The Glass Buttes volcanic complex is a cluster of bimodal (basalt-rhyolite), Miocene to Pleistocene age lava flows and domes located in Oregon's High Lava Plains province, a broad region of Cenozoic bimodal volcanism in south-central Oregon. The High Lava Plains is deformed by northwest-striking faults of the Brothers Fault Zone, a diffuse, ~N40°W trending zone of en echelon faults cutting ~250 km obliquely across the High Lava Plains. Individual fault segments within the Brothers Fault Zone are typically <20 km long, strike ~N40°W, have apparent normal separation with 10-100 m throw. A smaller population of ~5-10 km long faults striking ~N30°E exhibits mutually crosscutting relationships with the dominant northwest striking faults. Basaltic volcanic rocks in the Glass Buttes area erupted during the late Miocene and Pleistocene. The oldest and youngest lavas are 6.49±0.03 Ma and 1.39±0.18 Ma, respectively, based on ⁴⁰Ar/³⁹Ar ages of five basaltic units. Numerous small mafic vents both within and around the margins of the main silicic dome complex are commonly localized along northwest-striking faults of the Brothers Fault Zone. These vents erupted a diverse suite of basalt to basaltic andesite lava flows that are here differentiated into 15 stratigraphic units based on hand sample texture and mineralogy as well as major and trace element geochemistry. The structural fabric of the Glass Buttes area is dominated by small displacement, discontinuous, en echelon, northwest-striking fault scarps that result from normal to slightly oblique displacements and are commonly linked by relay ramps. Northwest alignment of basaltic and rhyolitic vents, paleotopography, and cross-cutting relationships suggest these faults have been active since at least 6.49±0.03 Ma, the age of the rhyolite lavas in the eastern Glass Buttes are. Faults displace Quaternary sedimentary deposits indicating these structures continue to be active into the Quaternary. Long-term extension rates across northwest-striking faults calculated from 2-5 km long cross section restorations range from 0.004 – 0.02 mm/yr with an average of 0.12 mm/yr. A subordinate population of discontinuous northeast-striking faults form scarps and exhibit mutually cross-cutting relationships with the dominant northwest-striking population. Cross-cutting relationships indicate faulting on northeast-striking faults ceased sometime between 4.70±0.27 Ma and 1.39±0.18 Ma. Gravity data at Glass Buttes reveals prominent northwest- and northeast-trending gravity gradients that closely parallel the strikes of surface faults. These are interpreted as large, deep-seated, normal faults that express themselves in the young basalts at the surface as the discontinuous, en echelon fault segments seen throughout the study area and BFZ in general. Elevated geothermal gradients are localized along these deep-seated structures at two locations: (1) where northwest- and northeast-striking faults intersect,(2) along a very prominent northwest-striking active normal fault bounding the southwest flank of Glass Butte. High average heat flow and elevated average geothermal gradients across the High Lava Plains, and the presence of hydrothermal alteration motivated geothermal resource exploration at Glass Buttes. Temperature gradient drilling by Phillips Petroleum and others between 1977-1981 to depths of up to 600 m defined a local geothermal anomaly underlying the Glass Buttes volcanic complex with a maximum gradient of 224 °C/km. Stratigraphic constraints indicate that near-surface hydrothermal alteration associated with mercury ores ceased before 4.70±0.27 Ma, and is likely associated with the 6.49±0.03 Ma rhyolite eruptions in the eastern part of Glass Buttes. The modern thermal anomaly is not directly related to the pre-4.70±0.27 Ma hydrothermal system; rather it is likely a result of deep fluid circulation along major extensional faults in the area. / Graduation date: 2013 / Includes accompanying DVD with digital data supplement (8 GB).

Plastic flow in bulk metallic glasses (BMGs) localizes into narrow bands, which, in the absence of a microstructure that could obstruct them, propagate unhindered under tensile loading. In constrained deformation conditions such as indentation and at notch roots, extensive shear band formation can occur. A key issue in the context of fracture of BMGs that is yet to be understood comprehensively is how their toughness is controlled by various state parameters. Towards this end, the change in fracture toughness and plasticity with short term annealing above and below the glass transition temperature, Tg, is studied in a Zr-based BMG. Elastic properties like shear modulus, Poisson's ratio as well as parameters defining the internal state like the fictive temperature, Tf, density, and free volume are measured and correlation with the toughness was attempted at. While the elastic properties may help in distinguishing between tough and brittle glasses, they fail to reveal the reasons behind the toughness variations. Spherical-tip nanoindentation and microindentation tests were employed to probe the size, distributions and activation energies of the microscopic plastic carriers with the former and shear band densities with the latter. Results indicate that specimens annealed at a higher temperature, Ta, exhibit profuse shear banding with negligible changes in the local yield strengths. Statistical analysis of the nanoindentation data by incorporating the nucleation rate theory and the results of the cooperative shear model (CSM), reveals that short term annealing doesn't alter the shear transformation zone (STZ) size much. However, density estimates indicate changes in the free volume content across specimens. A model combining STZ activation and free volume accumulation predicts a higher rate in the reduction of the cumulative STZ activation barrier in specimens with a higher initial free volume content. Of the macroscopic physical properties, the specimen density is revealed to be a useful qualitative measure of enhancement in fracture toughness and plasticity in BMGs. We turn our attention next to the brittle fracture in BMGs, with the specific objective of understanding the mechanisms of failure. For this purpose, mode I fracture experiments were conducted on embrittled BMG samples and the fracture surface features were analyzed in detail. Wallner lines, which result from the interaction between the propagating crack front and shear waves emanating from a secondary source, were observed on the fracture surface and geometric analysis of them indicates that the maximum crack velocity to be ~800 m/s, which corresponds to ~0.32 times the shear wave speed. Fractography reveals that the sharp crack nucleation at the notch tip occurs at the mid-section of the specimens with the observation of flat and half-penny shaped cracks. On this basis, we conclude that the crack initiation in brittle BMGs occurs through hydrostatic stress assisted cavity nucleation ahead of the notch tip. High magnification scanning electron and atomic force microscopies of the dynamic crack growth regions reveal highly organized, nanoscale periodic patterns with a spacing of ~79 nm. Juxtaposition of the crack velocity with this spacing suggests that that the crack takes ~10-10 s for peak-to-peak propagation. This, and the estimated adiabatic temperature rise ahead of the propagating crack tip that suggests local softening, are utilized to critically discuss possible causes for the nanocorrugation formation. The Taylor’s fluid meniscus instability is unequivocally ruled out. Then, two other possible mechanisms, viz. (a) crack tip blunting and resharpening through nanovoid nucleation and growth ahead of the crack tip and eventual coalescence, and (b) dynamic oscillation of the crack in a thin slab of softened zone ahead of the crack-tip, are critically discussed. One way of alleviating the fracture-related issues in BMGs is to impart a microstructure to it, which would either impede the growth of shear bands or promote the multiplication of them. One such approach is through the BMG composites (BMGCs) route, wherein a crystalline second phase incorporated in the BMG matrix. There is a need to study the effects of reinforcement content, size and distribution on the mechanical behavior of the BMGC so as to achieve an optimum combination of strength and ductility. For this purpose, an investigation into the microstructure and tensile properties of Zr/Ti-based BMG composites of the same composition, but produced by different routes, was conducted so as to identify “structure–property” connections in these materials. This was accomplished by employing four different processing methods—arc melting, suction casting, semi-solid forging and induction melting on a water-cooled copper boat—on composites with two different dendrite volume fractions, Vd. The change in processing parameters only affects microstructural length scales such as the interdendritic spacing, λ, and dendrite size, δ, whereas compositions of the matrix and dendrite are unaffected. Broadly, the composite’s properties are insensitive to the microstructural length scales when Vd is high (∼75%), whereas they become process dependent for relatively lower Vd (∼55%). Larger δ in arc-melted and forged specimens result in higher ductility (7–9%) and lower hardening rates, whereas smaller dendrites increase the hardening rate. A bimodal distribution of dendrites offers excellent ductility at a marginal cost of yield strength. Finer λ result in marked improvements in both ductility and yield strength, due to the confinement of shear band nucleation sites in smaller volumes of the glassy phase. Forging in the semi-solid state imparts such a microstructure.

The goal of the thesis was to make available a reference for the beginning appreciation of stained glass windows. It was designed for the person who has no prior experience in stained glass, and therefore the information is kept general and non-technical. A short history of stained glass is contained within the first section, and the second section is a self-guided tour of stained glass in West Portland. The historical information was pieced together from the library resources of Portland State University. The subject itself is difficult, as extensive reference material and primary sources are simply not available. The second section was designed specifically for the Portland resident. Seven churches and a synagogue were selected within walking distance of one another. A map is included, and the reader is urged to take this self-guided tour. The data was gathered from church records, newspaper articles, the Oregon Historical Society, professional glass craftsmen and signatures on the windows. After extensive research, it is discouraging to note that almost no information on Portland stained glass is available. This is attributed in part to the attitude of many of the relative unimportance of stained glass, and the habit of church records and newspaper accounts to limit their reports to personalities rather than facts. Since the basic theme of the thesis deals with a visual art, it was necessary to relate as much visual information as possible. Twenty-five photographs were chosen from reference books, the British Museum, the Oregon Historical Society and private collections. Calligraphy, maps and drawings are also included. The thesis is limited in scope and written primarily for Portland residents and visitors. It is an introduction which presents no conclusions. It is a beginning reference for those who have just begun to take notice of stained glass.

Title from PDF of title page. / Document formatted into pages; contains 72 pages. / Thesis (M.A.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: Archaeological investigations of Indian Key Historic State Park in the Florida Keys have uncovered a wide range of historical artifacts from throughout the nineteenth century that reveal how the site was reused and reoccupied through time. This thesis focuses on the glass component recovered from a house cistern complex (Feature F) and a warehouse (Features A and C) during the 1998 to 2002 field seasons. Glass artifacts range from a variety of bottle glass including alcohol bottles and proprietary medicines, to cut glass such as tumblers and decanters, to window glass. Feature F's analysis has shown that it maintained a primarily domestic nature despite having been reused by different groups at different times. Glass recovered from Feature F was primarily alcohol bottles, but large numbers of food bottles, medicines, and window glass was also found. The warehouse was used commercially and appears to have been continuously reused. / ABSTRACT: The most abundant item recovered from the warehouse was window glass; however large quantities of alcohol bottle fragments were also recovered. Also included in the glass analysis is a study of window glass dating techniques using glass thickness. By using a formula originally developed by Randall Moir (1982), and following an example set by Grant L. Day (2001), I was able to illustrate a process for dating nineteenth century window glass that is fairly accurate for determining periods of transition, addition, and reconstruction to buildings occupied over long time periods. Comparison of the glass from these two features using window glass dating formulas and other comparative evaluations as well as dating and functional analysis is revealing useful information about each of these structures individually, as well as about activity on the island as a whole. / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.

Microbeam radiation therapy (MRT) is an experimental form of radiation treatment which causes less damage to normal tissue in comparison with customary broad-beam radiation treatment. In this method the synchrotron generated X-ray beam is passed through a multislit collimator and applied to the tumor in the form of an array of planar microbeams. MRT dosimetry is an extremely challenging task and no current detector can provide the required wide dynamic rang and high spatial resolution. In this thesis, fluorophosphate (FP) and fluoroaluminate (FA) glass plates doped with trivalent samarium (Sm3+) are characterized towards developing a potential X-ray detector suitable for MRT dosimetry. The detection is based on the difference in the photoluminescence signatures of Sm3+ ions and Sm2+ ions; the latter are formed under X-ray irradiation. This valency conversion is accompanied by the formation of defects including hole centers (HCs) and electron centers (ECs) in the glass structure which absorb light in the UV and visible regions (induced absorbance). Both FP and FA glasses show promising dynamic range for MRT and may be used as a linear sensor up to ~150 Gy and as a nonlinear sensor up to ∼2400 Gy, where saturation is reached. X-ray induced defects saturate at the same dose. The optimum doping concentration is in the 0.001˗ 0.2 at.% range. Doping with higher concentrations will decrease the conversion efficiency. The glass plates also show a very promising spatial resolution (as high as a few microns) for recording the dose profile of microbeams which is readout using a confocal fluorescence microscopy technique. These plates are restorable as well and the response is reproducible. The effects of previous X-ray exposure including samarium valency conversion as well as induced absorbance may be erased by annealing at temperatures exceeding the glass transition temperature Tg while annealing at TA < Tg enhances the response. This enhancement is explained by a thermally stimulated relaxation of host glass ionic matrix surrounding X-ray induced Sm2+ ions. Optical erasure is another practical means to erase the recorded data. Nearly complete Sm2+ to Sm3+ reconversion (erasure) is achieved by intense optical illumination at 405 nm. While, existing X-ray induced bands would be only partially erased. Electron spin resonance (ESR) and optical absorbance spectroscopy are used to investigate the nature of X-ray induced defects and their correlation with Sm valency conversion. A model based on competition between defect center formation and the Sm3+ ⇆ Sm2+ conversion successfully explains the different processes occurring in the glass matrix under X-ray irradiation.

Woven glass composites have been used for many years in commercial applications due to their light weight, competitive price and good engineering properties. Absorption of energy by laminated composite material results in damage in various forms, the most common of which is delamination. Inter-laminar fracture causes the layers of composite to separate, resulting in a reduction in stiffness and strength of the composite structure, matrix cracking and in some cases fibre breakage takes place. The aim of this project was to improve the inter-laminar bond strength between woven glass fabric and resin. Air jet texturing was selected to provide a small amount of bulk to the glass yarn. The purpose was to provide more surface contact between the fibres and resin and also to increase the adhesion between the neighbouring layers. These were expected to enhance the resistance to delamination in the woven glass composites.Glass yarns were textured by a Stähle air jet texturing machine. Core-and-effect yarn was produced instead of a simple air textured yarn. Hand loom and vacuum bagging techniques were used for making the fabric and composite panels from both textured and non-textured yarns. Density and fibre volume content were established for physical characterisation. Breaking strength (tenacity) of the yarns and tensile, flexure, inter-laminar shear strength (ILSS) and fracture toughness (mode 1) properties of the composites were determined. Projection microscopy and SEM imaging techniques were used to assess the fractured surfaces of the composite specimens. The yarn tenacity and the tensile properties of the composites were significantly reduced after the texturing process, whereas flexure properties were unchanged. However, significant improvement was observed in the ILSS and fracture toughness of the composites after the texturing process. It was also observed that the composites made from the fabrics with textured yarns in only the weft direction are the most advantageous as they maintained the tensile and flexure properties but have significantly higher inter-laminar shear strength.

Glass Buttes complex lies at the northern margin of the Basin and Range province in central Oregon and is cut by the northwest-trending Brothers fault zone. An older acrystalline volcanic sequence of high-silica rhyolites (>75% SiO2) forms a broad platform composed of domes and flows with minor pyroclastic deposits. The high-silica rhyolite sequence is divided on the basis of texture into 1) zoned flows and domes, 2) obsidian flows, 3) felsite flows, and 4) biotite-phyric flows and domes.

In the theoretical part of diploma thesis basic knowledge about glass are given (materials, production process, a brief overview of glass products for construction industry) and statistics of waste production, primarily with an emphasis on various types of waste glasses were also mentioned. The following chapters of the thesis are focused on waste glass processing technologies. Various studies about the application of waste or recycled glass in manufacturing of building materials are summarized. In the practical part of diploma thesis were suggested appropriate secondary raw materials that were used to prepare materials based on thermally modified glass foam. In the practical part of the thesis was carried out a set of experiments and analysis, including evaluation in terms of the proposed alternative fillers and materials made of them.

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