur la plaque a l’extrémité de la TPC et la troisième coordonnée est dérivée du temps de dérive. Dans le cadre de cette thèse, une mini-TPC a été construite a Saclay dans le but de tester plusieurs prototypes de détecteurs "Ingrid". En outre, un système compose de 8 puces nommé "Octopuce" a été construit pour développer des algorithmes de reconstruction de traces. Nous avons effectué plusieurs mesures à l'aide de source radioactive à Saclay. Par ailleurs, de grands modules ont été testés avec un prototype de grande TPC (LP) sur un faisceau de test à DESY. Les résultats obtenus avec deux modules différents ont été présentés et les résultats sont en bon accord avec la prédiction théorique. La présence de la matière noire fournit une bonne indication d'apparition de nouveaux phénomènes a proximité de l'échelle électrofaible, et l'hypothèse populaire d’existence des WIMP doit être testé. Comme les couplages des WIMP aux différentes espèces de particules du modèle standard sont a priori inconnus, la recherche de la production de WIMP en collisions e+e- est complémentaire à la production dans les collisions pp ou a la détection directe de WIMPs primordiaux par leur diffusion sur des nucléons. Dans ce travail, nous étudions possibilité de découverte (ou l'exclusion) de production de paires de WIMPs avec l’ILC. Dans ce processus, un unique photon est rayonne dans l'état initial et une énergie manquante est requise. Nous montrons que l’ILC peut découvrir cette signature, même si l'annihilation en paires électron-positon contribue faiblement au taux d’annihilation de la matière noire dans l'univers primordial. Nous avons traduit la sensibilité en terme d’échelles de masse pour différents types d’opérateurs effectifs et montré que la masse et les couplages des WIMPs peuvent être mesurés avec une précision de l’ordre de 1% si leur détection est avérée. En outre, des études de production de WIMPs avec l’ILC sont complémentaires aux études avec des états finaux mono-X au LHC, car ils testent le couplage WIMP-lepton. Au LHC, le couplage WIMP-proton est testé a une l'échelle de 1 TeV. Avec l’ILC, en utilisant une luminosité intégrée de 500 fb⁻¹, une énergie dans le centre de masse de √s = 500 GeV et avec des faisceau non polarisés, une limite pour l’échelle sur l'interaction de contact Λ de l’ordre de 2 TeV est accessible. De plus, les configurations de polarisation appropriées permettent d'améliorer la sensibilité pour les recherches de matière noire à l’ILC, en supposant que le couplage des paires de WIMP aux électrons et aux positons dépend du choix de l'opérateur. / The International Linear Collider (ILC) is planned to be the next major project in the High Energy Physics. ILC is proposed to have two detectors, namely International Large Detector (ILD), and Silicon Detector (SiD). This thesis is done in the framework of the ILD. One of the main components of the ILD detector is the Time Projection Chamber (TPC). This PhD thesis concentrates on the development of TPC readout, based on integration of the Micro-pattern gas detectors (Micromegas) and CMOS pixel chips ("Timepix"). This new type of device is named "InGrid". Main requirements for "InGrid" is to achieve sensitivity to single electrons and a very high spatial resolution (~30 μm). In TPC one reconstructs tracks using 2D-charge profile on the TPC endplate and the third coordinate is derived from the drift time information. In Saclay mini-TPC was built. Using this mini-TPC, several prototype "Ingrid" detectors have been tested in the course of this PhD. In addition, 8-chips system named “Octopuce” was built to develop track reconstruction algorithms. We have performed several measurements using laboratory radioactive source in Saclay. In addition, the large modules were tested at a Large TPC Prototype (LP) in a test beam area at DESY. Results with two different modules were presented. Obtained results well agreed with theoretical prediction. The existence of Dark Matter provides a strong indication for the appearance of new phenomena near the electroweak scale, and the popular WIMP hypothesis is out there to be tested. Since the couplings of WIMPs to different species of Standard Model particles are a priori unknown, the investigation of WIMP production in e+e- collisions is fundamentally complementary to production in pp collisions or direct detection of primordial WIMPs scattering on nucleons. In this work we investigate the discovery (or exclusion) reach of the ILC based on the production of a pair of WIMPs, which recoils against an energetic photon from initial state radiation. We show that the ILC can discover this signature even if annihilation to electrons provides only a small fraction of the total dark matter annihilation rate in the early universe. We translated the sensitivity into mass scales of various effective operators and showed that the WIMPs mass and couplings can be measured at the percent level in case of an observation. Furthermore, WIMPs studies on ILC are complementary to current LHC in the mono-X final states, because they test WIMP-lepton coupling. LHC studies WIMP-proton coupling at the scale of 1 TeV. ILC could reach limits up to 2 TeV on the contact interaction scale Λ for the vector operator by using an integrated luminosity at 500 fb⁻¹, at the center-of-mass √s = 500 GeV with unpolarized beams. Moreover, proper polarization configurations allows to improve sensitivity for the Dark Matter searches at the ILC, assuming WIMPs pair couple differently to electron and positron for different operators.

Thesis (M.S.)--Mississippi State University. Department of Physics and Astronomy. / Title from title screen. Includes bibliographical references.

The focus of this thesis is the development of Resistive Plate Chambers (RPCs) with ceramic electrodes. The use of ceramic composites, Si3N4/SiC, opens the way for the application of RPCs in harsh radiation environments. Future Experiments like the Compressed Baryonic Matter (CBM) at the Facility for Antiproton and Ion Research (FAIR) in Darmstadt will need new RPCs with high rate capabilities and high radiation tolerance. Ceramic composites are specially suited for this purpose due to their resistance to radiation and chemical contamination. The bulk resistivity of these ceramics is in the range 10^7 - 10^13 Ohm cm. The bulk resistivity of the electrodes is the main factor determining the rate capabilities of a RPC, therefore a specifific measuring station and a measurement protocol has been set for these measurements. The dependence of the bulk resistivity on the difffferent steps of the manufacturing process has been studied. Other electrical parameters like the relaxation time, the relative permittivity and the tangent loss have also been investigated. Simulation codes for the investigation of RPC functionality was developed using the gas detectors simulation framework GARFIELD++. The parameters of the two mixtures used in RPC operation have been extracted. Furthermore, theoretical predictions on time resolution and effi ciency have been calculated and compared with experimental results. Two ceramic materials have been used to assemble RPCs. Si3N4/SiC and Al2O3 with a thin (nm thick) chromium layer deposited over it. Several prototypes have been assembled with active areas of 5x 5 cm^2, 10x 10 cm^2 and 20 x20 cm^2. The number of gaps ranges from two to six. The gas gap widths were 250 micro meter and 300 micrometer. As separator material mylar foils, fifishing line and high-resistive ceramics have been used. Different detector architectures have been built and their effffect on RPC performance analysed. The RPCs developed at HZDR and ITEP (Moscow) were systematically tested in electron and proton beams and with cosmic radiation over the course of three years. The performance of the RPCs was extracted from the measured data. The main parameters like time resolution, effi ciency, rate capabilities, cluster size, detector currents and avalanche charge were obtained and compared with other RPC systems in the world. A comparison with phenomenological models was performed.

The objective of this research is to apply micromachined silicon-based resonant gravimetric sensors to the detection of gas-phase volatile organic compounds (VOCs). This is done in two primary tasks: 1) the optimization and application of silicon disk resonators to the detection of gas-phase VOCs, and 2) the development and application of a novel gravimetric-capacitive multisensor platform for the detection of gas-phase VOCs. In the rst task, the design and fabrication of a silicon-based disk resonator structure utilizing an in-plane resonance mode is undertaken. The resonance characteristics of the disk resonator are characterized and optimized. The optimized characteristics include the resonator Q-factor as a function of geometric parameters, and the dynamic displacement of the in-plane resonance mode. The Q-factors of the disk resonators range from 2600 to 4360 at atmosphere for disk silicon thicknesses from 7 µm to 18 µm, respectively. The resonance frequency of the in-plane resonance mode ranges from 260 kHz up to 750 kHz. The disk resonators are applied to the sensing of gas-phase VOCs using (poly)isobutylene as a sensitive layer. Limits of detection for benzene, toluene and m-xylene vapors of 5.3 ppm, 1.2 ppm, and 0.6 ppm are respectively obtained. Finally, models for the limits of detection and chemical sensitivity of the resonator structures are developed for the case of the polymer layers used. In the second task, a silicon-based resonator is combined with a capacitive structure to produce a multisensor structure for the sensing of gas-phase VOCs. Fabrication of the multisensor structure is undertaken, and the sensor is theoretically modeled. The baseline capacitance of the capacitor component of the multisensor is estimated to be 170 fF. Finally, initial VOC detection results for the capacitive aspect of the sensor are obtained.

Today there is a great deal of interest in the development of gas sensors for applications like air pollution monitoring, indoor environment control, detection of harmful gases in mines etc. Based on different sensing principles, a large variety of sensors such as semiconductor gas sensors, thermoelectric gas sensors, optical sensors and thermal conductivity sensors have been developed. The present thesis reports a detailed account of a novel method followed for the design and development of a thermoelectric gas sensor for sensing of Volatile Organic Compounds. Thermoelectric effect is one of the highly reliable and important working principles that is widely being put into practical applications. The thermoelectric property of semiconducting tin oxide film has been utilized in the sensor that has been developed. The thermoelectric property of semiconducting tin oxide film has been utilized in the sensor. The deposition parameters for sputtering of tin oxide film have been optimized to obtain a high seebeck coefficient. A test set-up to characterize the deposited films for their thermoelectric property has been designed and developed. A novel method of increasing the seebeck coefficient of tin oxide films has been successfully implemented. Thin films of chromium, copper and silver were used for this purpose. Deposition of the semiconducting oxide on strips of metal films has led to a noticeable increase in the seebeck coefficient of the oxide film without significantly affecting its thermal conductivity. The next part of our work involved development of a gas sensor using this thermoelectric film. These sensors were further tested for their response to volatile organic compounds. The sensor showed significant sensitivity to the test gases at relatively low temperatures. In addition to this, the developed sensor is also selective to acetone gas.

Thesis (M.Sc. (Physics)) -- University of Limpopo, 2022 / The gas sensing performance of two-dimensional (2D) hexagonal boron nitride nanosheets (h-BNNSs) has being studied by means of computational and experimental methods. The structural, stability and vacancies properties of both defect free and defected 2D h-BNNSs were studied using the classical molecular dynamics (MD) approach. The calculations were performed in the NVT Evans and NPT hoover ensembles using the Tersoff potentials with the Verlet leapfrog algorithm to obtain reliable structural properties and energies for defect free, boron (B) and nitrogen (N) vacancies. B and N defect energies were calculated relative to the bulk defect free total energies, and the results suggest that N vacancy is the most stable vacancy as compared to the B vacancy. The radial distribution functions and structure factors were used to predict the most probable structural form. Mean square displacements suggests the mobility of B and N atoms in the system is increasing with an increase in the surface area of the nanosheets. Results obtained are compared with the bulk defect free h-BNNSs. Experimentally, 2D h-BNNSs were synthesised using the wet chemical reaction method through chemical vapour deposition (CVD) catalyst free approach. The X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR), Raman Spectroscopy (RM), UV-visible Spectroscopy (UV-VIS), dynamic light scattering (DLS), Energy Dispersion Spectroscopy (EDS) and Brunauer-Emmett Teller (BET) were adopted to attain the structural properties of the nanosheets. Each spectroscopic technique affirmed unique features about the surface morphology of h BNNSs. The crystallinity of the nanosheets with the stacking of the B and N vii honeycomb lattice was validated by the XRD, while the TEM disclosed the specimen orientations and chemical compositions of phases with the number of layers of a planar honeycomb BN sheet, the EDS express the atoms present in the samples and BET validated the surface area of the materials. The FTIR, RM, DLS and the UV-vis expressed the formation of the in-plane, out-of-plane h-BN vibrations and, the nature of the surface with the thickness, particles stability together with the optical properties of the nanosheets. From TEM, FTIR, RS and BET the material fabricated at 800°C showed different morphologies, large number of disordering together with high surface area, which enhances the sensing properties of the nanosheets. However, with an increase in temperature the sensitivity of the nanosheets was found to decrease. Additionally, the UV-vis results, confirmed a lower energy band gap of 4.79, 4.55 and 4.70 eV for materials fabricated at 800, 900 and 1000 °C, that improved the semiconducting properties of the materials, which in return enhanced the sensing properties of the nanosheets. The gas sensing properties of the 2D h BNNSs were also investigated on hydrogen sulphide (H2S) and carbon monoxide (CO). The fabricated sensor based on 800 – 900 °C h-BNNSs showed good sensitivity towards ppm of H2S at 250 °C. The excellent gas sensing properties could be attributed to high surface area, small crystallite size, defect/disordering of h BNNSs. Overall, the h-BNNSs were found to be more sensitive to H2S over CO. / University of Limpopo (UL) Mintek Council for Scientific and Industrial Research (CSIR) Center for High Performance Computing (CHPC)