Estudos relacionados ao consumo de recursos e à emissão de resíduos na escala territorial local se originaram nas pioneiras pesquisas associadas ao conceito de metabolismo urbano. Nos últimos 15 anos, observa-se um crescimento do número de estudos aplicados a cidades, municípios ou regiões metropolitanas. A Análise dos Fluxos de Materiais - AFM (Material Flow Analysis) vem se consolidando como a abordagem metodológica predominante para esse tipo de investigação, a qual objetiva prover informações sobre fluxos de materiais e de energia, usualmente em unidades de massa, entrando e deixando uma sociedade. No entanto, todos os casos estudados na literatura prévia correspondem a capitais nacionais ou a municípios com centralidade econômica e de gestão do território na região as quais pertencem. Adicionalmente, não há estudos desenvolvidos no Brasil. Em face dessas lacunas, o objetivo principal deste trabalho é a caracterização dos fluxos de materiais associados ao metabolismo de um município brasileiro de pequeno porte (MBPP). Para tanto se adotou como estudo de caso o município de Feliz-RS. Como objetivos intermediários da pesquisa estabeleceram-se: a) Identificação dos métodos existentes para caracterização de fluxos de materiais na escala local e análise das possibilidades de aplicação no contexto dos MBPP; b) Desenvolvimento de um detalhamento metodológico da AFM, para a caracterização dos fluxos de materiais de MBPP; c) Análise das limitações e oportunidades para uso da AFM, na avaliação de sustentabilidade ambiental de municípios. Como resultados, avalia-se que o detalhamento metodológico desenvolvido é funcional e replicável para municípios brasileiros com o mesmo perfil, além de fornecer informações bastante detalhadas acerca dos fluxos ocorrentes no município adotado como caso. Assim, é possível realizar análises com diferentes níveis de desagregação. Quanto aos fluxos de materiais de Feliz, encontrou-se que o consumo doméstico de materiais per capita (DMC/ per capita) do município é alto, se comparado àqueles já caracterizados na literatura. Essa constatação corrobora com a proposição de que municípios com produção primária e secundária tendem a demandar, proporcionalmente, mais recursos do que aqueles que são consumidores finais. Quanto ao uso da AFM, na avaliação de sustentabilidade ambiental, verifica-se um alto potencial, com vantagens, em relação a outros métodos correntemente adotados. Entretanto, essas oportunidades ainda são pouco exploradas no contexto internacional e ignoradas no Brasil, ao se analisar a literatura existente. / Studies related to resources consumption and wastes emissions in a local territorial scale were originated from pioneering researches related to the urban metabolism concept. Over the past 15 years, there was a growth in the number of such studies applied to cities, municipalities and metropolitan areas. At the same time, Material Flow Analysis - MFA was consolidated as the predominant methodological approach for this type of research. However, it must be pointed out that all studied cases have been related to national capitals or counties, with economics centrality and land management in their own area. Besides, no studies of this nature were found as being developed in Brazil. Thus, the main goal of the research presented in this paper was to characterize material flows associated with the metabolism of a small Brazilian municipality and for this purpose the municipality of Feliz was adopted as a case study. Three intermediate objectives were established: a) To identify existing methods for material flows characterization on the local scale and to analyse the possibilities of applying them in the context of small Brazilian municipalities; b) to develop a MFA methodological detailing for the characterization of material flows of small Brazilian municipalities; c) to analyse constraints and opportunities for the use of MFA in the assessment of municipalities environmental sustainability. As results, it is considered that the methodological detailing developed raises the possibility of replicating the procedures applied in Feliz to other Brazilian municipalities, being this research a first and referential step in this direction. Besides, it provides very detailed information on flows occurring in the municipality adopted as the case study. Thus, it is possible ti further develop of analyses considering different levels of disaggregation. Concerning the material flows associated with the metabolism of Feliz, it was found that the studied municipality presents a DMC per capita comparable or superior to that of larger municipalities already analyzed by previous researches. This finding corroborates the hypothesis that municipalities with primary and secondary production tend to demand proportionately more resources than those who are the final consumers. Regarding the use of the MFA in the assessment of municipalities environmental sustainability, it was verified that it presents a high potential, with advantages over other methods currently adopted. However, when analyzing the existing literature it was noticed that these opportunities are still little explored in the international context and ignored in Brazil.

Les réserves de pétrole sont sur le déclin, les prix des ressources fossiles fluctuent et le CO 2 dégagé par leur consommation contribue inéluctablement au réchauffement climatique. Ce phénomène, conduit notre société vers l'utilisation accrue de biomasse pour la génération d'énergie, de composés chimiques et de matériaux. La réduction des déchets est considérée comme indissociable de cette transition énergétique et en opposition aux préjugés, l’accroissement des déchets organiques peut être bénéfique dans cette recherche de solutions alternatives. En effet, cela conduit à la génération de grandes quantités de matières qui peuvent représenter de potentielles ressources. De plus, changer le statut des déchets en coproduits pour la production de bioénergies n’entre pas en concurrence avec les filières alimentaires et cela constitue un des principaux enjeux des biotechnologies. Sous certaines conditions, les bioconversions anaérobies représentent des procédés d’ingénierie prometteurs pour accomplir le double enjeu de la valorisation des coproduits et de la production de molécules d’intérêt énergétique et chimique (biocarburants, chimie verte...). En revanche, l’innovation dans les biotechnologies blanches est nécessaire pour la production robuste, performante, rentable et environnementalement acceptable de biomolécules à partir de ressources renouvelables. Dans ce contexte, la société AFYREN a été pensée et créée pour répondre à ce défi mondial via sa technologie « tout en un », AFYNERIE, qui s’inspire de la nature et des sciences. L’objectif premier de ce travail de thèse, cœur du procédé AFYNERIE, était d’étudier les performances de microorganismes anaérobies, sous forme de souches pures ou de consortia pour la valorisation de substrats plus ou moins complexes via un processus de méthanogenèse avortée. Pour cela, il était nécessaire de considérer, déjà à l’échelle du laboratoire, une projection dans le monde industriel. Nous avons alors démontré les capacités de la diversité microbienne à produire des molécules plateformes à partir de coproduits agro-industriels réels en mode stérile puis non stérile. Cette étude s’est appuyée en parallèle sur la caractérisation et la dynamique des populations microbiennes mises en jeu. Ensuite, l’accumulation des métabolites, à la fois inhibiteurs et d’intérêt, dans les milieux fermentaires en mode discontinu et avec des rendements compétitifs, a débouché sur la nécessité de surpasser ces limitations par le passage à un mode continu. Pour ce faire, un procédé d’extraction biocompatible des synthons issus de l’opération de fermentation a été mise en œuvre selon différents mode de réalisations. Ce couplage des opérations unitaires, sous forme de fermentation extractive, a livré des résultats prometteurs tout en étant bâtit dans un cadre de bioraffinerie et d’écologie industrielle qui tend vers le « zéro déchet ». Enfin, à l’inverse des autres technologies émergentes, pour se placer dans une approche de drop-in, la biologie et la chimie ont été associées. Le but a été d’illustrer la multipotence des acides gras volatils (AGVs) en termes d’applications industrielles et de réaliser la preuve de concept de la transformation de la biomasse non alimentaire en biomolécules d’intérêt énergétique et chimique. Ces travaux ont permis de soulever les points clés du changement d’échelle du procédé AFYNERIE et d’entrevoir des perspectives tant fondamentales qu’appliquées. Cette brique technologique, de par sa philosophie multi-intrants/multi-produits, couplant fermentation-extraction-synthèse, permet d’initier la transition au stade pilote d’un procédé innovant compatible avec une future économie biosourcée. / Fossil oil reserves are decreasing, oil prices are fluctuating, and the CO 2 released by oil consumption contributes to global warming. These are driving our society towards increased use of biomass for energy, chemical compounds and other materials. Minimizing waste has been seen as a concern associated with alternative energy efforts. Contrary to expectation, increasing organic waste can be beneficial for alternative energy efforts, because it would result in large amounts of organic resources that can be potential raw materials. Moreover, using waste as a resource for bioenergy production does not compete with human or animal food or agricultural surfaces, and that is one of the greatest challenges facing biotechnology. Using waste as a resource for biomolecule production would thus be an interesting approach to reducing waste in the environment and producing renewable materials. Under specific conditions, detrital biomass can be converted into biomolecules of interest by microorganisms. Anaerobic fermentation techniques represent promising engineering processes for accomplishing the dual goals of waste reduction and renewable biomolecule production for biofuel and green chemistry markets. On the other hand, innovative fermentation processes are necessary for the strong, successful, cost-effective and eco-friendly production of bulk chemicals from renewable resources. In this context, AFYREN company was thought and founded to answer this world challenge through its “all in one” technology, AFYNERIE, which is inspired from the nature and sciences. The first objective of this thesis, heart of the AFYNERIE process, was to study the performances of anaerobic microorganisms, in the form of pure strains or of consortia for the valorization of more or less complex substrata via a process of failed methanogenesis. For that purpose, it was necessary to consider, already at the laboratory scale, a projection in the industrial world. Then, we demonstrated the capacities of the microbial diversity to produce platform molecules from real agro-industrial by-products in sterile and then non sterile mode. This study leaned in parallel on the characterization and the dynamics of involved microbial populations. Then, the accumulation of metabolites, which are at the same time inhibitory and of interest, in fermentative media in batch mode and with competitive yields, resulted in the necessity of surpassing these limitations by the passage in a continuous mode. To do this, a process consisted of a biocompatible extraction of synthons stemming from the operation of fermentation was implemented according to different mode of realizations. This coupling of single operations, in the form of extractive fermentation, delivered promising results while builds in a frame of biorefinery and industrial ecology which tightens towards a “zero waste”. Finally, contrary to the other emergent technologies, to take place in a drop-in approach, biology and chemistry were associated. The purpose was to illustrate the versatility of volatile fatty acids (VFAs) in terms of industrial applications and to realize the proof of concept of the transformation of the non-food biomass in biomolecules of energy and chemical interest. These works allowed to underline key points of the scale-up of AFYNERIE process and to glimpse perspectives fundamental as well as applied perspectives. This technological brick, due to its multi-inputs / multi-products philosophy, coupling fermentation-extraction-synthesis, allows to introduce the transition to the pilot stage of an innovative process compatible with a future biobased economy.

<p>Design of products permits to yield goods and services to produce satisfaction on customers, which is measured as value. However, it is at this stage in which most of the environmental impact, from a lifecycle perspective, is added to the product. Eco-design aims at increasing value of products while reducing the burdens on the environment by means conscious design towards efficient use of resources. That efficiency, referred to as eco-efficiency, can be increased in a number of manners within environmental engineering. Traditionally, different fields have tackled materials, energy flows and products from different angles or approaches. In this thesis we describe Functional Sales (FS) and Industrial Ecology (IE) as examples of these. Within this latter, we put emphasis on Industrial Symbiosis (IS) and Eco-effectiveness. We consider these approaches are suitable to work in the framework of eco-design to increase ecoefficiency. By adding services to material products, and managing material and energy flows with a more ecological consciousness, we expect to increase value of products while reducing the impact on the environment.</p><p>To analyse this potential improvement, we developed a method involving a new eco-efficiency index (VERI), that recursively intends to ease decisions on possible eco-efficient alternatives. This index and its method are applied to a case study on management of olive oil supply in region of Murcia, Spain. Here, we propose three scenarios that will involve the implementation of FS and IE to compare the outcomes in value and environmental performance against an idealised current supply chain. The results obtained, although not accurate, suggest that FS and EI should be more taken into account in eco-design and, this latter, to also consider holistic viewpoints to find more eco-efficient alternatives for a product development.</p>

<p>The Norwegian system for depositing and recycling of PET bottles (Resirk/PET system)started in May 2000, and is based on Norsk Resirk's mission of improving cost- and environmental efficiency of this system. Has this been achieved? What can explain the changes that occurred in the system during recent years? I have found that the eco-efficiency of the Resirk/PET system increased considerably every year between 2000 and 2003. The net greenhouse gas (GHG emission was improved from -562 kg CO2e (562 kg CO2 equivalents avoided generated) for waste management of one tonne consumed bottles in 2000 to -1442 kg CO2e per tonne in 2003, while the net cost was reduced from 4062 €/tonne in 2000 to 2683 €/tonne in 2003. This eco-efficiency improvement was very much driven by the increased volume and return rate of PET bottles during this period. The environmental performance of the Resirk/PET system was high compared to other waste management systems for PET bottles, while the economical performance was considerably lower. The interactive development of the bottled non-carbonated mineral water Imsdal contributed significantly to the increase of the Resirk/PET system’s volume and return rate and hence the system’s improved eco-efficiency. A white spirit sabotage on Imsdal in August 2002 contributed to the development of Imsdal as well as the Resirk/PET system’s change of the design and material specification for participating PET bottles. By combining the quantitative eco efficiency framework with the qualitative framework of interactive resourced development, information about how much eco-efficiency of a defined system has changed, as well as an understanding of reasons for changes within the system, has been acquired. Such a combination should be possible to apply for analysis of other systems as well, and may be a valuable contribution to the field of industrial ecology since the methods complement each other in a fruitful way. The eco-efficiency of the Resirk/PET system can be improved further by:</p><p>- Regarding used PET bottles as a resource to be applied for production</p><p>- Reducing packaging tax for PET bottles</p><p>- Increasing the bottle deposit</p><p>- Keeping the PET specification updated</p><p>- Improving collection efficiency</p><p>- Improving cost efficiency of marketing and information</p><p>- Increasing compaction and filling degree of reverse vending machines</p><p>- Considering automatic sorting</p><p>- Keeping focus on producing high quality PET flakes.</p><p>In addition to having showed that the approaches of eco-efficiency and interactive resource development can be combined, this thesis may have implications on how ecoefficiency can be quantified in waste management systems, and how the concepts of adaptation and friction in resource structures are dealt with.</p>

The Norwegian system for depositing and recycling of PET bottles (Resirk/PET system)started in May 2000, and is based on Norsk Resirk's mission of improving cost- and environmental efficiency of this system. Has this been achieved? What can explain the changes that occurred in the system during recent years? I have found that the eco-efficiency of the Resirk/PET system increased considerably every year between 2000 and 2003. The net greenhouse gas (GHG emission was improved from -562 kg CO2e (562 kg CO2 equivalents avoided generated) for waste management of one tonne consumed bottles in 2000 to -1442 kg CO2e per tonne in 2003, while the net cost was reduced from 4062 €/tonne in 2000 to 2683 €/tonne in 2003. This eco-efficiency improvement was very much driven by the increased volume and return rate of PET bottles during this period. The environmental performance of the Resirk/PET system was high compared to other waste management systems for PET bottles, while the economical performance was considerably lower. The interactive development of the bottled non-carbonated mineral water Imsdal contributed significantly to the increase of the Resirk/PET system’s volume and return rate and hence the system’s improved eco-efficiency. A white spirit sabotage on Imsdal in August 2002 contributed to the development of Imsdal as well as the Resirk/PET system’s change of the design and material specification for participating PET bottles. By combining the quantitative eco efficiency framework with the qualitative framework of interactive resourced development, information about how much eco-efficiency of a defined system has changed, as well as an understanding of reasons for changes within the system, has been acquired. Such a combination should be possible to apply for analysis of other systems as well, and may be a valuable contribution to the field of industrial ecology since the methods complement each other in a fruitful way. The eco-efficiency of the Resirk/PET system can be improved further by: - Regarding used PET bottles as a resource to be applied for production - Reducing packaging tax for PET bottles - Increasing the bottle deposit - Keeping the PET specification updated - Improving collection efficiency - Improving cost efficiency of marketing and information - Increasing compaction and filling degree of reverse vending machines - Considering automatic sorting - Keeping focus on producing high quality PET flakes. In addition to having showed that the approaches of eco-efficiency and interactive resource development can be combined, this thesis may have implications on how ecoefficiency can be quantified in waste management systems, and how the concepts of adaptation and friction in resource structures are dealt with.

Engineering research and development work is undergoing a reorientation from focusing on specific parts of different systems to a broader perspective of systems level, albeit at a slower pace. This reorientation should be further developed and enhanced with the aim of organizing and structuring our technical systems in meeting sustainability requirements in face of global ecological threats that have far-reaching social and economic implications, which can no longer be captured using conventional approach of research. Until a list of universally acceptable, clear, and measurable indicators of sustainable development is developed, the work with sustainability metrics should continue to evolve as a relative measure of ecological, economic, and social performance of human activities in general, and technical systems in particular. This work can be done by comparing the relative performance of alternative technologies of providing the same well-defined function or service; or by characterizing technologies that enjoy different levels of societal priorities using relevant performance indicators. In both cases, concepts and methods of industrial ecology play a vital role. This thesis is about the development and application of a systematic approach for the assessment of the performance of technical systems from the perspective of systems analysis, sustainability, sustainability assessment, and industrial ecology. The systematic approach developed and characterized in this thesis advocates for a simultaneous assessment of the ecological, economic, and social dimensions of performance of technologies in avoiding sub-optimization and problem shifting between dimensions. It gives a holistic picture by taking a life cycle perspective of all important aspects. The systematic assessment of technical systems provides an even-handed assessment resulting in a cumulative knowledge. A modular structure of the approach makes it flexible enough in terms of comparing a number of alternatives at the same time, and carrying out the assessment of the three dimensions independently. It should give way to transparent system where the level of quality of input data can be comprehended. The assessment approach should focus on a selected number of key input data, tested calculation procedures, and comprehensible result presentation. The challenge in developing and applying this approach is the complexity of method integration and information processing. The different parts to be included in the same platform come in with additional uncertainties hampering result interpretations. The hitherto tendency of promoting disciplinary lines will continue to challenge further developments of such interdisciplinary approaches. The thesis draws on the experience from ORWARE, a Swedish technology assessment tool applied in the assessment of waste management systems and energy systems; and from the EcoEffect tool used in the assessment of building properties; all assessed as components of a larger system. The thesis underlines the importance of sustainability considerations beginning from the research and development phase of technical systems. The core message of this thesis is that technical systems should be researched as indivisible parts of a complex whole that includes society and the natural environment. Results from such researches can then be transformed into design codes and specifications for use in the research and development, planning and structuring, and implementation and management of technical systems. / QC 20100505

Within the greater movement of sustainable development, industrial practices have been identified as a key area in which much improvement is both necessary and possible. The development and operation of industrial parks have become a focus of these efforts. The basic premise of this thesis is that a sustainable industrial park should function in an economically competitive manner that provides for human needs through market mechanisms while doing so in alliance with the local community, in congruence with the local ecosystem and within the carrying capacity of the planet. From a municipal planning and economic development perspective, this thesis focuses upon the development of a municipal strategy to effectuate sustainable industrial development and operations. Utilizing a blended theoretical approach incorporating general systems theory and planning theories, the proposed industrial park surrounding the Hamilton International Airport, in the City of Hamilton, Ontario, Canada, has been analyzed to develop a viable sustainability vision for the park, identify barriers to implementing and achieving that vision, and formulate a municipal strategy to promote and enable the pursuit and realization of that vision. It was found that there is an important role for the municipality to assume and numerous opportunities for concrete municipal action throughout the planning, development and operational stages of the industrial park. Upon reflection of the research process, the findings were extrapolated to garner wider applicability and relevance to other municipalities provincially, nationally, and internationally, as well as to the professional and academic community involved in industrial sustainability.

Design of products permits to yield goods and services to produce satisfaction on customers, which is measured as value. However, it is at this stage in which most of the environmental impact, from a lifecycle perspective, is added to the product. Eco-design aims at increasing value of products while reducing the burdens on the environment by means conscious design towards efficient use of resources. That efficiency, referred to as eco-efficiency, can be increased in a number of manners within environmental engineering. Traditionally, different fields have tackled materials, energy flows and products from different angles or approaches. In this thesis we describe Functional Sales (FS) and Industrial Ecology (IE) as examples of these. Within this latter, we put emphasis on Industrial Symbiosis (IS) and Eco-effectiveness. We consider these approaches are suitable to work in the framework of eco-design to increase ecoefficiency. By adding services to material products, and managing material and energy flows with a more ecological consciousness, we expect to increase value of products while reducing the impact on the environment. To analyse this potential improvement, we developed a method involving a new eco-efficiency index (VERI), that recursively intends to ease decisions on possible eco-efficient alternatives. This index and its method are applied to a case study on management of olive oil supply in region of Murcia, Spain. Here, we propose three scenarios that will involve the implementation of FS and IE to compare the outcomes in value and environmental performance against an idealised current supply chain. The results obtained, although not accurate, suggest that FS and EI should be more taken into account in eco-design and, this latter, to also consider holistic viewpoints to find more eco-efficient alternatives for a product development.

Within the greater movement of sustainable development, industrial practices have been identified as a key area in which much improvement is both necessary and possible. The development and operation of industrial parks have become a focus of these efforts. The basic premise of this thesis is that a sustainable industrial park should function in an economically competitive manner that provides for human needs through market mechanisms while doing so in alliance with the local community, in congruence with the local ecosystem and within the carrying capacity of the planet. From a municipal planning and economic development perspective, this thesis focuses upon the development of a municipal strategy to effectuate sustainable industrial development and operations. Utilizing a blended theoretical approach incorporating general systems theory and planning theories, the proposed industrial park surrounding the Hamilton International Airport, in the City of Hamilton, Ontario, Canada, has been analyzed to develop a viable sustainability vision for the park, identify barriers to implementing and achieving that vision, and formulate a municipal strategy to promote and enable the pursuit and realization of that vision. It was found that there is an important role for the municipality to assume and numerous opportunities for concrete municipal action throughout the planning, development and operational stages of the industrial park. Upon reflection of the research process, the findings were extrapolated to garner wider applicability and relevance to other municipalities provincially, nationally, and internationally, as well as to the professional and academic community involved in industrial sustainability.

Contaminated sites in low prioritized regions demand remediation technologies that are cost- and energy-effective and locally adapted. Parameters such as the time frame during which bioremediation degradation needs to occur may not be as restraining as in urban environments. This licentiate project aims to explore opportunities and constraints for appropriate soil remediation based on organic by-products in tropical developing countries and sparsely populated areas in industrial countries. Ecological Engineering and the Framework for Strategic Sustainable Development were explored as planning tools to steer bioremediation methods towards sustainability. The use of the five concepts of Ecological Engineering within the Framework for Strategic Sustainable Development can steer bioremediation in low prioritized regions towards sustainability. Pilot-scale and laboratory experiments were undertaken to evaluate the feasibility of such bioremediation methods. Experiments carried out at the experiment station in Chontales, Nicaragua showed some promising results, but also revealed problems associated with the clay rich soils, which are typical for tropical regions. Treatment of diesel contaminated ultisol with 6 mL whey kg-1 dw in a pilot-scale experiment considerably increased the degradation rate of diesel constituents, but no effects on the degradation rates were observed after treatment with compost tea or pyroligneous acid.The soil columns study suggests that despite a favorable particle size distribution for microbial transport, the sandy loam retained a greater fraction of the microorganisms present in the ACT in the top 10 cm than the clay loam, presumably because the lower bulk density and higher SOM in the clay loam aided transport and growth of microorganisms.