Internal loading of phosphorus (P) from lake sediments can delay the recovery of lakes from eutrophication for years to decades following decreases in external nutrient inputs. While internal P loading is a pervasive problem in freshwater systems, molecular speciation of P in benthic sediments of these systems remains poorly characterized. As different P species will exhibit different responses to changing sediment-water interface (SWI) geochemistry, quantifying P speciation in sediments is a critical step in understanding P dynamics in sediment-water systems. Here, various synchrotron-based techniques were employed to directly probe the bonding environments of P and iron (Fe) in natural and experimentally manipulated lake sediments in order to link chemical speciation to chemical behavior and to identify the geochemical drivers that mediate this linkage. We manipulated SWI redox conditions in mesocosm experiments to investigate the impacts of prolonged anoxia and redox oscillations on P mobility and speciation in sediments. Mesocosm experiments demonstrate that oscillating redox conditions near the SWI may drive accelerated P release from sediments relative to uninterrupted reducing conditions. Sediment P is found to be predominantly associated with Fe oxyhydroxides, calcium carbonate, and apatite minerals in three shallow hyper/eutrophic lakes in northern Vermont. In Missisquoi Bay and Lake Carmi, Fe redox cycling controls P mobility via precipitation and dissolution of Fe oxyhydroxides. In the hypereutrophic Shelburne Pond, the presence of Fe sulfides precludes redox-driven P cycling and P mobility is instead dominated by organic matter mineralization. Our results demonstrate that internal P loading can manifest differently in similar shallow lake systems due to differences in lake configuration, sediment P and Fe speciation, and organic content of sediments. This work demonstrates the potential utility, as well as the limitations, of P K- edge X-ray absorption near edge structure spectroscopy in determining sediment P speciation in freshwater lakes.

Title: A time motion analysis of lead climbing of elite climbers in the competition route of Czech Cup. Objectives: The aim of this works is to perform time motion analysis of lead climbing of elite climbers in the competition route of Czech Cup. Methods: Data were collected by video recording. Observation criteria were set (total time, holding, quickdraw clipping, rest and chalking). 8 climbers were measured on the 10- UIAA difficulty route. Results: The average climbing time was 203 ± 32,6 s, the average holding time was 7,1 ± 0,8 s (total 161,3 ± 29,2 s), the average rets period was 1,2 ± 0,4 s (total 6,5 ± 3,3 s), the average quickdraw clipping time was 2,3 ± 0,4 s (total 24,9 ± 4,6 s), the average chalking time was 2,1 ± 0,6 s (total 16 ± 3,7 s) and the average hand-transfer time was 0,9 ± 0,2 s (total 38,4 ± 9,1 s). Climbers climbed 4,8 meters per minute. Conclusions: The static part almost four times prevails the dynamic part. There were no significant differences between right and left hand in our measurements. Keywords: holding, loading, rest, static phase, dynamic phase

Mechanical loading can modulate tissue plasticity and has potential applications in rehabilitation science and regenerative medicine. To safely and effectively introduce mechanical loads to human cells, tissues, and the entire body, we need to understand the optimal loading environment to promote growth and health. The purpose of this research was 1) to validate a limb vibration and compression system; 2) to determine the effect of limb vibration on neural excitability measured by sub-threshold TMS-conditioned H-reflexes and supra-threshold TMS; 3) to determine changes in center of pressure, muscle activity, and kinematics during a postural task following limb vibration; 4) to determine the effect of vibration on accuracy and long latency responses during a weight bearing visuomotor task. The major findings of this research are 1) the mechanical system presented in the manuscript can deliver limb vibration and compression reliably, accurate, and safely to human tissue; 2) sub-threshold cortical stimulation reduces the vibration-induced presynaptic inhibition of the H-reflex. This reduction cannot be attributed to an increase in cortical excitability during limb vibration because the MEP remains unchanged with limb vibration; 3) limb vibration altered the soleus and tibialis EMG activity during a postural control task. The vibration-induced increase in muscle activity was associated with unchanged center of pressure variability and reduced center of pressure complexity; 4) healthy individuals were able to accommodate extraneous afferent information due to the vibration interventions They maintained similar levels of accuracy of a visuomotor tracking task and unchanged long latency responses during an unexpected perturbation.

For surface-water resource management studies, it is important to quantify all of the mechanisms that contribute to water quantity and influence water quality. In this regard, various methods have been used to ground-water fluxes in lake systems. These have included physical measurements (e.g., seepage meters), flow-net analyses, water budgets, chemical tracers, ground-water flow models, and statistical analyses. The method developed for this study for calculating ground-water inflow uses a simplified, 1-layer (surficial aquifer) ground-water flow model. The test area was on a set of lakes known as the Winter Haven Chain of Lakes in Polk County, Florida. The technique combines the use of a numerical model (MODFLOW) with an inverse prediction technique (PEST) to determine net surficial recharge rates. Within the model, the lakes were represented as constant-head boundaries. A general, surficial ground water no-flow boundary was delineated around the entire lake system based on the topographic boundaries. The model used annual average lake elevations to create a constant-head boundary for each lake for each year. Annual average elevations of surficial well heads were used as target well data. Model results generally support previous studies in the region, concluding that the lake chain receives significant inflow from the surficial aquifer and leaks to the Floridan aquifer. As a consequence, ground-water quality constituency was found to be of critical importance. One of the most important observations from this study is the need for accurate ground-water concentrations for ridge lake water quality management. The initial measured values used in this study were highly variable, uncertain, and likely underestimated the effect that ground water has on nutrient loading to the Winter Haven Chain of Lakes.

An interdisciplinary approach at the interface between geodesy and geophysics has recently resolved several Earth science problems at regional and global scales. I use the term “geophysical geodesy” to distinguish the technical and theoretical aspect of geodesy from geophysical applications of geodetic techniques. Using a wide range of Earth observation data, I study the spatio-temporal characteristics of Earth surface deformation in the United States associated with several geophysical processes, including natural and anthropogenic subsidence and uplift, regional relative sea-level rise, and continental hydrological loading. The theoretical portion of this dissertation applies loading theory and develops a new hybrid method to improve the estimate of hydrologically-induced vertical deformation at time scales from sub-annual to multi-annual. The application part of this dissertation benefits from GPS and other geodetic and geologic data sets to study and model Earth’s surface uplift due to CO2 injection at an oil reservoir in coastal Texas, and coastal subsidence and nuisance flooding along the Mississippi River Delta and eastern seaboard of the United States.

Background: To date, research has primarily focused on the subjective and objective measurement of vocal fatigue in professional voice users such as teachers and singers. However, these studies have not examined the effects of psychosocial factors (e.g., lack of sleep, emotional distress) leading to vocal fatigue in depth. Much like the professional voice users, students seeking to be professional voice users may face several psychosocial difficulties, may also experience similar vocal demands, and may develop vocal fatigue. Goal: The purpose of this study is to identify the relationship between psychosocial factors and vocal fatigue in students majoring in Communication Sciences and Disorders. Methods: During this study, graduate and undergraduate students completed a survey consisting of questions on employment, general health, vocal demands, and several standardized measures, (e.g., Beck’s Depression Inventory, Perceived Stress Scale, and the Vocal Fatigue Index). Vocal fatigue was induced using an adapted LingWAVES vocal loading task (~30-min duration) where participants had to meet a specific intensity goal as well as modify their pitch and voice quality. Recordings of phonation and passage reading were also made pre- and post-loading to evaluate the effects of vocal exertion. The VFI score and two objective measures (fundamental frequency and sound pressure level) were acquired and analyzed in addition to the scores from the surveys. Results: Results revealed that all students were moderately stressed, while graduate students reported more depression. All students demonstrated vocal fatigue in both subjective and objective outcome measures. Moderate-high correlation between total psychosocial scores and VFI as well as phonation Sound Pressure Level (SPL) were observed.

No description available.

This dissertation presents a new technique for miniaturization of printed RF circuits and antennas. The technique is based on lumped circuit elements and volumetric reactive pin loadings. The vertical arrangement of the pins is shown to provide a meandered current path within the device volume enhancing the miniaturization achieved with sole application of lumped circuit components. The technique is applied for antenna and filter size reduction. In antenna applications, it is shown that due to the presence of the reactive pin loading the overall size of a printed antenna can be miniaturized without affecting the radiation efficiency performance. One of the major advantages of this approach over the existing miniaturization techniques is that it allows reducing the overall size of the antenna (i.e. the substrate size) in addition to its metallization footprint area. Specifically, three antenna designs are presented for GPS and ISM applications. Firstly, a miniaturized wide-band CDL antenna has been introduced. The antenna consists of two loops which are loaded with lumped inductors and coupling capacitors. The design is shown to exhibits 49% smaller footprint size as compared to a traditional patch antenna without degrading the bandwidth performance. Secondly, a circular polarized compact dual-band CDL GPS antenna loaded with lumped capacitors and vertical pins is shown. The antenna operates with >50% lesser area as compared to a traditional L2 patch antenna without degrading its radiation performance. Thirdly, a patch antenna with its cavity loaded with CSRRs is presented. The novelty of the design is that it provides circularly symmetric arrangement of CSRRs thereby enabling the antenna to exhibit circular polarization (CP). Apart from CSRR, further size reduction is obtained by simultaneously reducing the substrate size and ground plane metallization around the CSRRs and loading it with pins. The antenna is 44% smaller than a traditional patch antenna without causing degradation in the antenna's radiation efficiency performance. To extend the volumetric loading to filter applications, the last chapter of the dissertation presents a detailed analysis to understand how geometrical factors (e.g. periodicity, radius, width of the host transmission line, etc) affect the miniaturization performance and quality factor. As a design example, a 2GHz pin loaded hairline filter with 17% -3dB |S21| bandwidth and 1.5dB insertion loss is demonstrated. The footprint size of the filter is ~λ0/16×λ0/9 @ 2GHz and is 45% smaller than its traditional counterpart.

The purpose of this study was to ascertain whether simplifying mandibular overdenture treatment utilising single stage surgery and immediate prosthetic loading of a single implant, will achieve similar implant success rates and functional improvement to that expected using conventional techniques. As part of this study, the Mk III Brånemark implant with an oxidised surface (TiUnite™ Nobel Biocare AB, Göteborg, Sweden) was compared to the classical machined Mk III Brånemark fixture.Materials and Methods: 35 patients with a mean age of 68 years and problematic mandibular dentures were treated. The primary complaints among the patients referred to the clinic for treatment related to poor retention of the mandibular denture, instability, denture sores and phonetic problems. Patients were initially placed randomly into the “machined surface” or “oxidised surface” group. A single implant was placed into the mandibular midline with high initial stability. A ball attachment was placed and the retentive cap incorporated into the existing denture. Reviews took place at 3,12 6 6 and 36 months. Clinical assessments, radiographs made with custom film holders, and stability measurements by both manual and resonance frequency analysis methods were recorded. All complications, failures, maintenance and reasons for dropout were noted. Visual analogue scale questionnaires were utilised to record patient satisfaction. (ANOVA p<.05) Results: Three out of 8 machined surface implants failed, representing an unacceptably high failure rate (37.5%). The machined surface was therefore discontinued for this study. Three oxidised surface implants did not achieve sufficient primary stability to be immediately loaded, so were treated with a two stage delayed loading protocol. The 25 immediately loaded oxidised surface implants were all classified as surviving at the 36-month recall. Patient satisfaction was very high with a significant increase in all comfort and functional parameters. Conclusions: Within the limitations of this study and research design, it appears that the immediately loaded single implant retained mandibular overdenture, using an oxidised implant surface in a small group of maladaptive patients, can provide a beneficial treatment outcome over a three year observation period. If insufficient stability at insertion is not achieved for immediate loading, then a delayed loading protocol should be utilised.

Insitu cementitious stabilisation is an economical, environmentally sustainable and socially advantageous means of rehabilitating pavements. With the recent availability of a wide range of binders and advanced construction equipment, the characterisation of cementitiously stabilised pavement materials has become the focus of further advancement of this technology. Australian practice has moved towards the use of Indirect Diametric Tensile (IDT) methods for the characterisation of these materials. A draft protocol for the IDT test has been prepared and specifies samples to be compacted by gyratory compactor. This procedure provides for both monotonic and repeated load testing, which aims to measure the material???s strength, modulus and fatigue life. A range of host materials, including a new crushed rock and a reclaimed existing pavement base course, were assessed when stabilised with a General Purpose cement binder as well as with a slag-lime blended binder. Materials were assess for their inherent material properties, Unconfined Compression Strength (UCS), Unconfined Compression modulus, IDT strength and modulus under both monotonic and repeated load. A number of amendments and refinements to the testing protocol were recommended. These included the use of minimum binder contents to ensure the binder was uniformly distributed and to promote heavy binding of the materials to ensure they behaved elastically. It was also recommended that samples be gyratory compacted to a pre-determined sample height to allow a constant density to be achieved. The variability of the test results was examined. UCS results were found to be comparatively as variable as other researchers had reported. IDT strength results contained a similar level of variability, which was considered to be acceptable. Modulus results, both monotonic and repeated load, were found to be five to ten times more variable than strength results, which is a generally accepted trend for modulus testing. Under repeated loading, some challenges with the test protocol were encountered. The primary challenge was obtaining reliable and repeatable diametrical displacement data for modulus calculation. This was partially overcome by the insertion of smooth spacers to prevent the Linear Voltage Displacement Transformer (LVDTs) becoming caught on the sample sides. The achievement of reliable and repeatable IDT modulus results through improved displacement measurements should be the focus of future research efforts in this area.