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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
81

Selective toluene disproportionation over ZSM-5 zeolite

Albahar, Mohammed January 2018 (has links)
This research aimed at improving p-xylene selectivity in toluene disproportionation over ZSM-5 zeolite by exploring the effect of crystal size and various post synthetic modification methods. A comprehensive study of the effect of different modifications on the physicochemical properties of ZSM-5 was investigated using X-ray diffraction (XRD), pyridine adsorption, Fourier transform infra-red (FTIR), 29Si magic-angle spinning nuclear magnetic resonance (MAS NMR), BET surface area by N2 adsorption, inductively coupled plasma (ICP) and scanning electron microscopy (SEM). The catalytic performance of each catalyst was studied in a fixed bed reactor at a temperature 475 °C, WHSV 3-83 h-1 and two different pressures (1 and 10 bar). ZSM-5 zeolites with different crystal sizes (5, 50 and 100 ÂÂμm) were synthesized in house and compared with the commercially obtained ZSM-5 having a crystal size of 0.5 ÂÂμm. The increase in crystal size improved p-xylene selectivity which was attributed to the diffusion constraints imposed by the longer diffusion path lengths of large crystals. The highest p-xylene selectivity (58 %) was achieved over ZSM-5 with the largest crystal size 100 ÂÂμm at the highest WHSV 83 h-1. However, it was accompanied by a low conversion (2 wt. %). ZSM-5 with crystal size of 5 ÂÂμm delivered the best results in terms of the combination of para-selectivity (40 %) and toluene conversion (15 wt. %). The p-xylene produced in the channels of ZSM-5 can quickly isomerise to o-xylene and m-xylene on the external unselective acid sites. Different post modification methods were applied in this study in attempt to suppress the fast isomerization reaction by deactivating the external acid sites. This was achieved to some extent by depositing an inert silica layer using different silica agents, amounts and number of modification cycles and as a result p-xylene selectivity was significantly improved (84 %), especially over large crystals 5 ÂÂμm. The decrease in Brà̧nsted acidity (FTIR) suggested the success of the silylation method. Furthermore, impregnation of lanthanum and phosphorus on ZSM-5 improved p-xylene selectivity (40 %). FTIR measurements showed a drastic drop in the number of Brà̧nsted and Lewis acid sites after loading phosphorus which led to a large reduction in toluene conversion. Lanthanum impregnation had less effect on conversion and increased selectivity with decreased Brà̧nsted sites and pore volume reduction showed by N2 adsorption suggesting some pore narrowing. There are several approaches that can be considered in future to further improve p-xylene selectivity. Improving the synthesis of large crystals to balance acidity and crystal size can lead to the enhancement of p-xylene selectivity. Also, performing toluene disproportionation on optimised pre-coked ZSM-5 large crystals at high pressure can help to maintain the conversion while increasing p-xylene selectivity. Another approach would be to apply silylation modification to extruded large crystals ZSM-5.
82

Fast-timing measurements with a spatially-distributed source

Mallaburn, Michael January 2017 (has links)
The effect of the spatial distribution of a radioactive source on timing measurements has been investigated with particular consideration toward the focal plane of recoil separators. The work conducted during this thesis is a precursor to understand the magnitude of such effects for the upcoming fast timing array (FATIMA) at FAIR. An experiment was undertaken at the University of Jyvaskyla using the K130 cyclotron to accelerate a 36-Ar beam to 190 MeV, directed onto a 106-Cd target, to produce recoils of 138-Gd and 136-Sm via fusion-evaporation reactions. Recoils directed using RITU to the focal-plane DSSSD of GREAT were distributed over the majority of the 124-mm by 40-mm extension of the DSSSD. A new array consisting of eight lanthanum bromide detectors was used to measure the time between coincident prompt-gamma rays emitted following the de-excitation of isomeric recoil states implanted into the DSSSD. Lifetimes were measured to be 213(20) ps and 200(100) ps for the first-excited 2+ states in 138-Gd and 136-Sm, respectively. Positional information, extracted from the DSSSD, was used to correct for the difference in the time-of-flight of gamma rays as they travelled from the implantation position to the lanthanum bromide detectors. When accounted for, the lifetimes were remeasured to be 217(20) ps and 210(90) ps, respectively, showing no significant change in value or error. A method of quantifying the increase in uncertainty of a lifetime measurement due to the spatial distribution of the source and the position of the surrounding detectors, supported by simulation, has been provided to explain these observations. A new technique for extracting the time-walk from each of the CFDs in a multi-detector array has been presented. The new technique offers a reduced complexity in calculations by accounting for the correlated time-walks present in time measurements from different detector-pairs sharing a common CFD. Work towards a technique for extracting lifetimes from time data has been presented. Dubbed the Symmetrised-Convolution Lifetime Measurement (SCLM) method, this technique essentially applies a model-dependent convolution of the prompt-response with nuclear exponential decay on both time spectra, obtained by inverting the start and stop conditions of a TAC, simultaneously and draws parallels to the Mirror Symmetric Centroid Difference method.
83

Estudo de síntese de silicato de lantânio tipo apatita pelo método sol-gel seguido de precipitação de Na2SiO3 / Synthesis study of lanthanum silicate apatite type by sol-gel method followed by precipitation from Na2SiO3

Fernando dos Santos Silva 01 December 2016 (has links)
Cerâmicas de silicato de lantânio tipo apatita têm sido estudadas devido ao grande interesse tecnológico para aplicação como eletrólito em células a combustível de óxido sólido de temperatura intermediária (IT-SOFC: Intermediate Temperature Solid Oxide Fuel Cell). A condutividade iônica dessas cerâmicas em temperaturas intermediárias (600-800°C) é maior do que a da YSZ (Ytria Stabilized Zirconia) utilizada como eletrólito em SOFCs de alta temperatura (800-1000°C). Neste trabalho, silicato de lantânio tipo apatita foi sintetizado pelo método sol-gel seguido de precipitação, a partir de Na2SiO3 como fonte de sílica. No método proposto, estudou-se rotas de síntese em meio ácido e básico para a formação do gel de sílica, seguida de precipitação. A fase cristalina de silicato de lantânio tipo apatita foi obtida pela calcinação de pós sintetizados a 900°C. Esta temperatura é muito inferior às praticadas em outros métodos convencionais de síntese. As análises por difração de raios X (DRX) mostraram silicato de lantânio tipo apatita como fase principal do material sintetizado na rota de síntese em pH ácido. No entanto, uma fase secundária indesejável, La2Si2O7, foi identificada quando o pó cerâmico foi calcinado a 1200°C. Por outro lado, pela rota básica, fase única de silicato de lantânio tipo apatita foi obtida após tratamento térmico dos precursores a 900 e 1200°C. Pastilha cerâmica obtida a partir dos pós obtidos e sinterizados a 1400°C por 4h, apresentaram fase cristalina pura de silicato de lantânio tipo apatita. Microscopia eletrônica de varredura (MEV) foi utilizada para observar a morfologia dos pós e microestrutura das pastilhas sinterizadas. Pós cerâmicos finos com tamanho de partículas submicrométricas e microestrutura típica de apatita foram alcançadas pelo método proposto. / Lanthanum silicate apatite-type ceramics have been studied because of the great technological interest for IT-SOFC applications as electrolyte (Intermediate Temperature Solid Oxide Fuel Cell). Ionic conductivity of those ceramics at intermediate temperatures (600-800°C) is higher than that of YSZ (Ytria Stabilized Zirconia) electrolyte used at high-temperatures (800-1000 °C) SOFCs. In this work, lanthanum silicate apatite-type was synthesized by sol-gel method followed by precipitation from Na2SiO3 as a source of silica. In the proposed method, synthesis routes in acid and basic medium to the formation of silica gel, followed by precipitation were studied. Apatite crystalline phase of lanthanum silicate ceramic was obtained by calcining the powders at 900°C. This temperature is much lower than those other conventional methods of synthesis. Analysis by x-ray diffraction (XRD) showed the lanthanum silicate apatite-type phase as the main phase of the synthesized material at the pH acid synthesis route. However, undesirable secondary phase, La2Si2O7, was recognized when the powder was calcined at 1200°C. On the other hand, by the basic route, single apatite-type phase powder was obtained after thermal treatment of the precursors at 900 and 1200°C. Ceramic pellet obtained from those powders sintered at 1400°C for 4h, presented pure apatite crystalline phase of lanthanum silicate. Scanning electron microscopy (SEM) was used to observe morphology of powders and microstructure of sintered pellets. Sub micrometric size powders and apatite typical microstructure ceramic were reached by the suggested method.
84

Synthèse de nouveaux catalyseurs nanostructurés par dépôts physiques à base de pérovskite de lanthane / New nanostructured catalysts with pérovskites of lanthanum obtained by processes of physical deposit

Vilasi, Pauline 20 December 2018 (has links)
Ce travail de thèse est issu d’une collaboration entre les laboratoires de recherche FEMTO-ST de l’université technologique de Belfort-Montbéliard et IRCELYON de l’université Claude Bernard à Villeurbanne. Les objectifs de cette étude portent sur la faisabilité d’élaborer par pulvérisation cathodique magnétron des films minces de cobaltite de lanthane nanostructurés. En effet, ces films présentent des propriétés catalytiques intéressantes pour l’oxydation des composés organiques volatiles comme le propène (C3H6) ou le monoxyde de carbone (CO) qui constituent la principale source de pollution de l’air. Il sera montré dans un premier temps que les cobaltites de lanthane de formule LaCoO3 ne sont pas efficaces pour ce type d’application. La composition chimique de ce matériau sera donc modifiée en y incorporant de l’argent de manière à faire varier les propriétés physico-chimiques des films et d’augmenter leurs performances catalytiques. La morphologie des films est directement impactée par l’introduction de Ag puisqu’elle évolue d’un système dense à un système « nanofilaire ». Une autre série de dépôts sera également élaborée et testée en catalyse constituée de cobaltites de lanthane dopées avec de l’argent mais aussi du cérium. On retiendra alors que les films de LaCoO3 + Ag sont plutôt efficaces et prometteurs puisqu’ils présentent des performances catalytiques se rapprochant de celles du platine (catalyseur de référence). Néanmoins, bien que les films aient toujours cette morphologie nanofilaire, les compositions chimiques des films élaborés à base de LaCoO3 + Ag + Ce doivent être optimisées afin d’augmenter leurs activités catalytiques. / This work was made in the frame of a scientific research relationships between the laboratory FEMTO-ST of the Technological University of Belfort-Montbéliard and the laboratory IRCELYON of the Claude Bernard University of Villeurbanne. This study aims at characterizing the feasibility of nanostructured lanthanum cobaltite thin films via magnetron sputtering. Indeed, it is well known these materials have interesting catalytic properties regarding the oxidation of volatile organic compounds such as propene (C3H6) or carbon monoxide (CO), the latter being the main source of air pollution. First, it has been shown that lanthanum cobaltites of formula LaCoO3 are not efficient for this type of application. The chemical composition of this material was then modified by incorporating silver so as to vary the physicochemical properties of the films and increase their catalytic performance. In consequence, the morphology of the films was directly impacted by the introduction of Ag since it evolved from a dense system to a "nanowire" system. Another series of deposits based on cobaltite modified by both silver and cerium additions have been also developed and tested during catalytic tests. It should be noted that the Ag containing thin films of LaCoO3 are rather efficient and then promising since they have catalytic performances close to those of platinum (the reference catalyst). Concerning the Ag and Ce containing perovskite films, although they still have this peculiar nanowired morphology, their chemical compositions have to be optimized in order to increase their catalytic activities.
85

Quantitative imaging with PET : performance and applications of 76Br, 52Fe, 110mIn and 134La

Lubberink, Mark January 2001 (has links)
The use of positron emission tomography (PET) has so far mainly been limited to a few nuclides with short half-lives such as 11C and 18F. Certain applications require nuclides with longer half-lives, such as 76Br and 52Fe. In radionuclide therapy positron emitting analogues of therapeutic nuclides, such as 110mIn, or daughter nuclides, such as 134La, can enable improved dosimetry with the use of PET. A challenge associated with the use of these positron emitters is that they emit gamma radiation in cascade with positrons, which complicates quantitative PET imaging. Other possible problems are the high energies of the emitted positrons, and the decay of 52Fe to the short-lived positron emitter 52mMn. Performance measurements were made to investigate the effects of these decay characteristics on the quantitative accuracy, spatial resolution, and other parameters of PET. The distribution of gamma radiation coincidences in PET data was studied and correction methods were implemented and evaluated. PET resolution degrades with 1-2 mm for the studied nuclides in comparison with 18F. The implemented sinogram tail fit and delayed coincidence based gamma radiation coincidence correction methods lead to a quantitative accuracy similar as for 18F and to improved image contrast. Standard dead time corrections are not adequate for gamma-emitting nuclides. Noise equivalent count rates are considerably lower for 76Br than for 18F at clinically relevant radioactivity concentrations. A method to correct 52Fe patient data for the contribution of 52mMn is discussed. The use of 110mIn is evaluated in a patient study and compared to SPECT imaging with 111In. A dosimetric and PET evaluation of the use of 134Ce/134La for radionuclide therapy and dosimetry is presented. Dosimetry of 76Br-labelled antibodies is studied in a pig model. Finally, the possibility to use PET for dosimetry during radionuclide therapy is studied and a nonuniform dose calculation program is presented.
86

Studies on Synthesis, Structural and Electrical Properties of Complex Oxide Thin Films: Ba1-xSrxTiO3 and La2-xSrxNiO4

Podpirka, Adrian Alexander 27 July 2012 (has links)
High performance miniaturized passives are of great importance for advanced nanoelectronic packages for several applications including efficient power delivery. Low cost thin film capacitors fabricated directly on package (and/or on-chip) are an attractive approach towards realizing such devices. This thesis aims to explore fundamental frequency dependent dielectric and insulating properties of thin film high-k dielectric constant in the perovskite and perovskite-related complex oxides. Throughout this thesis, we have successfully observed the role of structure, strain and oxygen stoichiometry on the dielectric properties of thin film complex oxides, allowing a greater understanding of processing conditions and polarization mechanisms. In the first section of the thesis, we explore novel processing methods in the conventional ferroelectric, barium strontium titanate, \(Ba_{1-x}Sr_xTiO_3 (BST)\), using ultraviolet enhanced oxidation techniques in order to achieve improvements in the dielectric properties. Using this method, we also explore the growth of BST on inexpensive non-noble metals such as Ni which presents technical challenges due to the ability to oxidize at high temperatures. We observe a significant lowering of the dielectric loss while also lowering the process temperature which allows us to maintain an intimate interface between the dielectric layer and the metal electrode. The second section of this thesis explores the novel dielectric material, Lanthanum Strontium Nickelate, \(La_{2-x}Sr_xNiO_4 (LSNO)\), which exhibits a colossal dielectric response. For the first time, we report on the colossal dielectric properties of polycrystalline and epitaxial thin film LSNO. We observe a significant polarization dependence on the microstructure due to the grain/grain boundary interaction with charged carriers. We next grew epitaxial films on various insulating oxide substrates in order to decouple the grain boundary interaction. Here we observed substrate dependent dielectric properties associated with induced strain. We also observe, due to the p-type carriers in LSNO, pn junction formation when grown epitaxially on the conducting oxide degenerate n-type Nb-doped \(SrTiO_3\). Finally we explore the growth mechanism of epitaxial LSNO as a function of high oxygen content. Due to the ability for LSNO to take in interstitial oxygen, a reoriented growth is observed at a critical thickness, thereby allowing us to vary anisotropy as a function of deposition conditions. / Engineering and Applied Sciences
87

Development of a semi-autonomous directional and spectroscopic radiation detection mobile platform

Miller, Alexander Luke 01 March 2014 (has links)
This thesis presents a method for a small, inexpensive mobile robot equipped with a single high resolution scintillation detector to quickly survey an area and convey information about local sources of gamma radiation to a remote human operator. This is achieved by surrounding the detector with a lead sheath that blocks all gamma rays except those incident along the detector???s axial direction. A horizontal scan is performed by rotating the detector and a directional profile of gamma radiation is constructed. In addition a visual panorama of the local area is assembled using a camera mounted on the detector. A plot of the detector signal versus angle is then overlaid on top of the visual panorama and visible peaks clearly indicate the direction of local gamma radiation sources. Moreover, measuring the energy spectrum of gamma rays in each direction produces a 2D count frequency histogram where distinct peaks indicate the energy and direction of local gamma ray sources allowing the identification of different radio-isotopes.
88

Investigation of deposition parameters in ultrasonic spray pyrolysis for fabrication of solid oxide fuel cell cathode

Amani Hamedani, Hoda 19 November 2008 (has links)
Solid oxide fuel cell (SOFC) research is currently underway to improve performance, cost and durability by lowering the operating temperature to ~600°C. One approach is to design fabrication processes capable of tailoring desirable cathode microstructures to enhance mass and charge transfer properties through the porous medium. The aim of this study is to develop a cost effective fabrication technique for deposition of novel microstructures, specifically, functionally graded thin films of LSM oxide with porosity graded structure for use as IT- SOFCs cathode. Spray pyrolysis method was chosen as a low-temperature processing technique for deposition of porous LSM films onto dense YSZ substrates. The effort was directed toward the optimization of the processing conditions for deposition of high quality LSM films with variety of morphologies in the range of dense to porous microstructures. Results of optimization studies on spray parameters revealed that the substrate surface temperature is the most critical parameter influencing the roughness and morphology, porosity, cracking and crystallinity of the film. Physical and chemical properties of deposited thin films such as porosity, morphology, phase crystallinity and compositional homogeneity have shown to be extensively dependent on the deposition temperature as well as solution flow rate and the type of precursor solution among other parameters. The LSM film prepared from organo-metallic precursor and organic solvent showed a homogeneous crack-free microstructure before and after heat treatment as opposed to aqueous solution. Also, increasing the deposition temperature and the solution flow rate, in the specific range of 520-580 ℃ and 0.73-1.58 ml/min, respectively, leads to change the microstructure from a dense to a highly porous film. Taking the advantage of simplicity of spray pyrolysis technique combined with using metal-organic compounds, the conventional ultrasonic spray system was modified to a novel system whereby highly crystalline multi-layered porosity graded LSM cathode with columnar morphology and good electrical conductivity in the range of 500-700 °C was fabricated through a multi-step spray and via applying optimum combination of spray parameters. This achievement for the current graded LSM cathode would allow its use in IT-SOFCs.
89

Energy production from coal syngas containing H₂S via solid oxide fuel cells utilizing lanthanum strontium vanadate anodes

Cooper, Matthew E. January 2008 (has links)
Thesis (Ph.D.)--Ohio University, August, 2008. / Title from PDF t.p. Includes bibliographical references.
90

Mean-field and density-functional studies of charge ordering and magnetic transitions in lanthanum manganites /

Mishra, Snigdharaj K. January 1997 (has links)
Thesis (Ph. D.)--University of Missouri-Columbia, 1997. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

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