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The application of membrane bioreactors (MBRs) to wastewater treatment is increasing due to their ability to operate at high biomass concentrations and to deliver effluents of high quality. The major challenges associated with the application of MBRs is fouling which can shorten the useful life of the membrane, increase in the amount of energy consumed, and the cost for membrane cleaning. The main reasons for fouling are the deposition of solids as a cake layer, pore plugging by colloidal particles, adsorption of soluble compounds and biofouling. Fouling is a particular problem for activated sludge membrane bioreactors (AS-MBRs) since this process deals with liquors having a high concentration of total solids as well as dissolved compounds such as extracellular polymeric substances (EPS). The combination of a moving bed biofilm reactor and a membrane reactor (MBBR-MR) has significant potential. It may be considered as a compact wastewater treatment process which can compensate for the drawbacks of AS-MBRs. Readily biodegradable COD is removed in the MBBR while particulate matter is separated by the membrane. To further reduce the membrane fouling the effects of adding an intermediate coagulation stage was investigated critically on membrane fouling. The present study includes an overall assessment of the performance of a combined MBBR-MR system, based on the chemical oxygen demand (COD) removal efficiency and membrane fouling mechanism. The required test runs were conducted using pilot-scale MBBR and ultra filtration membrane. The pilot MBBR had a working volume of 1.8 m3 with a 60% carrier fill fraction. The MBBR was operated with loading rate of 78 ± 21 g/m2/d (HRT of 4 h). The ultra-filtration was spiral wound and composed of polyethersulfone (PES) with a pore size of 0.03 microns. The MBBR feed was obtained from a final treated wastewater effluent in a food processing plant located in SW Ontario. In this research, ferric chloride was also employed as a coagulant and influences of different coagulant doses and permeate fluxes on membrane fouling were studied. Based on the experimental results, it was found that the combination of MBBR with membrane filtration can produce a constant high quality permeate that is appropriate for water reuse purposes. The composition analysis of permeate showed that the stream is free of suspended solids and the average COD turns to 75 ± 25 mg/l. In addition, the MBBR had a SCOD removal of 76% ± 7% which is considered as a reasonable efficiency for a single reactor. Operating the membrane without adding coagulant caused rapid fouling in a short time period and the Trans Membrane Pressure (TMP) reached the maximum allowable pressure of 10 psi. However, addition of coagulant was found to decrease the fouling of the membrane as well as increasing the filtration time. The extent of the pre-coagulation effect on membrane fouling was found to strongly depend on the dosage of the coagulant and the MBBR effluent characteristics. A coagulant dose of 400 mg/l with a permeate flux of 7.6 LMH performed the best at reducing membrane fouling. Colloidal fouling was found to be a significant fouling mechanism at low coagulant dose (e.g. 200 mg/l), while cake formation appeared to be mainly responsible for fouling at higher coagulant doses. Permeate flux was found to have a significant effect on the fouling of the membrane. The presence of colloidal matters at low fluxes and TSS at higher fluxes were responsible for fouling of the membrane by blocking the pores and formation of the cake layer on the membrane surface, respectively. Then later addition of Dissolved Air Flotation (DAF) inside the factory had a noticeable effect on wastewater characteristics and consequently on fouling of the membrane. A 22% and 31% improvement in TCOD and TSS in the wastewater was observed leading to reduction in the fouling.

The application of membrane bioreactors (MBRs) to wastewater treatment is increasing due to their ability to operate at high biomass concentrations and to deliver effluents of high quality. The major challenges associated with the application of MBRs is fouling which can shorten the useful life of the membrane, increase in the amount of energy consumed, and the cost for membrane cleaning. The main reasons for fouling are the deposition of solids as a cake layer, pore plugging by colloidal particles, adsorption of soluble compounds and biofouling. Fouling is a particular problem for activated sludge membrane bioreactors (AS-MBRs) since this process deals with liquors having a high concentration of total solids as well as dissolved compounds such as extracellular polymeric substances (EPS). The combination of a moving bed biofilm reactor and a membrane reactor (MBBR-MR) has significant potential. It may be considered as a compact wastewater treatment process which can compensate for the drawbacks of AS-MBRs. Readily biodegradable COD is removed in the MBBR while particulate matter is separated by the membrane. To further reduce the membrane fouling the effects of adding an intermediate coagulation stage was investigated critically on membrane fouling. The present study includes an overall assessment of the performance of a combined MBBR-MR system, based on the chemical oxygen demand (COD) removal efficiency and membrane fouling mechanism. The required test runs were conducted using pilot-scale MBBR and ultra filtration membrane. The pilot MBBR had a working volume of 1.8 m3 with a 60% carrier fill fraction. The MBBR was operated with loading rate of 78 ± 21 g/m2/d (HRT of 4 h). The ultra-filtration was spiral wound and composed of polyethersulfone (PES) with a pore size of 0.03 microns. The MBBR feed was obtained from a final treated wastewater effluent in a food processing plant located in SW Ontario. In this research, ferric chloride was also employed as a coagulant and influences of different coagulant doses and permeate fluxes on membrane fouling were studied. Based on the experimental results, it was found that the combination of MBBR with membrane filtration can produce a constant high quality permeate that is appropriate for water reuse purposes. The composition analysis of permeate showed that the stream is free of suspended solids and the average COD turns to 75 ± 25 mg/l. In addition, the MBBR had a SCOD removal of 76% ± 7% which is considered as a reasonable efficiency for a single reactor. Operating the membrane without adding coagulant caused rapid fouling in a short time period and the Trans Membrane Pressure (TMP) reached the maximum allowable pressure of 10 psi. However, addition of coagulant was found to decrease the fouling of the membrane as well as increasing the filtration time. The extent of the pre-coagulation effect on membrane fouling was found to strongly depend on the dosage of the coagulant and the MBBR effluent characteristics. A coagulant dose of 400 mg/l with a permeate flux of 7.6 LMH performed the best at reducing membrane fouling. Colloidal fouling was found to be a significant fouling mechanism at low coagulant dose (e.g. 200 mg/l), while cake formation appeared to be mainly responsible for fouling at higher coagulant doses. Permeate flux was found to have a significant effect on the fouling of the membrane. The presence of colloidal matters at low fluxes and TSS at higher fluxes were responsible for fouling of the membrane by blocking the pores and formation of the cake layer on the membrane surface, respectively. Then later addition of Dissolved Air Flotation (DAF) inside the factory had a noticeable effect on wastewater characteristics and consequently on fouling of the membrane. A 22% and 31% improvement in TCOD and TSS in the wastewater was observed leading to reduction in the fouling.

The overall goal of the thesis was to develop and optimize the moving bed biofilm reactor technology under anaerobic conditions. The thesis work was divided into two different series of experiments. Hence, at first, the reactor start-up on synthetic substrate was evaluated and it was proven that the anaerobic moving bed biofilm reactor technology could successfully treat concentrated wastewater. Subsequently, a study on Fort Garry Brewery wastewater was conducted to optimize the process for a typical North American industrial wastewater. The aim was successfully achieved and a potential design to treat Fort Garry Brewery wastewater was developed. The anaerobic moving bed biofilm reactor was found to be capable in treating brewery wastewater with potential savings to the industry paying surcharges for discharging wastewater over the city sewer bylaw limits. / October 2016

Integrated aquaculture systems (IAS) are a type of recirculating aquaculture systems (RAS) where the wastewater is treated and returned to the fish tanks. The important difference between the two is that in an IAS, wastes from the aquaculture component are recovered as fertilizer to produce an agricultural product whereas in an RAS, waste organics, nutrients and solids are treated and discharged. A pilot marine IAS at Mote Aquaculture Research Park in Sarasota, FL was studied for this project. Water quality monitoring, measurements of fish health and growth rates of fish and plants were performed over a two-year period to determine the effectiveness of the system in producing fish and plant products and removing pollutants. The goal of this portion of the project was to develop, calibrate and evaluate a model of the system, to understand the nitrogen transformations within the Mote IAS and to investigate other potential configurations of the Mote IAS. The model was divided into the various compartments to simulate each stage of the system, which included fish tanks, a drum filter for solids removal, and moving bed bioreactor (MBBR) for nitrification and disinfection. A solids tank after the drum filter was used to store the drum filter effluent slurry, which was then divided between three treatment processes: a geotube, a sand filter followed by a plant bed, and a plant bed alone. Nitrogen species modeled were particulate organic nitrogen (PON), dissolved organic nitrogen (DON), ammonium and nitrate. Of the physical components of the IAS, models of the MBBR and the two plant raceways included physical, chemical and biological nitrogen transformation processes. The sand filter, solids tank and geotube models were simple mass balances, incorporating factional removals of each species based on the observed data. Other variables modeled included temperature, dissolved oxygen, volatile suspended solids and chemical oxygen demand concentrations. The model was built in a computer program, STELLATM, to simulate the Mote IAS. The model calibration involved experimental, literature and calibrated parameters. Parameters were adjusted until the model's output was a best fit to the observed data by minimizing the sum of the squared residuals. During the sensitivity analysis, two model parameters caused large variations in the model output. The denitrifier constant caused the most variation to the model's output followed by the denitrifier fraction of volatile suspended solids. Of the removal processes, denitrification was the largest nitrogen removal mechanism from the model, accounting for 59% and 55% of the nitrogen removed from the south and north plant raceways respectively. Plant and soil uptake represented only 0.2% of the overall nitrogen removal processes followed by 0.1% by sedimentation. Finally, the model was used to investigate other treatment designs if the Mote IAS was redesigned. The first option involved a geotube and one plant raceway in series to treat the solid waste while the second option did not have a geotube, but two plant raceways. The first option was the most effective at removing nitrogen while the second was as effective as the original system and would cost less.

Papermaking process require large amounts of energy and water; therefore, pulp and paper mills can be potentially very polluting. The wastewater resulting from the papermaking process must be carefully managed as it is very rich in dissolved organic matter and contain compounds that make it difficult to treat. MBBR technology emerged as a possibility to increase the treatment capacity and to make more compact treatment systems designed to remove high organic loads, since in addition to having biomass in suspension as the activated sludge process, also has biomass adhered to plastic supports. This research was commissioned by Stora Enso Kvarnsveden and emerged in need of a bioreactor modification due to reduction of the wastewater load after the closure of PM11 in 2013 and PM8 in 2017. An evaluation of the performance of bioreactors is necessary with possible results to only run one bioreactor in the future and save energy. For performance analysis, two weeks of measurements were performed, one with the two bioreactors running at the same time and one with only K150 reactor running, trying to simulate what happens if one of them is stopped. Analysis of the main operating parameters of the MBBR system were evaluated during this research. As result, it was recommended an action to remove the excess of adhered biomass and an increase of the filling rating to 50%, in order to optimize TOC reduction.

The separation of solids from biological wastewater treatment is an important step in the treatment process, as it has a significant impact on effluent water quality. The moving bed biofilm reactor (MBBR) technology is a proven upgrade or replacement wastewater treatment system for carbon and nitrogen removal. However, a challenge of this technology is the characteristics of the effluent solids that results in their poor settlement; with settling being the common method of solids removal. The main objective of this research is to understand and expand the current knowledge on the settling characteristics of MBBR produced solids and the parameters that influence them. In particular, in this dissertation, the impacts are studied of carrier types, biofilm thickness restraint design of carriers, and varying carbonaceous loading rates on MBBR performance, biofilm morphology, biofilm thickness, biofilm mass, biofilm density, biofilm detachment rate, solids production, particle size distribution (PSD) and particle settling velocity distribution (PSVD). With this aim, three MBBR reactors housing three different carrier types were operated with varying loading rates. In order to investigate the effect of carrier geometrical properties on the MBBR system, the conventional, cylindrically-shaped, flat AnoxK™ K5 carrier with protected voids was compared to two newly-designed, saddle-shaped Z-carriers with the fully exposed surface area. Moreover, the AnoxK™ Z-200 carrier was compared to the AnoxK™ Z-400 carrier to evaluate the biofilm thickness restraint design of these carriers, where the Z-200 carrier is designed for greater biofilm thickness-restraint. The Z-200 carrier is designed to limit the biofilm thickness to the level of 200 µm as opposed to 400 µm for the Z-400 carrier. Finally, to investigate the effects of varying carbonaceous loading rates on system removal performance, biofilm characteristics and solids characteristics, further analyses were performed at three different loading rates of 1.5 to 2.5 and 6.0 g-sBOD/m2·d in steady-state conditions. The PSD and the PSVD analyses were combined to relate these two properties. A settling velocity distribution analytical method, the ViCAs, was applied in combination with microscopy imaging and micro-flow imaging to investigate the relation of PSD and settling behaviour of MBBR produced particles. The obtained results have indicated that the carrier type significantly impacted the MBBR performance, biofilm, and particle characteristics. As such, the K5 carrier MBBR system demonstrated a statistically significantly higher carbonaceous removal rate and efficiency (3.8 ± 0.3 g-sBOD/m2·d and 59.9 ± 3.0% sBOD removal), higher biofilm thickness (281.1 ± 8.7 μm), higher biofilm mass per carrier (43.9 ± 1.0 mg), lower biofilm density (65.0 ± 1.5 kg/m3), lower biofilm detachment rate (1.7 ± 0.7 g-TSS/ m2·d) and hence lower solids production (0.7 ± 0.3 g-TSS/d) compared to the two Z-carriers. The Z-carriers' different shape exposes the biofilm to additional shear stress, which could explain why the Z-carriers have thinner and denser biofilm, resulting in higher solids production and lower system performance in comparison with K5. Moreover, the carrier type was also observed to impact the particle characteristics significantly. PSD analysis demonstrated a higher percentage of small particles in the Z-carrier system effluent and hence a significantly lower solids settling efficiency. Therefore, the solids produced in the K5 reactor have shown enhanced settling behaviour, consisting of larger particles with faster settling velocities compared to Z-carriers. This dissertation also investigated the effects of restraint biofilm thickness on MBBR performance by comparing the Z-200 biofilm thickness-restraint carrier to the Z-400 carrier. No significant difference was observed in removal efficiency, biofilm morphology, biofilm density, biofilm detachment rate, and solids production between the Z-200 to the Z-400 carriers. The PSD and the PSVD analyses did not illustrate any significant difference in the particles’ settling behaviour for these two biofilm thickness restraint carriers, indicating that the biofilm thickness-restraint carrier design was not a controlling factor in the settling potential of MBBR produced solids. Finally, this research studied the effect of varying loading rates and demonstrated a positive, strong linear correlation between the measured sBOD loading rate and the removal rate, indicating first-order BOD removal kinetics. The biofilm thickness, biofilm density and biofilm mass decreased when the surface area loading rate (SALR) was increased from 2.5 to 6.0 g-sBOD/m2·d. The solids retention time (SRT) was also shown to decrease by increasing the SALR, where the lowest SRT (1.7 ± 0.1 days) was observed at the highest SALR, with the highest cell viability (81.8 ± 1.7%). Significantly higher biofilm detachment rate and yield were observed at SALR 2.5, with the thickest biofilm and a higher percentage of dead cells. Consequently, a higher fraction of larger and rapidly settling particles was observed at SALR of 2.5 g-sBOD/m2·d, which leads to a significantly better settling behaviour of the MBBR effluent solids. This study expands the current knowledge of MBBR-produced particle characteristics and settling behaviour. A comprehensive understanding of the MBBR system performance and the potential influencing factors on the MBBR produced solids, particle characteristics, and their settleability will lead to optimized MBBR design for future pilot- and full-scale applications of the MBBR.

Dala Vatten AB has been operating two municipal wastewater treatment plant namely Gagnef wastewater treatment plant and Tällberg wastewater treatment plant since 1970’s and 1950’s respectively in Dalarna, middle of Sweden. These both traditional treatment plants have been updated with continuous and intermittent aerated biological treatment facilities: Moving bed biofilm reactor (MBBR) in 2012 and 2007 respectively. Recently, more detailed process performance and evaluation of both plants is required focusing on energy consumption. The objective of this master thesis is thus to investigate the opportunities in reducing energy consumption from both plants to save operation cost, identify the opportunities for chemical saving, if possible reduce the excess sludge so produced from the plant and potential optimization of the process for its plant’s sustainability. The laboratory study was made in May and August, 2015 with grab sampling and flow proportional sampling method. The analysation was carried out with several wastewater parameters: BOD7, COD, TOC, TP, NH4-N and TN with Hach Lange analysing method. Results showed that both continue and intermittent aerated plants have higher process performance with lower effluent organic (BOD7, COD) and TP loading to the recipient. Gagnef WWTP with continuous aeration has demonstrated an excessive use of chemical, sludge production and high-energy consumption by the blower serving MBBR during the studied period. By contrast, Tällberg WWTP with intermittent aeration has proved to be successful in terms of lower energy consumption by the blower serving the MBBR but failed to show improved specific energy efficiency for each pollutant load during the studied period. The recommendation in improvising energy saving and saving operation cost at both treatment plants was put forward.

In the last decade, several novel and cost-effective biological nitrogen removal technologies have been developed. The discovery of anaerobic ammonium oxidation (Anammox), about 15 years ago, has resulted in new opportunities for research and development of sustainable nitrogen removal systems. Compared to conventional nitrification/denitrification, Anammox eliminates necessity of external organic carbon source, has a smaller production of excess sludge, reduces energy demand for aeration (up to 60-90%) and CO2 emissions (up to 90%). Systems based on Anammox can be of great help to comply with stricter wastewater discharge regulations and reduce environmental problems caused by nutrients discharges (e.g. eutrophication). This thesis investigates the partial nitritation/Anammox in one stage system under oxygen limited condi-tions (also called CANON or Deammonification) and with the Moving Bed Biofilm Reactor (MBBR™) technology. Anammox process coupled with partial nitritation can be particularly suitable to treat ammo-nium-rich wastewater with low content of biodegradable organic matter, such as the reject water from dewatering of digested sludge, which is usually recirculated back to the main stream of wastewater treat-ment plants, accounting for the 15-20% of the total nitrogen load. Partial nitritation/Anammox process was successfully tested on a pilot plant scale for four months at 25°C, in a 200 L Continuous Stirred Tank Reactor (CSTR), filled with 40% of Kaldnes media (model K1). At an Ammonium Surface Load (ASL) of 3.45 gN m-2d-1, the removal rate was about 2.85 gN m-2d-1. Removal efficiencies of 95%, 85% and 83% were respectively achieved for NH4+-N, inorganic nitrogen, and Total Nitrogen (TN). Bacteria activity was followed by batch tests such as Specific Anammox Activity (SAA), Oxygen Uptake Rate (OUR) and Nitrate Uptake Rate (NUR), which revealed an increase in activi-ty for Nitrosomonas and Anammox bacteria within the biofilm. Dissolved oxygen concentration in the bulk liquid was a crucial parameter, whereas pH and conductivity turned out to be two useful monitoring tools. Two laboratory-scale reactors were previously run for two months each, in order to evaluate the one-stage partial nitritation/Anammox process with a lower ASL. One reactor was fed with diluted reject water, whereas the other one treated the effluent from UASB (Up-flow Anaerobic Sludge Blanket) reactor after sand filtration. Fairly good efficiency (>75%) were reached but, however, in the last case the low ammo-nium nitrogen load could represent a problem for a stable full-scale installation and long-term growth of Anammox bacteria. Some suggestions for full-scale implementation and further research are proposed in the last chapter of this master thesis.

Klädindustrin är idag en stor bidragande orsak till negativa miljöpåverkningar. Om avtrycket från den industrin ska minska behöver det ”fast fashion” fasas ut och ett nytt sätt att se på kläder implementeras. De enklaste sätten att minska avtrycket är att återanvända eller återvinna kläder. Renewcell återvinner textilier och bryter ner bomullen och återvinner den som nytt material - Circulose®. Det materialet skickas vidare för att bli nya kläder och på så sätt stängs loopen för textilindustrin. Av produktionen av Circulose® tillkommer ett nytt slags processavlopp som inte hunnits forskas mycket på. Paralleller till textilindustrin kan visserligen dras och där är processavloppen av heterogen karaktär. Renewcell vill se om det går att reducera det organiska materialet i avloppet till en nivå på 10 mg/l. Den här studien vill hjälpa till att fylla det forskningsgap som finns för reningsteknik inom textilåtervinningsindustrin idag. Med en ny marknad i uppstart är det viktigt att avlopp hanteras på ett bra och ansvarsfullt sätt. Syftet med studien var att undersöka experimentellt och litterärt om det går att reducera ner BOD7 i Renewcells processavloppet till 10 mg/l. En MBBR har efterforskats och jämförts med en MBR, där en MBBR ansågs vara mer resistent mot variationer och farliga ämnen. Det byggdes en MBBR i laborationsskala kopplat till processavloppet för att analysera reduktionen av BOD7 och för att göra en experimentell undersökning hur den kemiska fällningen påverkas om vattnet behandlades biologiskt först. Studien resulterade i att Renewcells karaktär på processavlopp är heterogent och är hanterbart av mikroorganismer. Dock, på grund av att ingen fullt utvecklad biofilm nåddes samt variationer i processen är det fortfarande osäkert om det fungerar att implementera en MBBR hos Renewcell. Processförändringar som ett produktionsstopp är inga problem för en fullt utvecklad MBBR att hantera. Processavloppet innehåller en stor mängd organiskt material, men saknar tillräckligt med näringsämnen. För detta projekt var 58 % reduktion av BOD7 den högsta som redovisades och det nåddes inte heller en fullt utvecklad biofilm. Att biologiskt behandla avloppet innan en kemisk fällning gav positiva resultat då reduktionen av metalljoner förbättrades. Allt som allt anses det vara möjligt att implementera en MBBR hos Renewcell om rätt förutsättningar finns och det ges en möjlighet att utveckla en biofilm fullt ut. Förhoppningsvis kan denna förstudie visa vägen för vidare studier inom området. / The clothing industry is one of the major causes for negative environmental impacts. The “fast-fashion” needs to be phased out and a more climate-friendly way of using clothes implemented. The easiest ways to do this is to reuse or recycle clothes. Renewcell recycles used textiles and dissolve the cotton into pulp and makes a new material of it - Circulose®, which is sent to become new clothes and, in that way, helps to close the loop for textile industry. With the production of Circulose® a new kind of wastewater is produced which has not yet been thoroughly researched. A parallel to the textile industry’s wastewater can be drawn, and that is of heterogeneous nature and can change quickly from day to day. It is in Renewcell’s interest to reduce the organic matter in the wastewater, more than they do today with their current chemical and mechanic wastewater treatment plant does. This study wants to help fill the research gap that exists for purification technology in the textile recycling industry today. Since it is a new field of technology, it is of importance to thoroughly invest in how to treat the wastewater responsibly. The purpose of this study was to investigate, both experimentally and literary, whether the possibility to reduce BOD7 to 10 mg/l in the wastewater treatment plant. With an investigation of MBBR and by compare it with an MBR it was concluded that a MBBRis a better fit for Renewcell since it is considered to be more resistant to variations and hazardous substances. To strengthen that conclusion a MBBR in laboratory scale was built and wastewater directly from the recycling process treated. The reduction of BOD7 and how it would come to affect the chemical precipitation was analyzed. The results of the study concluded that Renewcells wastewater is heterogenous and manageable for microorganisms. However, the due to the variations in the process such as dosing of biologically harmful substances it might not be possible for Renewcell to implement a MBBR. Process variations as a stop in production of wastewater for a shorter time period is manageable. The wastewater contains enough organic matter, but an extra addition of nutrients is needed. For this project the MBBR-process fluctuated in reduction of organic matter and the highest amount achieved was 58 %. No fully developed biofilm was achieved either. Biologically treating the process effluent before the chemical precipitation gave positive results as the reduction of metal ions was improved. All in all, it is believed to be possible to implement a MBBR at Renewcell if the process is given the required conditions from the beginning and a biofilm can be fully developed. Hopefully, this pilot study can show the way for future research within the field.