Idag står världen inför en rad olika miljörelaterade problem. Ett av dessa och det kanske mest omtalade är hur utsläpp av växthusgaser sakta men säkert höjer planetens medeltemperatur. Hållbar utveckling är ett begrepp som driver diskussionen framåt om vad vi behöver göra och hur vi behöver förändras för att lösa problemen. Växthusgaserna och deras hot mot klimatet är starkt relaterat till energi. Förnyelsebara energikällor skulle kunna vara en dellösning på problemet men de kräver energilagring av olika former för att kunna ersätta sina fossila konkurrenter. Termisk energilagring är ett sätt att lagra energi på och kan delas upp i tre olika grupper. Dessa är sensibel, latent och termokemisk värmelagring. Syftet med denna litteraturstudie var att kartlägga olika applikationer av latent värmelagring som kan bidra till ett mer hållbart samhälle i framtiden. Resultatet visar att det finns många olika typer av så kallade fasomvandlingsmaterial (PCMs). Beroende på vid vilka temperaturer värme ska lagras vid används olika PCMs. PCMs kan användas för latent värmelagring inom många olika områden. Byggnader är ett av dessa områden där PCMs kan användas för att kyla och värma utrymmen antingen genom integration i ventilationssystem eller i själva byggnadsmaterialen. Latent värmelagring kan också användas i termiska solkraftverk. Latent värmelagring har på senare tid fått stor uppmärksamhet tack vare PCMs förmåga att lagra värme i små volymer och under konstant temperatur. Dock möter tekniken problem vid värmeöverföringen vilket t.ex. är fallet i lagring av termisk solenergi. Forskning pågår därför för att generellt höja PCMs termiska egenskaper. Ett exempel på detta är Nano-PCM. Resultatet visar även att latent värmelagring idag används av företag som affärsidé för olika tillämpningar. Från resultatet går det att dra slutsatsen att latent värmelagring används idag men att det krävs ytterligare forskning för att tekniken ska kunna konkurrera med andra värmelagringsmetoder. / Today, the world faces a number of environmental-related problems. One of these and perhaps most discussed is how emissions of greenhouse gases slowly but surely raise the planet’s average temperature. Sustainable development is a concept that drives the discussion forward and tells us what we need to do and how we need to change to solve the problems. Greenhouse gases and their threats to the climate are strongly related to energy. Renewable sources of energy could be a partial solution to the problem, but they require energy storage of different forms to replace their fossil competitors. Thermal energy storage is a way of storing energy and can be divided into three different groups. These are sensible, latent and thermochemical heat storage. The purpose of this literature study was to map different applications of latent heat storage that can contribute to a more sustainable society in the future. The result shows that there are many different types of phase changing materials (PCMs). Depending on the temperature at which heat is to be stored, different PCMs are used. PCMs can be used for latent heat storage in many different areas. Buildings are one of these areas where PCMs can be used to cool and heat spaces either through integration into ventilation systems or in the building materials itself. Latent heat storage can also be used in thermal solar power plants. Latent heat storage has recently received great attention thanks to PCMs ability to store heat in small volumes and under constant temperature. However, the technology is experiencing problems in the heat transfer, such is the case in the storage of thermal solar energy. Research is therefore ongoing to generally increase PCMs thermal properties. An example of this is Nano-PCM. The result also shows that latent heat storage today is used by companies as a business concept for various applications. From the result, it can be concluded that latent heat storage is used today, but that further research is required for the technology to compete with other heat storage methods.

Irreversible electroporation has recently emerged as an effective focal ablation technique. When performed clinically, the procedure involves placing electrodes into, or around, a target tissue and applying a series of short, but intense, pulsed electric fields. Oftentimes, patient specific treatment plans are employed to guide procedures by merging medical imaging with algorithms for determining the electric field distribution in the tissue. The electric field dictates treatment outcomes by increasing a cell's transmembrane potential to levels where it becomes energetically favorable for the membrane to shift to a state of enhanced permeability. If the membrane remains permeabilized long enough to disrupt homeostasis, cells eventually die. By utilizing this phenomenon, irreversible electroporation has had success in killing cancer cells and treating localized tumors. Additionally, if the pulse parameters are chosen to limit Joule heating, irreversible electroporation can be performed safely on surgically inoperable tumors located next to major blood vessels and nerves. As with all technologies, there is room for improvement. One drawback associated with therapeutic irreversible electroporation is that patients must be temporarily paralyzed and maintained under general anesthesia to prevent intense muscle contractions occurring in response to pulsing. The muscle contractions may be painful and can dislodge the electrodes. To overcome this limitation, we have developed a system capable of achieving non-thermal irreversible electroporation without causing muscle contractions. This progress is the main focus of this dissertation. We describe the theoretical basis for how this new system utilizes alterations in pulse polarity and duration to induce electroporation with little associated excitation of muscle and nerves. Additionally, the system is shown to have the theoretical potential to improve lesion predictability, especially in regions containing multiple tissue types. We perform experiments on three-dimensional in vitro tumor constructs and in vivo on healthy rat brain tissue and implanted tumors in mice. The tumor constructs offer a new way to rapidly characterize the cellular response and optimize pulse parameters, and the tests conducted on live tissue confirm the ability of this new ablation system to be used without general anesthesia and a neuromuscular blockade. Situations can arise in which it is challenging to design an electroporation protocol that simultaneously covers the targeted tissue with a sufficient electric field and avoids unwanted thermal effects. For instance, thermal damage can occur unintentionally if the applied voltage or number of pulses are raised to ablate a large volume in a single treatment. Additionally, the new system for inducing ablation without muscle contractions actually requires an elevated electric field. To ensure that these procedures can continue to be performed safely next to major blood vessels and nerves, we have developed new electrode devices that absorb heat out of the tissue during treatment. These devices incorporate phase change materials that, in the past, have been reserved for industrial applications. We describe an experimentally validated numerical model of tissue electroporation with phase change electrodes that illustrates their ability to reduce the probability for thermal damage. Additionally, a parametric study is conducted on various electrode properties to narrow in on the ideal design. / Ph. D.

Orientador: Kamal Abdel Radi Ismail / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-08-11T03:46:08Z (GMT). No. of bitstreams: 1 Moraes_RaykleisonIgordosReis_M.pdf: 1558122 bytes, checksum: e287784c470caf116d151f9f9cc61f17 (MD5) Previous issue date: 2008 / Resumo: O presente trabalho procurou obter de uma forma detalhada o processo de formação de gelo no interior de cápsulas esféricas e geometrias alternativas recicláveis para o armazenamento de energia térmica, utilizando água e água-polietilenoglicol como PCM. Foi montada uma bancada de teste composta de um tanque de resfriamento e controlada com precisão de. As cápsulas utilizadas nos testes foram incrementadas com termopares tipo T, calibrados e localizados no centro da cápsula para investigar o efeito da solidificação do material. A faixa de variação de temperatura para os ensaios foram de - 25 à 5 ºC. Em seguida é apresentado um modelo matemático transiente em coordenadas esféricas e simulado usando a aproximação por diferenças finitas com o esquema da grade móvel. Os resultados experimentais são discutidos e as variáveis pesquisadas incluíram alguns parâmetros tais como: tempo de solidificação, temperatura do fluido de trabalho, concentração de polietilenoglicol, material da cápsula, velocidade, posição da frente de solidificação e o tamanho da cápsula no processo térmico de solidificação. O modelamento, junto com os resulta- dos experimentais forneceram parâmetros para construção de um armazenador modular para fins residenciais / Abstract: The present work looked for to get of a detailed form the similar process of icing in the interior of spherical capsules and geometrias for the storage of thermal energy being used water and water-polietilenoglicol as PCM. A composed group of benches of test of a controlled tank of cooling and with precision was mounted of ±1 ºC. Capsules used in the tests had been developed with thermocouples type T, calibrated and located in the center of the capsule to investigate the effect of the solidification of the material. The band of variation of temperature for the assays had been of 25 a 5 ºC. After that a transient in spherical coordinates is presented and simulated mathematic model using the approach for finite differences with the project of the movel scheme. The experimental results had been presented and argued some parameters such as: time for solidification, working fluid, concentration, capsule material , velocity and position of the solidification front and the size of the capsule in the thermal process of solidification. However, the together modeling with the experimental results had supplied parameters storing construction of a modular one for residential ends / Mestrado / Termica e Fluidos / Mestre em Engenharia Mecânica

The significant increase in energy requirements across the world, provides several opportunities for innovative methods to be developed to facilitate the storage and utilization of energy. The major energy demand is in the form of electrical energy for domestic as well as industrial sectors, a large part of which are the heating and cooling requirements. Appropriate utilization of thermal energy storage can effectively aid in reducing the electrical demand by storage and release of this thermal energy during peak hours. Thermal Energy Storage using Phase Change Materials (PCMs) is an attractive method of energy storage, with a wide variety of potential applications. Several configurations have been tested by researchers to develop energy storage devices with PCMs. The cycling of melting and solidification of PCMs results in storage and release of heat at a relatively small temperature difference. Design and deployment of these storage systems have certain challenges and considerations associated to them for instance, when used in buildings, PCMs should be non-toxic, non-corrosive, and others. In this thesis, we aim to provide models for designing Latent Thermal Energy Storage (LTES) devices with PCMs, based on their operating conditions, thermophysical properties of materials, and geometric parameters. The models are developed considering fluid dynamics and heat transfer involved in melting and solidification of PCMs. Parameters like inlet temperature and velocity, and volume of storage container are varied to determine the time taken for melting or solidification. For sizing and predicting performance of the storage devices we aim at presenting an analytical correlation, with time taken for melting as the variable defining the ‘charging/discharging time’ of storage device. Along with this, a transient model is developed to predict amount of PCM melted/solidified, along with rate of latent energy storage in defined time period intervals.

In this thesis, the possible usage of phase change materials in military shelters with the aim of decreasing the heating effect of the solar radiation is presented. In order to meet the rapidly growing demand for energy in military applications, a passive cooling technique, specifically, storing thermal energy with phase change materials is analyzed by using experimental approach. Not only different types of phase change materials but also different amounts of them are examined during the solar loading experiments. In order to simulate solar heat loading on prototype military shelters, solar radiation test or in other words sunshine test that is stated in military standard MIL

The thesis deals with the integration of phase change materials (PCMs) into building structures. The basic requirement is improved thermal stability during the summer season without using an air conditioner. This can be achieved by increasing the thermal storage capacity of the building structures. If the thermal capacity cannot be increased on the level of weight, phase change materials can be used. These materials are capable of storing latent heat and thus increasing the thermal storage capacity of the building. In the thesis the phase change materials were investigated in a thermal incubator by thermal analysis and, above all, in full-scale experiments using comparative measurements. The comparative measurements were carried out in two attic rooms at the Faculty of Civil Engineering, Brno University of Technology, where in one was used as a reference and the other for the experiment. Manufactured heat storage panels were installed in the experimental room. These panels are composed of a base plate; the capillary tubes placed on it are coated with modified plaster. The gypsum plaster is modified with micro-capsules paraffin for improving the thermal storage capacity. This system is connected to a thermal air-water pump, by which the storage panels can be additionally cooled or heated. In the experimental measurements, different operating modes were investigated and their effect on the indoor environment was evaluated. Thermal storage in PCMs dampens the temperature amplitude in the building during the summer season and, at the same time, allows the stored heat to be discharged during the night. Moreover, the time interval of withdrawing electric energy from the supply mains is much shorter than in the case of air conditioning. A conventional air conditioner must operate simultaneously with the thermal load, i.e. at the time of peak consumption of electric energy. Thanks to the set regimes, the installed system is capable of responding to external thermal condit

<p dir="ltr">Ice thermal energy storage (ITES) systems have long been an economic way to slash cooling costs in the commercial sector since the 1980s. An ITES system generates cooling in the formation of ice within a storage tank. This occurs during periods of the day when the cost of electricity is low, normally at night. This ice is then melted to absorb the energy within the conditioned space. While ITES systems have been prosperous in the commercial sector, they have yet to take root in the residential sector.</p><p dir="ltr">The U.S. Department of Energy (DoE) has published guidelines for TES. The DoE guidelines include providing a minimum of four hours of cooling, shifting 30-50% of a space’s cooling load to non-peak hours, minimizing the weight, volume, complexity, and cost of the system, creating a system than operates for over 10,000 cycles, enacting predictive control measures, and being modular to increase scale for larger single-family and multi-family homes [1]. The purpose of this research is to develop a model that meets these guidelines.</p><p dir="ltr">After extensive research in both experimental data, technical specifications, existing models, and best practices taken from the works of others a MATLAB model was generated. The modeled ITES system is comprised of a 1m diameter tank by 1m tall. Ice was selected as the PCM. A baseline model was constructed with parameters deemed to be ideal. This model generated an ITES system that can be charged in under four hours and is capable of providing a total of 22.18 kWh of cooling for a single-family home over a four-hour time period. This model was then validated with experimental data and found to have a root mean squared error of 0.0959 for the system state of charge. During the validation both the experimental and model estimation for the water/ice within the tank converged at the HTF supply temperature of -5.2°C.</p><p dir="ltr">With the model established, a parametric analysis was conducted to learn how adjusting a few of the system parameters impact it. The first parameter, reducing the pipe radius, has the potential to lead to a 152.6-minute reduction in charge time. The second parameter, varying the heat transfer fluid (HTF) within the prescribed zone of 0.7 kg/s to 1.2 kg/s, experienced a 4.8-minute increase in charge time for the former and a decrease in charge time by 5.4 minutes for the latter. The third parameter, increasing the pipe spacing and consequently increasing the ratio of mass of water to mass of HTF, yielded a negative impact. A 7.1mm increase in pipe spacing produced a 16.6-minute increase in charge time. Meanwhile, a 14.2mm increase in pipe spacing created a 93.3-minute increase in charge time and exceeded the charging time limit of five hours.</p><p dir="ltr">This functioning model establishes the foundation of creating a residential-scale ITES system. The adjustability and scalability of the code enable it to be modified to user specifications. Thus, allowing for various prototypes to be generated based on it. The model also lays the groundwork to synthesize a code containing an ITES system and a heat pump operating as one. This will aid in the understanding of residential-scale ITES systems and their energy effects.</p>

This thesis is a part of the research work for Azelio TES.POD (Thermal energy storage. power on demand). It is a patented thermal energy storage system developed by Swedish cleantech company Azelio AB. The objective of this thesis work to find an alternative charging technology system that can be validated to be efficient and safe in operation for the charging of TES.POD. Induction heating technology is chosen as an alternative charging solution. Derived design steps to implement induction heater as a charging unit then selection of PCM container compatible with induction heater. Later simulating to evaluate total flux path in Finite Element Method Magnetics (FEMM) simulation tool which proposes the electrical results. The electrical performance of the induction heater indicates almost 9% higher electrical losses than the charging mechanism of the existing TES.POD design. However, from a safety standpoint, the alternate charging approach appears to be safer in operation than the existing system. Additionally, it reflects better intuitiveness from a manufacturing viewpoint.

Das Kraftstoffdampfmanagement in PKW dient der Reduzierung von Kraftstoffdampfemissionen und umfasst deren Entstehung im Tank, sowie Verarbeitung im Adsorber. Im Hinblick auf eine effektive Emissionsreduzierung erfolgt in dieser Arbeit die Entwicklung eines multiphysikalischen Berechnungsmodells, das die Erschließung der Kraftstoffdampfmenge im Tank sowie der Adsorbercharakteristik erlaubt. Gleichzeitig wird eine Methode zur thermischen Adsorberoptimierung durch Phasenwechselmaterialien (PCM) vorgestellt. Letztere nutzen für ihren fest/flüssig-Phasenübergang im Adsorber umgesetzte Prozesswärmen und können damit dessen Arbeitskapazität erhöhen. Die Modellierung der tankinternen Kraftstoffdampfproduktion erfolgt basierend auf der Berechnung des Dampf-Flüssigkeit-Gleichgewichtes von Mehrstoffsystemen mit realen Fluidmodellen. Zudem wird eine thermodynamische Datenbank erstellt, die es erlaubt, reale ottomotorische Kraftstoffgemische durch Modellkraftstoffsysteme mit deutlich reduzierter Komponentenanzahl abzubilden. Es wird ein detailliertes nicht-isothermes 2D-rotationssymmetrisches Mehrkammeradsorbermodell für kompressible Fluidgemische entwickelt, das die temperaturabhängige Polyschichtsorption in porösen Festbetten wiedergibt und direkt über transiente Randbedingungen mit der instationären Kraftstoffverdampfung im Tank gekoppelt ist. Darin berücksichtigt sind unter anderem anisotrope Wärme- und Stofftransportprozesse innerhalb der Festbetten sowie Randeffekte infolge einer nicht-linearen Porositätsverteilung. Zwischen den Sorptionskammern wird eine dünnwandige Aluminium-Trennwand aus makroverkapseltem PCM integriert, die zur Temperierung der umliegenden Festbetten dient. Hierzu wird auf Basis einer diskontinuierlichen Form der Enthalpy-Porosity-Methode der nicht-isotherme Phasenwechsel im Latentwärmespeicher unter Berücksichtigung der konvektiven Schmelzbewegung modelliert und in Ort und Zeit mit dem Adsorbermodell gekoppelt. Das daraus resultierende partielle Differenzialgleichungssystem wird örtlich über eine Finite-Elemente-Methode und bzgl. der Zeit in Form eines impliziten Mehrschrittverfahrens diskretisiert. Die entsprechende numerische Lösung erfolgt mit Hilfe eines automatisch gedämpften Newton-Verfahrens. Anhand des Adsorbermodells lässt sich der Einfluss von Randeffekten auf das Ad- und Desorptionsverhalten erschließen, die eine Abhängigkeit von der Festbettgeometrie und des temperaturabhängigen Beladungszustandes zeigen. Diese Sorptionsprozesse werden durch experimentelle Versuchs- reihen an einem hierzu entwickelten Adsorber-Prototyp validiert. Als Ergebnis der numerischen Simulation anwendungsrelevanter Prüfzyklen zur Adsorber-Typisierung resultiert durch den Einsatz von PCM eine Effizienzsteigerung in der Arbeitskapazität des Adsorbers von ca. 14 − 19 %. Zudem kann gezeigt werden, dass auch in Betriebszuständen ohne latenten Phasenwechsel im PCM infolge der konvektiven Bewegung der Schmelze die Sorptionsfähigkeit teilweise um mehr als 11 % ansteigt. Gleichzeitig ist im Vergleich zu der einfachen Vergrößerung des chemischen Sorptionsspeichers der Effekt einer Festbetttemperierung durch PCM partiell bis zu 10 % höher. Durch das einfache Substituieren der klassischen Kunststofftrennwände zwischen den Festbetten durch dünnwandige PCM-Kammern wird die Kraftstoffdampfnachbehandlung ohne relevante Gewichts- und Volumenzunahme des Adsorbers bedeutend verbessert.

Das Kraftstoffdampfmanagement in PKW dient der Reduzierung von Kraftstoffdampfemissionen und umfasst deren Entstehung im Tank, sowie Verarbeitung im Adsorber. Im Hinblick auf eine effektive Emissionsreduzierung erfolgt in dieser Arbeit die Entwicklung eines multiphysikalischen Berechnungsmodells, das die Erschließung der Kraftstoffdampfmenge im Tank sowie der Adsorbercharakteristik erlaubt. Gleichzeitig wird eine Methode zur thermischen Adsorberoptimierung durch Phasenwechselmaterialien (PCM) vorgestellt. Letztere nutzen für ihren fest/flüssig-Phasenübergang im Adsorber umgesetzte Prozesswärmen und können damit dessen Arbeitskapazität erhöhen. Die Modellierung der tankinternen Kraftstoffdampfproduktion erfolgt basierend auf der Berechnung des Dampf-Flüssigkeit-Gleichgewichtes von Mehrstoffsystemen mit realen Fluidmodellen. Zudem wird eine thermodynamische Datenbank erstellt, die es erlaubt, reale ottomotorische Kraftstoffgemische durch Modellkraftstoffsysteme mit deutlich reduzierter Komponentenanzahl abzubilden. Es wird ein detailliertes nicht-isothermes 2D-rotationssymmetrisches Mehrkammeradsorbermodell für kompressible Fluidgemische entwickelt, das die temperaturabhängige Polyschichtsorption in porösen Festbetten wiedergibt und direkt über transiente Randbedingungen mit der instationären Kraftstoffverdampfung im Tank gekoppelt ist. Darin berücksichtigt sind unter anderem anisotrope Wärme- und Stofftransportprozesse innerhalb der Festbetten sowie Randeffekte infolge einer nicht-linearen Porositätsverteilung. Zwischen den Sorptionskammern wird eine dünnwandige Aluminium-Trennwand aus makroverkapseltem PCM integriert, die zur Temperierung der umliegenden Festbetten dient. Hierzu wird auf Basis einer diskontinuierlichen Form der Enthalpy-Porosity-Methode der nicht-isotherme Phasenwechsel im Latentwärmespeicher unter Berücksichtigung der konvektiven Schmelzbewegung modelliert und in Ort und Zeit mit dem Adsorbermodell gekoppelt. Das daraus resultierende partielle Differenzialgleichungssystem wird örtlich über eine Finite-Elemente-Methode und bzgl. der Zeit in Form eines impliziten Mehrschrittverfahrens diskretisiert. Die entsprechende numerische Lösung erfolgt mit Hilfe eines automatisch gedämpften Newton-Verfahrens. Anhand des Adsorbermodells lässt sich der Einfluss von Randeffekten auf das Ad- und Desorptionsverhalten erschließen, die eine Abhängigkeit von der Festbettgeometrie und des temperaturabhängigen Beladungszustandes zeigen. Diese Sorptionsprozesse werden durch experimentelle Versuchs- reihen an einem hierzu entwickelten Adsorber-Prototyp validiert. Als Ergebnis der numerischen Simulation anwendungsrelevanter Prüfzyklen zur Adsorber-Typisierung resultiert durch den Einsatz von PCM eine Effizienzsteigerung in der Arbeitskapazität des Adsorbers von ca. 14 − 19 %. Zudem kann gezeigt werden, dass auch in Betriebszuständen ohne latenten Phasenwechsel im PCM infolge der konvektiven Bewegung der Schmelze die Sorptionsfähigkeit teilweise um mehr als 11 % ansteigt. Gleichzeitig ist im Vergleich zu der einfachen Vergrößerung des chemischen Sorptionsspeichers der Effekt einer Festbetttemperierung durch PCM partiell bis zu 10 % höher. Durch das einfache Substituieren der klassischen Kunststofftrennwände zwischen den Festbetten durch dünnwandige PCM-Kammern wird die Kraftstoffdampfnachbehandlung ohne relevante Gewichts- und Volumenzunahme des Adsorbers bedeutend verbessert.