LiCoO₂thin films have been grown by pulsed laser deposition on stainless steel and SiO₂/Si substrates. The film deposited at 600°C in an oxygen partial pressure of 100mTorr shows an excellent crystallinity, stoichiometry and no impurity phase present. Microstructure and surface morphology of thin films were examined using a scanning electron microscope. The electrochemical properties of the thin films were studied with cyclic voltammetry and galvanostatic charge-discharge techniques in the potential range 3.0-4.2 V. The initial discharge capacity of the LiCoO2 thin films deposited on the stainless steel and SiO₂/Si substrates reached 23 and 27 µAh/cm², respectively. / Singapore-MIT Alliance (SMA)

The thesis explores preparation and properties of bismuthiron garnet (BIG) films and the incorporation of BIG films intoone-dimensional magneto-optical photonic crystals (MOPCs). Films were prepared by pulsed laser deposition. Weinvestigated or measured crystallinity, morphology,film-substrate interface, cracks, roughness, composition,magnetic coercivity, refractive index and extinctioncoefficient, and magneto-optical Faraday rotation (FR) andellipticity. The investigations were partly performed onselected samples, and partly on two series of films ondifferent substrates and of different thicknesses. BIG filmswere successfully tested for the application of magneto-opticalvisualization. The effect of annealing in oxygen atmosphere wasalso investigated - very careful annealing can increase FR byup to 20%. A smaller number of the above mentionedinvestigations were carried out on yttrium iron garnet (YIG)films as well. Periodical BIG-YIG multilayers with up to 25 single layerswere designed and prepared with the purpose to enhance FR at aselected wavelength. A central BIG layer was introduced asdefect layer into the MOPC structure and generated resonancesin optical transmittance and FR at a chosen design wavelength.In a 17- layer structure, at the wavelength of 748 nm, FR wasincreased from -2.6 deg/µm to -6.3 deg/µmat a smallreduction in transmittance from 69% to 58% as compared to asingle-layer BIG film of equivalent thickness. In contrast tothick BIG films, the MOPCs did not crack. We were first toreport preparation of all-garnet MOPCs and second toexperimentally demonstrate the MOPC principle inmagneto-optical garnets.

<p>The thesis explores preparation and properties of bismuthiron garnet (BIG) films and the incorporation of BIG films intoone-dimensional magneto-optical photonic crystals (MOPCs).</p><p>Films were prepared by pulsed laser deposition. Weinvestigated or measured crystallinity, morphology,film-substrate interface, cracks, roughness, composition,magnetic coercivity, refractive index and extinctioncoefficient, and magneto-optical Faraday rotation (FR) andellipticity. The investigations were partly performed onselected samples, and partly on two series of films ondifferent substrates and of different thicknesses. BIG filmswere successfully tested for the application of magneto-opticalvisualization. The effect of annealing in oxygen atmosphere wasalso investigated - very careful annealing can increase FR byup to 20%. A smaller number of the above mentionedinvestigations were carried out on yttrium iron garnet (YIG)films as well.</p><p>Periodical BIG-YIG multilayers with up to 25 single layerswere designed and prepared with the purpose to enhance FR at aselected wavelength. A central BIG layer was introduced asdefect layer into the MOPC structure and generated resonancesin optical transmittance and FR at a chosen design wavelength.In a 17- layer structure, at the wavelength of 748 nm, FR wasincreased from -2.6 deg/µm to -6.3 deg/µmat a smallreduction in transmittance from 69% to 58% as compared to asingle-layer BIG film of equivalent thickness. In contrast tothick BIG films, the MOPCs did not crack. We were first toreport preparation of all-garnet MOPCs and second toexperimentally demonstrate the MOPC principle inmagneto-optical garnets.</p>

Thesis (Ph. D.)--University of Missouri-Columbia, 1998. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 1998. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

No description available.

Bismuth-Strontium-Calcium-Copper-Oxide (BSCCO) compounds are an important family of compounds that have one of the highest transition temperatures among all high-temperature superconductors. The compound is known to exist in three distinct phases, commonly referred to as the 2201, 2212 and 2223 phases. Of these three phases, the 2212 and 2223 phases are the most important, as their transition temperature is higher than the boiling point of liquid nitrogen. It is desirable to produce the compound in thin film form, as the bulk samples are normally polycrystalline. This thesis compares thin films produced by two techniques for depositing BSCCO in order to understand the effect of various processing parameters on the final quality of the thin films. Thin films were grown by flash evaporation at Texas A&M University, and by pulsed laser deposition (PLD) at the University of Wollongong, Australia. The latter of these techniques is widely used for growing thin films of various compounds. Single-phase 2212 films were grown on a MgO substrate using the pulsed laser deposition technique from commercially available 2212 powder. The effect of annealing on the thin films was also studied.

Two sets of nanostructured Zinc Oxide (ZnO) thin films doped with varying nominal concentrations of rare earth (RE) ions were prepared by pulsed laser deposition (PLD). One set was doped with europium ions (ZnO:Eu³⁺) while the other was doped with erbium ions (ZnO:Er³⁺). The nominal concentration of RE ions ranged from 0.025 to 5 atomic %. The produced films were structurally, morphologically and optically characterised using different techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL), combined excitation and emission spectroscopy (CEES) and X-ray photoelectron spectroscopy (XPS). All films were found to possess a single-crystal hexagonal structure and were strongly oriented along the c-axis. However, the crystallinity of the investigated films seemed to deteriorate as the concentration of the rare earth ions increased. This deterioration is assumed to be due to the local distortion of the ZnO structure (host material) caused by the insertion of the relatively large RE ions, hence inducing structural stresses. Importantly, XRD measurements showed that no other crystalline phases related to europium or erbium, such as Eu₂O₃ or Er₂O₃, were observed. Surprisingly, the ZnO lattice constant (c) tended to become smaller as more RE³⁺ ions were added to the films. An explanation is offered whereby this observation can be taken as further evidence that Zn²⁺ ions were successfully substituted by RE³⁺ ions. Interestingly, doping ZnO films with RE³⁺ ions of a nominal concentration of ≥ 0.5 at.% or higher exhibited a drastic effect on the optical properties of the host matrix (ZnO) in which the near band edge luminescence characteristic of pure ZnO completely disappeared. According to SEM images, morphological changes also occur as dopant concentrations increase. Well-defined grains (crystallites) were clearly seen in films doped with ˂ 0.5 at.% of RE ions. However, these grains became hardly distinguishable at higher RE ion concentrations. Typical intra-4f shell transitions of RE³⁺ ions were observed when these ions were non-resonantly excited with UV radiation, indicating that energy had been efficiently transferred from ZnO to the rare earth ions. A plausible physical mechanism for this energy transfer is proposed. The radiative optical centres of rare earth ions were studied by CEES. In these experiments, both sets of films exhibited multiple optical sites. ZnO:Eu³⁺ thin films were found to have two distinct optical sites with differing site symmetries, whereas up to four optical sites were detected in the ZnO:Er³⁺ films.

Vertically aligned nanocomposite (VAN) oxide thin films are unique nanostructures with two-phase self-assembled, heteroepitaxially grown on single-crystal substrates. Both phases tend to grow vertically and simultaneously on a given substrate with lattice matching in the system. The nanostructured thin film system could form different in-plane morphologies including nano-checkerboard, nanopillar in matrix and nanomaze structures. The VAN thin films with tunable vertical lattice strain and novel microstructures provide fascinating approaches to achieve enhanced functionalities. In this dissertation, the microstructure and vertical strain effect on low-field magnetoresistance (LFMR) have been investigated in heteroepitaxial La0.7Sr0.3MnO3 (LSMO):CeO2 and LSMO:ZnO VAN thin films with a vertical strain of 0.13 % and 0.5 %, respectively. We demonstrate that LFMR can be tuned by column width and vertical strain in these VAN systems, i.e., smaller column width and larger vertical strain could result in a larger LFMR in the vertical nanocomposite heteroepitaxial thin films. The physical mechanism of enhanced LFMR in LSMO-based VAN has been explored. Single-phase LSMO and LSMO-based VANs have been grown on different substrates with different secondary phase compositions. Substrate effect in single-phase LSMO films shows that LFMR tends to increase with grain misorientation factor because the cross-section of electron conduction paths reduces as grain misorientation factor increases. (LSMO)1-x:(ZnO)x VAN heteroepitaxial films without large angle grain boundary (GB) have been used to study the pure phase boundary (PB) effect on the LFMR. It shows that increased PBs tends to reduce the cross-section of the conducting path and thus favor the spin-dependent tunneling in nanomaze structures with ferromagnetic/insulating/ferromagnetic vertical sandwiches. Tilted aligned LSMO nanostructured films with artificial GBs have been designed to investigate pure GBs influence on LFMR. The results indicate that decoupling of neighboring ferromagnetic (FM) domains by artificial GBs is necessary to achieve enhanced LFMR properties; and the strength of the GBs can be controlled by post-annealing to tune the LFMR effect. The VAN heteroepitaxial films display excellent microstructure compatibility and strain tuning. Perovskite oxides can be combined with many other oxide materials to form VAN architectures. The microstructure and lattice strain in the unique heteroepitaxial VANs can be used to engineer and tune the existing/new functionalities.

Thesis (Ph.D.)--University of Wollongong, 2005. / Typescript. Includes bibliographical references.