The Livingstone Range anticlinorium (LRA) is a long (>65 km) narrow (<5 km) structural culmination that coincides with a major hanging-wall ramp across which the Livingstone thrust cuts ~1000 m up-section eastward from a regional décollement in the upper part of Devonian Palliser Formation to another regional décollement within Jurassic Fernie Formation. The presence of Precambrian basement fluids prior to thrusting and folding is recorded in the LRA by deformed jasper+/-fluorite+/-sphalerite veins, and adjacent haloes of altered dolomitic host rock with high 87Sr/86Sr ratios (0.7094 to 0.7100) relative to most host rocks. Basement fluids are a possible source for anomalously radiogenic strontium that occurs in the diagenetically altered Paleozoic carbonate rocks in the LRA and throughout the Western Canada Sedimentary Basin, but underlying thick shale strata such as the Exshaw Formation are also a possible source. The earliest stages of thrusting deformation involved the development of distinctive chevron-style, flexural-slip thrust-propagation folds that have conspicuous blind thrust faults along their hinge zones. The hinge-zone thrust system of the Centre Peak anticline consists of a series of stacked detachment thrusts, each of which emerges from a different zone of interbed slip in the backlimb of the anticline and deflects the hinge zone eastward. Each successively higher detachment thrust dies out in the hinge zone at approximately the same stratigraphic level at which an overlying detachment thrust fault emerges from a bedding detachment zone in the backlimb. Fluid flow during thrust-propagation folding is recorded by dolomite+/-calcite veins with isotopic compositions that are similar to those of host rocks. Fluid flow occurred along faults related to thrust-propagation folding, and also along many tear faults and larger thrust faults. Veins in these fault zones have slightly higher 87Sr/86Sr ratios relative to adjacent host rocks and are interpreted to have formed from a mixture of formation fluids and hotter basement fluids in a rock-dominated system. Oxygen isotope thermometry of four syn-folding veins indicates they precipitated at anomalously high temperatures (>250°C). The youngest episode of fluid flow along thrust faults and tear faults is recorded by calcite veins with very low δ18O values (-18 to -9‰ PDB), which are interpreted to have precipitated along faults that were active while the LRA was being transported eastward and elevated by underlying thrust faults, and cooled by infiltrating meteoric water. The conduits along which significant meteoric fluid circulation occurred are marked by visibly altered host rocks that have anomalously low δ18O values and slightly lower δ13C values relative to most host rocks. Rapid cooling due to deep infiltration of meteoric water into the shallow brittle surface of the deforming earth is almost certainly not restricted to thrust and fold belts, nor is its thermal effect necessarily restricted to the upper few kilometers. This model for fluid flow has significant implications for predicting thermal conditions in deep metamorphic rocks that lie beneath the brittle crust, the most obvious effect being to push down the brittle/ductile transition zone, which would enhance even deeper meteoric fluid circulation and cause the deflection of underlying isotherms. / Thesis (Ph.D, Geological Sciences & Geological Engineering) -- Queen's University, 2007-11-01 15:25:23.854

This study aims to investigate the stable isotopic characteristics of meteoric and ground waters, and to obtain spring flow rates in the Coronet Peak Skifield, Queenstown. Spring flows were gathered during the winters of 2008 and 2009, whilst water samples were collected from precipitation, springs, reservoirs and groundwater during July, August and September 2009. The spring flows were examined and the water samples were analysed for δD and δ¹⁸O values using the CF-IRMS at the University of Canterbury. A database has been gathered from all natural water sources to give a local meteoric water line (LMWL) for the area that fits clearly with the global meteoric water line. The LMWL has an R2 value of 0.97 and the equation is δD = 8 δ¹⁸O +10. An understanding of evaporation as it occurs in the water storage reservoirs of the mountain has also been obtained, giving rise to a local evaporation line. The stable isotope ratios of hydrogen and oxygen within precipitation have been used extensively to characterise the hydrogeology with emphasis on altitude effects, storm duration and variations in storm track trajectories. Of these three phenomena, it is the trajectory of the storm track that is best shown to affect the composition of precipitation in this area. The air masses advancing on the study area from the north being more depleted in their isotopic signatures, with approximate δD and δ¹⁸O values of –130‰ and -16‰. The air masses approaching from a southerly direction are more positive in comparison, having approximate δD and δ¹⁸O values of –65‰ and -9‰. The altitude effect in precipitation on the Skifield has led to an altitude gradient being found: for every 100-metre increase in elevation, δ¹⁸O decreases by 0.71‰. However there were some inconsistencies. The influence on precipitation from storm duration is also inconsistent in this area. The R2 values range from 0.14 to 0.99, but this method does not take into account the position of the individual samples. Some samples did not plot in the expected order that is governed by a decrease in stable isotopic ratios with storm duration. The stable isotopic compositions within meteoric waters can be used as tracers of water sources. The isotope date of the springs also infers an altitude effect. The springs gave an altitude gradient of a decrease –0.43‰ with each 100-metre increase in elevation. This indicates that precipitation is the main influence on the stable isotopic composition of the springs in this area. However, data shows differences between the current precipitation and the groundwater compositions, indicating that present precipitation is not flowing from the springs, past precipitation is. The stable isotopic compositions of the springs have also been correlated with groundwater isotope data and suggest the sources of the springs are groundwater dominated. Although some springs compositions indicate an influence by current precipitation. This is shown by a negative stable isotopic trend in the precipitation sampled in August, corresponding with a relatively negative stable isotopic composition in some springs during this time period. Monitoring of spring flows on Coronet Peak have led to an average winter flow rate being established of 26.5 litres per second. Spring flow rates range from 0.25 – 6 litres per second. This monitoring has indicated the springs of the greatest yield that are not already being utilised on the Skifield. It is these springs that should be further investigated as to whether they would provide a sustainable source of water on the mountain. This locally derived water would then be utilised for the purposes of artificial snowmaking and other activities and amenities that are currently operated by NZ Ski on Coronet Peak.

There are four distinguishable groundwater systems in the Boise area, Idaho, U.S.A., identified as modern batholith, thermal batholith, Boise frontal fault, and Nampa-Caldwell systems (Figure 1). Modern batholith and thermal batholith groundwaters are located in Tertiary to Cretaceous aged granites and granodiorites of the Atlanta lobe of the Idaho Batholith. The frontal fault system near Boise, ID defines the southeastern edge of the Idaho Batholith, and divides the batholith from the western Snake River Plain. The Nampa-Caldwell system is in the volcanic, fluvial and pluvial sediments of the western Snake River Plain. Groundwater ages for these systems are modern, 5-15 ka, 10-20 ka, and 20-40 ka respectively. Local meteoric water lines (LMWL) using the delta 2H and delta 18O composition of the groundwater were defined for each system using linear regression techniques. LMWL had variable and defined single slopes of 6.94 and 8. Deuterium excess values (d) were found for each system for each linear regression method. Relative differences of the deuterium excess value assuming the two single slope methods were similar. Changes in moisture source humidity and temperature, and Boise area recharge temperatures calculated from stable isotopic data and the deuterium excess factor agree with other published data. At the moisture source there was a 9% humidity increase and a 7-6 °C decrease of sea surface temperature between the present and the last glacial maximum (LGM). The local temperature decreased 4-5 °C from the present to the LGM for the Boise area.

From the Proceedings of the 1971 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 22-23, 1971, Tempe, Arizona / The distribution of groundwater having temperature considered to be higher than normal is examined on a regional basis. Much of the work was done by searching the literature and examining USGS records. The geographic distribution of the thermal waters is reviewed; relation to structure, geothermal gradients and water quality are discussed. Current and past utilization of thermal water from both springs and wells of the state has never been very extensive. Conclusions were: (1) the occurrence of thermal water in the state is closely allied to major structural elements, especially major fault zones; (2) geothermal gradients vary widely from place to place; (3) the extent of 'bedrock' influence on thermal water occurrence is difficult to ascertain; (4) most thermal water in southern Arizona is derived from meteoric water.

Cette thèse est centrée sur la ceinture orogénique Attico-Cycladique formée durant l'orogénèse Alpine. Par une approche multi-méthodes et multi-échelles combinant géologie structurale, pétrographie, thermobarométrie des assemblages minéraux, géochimie élémentaire et isotopique, et données PVTX des inclusions fluides associées, ce travail vise à caractériser et comprendre les relations entre circulations fluides, interactions fluides/roches, déformation, et mobilisation-transport-dépôt des métaux. Les marbres et schistes de la péninsule du Lavrion et de l'île d'Eubée témoignent d'une évolution orogénique complexe marquée par une phase d'enfouissement à l'Eocène suivie par deux phases d'exhumation successives syn-et post-orogéniques. Les minéralisations de type Cu-Pb-Zn-Fe-Ag de la région du Lavrion sont synchrones de l’activation du détachement post-orogénique et de la mise en place de plutons de granodiorite. Leurs positions structurales témoignent d’un piégeage depuis un régime de déformation ductile jusqu'à fragile. Les minéralisations mises en place durant le régime de déformation ductile à ductile-fragile (skarn et remplacement de carbonate) sont associées à la décarbonatation des niveaux de marbres et à la circulation des fluides magmatiques. L'exhumation progressive de la racine orogénique se traduit par la transition des roches depuis une déformation ductile vers un régime fragile associé à l’ouverture du système aux fluides de surface et notamment aux fluides météoriques. Cette circulation est responsable d’une remobilisation des métaux des minéralisations primaires permettant alors une seconde phase de précipitation dans un régime cassant (veines épithermales) / This thesis is focused on the Attico-Cycladic orogenic wedge formed during the Alpine orogeny. From a multi-method and multi-scale approach using structural geology, petrography, mineral thermobarometry, element and isotope geochemistry, and PVTX data of associated fluid inclusions, this study deciphers the relationships between fluid circulation, fluid-rock interactions and mobilisation-transport-deposits of metals. Marbles and schists from the Evia Island and the Lavrion peninsula testify to a complex orogenic history marked by an Eocene burial phase followed by syn- and post-orogenic exhumation. Cu-Pb-Zn-Fe-Ag mineralisations from the Lavrion area are synchronous with the formation of the low-angle post-orogenic detachment and the emplacement of granodioritic magmas. The structural position of the deposits attests of an emplacement during ductile to brittle deformation conditions. Deposits associated with ductile to ductile-brittle deformation (skarn, carbonate replacement) are related to a marble decarbonation and magmatic fluid circulation. The progressive exhumation of the orogenic wedge allows the transition toward brittle conditions and opens the system to surficial meteoritic fluids. This meteoritic fluid circulation is responsible to remobilisation of metals from primary deposits allowing thus a second phase of deposition in a pure brittle deformation (epithermal veins)

PhDENV / Department of Hydrology and Water Resources / Geothermal springs are natural geological phenomena that occur throughout the world. South Africa is endowed with several springs of this nature. Thirty-one percent of all geothermal springs in the country are found in Limpopo province. The springs are classified according to the residing mountain: Soutpansberg, Waterberg and Drakensberg. This study focused on the geothermal springs within the Soutpansberg region; that is, Mphephu, Siloam, Sagole and Tshipise. The study was aimed at elucidating on the isotopic signatures and trace metals concentrations from the geothermal springs to their environmental media in Soutpansberg region. This study also assessed the interconnectivity of the isotopic signatures within the ecosystem and evaluated the potential human health risks associated with trace metals from geothermal springs and surrounding soils in the study areas. Geothermal springs and boreholes were sampled for a period of twelve months (May 2016 – May, 2017) to accommodate two major seasons in the study areas. The surrounding soils were sampled vertically from a depth of 10 cm to 50 cm for trace metals and isotopic compositions. Three different plants were sampled at each of the study sites, namely, Amarula tree, Guava tree and Mango tree at Siloam; Acacia tree, Fig tree and Amarula tree at Mphephu; Amarula tree, Lowveld mangosteen and Leadwood tree at Sagole; Sausage tree, Amarula tree and Acacia tree at Tshipise. To achieve the objectives, the physicochemical, geochemical and isotopic compositions of the geothermal springs, boreholes, soils and vegetation were analysed using ion chromatography (IC) (Dionex Model DX 500), inductively coupled plasma-mass spectrometer (ICP-MS), HTP-Elemental analyzer, Liquid water isotope analyzer (LWIA-45-EP) and Liquid scintillation analyzer. The temperature, electrical conductivity (EC), pH and total dissolved solid (TDS) of the geothermal springs and boreholes samples were measeured in situ and in the laboratory. Trace metals analysed in geothermal springs, boreholes, soil and vegetation include Beryllium (Be), Chromium (Cr), Manganese (Mn), Cobalt (Co), Nickel (Ni), Copper (Cu), Arsenic (As), Selenium (Se), Cadmium (Cd), Antimony (Sb), Barium (Ba), Vanadium (V), Zinc (Zn), and Mercury (Hg). vii | Isotopic signatures and trace metals in geothermal springs and their environmental media within Soutpansberg Results obtained from this study in the studied geothermal springs and boreholes were classified according to their temperature as hot and scalding; except for tepid boreholes. This study has provided comprehensive physicochemical, geochemical and isotopic compositions of the geothermal springs within the Soutpansberg region (Siloam, Mphephu, Sagole and Tshipise). The local meteoric line (δD = 7.56δ18O + 10.64) was generated from rainwater in Vhembe district. This is a crucial component for depicting the source and flow path of the geothermal springs/boreholes; and could be used for future isotopic hydrological studies within the locality. Rain formation processes within Soutpansberg occurred under isotopic equilibrium conditions with minor evaporation effect during rainfall. The δD and δ18O values of the geothermal spring water/boreholes confirm that the waters are of meteoric origin, which implies that rainfall is the fundamental component of these groundwaters because they were derived from the infiltration of rainwater, with significant contribution of another type of water in the deeper part of the aquifer. Na-Cl and Na-HCO3 were established as the water types, which are typical of marine and deep groundwaters which are influenced by the ion - exchange process. The reservoir/aquifer temperature of these springs ranges between 95 – 185°C (Na-K geothermometer), which implies most of the waters are mature water (not native). Hence, geothermal springs water is a mixture of the rainwater and salt water. Radiocarbon values of the geothermal springs ranged from 2700 to 7350 BP, this implies that they are submodern and a mixture of submodern and modern waters. Tritium relative age also corroborates with radiocarbon age, that is the groundwaters were recharged before and after 1952. This gives an indication that the rainfall contributes to the geothermal springs recharge. Various radiocarbon correction models were employed and constrained by tritium relative age. Ingerson and Pearson, Eichinger and Fontes and Garnier correction models have been shown to be the most appropriate models for radiocarbon correction of groundwater in this semi-arid region. Although, geothermal springs water and boreholes are not fit for drinking due to high fluoride content, they could be used for the following: domestic uses (drinking exclusive) due to its softness, direct heating in refrigeration, green-housing, spa, therapeutic uses, aquaculture, sericulture, concrete curing, coal washing and power generation. In contrast with mentioned uses, viii | Isotopic signatures and trace metals in geothermal springs and their environmental media within Soutpansberg the studied geothermal springs are currently used for domestic purposes (drinking inclusive), limited irrigation and spa (swimming and relaxation). This is an eco-hydrological study that shows the interconnectivity of isotopic signatures among water (rainwater, geothermal springs and boreholes), soils and vegetation. The soil-water reflects the rainwater/geothermal springs water in isotopic composition, which is more depleted as a result of isotopic fractionation in soil. δD values of soil-water increase, whereas δ13C values in soil-water decrease with the soil depth at all sites. Two equations connecting δD and δ13C in soil-water were deduced per season for soil-water; δ13C = 0.0812δD - 10.657 in winter; δ13C = -0.0278δD - 21.945 for summer. δ13C in soil-water is induced by Crassulacean Acid Metabolism (CAM) (mixture of C3 and C4 photosynthetic cycles) with a stronger C4 trend, which corroborates with δ13C of the geothermal springs. From literature, Amarula and Acacia trees have been documented for isotopic compositions, while this study has given additional information on other plants including Lowveld, Leadwood, Sausage, Fig, Guava and Mango trees. These plants are categorised as C3, C4 and CAM plants. C3 plants include Amarula, Lowveld and Leadwood trees; C4 plants include Acacia and Sausage trees; and CAM plants include Fig, Guava and Mango trees. This study shows that with CAM soils, there is a possibility of having either C3, C4 or CAM vegetation. This finding has shown that the δD and δ13C isotopes in water, soil and vegetation are interrelated, which has been statistically justified. This study has shown the potential human health risks associated with trace metals concentrations from geothermal springs and their surrounding soils. From the geothermal spring’s water, it was found that As, Cr and Cd were the highest contributors to the cancer risk with children having a higher risk than adults. Whereas in soils, it was found that Cr, As and Co were the highest contributors to the cancer risk in the studied communities. Therefore, the cancer risk is high in the general population; that is 1 in 72-162 individuals in children and 1 in 7-107 individuals for adults. The ingestion route seems to be the major contributor to excess lifetime cancer risk followed by the dermal pathway. Therefore, proper monitoring and control measures to protect human health, particularly in children, should be implemented for safety. The study also explored the use of surrounding trees ix | Isotopic signatures and trace metals in geothermal springs and their environmental media within Soutpansberg for phytoremediation and found their uptake capacity to be high, thus, they could be used as bio-indicators to assess the level of contamination of trace metals in the soil. In conclusion, this study has eludicated on the isotopic signatures and trace metals concentrations from the geothermal springs and their surrounding soils and vegetation within Soutpansberg. This study has contributed towards the advancement and enhancement of the existing knowledge of the geothermal systems, such that water resource management could be applied successfully in the respective areas with similar characteristics for the benefit of the local communities and society at large. Hence, this study recommends that proper monitoring and control measures need to be put in place to protect human health, especially in children. / NRF