Carbochlorination, a solvent-free top-down process, is a novel pathway for the hierarchization of zeolites. In contrast to other methods no further washing steps are required. The employed method should serve as a model system for the “upcycling” of coked and deactivated zeolites accumulated by the industry. In order to establish a basic understanding of the process, zeolite H-Y was taken as a model system and a thorough investigation of important reaction parameters, like chlorination temperature, time and concentration, carbon loading, and Si/Al ratio, was performed. Under optimized conditions, we have been able to hierarchize H-Y with high yield, doubling the mesopore volume while maintaining the crystallinity and surface area.

The aim of this thesis is to describe some central conceptual ideas expressed in the language of six computer interested boys. The starting-point is the philosophy of language of Ludwig Wittgenstein, where language is seen as something deeply integrated in our practices, traditions and culture. The use of our language shows its meaning. The material consists of 18 months of observations in the computer room of a secondary school and a series of three deep-interviews with each one of the boys over a period of three years. The computer has a central function in their identity work. Within our culture, this object - with its structure and its ways of operating - has become a metaphor for human thinking. It offers freedom and control. The discussions involved in this work and its form of representation problemize some of the fundamental assumptions of linguistics and the humanities. The three portraits (chapters 3-5) are to be understood as meaningful examples, while the persons portrayed are to be seen as symbols, inviting the reader to reflect over our culture and our practices. The fostering into the computer world and the ways of looking at the world are shown through the "personal voice", each followed by an interpretation linked to the theories and results of other researchers. In the boys' ways of using language there are differences and similarities. Learning, growing, creating, signifying 'freedom', can be seen as central notions in the identity work of one of them. With another of the boys there is a strong resemblance in his talking of computers and of his personal God; he "fixes" the world through dividing-lines, strong recommendations, further emphasized through the frequent use of the verb ska (shall, should). In the third portrait it is evident that the boy's abundance of words and narrative-making is a strategy of preventing nearness and to be able both to control the interview situation and to intensify the here and now. "Going deep" into computers make certain assumptions about the world more essential than others. Central concepts explicit in their common language game are logic, power and control (chapter 7). There is a common tendency to hierarchize and dichotomize the world; upper/under world, outer/inner world, logic/feeling, we/they, right/wrong. Stability can be seen as a summarizing notion. The deeper significance of their feeling of safety and control in the computer world is a fostering both into male dominance and into a dominant way of thinking about knowledge as something primarily logical, controllable and possible to account for. This masculinist language game is confirmed in different ways: individually, in the group and at a more subtle and symbolic level. / <p>Diss. Umeå : Univ., 1992</p> / digitalisering@umu

Mélanger un oxyde de gallium avec une zéolithe H-ZSM-5 donne les mêmes résultats catalytiques en craquage du n-hexane, déshydrogénation du cyclohexane et en aromatisation du propane qu'un catalyseur préparer par échange cationique avec un sel de gallium. En fait, le véritable catalyseur est synthétisé lors du prétraitement sous hydrogène pendant lequel le suboxyde de gallium (Ga2O) issu de la réduction de Ga2O3 réagit avec les sites de Brønsted de la zéolithe pour donner des hydrures de gallium. La réaction de déshydrogénation des alcanes fait intervenir un site catalytique bifonctionnel composé d'un site de Lewis du Ga et d'un site basique généré par l'oxygène de la charpente zéolithique. L'activation du propane se produit sur un hydrure de gallium via un mécanisme de type alkyle. Les aluminosilicates dopés avec Ga sont plus performants que les gallosilicates, ce qui signifie que les espèces de gallium sont plus actives en extra-réseau que dans le réseau de la zéolithe.Le coke généré lors de l'aromatisation du propane est très polyaromatique avec plus de quinze noyaux benzéniques, localisé dans les micropores il s'avère très toxique. La création de mésopores intracristallins sans modifier les propriétés acides de la zéolithe (nombre et force des sites acides) est possible par un traitement alcalin. Leur présence permet de limiter les réactions de transfert d'hydrogène mais est peu efficace pour contrôler la croissance du coke, les mésopores sont mêmes négatifs pour la réaction de déshydrogénation rendant les catalyseurs bifonctionnels hiérarchisés inefficaces en aromatisation du propane ; l'étape cinétiquement limitante pour cette réaction étant la déshydrogénation. / The mixing Ga2O3 with the H-ZSM-5 zeolite yields to the same catalytic performance in n-hexane cracking, cyclohexane dehydrogenation and propane aromatization than a bifunctional catalyst prepared by cationic exchange. The real catalyst appears upon hydrogen pretreatment in which gallium (Ga2O) suboxide that results from Ga2O3 reduction, reacts with the zeolite Brønsted sites to yield to gallium hydrides.The dehydrogenation reaction of alkanes involves a bifunctional catalytic site constituted of a Lewis site (Ga species) and basic site (an oxygen of the zeolite framework). The aluminosilicate catalysts loaded with Ga are more efficient than the gallosilicate catalysts, therefore extraframework gallium species is more active than the framework gallium species.The coke formed during the propane aromatization is very polyaromatic with more than fifteen benzenic rings, is very toxic. The creation of intracrystalline mesopores by alkaline treatment.preserves the acidic properties of the zeolite (number and strength of acidic sites). The mesopores allow limiting the hydrogen transfer reactions but is not very effective for impeding the growth of the coke, the presence of mesopores are even negative for the dehydrogenation reaction making inefficient the hierarchical bifunctional catalysts in propane aromatization; the kinetically limiting step for this reaction being dehydrogenation.

Carbochlorination, a solvent-free top-down process, is a novel pathway for the hierarchization of zeolites. In contrast to other methods no further washing steps are required. The employed method should serve as a model system for the “upcycling” of coked and deactivated zeolites accumulated by the industry. In order to establish a basic understanding of the process, zeolite H-Y was taken as a model system and a thorough investigation of important reaction parameters, like chlorination temperature, time and concentration, carbon loading, and Si/Al ratio, was performed. Under optimized conditions, we have been able to hierarchize H-Y with high yield, doubling the mesopore volume while maintaining the crystallinity and surface area.

Les travaux effectués durant cette thèse portent sur l’appariement de formes planes basé sur une squelettisation hiérarchique. Dans un premier temps, nous avons abordé la création d’un squelette de forme grâce à un algorithme associant des outils de la géométrie discrète et des filtres. Cette association permet d’acquérir un squelette regroupant les propriétés désirées dans le cadre de l’appariement. Néanmoins, le squelette obtenu reste une représentation de la forme ne différenciant pas les branches représentant l’allure générale de celles représentant un détail de la forme. Or, lors de l’appariement, il semble plus intéressant d’associer des branches ayant le même ordre d’importance, mais aussi de donner plus de poids aux associations décrivant un aspect global des formes. Notre deuxième contribution porte sur la résolution de ce problème. Elle concerne donc la hiérarchisation des branches du squelette, précédemment créé, en leur attribuant une pondération reflétant leur importance dans la forme. À cet effet, nous lissons progressivement une forme et étudions la persistance des branches pour leur attribuer un poids. L’ultime étape consiste donc à apparier les formes grâce à leur squelette hiérarchique modélisé par un hypergraphe. En d’autres termes, nous associons les branches deux à deux pour déterminer une mesure de dissimilarité entre deux formes. Pour ce faire, nous prenons en compte la géométrie des formes, la position relative des différentes parties des formes ainsi que de leur importance. / The works performed during this thesis focuses on the matching of planar shapes based on a hierarchical skeletonisation. First, we approached the creation of a shape skeleton using an algorithm combining the tools of discrete geometry and filters. This combination allows to acquire a skeleton gathering the desired properties in the context of matching. Nevertheless, the resulting skeleton remains a representation of the shape, which does not differentiate branches representing the general shape of those coming from a detail of the shape. But when matching, it seems more interesting to pair branches of the same order of importance, but also to give more weight to associations describing an overall appearance of shapes. Our second contribution focuses on solving this problem. It concerns the prioritization of skeletal branches, previously created by assigning a weight reflecting their importance in shape. To this end, we gradually smooth a shape and study the persistence of branches to assign a weight. The final step is to match the shapes with their hierarchical skeleton modeled as a hypergraph. In other words, we associate the branches two by two to determine a dissimilarity measure between two shapes. To do this, we take into account the geometry of the shapes, the relative position of different parts of the shapes and their importance.

Deux zéolithes nanocristaux de type *BEA et CP814E commerciales avec de différentes propriétés texturales, et une zéolithe microcristaux de type *BEA qui a été synthétisée durant cette thèse, ont été modifiées par une desilication en utilisant de différents traitements alcalins. Toutes les zéolithes parentes et certaines désilicées ont été sélectionnée pour le craquage du n-hexane, où aucune amélioration significative de la conversion n'a été observée après la désilication. Toutes les zéolithes parentes et quelques désilicées sélectionnées ont été transformés en leur forme bifonctionnelle par imprégnation du platine pour d'étudier l'impact de la désilication dans l'hydroisomérization de n-C10. On a constaté que l'amélioration des propriétés texturales par la désilication n'était pas toujours la cause d'une augmentation ou d'une diminution de l'activité et de la sélectivité du catalyseur, mais plutôt de la localisation des particules de Pt et leur distance prédite des sites acides. Cependant, la présence des mésopores inter- et intracristallins, en plus de la distance de Pt-H+, sont des importants caractéristiques qui affectent l'activité et la sélectivité. Nous avons également étudié l'impact de la longueur de chaîne dans l'hydroisomérization de n-C12 et de n-C14. Un phénomène spécial dans le cas de n-C12 est apparu, où le rendement d'isomérisation semblait inférieur à celui obtenu sur n-C10 et n-C14, ce qui suggère que cela résulte de l'effet de confinement. La série microcristaux a montré une amélioration de l'activité dans la transformation n-C14, mais une diminution de la sélectivité des isomères à cause des limites de diffusion potentielles. / Two commercial nanocrystal *BEA zeolites with different textural properties and a microcrystal synthesized *BEA zeolite, were desilicated using different alkaline treatment; classical in presence of Noah alone, or incorporated with a pore directing agent. All parent zeolites and some selected desilicated samples were chosen for catalytic cracking of n-hexane, where no significant improvement of n-hexane conversion was observed after desilication. To investigate the impact of desilication on the hyrdoisomerization of n-C10, all parent and the some selected desilicated zeolites were transformed into their bifunctional form by platinum loading. The improvement of the textural properties by desilication using the different pore directing agents, was not always the cause behind an increase or decrease in the activity and selectivity of the catalyst, but rather was more the location of the Pt particles and their predicted distance from the acidic sites. However, the synergetic effect of both the textural and bifunctional characteristics was positive. Tests on hydroisomerization of n-C12 and n-C14 to investigate the impact of chain length were done. In the nanocrystal series, a special phenomenon on n-C12 appeared where the isomerization yield seemed to be less than that obtained on n-C10 and n-C14, suggesting that this would be due the confinement effect, which was shown to be more effective in case of n-C12. The microcrystal series showed an improvement of the activity over all the catalysts in case of n-C14 transformation, but a decrease in isomers selectivity as observed due to probable diffusional limitations within the channels of these series catalysts.

The diploma thesis deals with the analysis of the transport-geographical attributes of the South Bohemian Region. Basically, the thesis considers two important characteristics of the settlement structure-transport relationship. These are transport regionalization and hierarchization of the transport centres. Besides the viewpoint of the public transport the diploma thesis also deals with the individual automobile transport. The first chapters describe goals of the thesis and analyse relevant literature. These are followed by detailed methodological part containing the description of the choice of the settlement centres, delimitation of the transport regions and the analysis of hierarchy of the transport nodes. The further chapters analyse the real condition of the South Bohemian Region itself from the points of view of the attributes mentioned above.

The subject of this thesis is the question of immigration in contemporary (Western) European societies which is treated by detailed exposition of the concrete historical case of immigration from the Maghreb countries (Algeria, Morocco, Tunisia) to France during the 20th century. The first part of the work consists of the brief history of immigration to France and of the wider theoretical context for the sociological inquiry of the phenomena linked with immigration, especially the paradoxical situation which results from the fact of immigration in the nation states and the logic of the formation of the interethnic relations. As a theoretical support for following analysis, several theories are presented: Goffman's theory of stigmatization, Becker's labelling theory, theory of the social representations of Moscovici and Merton's concept of self-fullfilling prophecy. In the second part, the particular case of immigration from Maghreb countries to France is examined with the special attention to the social representations made in French society in the context of this historical process. The main subject of this work is the situation of the descendants of immigrants from Maghreb countries in the French society, especially their position in its social structure - the third part therefore consists of the analysis...