Hydropower regulation of rivers exhibits a threat to the riverine ecosystems. Fragmentation of flow, landscape disturbances, and water retention are key features of regulated catchments, resulting in reduced floods and geochemical tr¬ansport, non-natural water level fluctuations, and thus disturbed exchange between the river and the aquifer. Storing of water in reservoirs reduces peak flow and turbidity, which increases particle settling and sometimes favours enhanced primary production and formation of a clogging layer. This in turn alters the interaction between surface water and groundwater, with potential secondary effects on the entire watershed. In Scandinavia, only eight large rivers (16%) remain entirely unregulated. The Lule River, the primary focus of this study, belongs to the most regulated rivers of Eurasia with a degree of regulation (i.e. the volume of water that can be stored in the reservoirs and used for regulation) of 72%, and is exposed to both seasonal and short-time regulation.Using hydrogeochemical analysis of two adjacent boreal rivers (pristine Kalix and regulated Lule River) discharging into the Gulf of Bothnia, the effects of regulation on river geochemistry were investigated. For the Lule River, the average maximum runoff was almost halved while the average minimum runoff was tripled as a result of the regulation. The winter transport fraction of total organic carbon, Fe, Si, suspended Mn and P in the Lule River was at least two to three times higher than in the pristine river. During summer, the suspended C/N ratio in the regulated river was 10-20, compared to <10 for the pristine river, suggesting a presence of predominantly decaying organic material due to longer residence times for the regulated river. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. Hence, a pronounced impact on the ecosystem of the river, the hyporheic/riparian zone, and the Gulf of Bothnia is expected.In spite of vast anthropogenic pressure on riverine ecosystems, the knowledge regarding the hyporheic zone (the interface between rivers and aquifers where exchange between surface water and groundwater occurs) is limited for regulated rivers. Therefore, this study was extended to also cover the hyporheic exchange along the Lule River. Temporal changes in hyporheic fluxes across the river channel (rates and directions) were determined using seepage measurements and continuous observations of water stages, temperatures, and electrical conductivity for both the river and the groundwater. While the river water level changed frequently (typically twice a day with up to ± 0.5 m), the river remained gaining 90% of the time, and the largest number of observed changes in flow direction (observed at 5 m orthogonal distance from the river) was six times per week. Flow velocities ≤10-4 m d-1 ( zero flow) constituted 1.5% of the total observation time.Although no changes in water temperature were observed for the hyporheic zone, effects of river level variations were detected up to 5 m inland, where electrical conductivity occasionally decreased to surface water levels indicating infiltration of river water into the aquifer (negative fluxes). River discharge regulation may therefore have severe implications on biogeochemical processes and deteriorate the hydroecological functions of the hyporheic zone.

Little attention has been paid to tailings from skarn ore deposits and their environmental impact, even though they can contain elevated content of elements of potential concern. Historical skarn tailings from a former scheelite mine at Yxsjöberg, Sweden, containing e.g. Be, Bi, Cu, F, Sn, S, W, and Zn were geochemically characterized as a first step to evaluate the potential environmental impact and if re-mining of the tailings can be a remediation option. Beryllium, Bi, F, and W are considered as elements of potential concern, and are at the same time listed by the European Commission (2017) as critical raw materials. Scheelite is considered as a relatively stable mineral but most research has been focused on extraction processes. A few laboratory studies have shown weathering of scheelite by artificial groundwater, where the release of WO42-was hypothesized to be due to anion exchange by CO32-. Thus, the release of W from scheelite should be favorable in skarn tailings due to the presence of carbonates. The tailings at Yxsjöberg were deposited between 1897 and 1963 in the Smaltjärnen Repository without dams or a complete cover, and have been in contact with the atmosphere for more than 30 years. Four vertical cores (P2, P4, P5, and P7) throughout the tailings were taken and divided into 134 subsamples, and analyzed for their total chemical composition and paste pH. Selected samples from different depths were mineralogically characterized using optical microscopy, scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), Raman vibrational spectroscopy, and X-ray diffraction (XRD). Minerals, hand-picked from drilled rock cores, were analyzed for the element content, and a modified Element to Mineral Conversion (EMC) in combination with a 7-step sequential extraction of the tailings was used to pinpoint the quantitative distribution of elements between the minerals in the tailings. Scheelite weathering and secondary sequestration of W was studied in detail in one representative core. The release of elements to groundwater in the tailings and downstream surface water was measured monthly during 2018 to especially examine the mobility of W. The average concentrations of Be, Bi, Cu, Sn, Zn, W, F and S in the tailings were 280, 490, 950, 560, 300, and 960 ppm, and 1.9 and 1.2 wt.%, respectively. The uppermost tailings have been exposed to the atmosphere for more 30 years, with intensive pyrrhotite oxidation and carbonate dissolution, resulting in low pH (<4) condition, release of elements, and subsequent formations of secondary minerals such as gypsum and hydrous ferric oxides (HFO). Two different deposition periods were identified in one vertical profile. The later period of deposition extended from the ground surface down to 3.5 m, and the older from 3.6 to 6 m. Both periods had unoxidized tailings in the bottom and oxidized sulfides, depletion of calcite and HFO formations upwards. Tungsten was primarily found in scheelite and the abundance was 0.1 wt.% in the tailings at Yxsjöberg. Accumulation peaks of W were found with depth in P2, P4 and P7. In the upper peak of P4, 30% of the total W was associated with secondary HFO. This indicates that weathering of scheelite and secondary capturing of W had occurred in the tailings. At present time, a peak of W in water soluble phases where coinciding with accumulated C in the solid phase at 2.5m depth. Carbonate ions were released when calcite was neutralizing the acid produced in the upper oxidized tailings and the released CO32-was transported downwards to conditions with pH >7. There, it mainly had precipitated as secondary calcite, but small parts are hypothesized to have exchanged WO42-on the surface of scheelite,releasing WO42-to the pore water. In the oxidized tailings of the older and deeper tailing,goethite was found as rims around scheelite grains. This is probably due to Fe ions attracted to the negative surface of scheelite. This is suggested to decrease further weathering of scheelite, and also to some extent decrease the release of WO42-to the groundwater from above lying layers through adsorption. The changes in geochemical conditions in the tailings have decreased the water quality in receiving waters of Smaltjärnens Repository with increased concentrations of Ca, F, Fe,Mn, and SO42-. pH was on average 6.3 in the groundwater in the tailings and 5.7 in the surface water 300 m downstream. EC was on average 2.6 mS/cm in the groundwater and 131 μS/cm in the surface water. Low concentrations of dissolved W was found in the groundwater (max: 20 μg/l) in the tailings and in the downstream surface water the W concentration (max: 0.2 μg/l) was 20 times larger than the reference sample. These results show that scheelite is releasing W to a limited degree to downstream waters and are therefore a potential resource to re-mine to support the supply of critical raw materials in the EU. Beryllium, F, and Zn were released to the downstream surface water from the Smaltjärnen Repository, and to a higher degree than W. The rare and easily-weathered mineral danalite (Fe4Be3(SiO4)3S) contained approximately 40% of the total Be and Zn concentrations in the tailings and is suggested to be the major source to the release of Be and Zn. Fluorine was mainly found in fluorite which showed signs of weathering in the acidic condition in the uppermost oxidized tailings, subsequent with decreased content in the tailings. The mobility of these elements will be further studied.

Acid rock drainage (ARD), caused by the oxidation of sulphide bearing minerals, continues to be an environmental impact of both closed and operational mines, leading to waters with low pH values and high metal concentrations (Park et al., 2019). A potential treatment method for ARD is controlled eutrophication, where algae growth is stimulated in the water and metals are accumulated within the algae cells or sorbed to the outside of the cell walls (Samal et al., 2020). The aim of this study is to determine if the addition of wood ash to acidic mine waters can increase the pH, stimulate algal growth, and lower metal concentrations in the water. Two types of wood ash, as well as KNO3 and KH2PO4 were utilized for this study, along with three water sample types: neutral (pH of 7.0) water from Åkerberg pit lake, acidic (pH of 5.7) water from Maurliden mine site (Maurliden East), and very acidic (pH of 2.3) water from Maurliden mine site (Maurliden West). Two experiments were performed, Experiment I (Exp. I) involved a one-time addition of wood ash and KNO3 to samples from each of the three sites, and Experiment II (Exp. II) involved a feeding style ash addition where ash was added every five days to samples from Åkerberg and Maurliden East. Exp. II also included one sample set where artificial nutrients only (KNO3 and KH2PO4) were added to Maurliden East samples. Samples were placed inside of a climate chamber to provide daily irradiation and pH, electrical conductivity (EC), and fluorescence signal measurements were taken daily. Additionally, absorbance samples and O2 saturation measurements were taken daily for Exp. II. At the end of each experiment, samples were sent to an accredited laboratory for elemental analysis and chl-a analysis.  Algal growth was observed in Exp. I in Åkerberg samples only, and in Exp. II in Åkerberg samples and in Maurliden East samples with artificial nutrient additions only. The algal growth rate was similar in both experiments; however, Exp. II yielded a higher concentration of chl-a than Exp. I. Precipitates were observed in all samples in both experiments, including in control samples. pH results cannot confirm the ability of the wood ash to increase the pH in the samples from Maurliden East or West, and metal concentration decreases in these samples are most likely due to precipitation reactions. Metal concentration decreases in Åkerberg samples could be due to precipitation reactions and/or algal uptake.

Groundwater and artificially recharged groundwater are important sources offreshwater in Sweden. In growing societies an ever larger demand is put onmunicipalities drinking water production facilities. Especially in coastal areas oraquifers that are located below the highest coastal line, there can be ionically strongpaleowaters at greater depths which then risk being pumped up to the municipal watersupply. A common problem for municipal water works is that production wells pumpup ionically strong water, with a high electrical conductivity when the production wellsare stressed at high effect or longer periods of constant pumping. At the waterworks ofGäddvik in Luleå municipality certain wells have shown tendencies of higher electricalconductivities in the produced water, while some wells seem to never produce waterwith higher electrical conductivity, no matter how much they are pumped. Highelectrical conductivities has earlier been assumed to be paleowaters from below theaquifer with great concentrations of chloride, but this is not certain.This work investigates the possibilities of characterizing groundwater by using theoxygen isotopes 16O & 18O as well as main element analysis. In the work a field surveywas performed where groundwater was pumped up from 26 observational wells and 5productional wells at Gäddviks aquifer in Luleå. The samples were analyzed for isotopesof both oxygen and hydrogen as well as the main elements. The results have shown thatit is possible to correlate the heaviest isotopic signatures of oxygen with the highestmeasured values of chloride. This indicates that there is a potential value for identifyingpaleowaters with the help of oxygen isotopes especially when correlated to mainelement data.

The purpose of this study was to assess changes in the in-lake conditions of lake Kassjön, northern Sweden, in response to environmental and climate changes over the past ca. 6500 years. Sediment concentrations of different elements and biogenic silica (bSi) were measured with wavelength dispersive X-ray fluorescence spectrometry (XRF) and Fourier transform infrared spectroscopy (FTIR), respectively. The lake-water total organic carbon (LWTOC) content was inferred based on near-infrared spectroscopy (NIRS). The marine sediment was distinguished from the lacustrine sediment by higher dry bulk density, lithogenic element concentrations and Br content, and lower bSi concentrations. After lake formation, the dry bulk density, lithogenic element concentrations and metal contents decreased, while organic matter (OM), bSi and LWTOC increased. The main reasons for these changes are soil development and vegetation establishment. Spruce immigration around 3000 BP induced considerable changes to the sediment concentrations indicative of increased erosion versus weathering, and LWTOC declined. These changes are mainly related the different characteristics of spruce compared to birch. Human influences in the catchment were also clearly visible, but the rest of the sediment sequence demonstrated that natural changes can be of a similar magnitude. Overall, relatively small-scale, catchment specific processes seem to be more important for changes in the lake conditions than general climate change.

Volcanic-hosted massive sulfide (VMS) deposits are one of the main sources for zinc, copper, lead, silver and gold in Sweden. The majority of VMS deposits in Sweden are located in the Bergslagen region and the Skellefte district (Fig. 1). The Skellefte district hosts approximately 80 VMS deposits whereas 21 deposits have been mined since 1924 and 6 mines are currently in operation. VMS deposits tend to form more often on the intersection of the normal/reverse and transfer faults since there is an increased conductivity for hydrothermal fluids and increased fluid flow, so a structural interpretation of regional and deposit scale is important for exploration. The alteration patterns and mapped structures observed in the West Maurliden coincide with major structures found in the Skellefte district. Using this data and data from previous authors a general structural evolution of the Maurliden deposit has been constructed which shows the presumed outcome from the early extensional and later compressional stages ongoing in the region. Study of the mineralization shows that there is also the possibility to find mineralized rock within possible low strain blocks which might contain preserved primary textures and structures. A schematic plan view of the structure assemblage in the Skellefte district was established which shows perspective areas for future exploration.

The Swedish mining industry has changed from the historical situation with several smaller mines to the present situation with a few, bigger mines. This results in presence of abandoned mines around Sweden. Remediation of mines is regulated by legislation and the present demands are considerably higher than it was some decades ago.  The Storliden mine was a Zink- and Coppermine active between 2001-2008. Storliden is located in Malå municipality, Västerbotten county, and is included in the Skellefte district, known for its sulfide mineralizations.  The ore was broken underground with a technique called cut and fill mining. It was estimated that the ore was to be consumed in 2007, but due to rising ore prices, the mine was operated until 2008. Remediation was done through backfilling the mine with waste rock from Storliden and Boliden’s mines Renström, Kedträsk, and Kankberg. Also, tailings, concrete, and sludge from the sedimentation basins were backfilled. Today, the mine is filled with water.  High Arsenic concentrations in water is a serious health issue in parts of the world. Bangladesh is perhaps the most common example where Arsenic in groundwater has caused health problems for millions of people. In Sweden, the Skellefte field is known for its elevated Arsenic concentrations in the bedrock, related to sulfide mineralizations. Studies confirm a correlation between Arsenic-bearing bedrock and elevated concentrations in water.  This thesis work has been conducted together with the consultant company Golder Associates (Golder) in Luleå. Golder has performed environmental investigations in the Storliden area during the period 2018-2020. Installation and sampling of groundwater wells were included in this investigation. High concentrations of Arsenic was found in some of the groundwater wells. This thesis aims to review potential sources of Arsenic and their potential significance. The purposes are to be fulfilled by evaluating and interpreting the results from the sampling, Piper diagrams, ratios, and modeling in the program PHREEQC.  The results indicate that the presence of Arsenopyrite in the bedrock is the most likely source of the elevated concentrations of Arsenic in deep groundwater. Oxidation of Arsenopyrite is likely caused by mainly dissolved oxygen in groundwater. Further, the water quality differs from different depths, indicating that deep groundwater and water flow from the mine via the ramp do not have any immediate connection. It is likely that remains of tailings on the industrial area cause low pH and leaching of metals locally.  High concentrations of Arsenic can occur very locally, highlighting the importance of conducting sampling of groundwater used as drinking water in areas where sulfide mineralizations are confirmed or suspected. Further, a relation between the time that water is in contact with the bedrock/mineralization and the concentration of Arsenic is stated. Higher concentration HCO3- tends to correlate with elevated Arsenic concentration. / Sveriges gruvindustri har förändrats i snabb takt, från ett flertal mindre gruvor till dagens läge med ett mindre antal större gruvor. Detta resulterar i förekomst av nedlagda gruvor runt om i Sverige. Efterbehandling av gruvor regleras genom lagstiftning, och kraven idag är betydligt högre än för bara något decennium sedan.   Storlidengruvan var en zink- och koppargruva verksam mellan 2001–2008. Storliden ligger i Malå kommun och området ingår i Skelleftefältet, känt för sina sulfidmineraliseringar. Malmen bröts i en underjordsgruva med så kallad igensättningsbrytning, dvs. tomrum har succesivt fyllts ut med material under driften. Malmen beräknades vara förbrukad 2007, men när malmpriset ökade kunde gruvan leva vidare till 2008. Efterbehandlingen innebar att fylla igen gruvan med gråberg från Storliden men också gråberg från Bolidens gruvor Renström, Kedträsk och Kankberg. Dessutom användes anrikningssand, cement och slam från sedimentationsbassängerna för att fylla igen gruvan. Länshållning av gruvan upphörde och idag är gruvan vattenfylld. Höga arsenikhalter i vatten är ett hälsoproblem i delar av världen. Det kanske vanligaste exemplet är Bangladesh, där arsenik i grundvatten har orsakat hälsoproblem för miljontals människor. I Sverige är Skelleftefältet utmärkande för den höga arsenikhalten i berggrunden. Naturlig arsenikhalt i borrade brunnar har undersökts i flera studier som visar ett samband mellan arsenikhaltig berggrund och förhöjda halter i vatten.  Examensarbetet har utförts tillsammans med konsultföretaget Golder Associates i Luleå. Golder har fått i uppdrag att utföra miljötekniska undersökningar i Storlidenområdet, bland annat ingick installation och provtagning av grundvattenrör. Denna provtagning skedde under perioden 2018–2020. I några av grundvattenrören påträffades förhöjda halter av arsenik. Detta examensarbete syftar till att utreda förekomsten av Arsenik i grundvattnet, undersöka vilka källor som kan vara orsaken till arsenikhalterna samt källornas förväntade betydelse. Detta har gjorts genom att utvärdera och tolka resultaten från provtagningarna samt användningen av Piper-diagram, geokemiska kvoter och geokemisk modellering i programmet PHREEQC. Resultaten indikerar att förekomst av arsenikkis som mineralisering i berggrunden är den mest troliga källan till de förhöjda halterna av arsenik i djupt grundvatten. Oxidationen av arsenikkis sker troligtvis främst av löst syre i grundvattnet. Vidare skiljer sig vattenkvalitén åt från olika djup och delar av området som provtagits, dvs. det verkar inte finnas någon omedelbar koppling mellan djupt grundvatten och vatten som kommer via rampen som leder till gruvan. Det är troligt att rester av anrikningssand på industriområdet orsakar lågt pH och metallutlakning lokalt.  Höga arsenikhalter kan förekomma lokalt, vilket understryker vikten av att utföra provtagning av grundvatten som används för dricksvatten i områden där misstänkt eller konstaterade sulfidmineraliseringar förekommer, eftersom arsenik annars kan vara en mycket skadlig ”diffus” förorening. Vidare konstateras också samband mellan den tid som vatten är i kontakt med mineralisering och arsenikhalt. Högre halt HCO3- tenderar att korrelera med förhöjd arsenikhalt

Lake Victoria situated in East Africa faces an acute problem with eutrophication. Many reasons like agricultural production, industrialization, anthropogenic processes, the introduction of species, and economic activities have caused a stress to the overall well-being of the lake. Excess carbon, nitrogen, and phosphorus drive an increase in productivity which affects eutrophication. Previous studies on sediments and nutrient concentrations in the lake have concluded that nutrient concentrations increase due to release from the catchment. This study focuses on catchment sediments collected from four different sites and compares the results with sediments from two additional sites in the lake. The sediment core from Siaya indicates the highest concentrations of TOC (180 g/kg), TN (13 g/kg) and TP (17000μg/L). It is a rural site and poor agricultural practices such as the burn and slash, use of too many fertilizers, clearance of land, atmospheric deposition and precipitation increase elemental concentrations in the sediments compared to the more urban sites. In the lake sediments, the BILL core had higher concentrations of TP (430g/kg) and TN (16 g/kg) compared to the other site (LV-95) which is located far away from the margins of the lake. This core, however, had high TOC levels (180g/kg). The increase of nutrient levels in lake sediments is thought to be due to non-point sources from the catchment. Analyses of stable carbon isotope were used to infer the different organic matter source in the sediments. Based on the range of values for δ13C vs. C/N it is inferred that aquatic algal production and C4 vascular plants are the dominant sources for the organic matter input. The chemical characterization of catchment and lake sediments provides a qualitative link to nutrient influx and eutrophication in the lake.

Heavy metals, such as mercury (Hg), have a long residence time in the atmosphere and can be transported long distances and deposited in the Arctic via wet and dry deposition. Still, there are few studies on the complex mercury cycle and how different plant groups absorb Hg. In this study, I investigated if and/or how Hg concentrations differ between different humus soils in tundra vegetation types in Alaska and Abisko. I also investigated the potential changes in Hg deposition with increasing elevation in Abisko (500, 750, and 1000 m a.s.l). Further, a comparison between the analyzing methods XRF (X-ray fluorescence) and HF digestion was evaluated to investigate if XRF is a suitable method for analyzing heavy metals in the humus layer of soils. To achieve this, humus soil samples from four different vegetation types in Alaska and two from Abisko were analyzed with a Hg analyzer (DMA-80 Direct Mercury Analyzer) and a handheld XRF. The results show that Hg concentration was highest in heath vegetation for Alaska and Abisko. Meanwhile, increasing elevation had no impact on Hg concentration in general, nor was there a difference within the two vegetation types. The comparison between HF digestion and XRF resulted in a positive linear relationship for P, Fe, and Al. The results highlight that Hg concentration differs between humus soil due to different vegetation types, although there is no clear explanation to the distribution of Hg in aboveground vegetation. Litterfall and precipitation may influence Hg concentrations with elevation, and the XRF samples need to be replicated multiple times to avoid errors, as my study shows.

Harmful substances containing acid or neutral rock drainages (ARD and NRD) are a major challenge related to the management of extractive industry wastes. This issue is particularly related to deposits containing sulphide minerals, which are prone to oxidization under the influence of atmospheric oxygen and water. The drainage quality depends mainly on the mineralogical and chemical composition of the extractive wastes, and especially on the ratio of acid-producing and neutralizing minerals, combined with reactions catalysed by microbes. Since harmful drainages play a major role in the generation of environmental issues for extractive industry, the accurate prediction of the drainage quality is of utmost importance. To design appropriate extractive waste facilities and drainage management, the characterisation of extractive wastes and assessment of the behaviour of the waste material is essential already before the actual mining activities start. Several methods have been developed to characterize extractive waste materials and to predict their short and long term behaviour, including e.g. geochemical laboratory tests, static tests and longer term kinetic tests, and geochemical modelling. The characterisation methods for assessing the ARD risk can be divided into static and kinetic tests. Static tests are short term laboratory analyses, usually used for preliminary investigation and screening. Kinetic tests are longer term tests, revealing information on the time scale of drainage events. Commonly used static tests for ARD prediction include acid–base accounting (ABA) tests and the net acid generation (NAG) test. Since acid and neutralisation potential largely depend on the ratio and quality of acid-producing and neutralizing minerals, mineralogical calculations could also be used for ARD prediction. The mobility of potentially harmful substances from extractive waste can be preliminary assessed using different geochemical laboratory tests, including selective extraction and leaching methods. The most commonly used selective extraction method in Finland is the aqua regia (AR) extraction. In addition to some silicates and secondary precipitate minerals, it is intended to dissolve elements bound especially to sulphide phases. A less commonly used method for element mobility prediction is the analysis of the single addition NAG test leachate. In this study, several Finnish waste rock sites were investigated and the performances of different preliminary drainage quality test methods evaluated and compared. The assessed acid production potential methods included the ABA test as presented in the standard EN 15875, the single addition NAG test as presented in the AMIRA guidebook, and a SEM mineralogy-based calculation. The assessed methods for element mobility prediction included the single addition NAG test leachate analysis and the AR extraction. According to the results, pyrrhotite seems to be the main mineral contributing to acid production, and the silicate minerals the main contributors to the neutralisation potential at the most Finnish waste rock sites. Since silicate minerals appear to have a significant role in ARD prevention, the behaviour of these minerals in mining environment should be more thoroughly investigated. In the investigated Finnish waste rocks, Co, Cr, Cu and Ni often occurred as elevated concentrations, and the most widely abundant harmful elements in the waste rock drainages were Co, Cu, Ni and Zn. The results suggest that an acid production prediction based on SEM mineralogical calculation is at least as accurate as the commonly used static laboratory methods. The AR extraction indicates well which elements might occur as elevated concentrations in the drainage. Also the NAG test leachate analysis performed well in element mobility assessment, but only when the NAG test leachate was sufficiently acidic, the leachate pH being below of 3-6, depending on the element of interest.