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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
71

Troca ionica focalizada - Aplicacao a separacao de elementos das terras raras

PUSCHEL, CLAUDIO R. 09 October 2014 (has links)
Made available in DSpace on 2014-10-09T12:24:25Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:04:22Z (GMT). No. of bitstreams: 1 00429.pdf: 872636 bytes, checksum: 9c83770eba88d0400824d10f4e45ebcb (MD5) / Dissertacao (Mestrado) / IEA/D / Instituto de Química - Universidade de São Paulo - IQ/USP
72

O Estudo do comportamento eletroquimico do ion La sup(3+) em meio a cloretos fundidos. A formacao de LaNi sub(5)

DIAS, CRISTIANE 09 October 2014 (has links)
Made available in DSpace on 2014-10-09T12:47:41Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:08:15Z (GMT). No. of bitstreams: 1 08318.pdf: 5216839 bytes, checksum: a5aa91f30daca6826d66086676357dd7 (MD5) / Dissertacao (Mestrado) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
73

The improvement of thermal and mechanical properties of La2Zr2O7-based pyrochlores as high temperature thermal barrier coatings

Wang, Yanfei January 2013 (has links)
To fully exploit the strengths of La2Zr2O7 pyroclores and promote them as a next-generation thermal barrier coating (TBC), the improvements of their thermally insulating property and fracture toughness are studied in this thesis. A strong phonon scattering source, rattlers, is found in Y3+-doped La2Zr2O7 pyrochlores. Rattlers dramatically flatten k (thermal conductivity)-T curves, or even make k approach the amorphous limit. The presence of rattlers is strongly dependent on (1) oversized atomic cages that are formed in pyrochlores; and (2) the occupation of smaller guest ions in those oversized cages. To maximize the rattling effect, In3+/Sc3+ ions that are much smaller than Y3+ are introduced to the La2Zr2O7 lattice. As envisaged, the smaller ions in the oversized lattice voids make k glass-like at a much lower doping content. Nevertheless, they are still not effective in reducing the high temperature plateau kmin. Instead, oxygen vacancies are very effective in reducing kmin, because they generate an electrostatic repulsion force among cations surrounding them, resulting in stronger lattice anharmonicity and weaker bonds. The plateau kmin is reduced dramatically by the filling of the B-sites in La2Zr2O7 with a 21% larger (and 50% heavier) Ce4+ guest ion rather than a 96% heavier (but similar-sized) Hf4+ ion, suggesting that a large absolute size of substitutional atoms is more effective in reducing kmin than a heavy absolute mass. This is because: (1) kmin is proportional to (E/M)0.5 (where E is the elastic modulus and M is the average atomic mass); (2) a larger size of guest ions tends to produce a weaker ionic bond and consequently, a lower E; and (3) the changing extent of E by introducing larger guest ions is much greater than that of M induced by adding heavier ones. Lastly, the fracture toughness (KIc) has been increased by dispersing the tetragonal 3 mol% Y2O3-stabilized zirconia (t-3YSZ) particulates in the La2Zr2O7 (LZ) matrix. The tendency of the dispersive t-3YSZ second phases transforming to monoclinic (m) phases strongly depends on the volume fraction introduced. For samples made from equilibrium route, they are toughened by phase transformations within the dispersive t-3YSZ second phases and a crack shielding effect arising from the residual compressive stress within the LZ matrix. An anticipated increase of KIc from ferroelastic toughening together with the residual compressive stress toughening highlights a potential to improve coating durability by depositing t’-3YSZ/LZ composite TBCs by the non-equilibrium route.
74

Recovery Of Hydrogen And Helium From Their Mixtures Using Metal Hydrides

Oztek, Muzaffer Tonguc 01 January 2005 (has links)
Waste streams of hydrogen and helium mixtures are produced at the Kennedy Space Center during purging of the hydrogen systems and supply lines. This process is done prior to and after hydrogen servicing. The purged waste gases are lost to the atmosphere, resulting in an annual loss of 2 million and 0.1 million standard cubic meters of helium and hydrogen, respectively. Recovery of these gases will have an economic benefit. Metals, alloys, and intermetallics are known to react with hydrogen in favorable conditions; therefore, they have the possibility of serving as separating and recovery agents. In this study, Mg2Ni, VTiNi and LaNi5 were studied for the separation of H2 from He, using differential scanning calorimetry and thermal volumetric analysis. The ability of LaNi5 to react with hydrogen reversibly at room temperature was verified, and further analysis focused on this compound. Size reduction and activation of LaNi5 by mechanical milling was investigated using different milling parameters for the purpose of activating the material for hydrogen absorption. Because it has been shown that addition of aluminum to LaNi5 resulted in improved hydriding and dehydriding properties, that system was studied further here. In this study, aluminum was added to LaNi5 by mechanical milling. Hydriding properties and elemental compositions of the samples were determined afterwards. The hydrogen absorption rate and capacity were compared to that of LaNi5. Both LaNi5 and its Al doped derivatives exhibited a reduced rate of hydrogen uptake and a reduced hydrogen capacity in the presence of helium. The effects of coating the samples with either gold-palladium or platinum were investigated. It was observed that coating the samples with Pt reduced the negative effect of He, whereas AuPd coating did not have any effect. Larger scale studies were done using a continuous U-tube hydride reactor, built and tested for separation of H2¬ from a 20:80 H2:He mixture. The amount of hydrogen retained in the bed was determined and found to be less than that for the batch systems.
75

A new generation of high temperature oxygen sensors

Spirig, John Vincent, January 2007 (has links)
Thesis (Ph. D.)--Ohio State University, 2007. / Title from first page of PDF file. Includes bibliographical references (p. 164-176).
76

Preparation and characterization of perovskite structure lanthanum gallate and lanthanum aluminate based oxides

Li, Shuai January 2009 (has links)
<!--[if !mso]> <object classid="clsid:38481807-CA0E-42D2-BF39-B33AF135CC4D" id=ieooui></object><mce:style><! st1\:*{behavior:url(#ieooui) } --> The present work was initiated to study the synthesis and properties of lanthanum gallate based oxides as intermediate temperature electrolyte for solid oxide fuel cells. The wet chemical method, polymer complexing route, was used to prepare the precursor powders. To further investigate the polymer complexing method, it was also applied to the preparation of lanthanum aluminate based oxides.   Single perovskite phase La0.8Sr0.2Ga0.83Mg0.17O2.815 can be prepared by the polymer complexing method using PVA as complexing agent. The thermal decomposition of the precursor powder undergoes three stages. While complete decomposition of the precursor is obtained at 1000°C. Further investigation of LaGaO3 doped with various amounts Sr or/and Mg was conducted. Three secondary phases were identified by X-ray diffraction, e.g. LaSrGaO4, LaSrGa3O7 and La4Ga2O9. The relative amount of these secondary phases depends on the doping compositions. Sr doping produced more Sr rich secondary phases with increasing content, while enhanced solid solubility was observed with Mg addition. Sintered samples showed dense microstructures with well-developed equiaxed grains, and the secondary phases were mainly in the grain boundaries. The oxygen ionic conductivity was enhanced by doping with Sr and Mg. Mg doping showed the increased activation energy of conductivity.   Preliminary study showed that the lanthanum gallate and ceria composite electrolyte is mainly fluorite CeO2 phase after sintering. The minority secondary phase, Sm3Ga5O12, was also detected by XRD. The composite electrolyte showed superior electrical performance. It exhibited the highest conductivity in the temperature range of 250–600°C, compared with lanthanum gallate and ceria specimens.   The phase pure perovskite La0.9Sr0.1Al0.85Mg0.1Co0.05O2.875 powders can easily be obtained by the polymer method using PVA as complexing agent. No secondary phase was detected after calcination at various temperatures (500–1100°C). The fully crystallized LaAlO3 phase was prepared after calcination at 900°C. Meanwhile the secondary phases were difficult to eliminate in the Sr- and Mg- doped LaGaO3 powder prepared by the same polymer method. It is thus concluded that the polymer, PVA in this work, provides more homogeneous mixing for cations of lanthanum aluminate based oxides, compared with the one for doped lanthanum gallate.   The influence of different complexing agents, e.g. PVA and PEG, was investigated in the synthesis of lanthanum aluminate powders. Minority impurity La2O3 existed in the PEG powder, but it could be eliminated after sintering at high temperatures. Although the pure phase LaAlO3 can be easily obtained in PVA powders calcined at 950°C, more seriously aggregated particles existed. PEG showed advantages over PVA in terms of better densification and microstructure control in the sintered products. To select proper polymers in complex oxide synthesis, the agglomeration and morphology of the powder are the most important factors to be considered. / QC 20100727
77

An investigation of some magnetic oxides grown by pulsed laser deposition

Sena, S. P. January 1998 (has links)
No description available.
78

Síntese e caracterização de pós de silicato de lantânio tipo apatita para eletrólito em SOFC / Synthesis and characterization of lanthanum silicate apatite type powders for SOFC electrolyte

Elias, Daniel Ricco 24 January 2014 (has links)
A temperatura de operação de células a combustível de óxido sólido (SOFCs) que utilizam zirconia estabilizada com itria (YSZ) como eletrólito é 1000 oC. Essa alta temperatura gera graves problemas relativos a materiais e vida util da célula. Por isso, condutores iônicos que possuem alta condutividade em temperaturas inferiores são pesquisados atualmente. Estudos mostraram que La10Si6O27 tipo apatita possui alta condutividade iônica de oxigenio, que é comparativamente maior que a de YSZ, a 500 oC, sendo, portanto, um potencial candidato como eletrólito para SOFC. O objetivo do presente trabalho é o desenvolvimento de técnicas de síntese de silicato de lantânio tipo apatita. Rotas inéditas de solgel modificada para sintetizar La9,33Si6O26 são propostas. Volumes estequiométricos de soluções de Na2SiO3 e LaCl3 foram misturados para a formação de gel de Si. Em seguida este gel foi calcinado a 900 °C, lavado, filtrado e tratado novamente a 900 °C. Em outra rota, volumes estequiométricos de soluções de Si (Na2SiO3 ou TEOS) e de La (LaCl3) foram utilizados para obtenção de gel de Si. Em seguida, hidróxido de La foi precipitado pela adição de uma base (NaOH ou NH4OH) ao gel. O material resultante foi calcinado a 900 °C, lavado, filtrado e tratado novamente a 900 °C. Pós de aglomerados fracos e alta sinterabilidade foram obtidos. DRX dos pós mostrou a estrutura de apatita monofásica a 900 oC. Morfologia de ceramica densa foi observada em imagens de MEV da superfície das pastilhas sinterizadas a 1200,1300 e 1400 oC por 4 h. Estas temperaturas e tempo de sinterização são significativas, pois no método convencional temperaturas superiores a 1700oC e tempos muito maiores são necessários para obtenção de tais cerâmicas. Densidades relativas superiores a 90% foram obtidas através dos métodos propostos. Uma conclusão importante é que TEOS, o reagente usual de alto custo, pode ser substituído por Na2SiO3, de preço muito mais baixo, para obter La9,33Si6O26 tipo apatita. / Solid oxide fuel cell (SOFCs) operating temperature that uses yttria stabilized zirconia (YSZ) as the electrolyte is 1000ºC. This high temperature causes serious problems concerning cell life and materials. Therefore, the ionic conductors which have high conductivity at lower temperature are currently researched. Studies have shown that the composition of La10Si6O27 apatite type has high oxygen ionic conductivity, which is comparably higher than that of YSZ, at 500 oC, it is therefore a potential candidate as for SOFC electrolyte. The objective of the present work is the development of lanthanum silicate with apatite type synthesis techniques. Novel modified solgel routes to synthesize La9.33Si6O26 are proposed. Stoichiometric volumes of Na2SiO3 and LaCl3 solutions were mixed for the formation of Si gel. This gel was calcined at 900 °C, washed, filtered and again thermally treated at 900 °C. In the other route, stoichiometric volumes of Si (Na2SiO3 or TEOS) and La (LaCl3) solutions were used for obtaining Si gel. Then, La hydroxide was precipitated by adding of a base (NaOH or NH4OH) to gel. Then the material was calcined at 900 °C, washed, filtered and again treated at 900 °C. Highly sinterable weakly agglomerated powders have been obtained. XRD patterns of the powders showed the single-phase apatite structure at 900 oC. Dense ceramic morphology was observed from the SEM images of surface of the pellets sintered at 1200, 1300 and 1400oC for 4h. This low temperature sintering and time of sintering are significant because the conventional method requires superior temperatures of 1700 oC to obtain the same dense ceramics. High relative densities higher than 90% was obtained via proposed methods. An Important conclusion is the TEOS, the usual high cost reagent, may be substituted by a cheap price Na2SiO3, to obtain apatite type La9.33Si6O26.
79

Estudo de síntese de silicato de lantânio tipo apatita pelo método sol-gel seguido de precipitação de Na2SiO3 / Synthesis study of lanthanum silicate apatite type by sol-gel method followed by precipitation from Na2SiO3

Silva, Fernando dos Santos 01 December 2016 (has links)
Cerâmicas de silicato de lantânio tipo apatita têm sido estudadas devido ao grande interesse tecnológico para aplicação como eletrólito em células a combustível de óxido sólido de temperatura intermediária (IT-SOFC: Intermediate Temperature Solid Oxide Fuel Cell). A condutividade iônica dessas cerâmicas em temperaturas intermediárias (600-800°C) é maior do que a da YSZ (Ytria Stabilized Zirconia) utilizada como eletrólito em SOFCs de alta temperatura (800-1000°C). Neste trabalho, silicato de lantânio tipo apatita foi sintetizado pelo método sol-gel seguido de precipitação, a partir de Na2SiO3 como fonte de sílica. No método proposto, estudou-se rotas de síntese em meio ácido e básico para a formação do gel de sílica, seguida de precipitação. A fase cristalina de silicato de lantânio tipo apatita foi obtida pela calcinação de pós sintetizados a 900°C. Esta temperatura é muito inferior às praticadas em outros métodos convencionais de síntese. As análises por difração de raios X (DRX) mostraram silicato de lantânio tipo apatita como fase principal do material sintetizado na rota de síntese em pH ácido. No entanto, uma fase secundária indesejável, La2Si2O7, foi identificada quando o pó cerâmico foi calcinado a 1200°C. Por outro lado, pela rota básica, fase única de silicato de lantânio tipo apatita foi obtida após tratamento térmico dos precursores a 900 e 1200°C. Pastilha cerâmica obtida a partir dos pós obtidos e sinterizados a 1400°C por 4h, apresentaram fase cristalina pura de silicato de lantânio tipo apatita. Microscopia eletrônica de varredura (MEV) foi utilizada para observar a morfologia dos pós e microestrutura das pastilhas sinterizadas. Pós cerâmicos finos com tamanho de partículas submicrométricas e microestrutura típica de apatita foram alcançadas pelo método proposto. / Lanthanum silicate apatite-type ceramics have been studied because of the great technological interest for IT-SOFC applications as electrolyte (Intermediate Temperature Solid Oxide Fuel Cell). Ionic conductivity of those ceramics at intermediate temperatures (600-800°C) is higher than that of YSZ (Ytria Stabilized Zirconia) electrolyte used at high-temperatures (800-1000 °C) SOFCs. In this work, lanthanum silicate apatite-type was synthesized by sol-gel method followed by precipitation from Na2SiO3 as a source of silica. In the proposed method, synthesis routes in acid and basic medium to the formation of silica gel, followed by precipitation were studied. Apatite crystalline phase of lanthanum silicate ceramic was obtained by calcining the powders at 900°C. This temperature is much lower than those other conventional methods of synthesis. Analysis by x-ray diffraction (XRD) showed the lanthanum silicate apatite-type phase as the main phase of the synthesized material at the pH acid synthesis route. However, undesirable secondary phase, La2Si2O7, was recognized when the powder was calcined at 1200°C. On the other hand, by the basic route, single apatite-type phase powder was obtained after thermal treatment of the precursors at 900 and 1200°C. Ceramic pellet obtained from those powders sintered at 1400°C for 4h, presented pure apatite crystalline phase of lanthanum silicate. Scanning electron microscopy (SEM) was used to observe morphology of powders and microstructure of sintered pellets. Sub micrometric size powders and apatite typical microstructure ceramic were reached by the suggested method.
80

Amorphous Metal Oxide Thin Films from Aqueous Precursors: New Routes to High-κ Dielectrics, Impact of Annealing Atmosphere Humidity, and Elucidation of Non-uniform Composition Profiles

Woods, Keenan 10 April 2018 (has links)
Metal oxide thin films serve as critical components in many modern technologies, including microelectronic devices. Industrial state-of-the-art production utilizes vapor-phase techniques to make high-quality (dense, smooth, uniform) thin film materials. However, vapor-phase techniques require large energy inputs and expensive equipment and precursors. Solution-phase routes to metal oxides have attracted great interest as cost-effective alternatives to vapor-phase methods and also offer the potential of large-area coverage, facile control of metal composition, and low-temperature processing. Solution deposition has previously been dominated by sol-gel routes, which utilize organic ligands, additives, and/or solvents. However, sol-gel films are often porous and contain residual carbon impurities, which can negatively impact device properties. All-inorganic aqueous routes produce dense, ultrasmooth films without carbon impurities, but the mechanisms involved in converting aqueous precursors to metal oxides are virtually unexplored. Understanding these mechanisms and the parameters that influence them is critical for widespread use of aqueous approaches to prepare microelectronic components. Additionally, understanding (and controlling) density and composition inhomogeneities is important for optimizing electronic properties. An overview of deposition approaches and the challenges facing aqueous routes are presented in Chapter I. A summary of thin film characterization techniques central to this work is given in Chapter II. This dissertation contributes to the field of solution-phase deposition by focusing on three areas. First, an all-inorganic aqueous route to high-κ metal oxide dielectrics is developed for two ternary systems. Chapters III and IV detail the film formation chemistry and film properties of lanthanum zirconium oxide (LZO) and zirconium aluminum oxide (ZAO), respectively. The functionality of these dielectrics as device components is also demonstrated. Second, the impact of steam annealing on the evolution of aqueous-derived films is reported. Chapter V demonstrates that steam annealing lowers processing temperatures by effectively reducing residual counterion content, improving film stability with respect to water absorption, and enhancing dielectric properties of LZO films. Third, density and composition inhomogeneities in aqueous-derived films are investigated. Chapters VI and VII examine density inhomogeneities in single- and multi-metal component thin films, respectively, and show that these density inhomogeneities are related to inhomogeneous metal component distributions. This dissertation includes previously published coauthored material.

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