Orientador: Falcondes José Mendes de Seixas / Resumo: Os conversores multipulsos têm sido muito utilizados para a melhoria da qualidade de energia elétrica em sistemas de retificação trifásicos. O principal motivo para tal afirmação é a robustez apresentada por esses conversores, aliada às características intrínsecas da estrutura, que resulta no cancelamento natural de certas componentes de corrente na rede, devido ao defasamento angular provocado pela ação do transformador ou autotransformador utilizado. O que se propõe nesse trabalho é a substituição de cada ponte retificadora a diodos, presente no conversor de 12 pulsos, por uma topologia retificadora trifásica semicontrolada, baseada no conversor boost operando no modo de condução descontínuo (MCD), de modo que, seja possível reduzir de maneira significativa a DHTi (Distorção Harmônica Total de corrente), bem como, incorporar os volumosos transformadores de interfase (IPTs) aos indutores boost de alta frequência, resultando na redução de peso e volume. Foram confeccionadas duas versões do conversor de 12 pulsos com retificadores semicontrolados, uma utilizando transformador isolador e a outra um autotransformador. O que se verificou para ambas as configurações é que a estrutura apresenta um reduzido conteúdo harmônico de corrente se comparado ao conversor tradicional e que, ao se operar no modo de condução descontínuo, faz-se possível o emprego de uma lógica de controle simples, possibilitando assim empregar somente uma malha de tensão, e reduzir significativamente a DHTi do... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: Multipulse converters have been widely employed for electrical power quality improvement in three-phase rectifiers systems. The main reason for this statement is the robustness shown by these structures, allied to their natural characteristics, resulting in harmonic canceling at the mains, due to the phase displacement provided by the transformer/autotransformer. In this work, it is proposed the replacement of each rectifier bridge, present in the 12-pulse converter, by a three-phase half-controlled rectifier topology, based on DCM (Discontinuous Conduction Mode) boost converter, thus making it possible to significative reduce the THDi (Total Harmonic Distortion) of the current injected on the mains by the structure. It also incorporates the voluminous IPT's (Interphase Transformer) in the boost high-frequency inductor, resulting in a reduction of weight and size. Two versions of the 12-pulse converter with semicontrolled rectifiers were made, one using an isolating transformer and other using an autotransformer. It was verified that both configurations present a reduced THDi when compared to the traditional converter. So, by electing DCM, it is possible to employ a simpler control logic, employing only one voltage loop and significantly reducing the THDi. / Doutor

This Ph.D. thesis is an exploration of carotenoids by ultrafast, time-resolved absorption spectroscopy to investigate their complicated relaxation processes, means of energy transfer, and dependence on structure. The introduction begins with an overview of carotenoids, intended for the reader to appreciate their importance and their complexity as revealed by decades of research in carotenoid photophysics. To understand the primary concerns of this research field, the reader is guided through basic theory of energetic processes, the experimental method, and methods of analysis. The main body of the text is the Research Chapter, containing four sections, each describing research using varied ultrafast transient absorption spectroscopies on carotenoids in solution and when bound to a host protein. Section 2.1 concerns an equilibration phenomenon in the lowest excited state of the carotenoid fucoxanthin in various solutions and temperatures by a multi-pulse transient absorption method. The same method is applied to fucoxanthin in a host antennae protein of the pennate diatom Phaeodactylum tricornutum to investigate the function of the equilibration in energy transfer to Chlorophyll a in Section 2.2. The next two sections regard the effect of carotenoid structure on its relaxation dynamics. Section 2.3 investigates the effect of the non-conjugated acyloxy group of two fucoxanthin derivatives in various solvents. Here, one of the energetic states involved in the equilibrium mentioned above is seen drastically affected. Lastly, Section 2.4 investigates alloxanthin, a carotenoid with an unusual pair of carbon-carbon triple bonds. Their effect on the conjugation is evaluated based upon the molecules' decay dynamics. A general summary and conclusion is provided at the end.

Dans le domaine de l'imagerie ultrasonore, l'imagerie non linéaire est devenue une branche importante. Imagerie non linéaire peut être divisée en imagerie harmonique tissulaire et imagerie harmonique de contraste, selon l'endroit où les signaux non linéaires viennent. Imagerie harmonique de contraste apparaît parce que les agents de contraste, qui sont injectés par voie intraveineuse pour améliorer les faibles échos rétrodiffusés par des cellules sanguines, peuvent vibrer non linéaire quand ils subissent une pression acoustique. Ces signaux non linéaires rétrodiffusés par des agents de contraste sont utilisés pour former des images harmoniques. Toutefois, lors de la propagation des ondes dans les tissus, les harmoniques de l'onde sont également générés dans le tissu. La présence de signaux harmoniques de tissus dégrade la qualité d'image en contraste imagerie harmonique. Cette thèse vise à mieux distinguer les échos des agents de contraste et les échos de tissus, concevant des nouvelles modalités, ou optimisant les modalités existantes. Nos efforts se concentrent principalement sur les techniques multi-impulsions en imagerie ultrasonore de contraste. Tout d'abord, nous proposons une formule de généraliser la plupart des techniques multi- impulsions. La formulation peut être utilisée pour prédire les éléments non linéaires dans chaque bande fréquentiel et de concevoir de nouvelles séquences de transmission pour augmenter ou diminuer composants non linéaires. Les résultats des simulations sur plusieurs techniques multi- impulsions sont en accord avec les résultats donnés dans les littératures précédentes. Deuxièmement, les techniques utilisant multi transmissions pour augmenter le CTR sont généralement basés sur la réponse des diffuseurs statiques. Cependant, diffuseur en mouvement a une influence inévitable sur des techniques. Il peut améliorer ou dégrader la technique. Des simulations, des expériences in vitro à partir d'une seule bulle et les nuages de bulles, et des expériences sur des rats montrent que le déphasage des échos rétrodiffusés par des bulles dépend du déphasage des transmissions, et que le mouvement de la bulle influe sur l’efficacité des techniques multi- impulsions. En outre, les résultats expérimentaux basés sur la technique de l'inversion de seconde harmonique (SHI) révèlent que le mouvement de la bulle peut être pris en compte pour optimiser les techniques multi-impulsions. Par ailleurs, une nouvelle technique, appelée double inversion de impulsion (DPI), a également été proposé. La technique PI est appliquée deux fois avant et après l'arrivée de l'agent de contraste dans la région d'intérêt. Les signaux résultants sont soustraits pour supprimer les harmoniques du tissu. Les simulations et les résultats in vitro ont montré une amélioration de CTR de DPI. Toutefois, la présence de mouvements de tissus peut limiter à l'efficacité de cette technique. Résultats in vivo confirment cette limitation. / In ultrasound imaging domain, nonlinear imaging has become an important branch. Nonlinear imaging can be divided into tissue harmonic imaging and contrast harmonic imaging, according to where the nonlinear signals come from. Contrast harmonic imaging emerges because contrast agents, which are intravenously injected to enhance the weak echoes backscattered from blood cells, can vibrate nonlinearly when they undergo an acoustic pressure. Then, these nonlinear signals backscattered by contrast agents are collected to form harmonic images. However, during the wave propagation in tissue, the harmonics of the transmitted wave are also generated in tissue. The presence of tissue harmonic signals degrades the image quality in contrast harmonic imaging. This thesis aims to better distinguish the echoes from contrast agents and the echoes from tissue, whether through designing new modalities, or investigating and optimizing the existing modalities. Our efforts are mainly focused on the multi-pulse techniques in ultrasound contrast imaging. Firstly, we propose a mathematical background to generalize most of the multi-pulse ultrasound imaging techniques that have been described in previous literatures. The formulation can be used to predict the nonlinear components in each frequency band and to design new transmission sequences to either increase or decrease specified nonlinear components in each harmonic band. Simulation results on several multi-pulse techniques are in agreement with the results given in previous literatures. Secondly, the techniques using multiple transmissions to increase the CTR are generally based on the response of static scatterers inside the imaged region. However, scatterer motion, for example in blood vessels, has an inevitable influence on the relevance of the techniques. It can either upgrade or degrade the technique involved. Simulations, in-vitro experiments from a single bubble and clouds of bubbles, and in-vivo experiments from rats show that the phase shift of the echoes backscattered from bubbles is dependent on the transmissions’ phase shift, and that the bubble motion influences the efficiency of multi-pulse techniques. Furthermore, experimental results based on the second-harmonic inversion (SHI) technique reveal that bubble motion can be taken into account to optimize multi-pulse techniques. Besides, a new technique, called double pulse inversion (DPI), has also been proposed. The PI technique is applied twice before and after the arrival of the contrast agents to the region of interest. The resulting PI signals are substracted to suppress the tissue-generated harmonics and to improve CTR. Simulations and in-vitro experimental results have shown an improved CTR of DPI. However, the presence of tissue movements may hamper the effectiveness of this technique. In-vivo experimental results confirm that the tissue motion of the rat during the acquisition is an inevitable barrier of this technique.

<p>The future International Linear Collider (ILC) and Compact Linear Collider (CLIC) are intended for precision measurements of phenomena discovered at the Large Hadron Collider (LHC) and also for the discovery of new physics. In order to offer optimal conditions for such experiments, the new colliders must produce very-high-luminosity collisions at energies in the TeV regime.</p><p>Emittance growth caused by imperfections in the main linacs is one of the factors limiting the luminosity of CLIC and ILC. In this thesis, various emittance preservation and luminosity tuning techniques have been tested and developed in order to meet the challenging luminosity requirements.</p><p>Beam-based alignment was shown to be insufficient for reduction of emittance growth. Emittance tuning bumps provide an additional powerful preservation tool. After initial studies of tuning bumps designed to treat certain imperfections, a general strategy for design of optimised bumps was developed. The new bumps are optimal both in terms of emittance reduction performance and convergence speed. They were clearly faster than previous bumps and reduced emittance growth by nearly two orders of magnitude both for CLIC and ILC.</p><p>Time-dependent imperfections such as ground motion and magnet vibrations also limit the performance of the colliders. This type of imperfections was studied in detail, and a new feedback system for optimal reduction of emittance growth was developed and shown to be approximately ten times more efficient than standard trajectory feedbacks.</p><p>The emittance tuning bumps require fast and accurate diagnostics. The possibility of measuring emittance using a wide laserwire was introduced and simulated with promising results. While luminosity cannot be directly measured fast enough, it was shown that a beamstrahlung tuning signal could be used for efficient optimisation of a number of collision parameters using tuning bumps in the Final Focus System.</p><p>Complete simulations of CLIC emittance tuning bumps, including static and dynamic imperfections and realistic tuning and emittance measurement procedures, showed that an emittance growth six times lower than that required may be obtained using these methods.</p>

In ultrasound imaging domain, nonlinear imaging has become an important branch. Nonlinear imaging can be divided into tissue harmonic imaging and contrast harmonic imaging, according to where the nonlinear signals come from. Contrast harmonic imaging emerges because contrast agents, which are intravenously injected to enhance the weak echoes backscattered from blood cells, can vibrate nonlinearly when they undergo an acoustic pressure. Then, these nonlinear signals backscattered by contrast agents are collected to form harmonic images. However, during the wave propagation in tissue, the harmonics of the transmitted wave are also generated in tissue. The presence of tissue harmonic signals degrades the image quality in contrast harmonic imaging. This thesis aims to better distinguish the echoes from contrast agents and the echoes from tissue, whether through designing new modalities, or investigating and optimizing the existing modalities. Our efforts are mainly focused on the multi-pulse techniques in ultrasound contrast imaging. Firstly, we propose a mathematical background to generalize most of the multi-pulse ultrasound imaging techniques that have been described in previous literatures. The formulation can be used to predict the nonlinear components in each frequency band and to design new transmission sequences to either increase or decrease specified nonlinear components in each harmonic band. Simulation results on several multi-pulse techniques are in agreement with the results given in previous literatures. Secondly, the techniques using multiple transmissions to increase the CTR are generally based on the response of static scatterers inside the imaged region. However, scatterer motion, for example in blood vessels, has an inevitable influence on the relevance of the techniques. It can either upgrade or degrade the technique involved. Simulations, in-vitro experiments from a single bubble and clouds of bubbles, and in-vivo experiments from rats show that the phase shift of the echoes backscattered from bubbles is dependent on the transmissions' phase shift, and that the bubble motion influences the efficiency of multi-pulse techniques. Furthermore, experimental results based on the second-harmonic inversion (SHI) technique reveal that bubble motion can be taken into account to optimize multi-pulse techniques. Besides, a new technique, called double pulse inversion (DPI), has also been proposed. The PI technique is applied twice before and after the arrival of the contrast agents to the region of interest. The resulting PI signals are substracted to suppress the tissue-generated harmonics and to improve CTR. Simulations and in-vitro experimental results have shown an improved CTR of DPI. However, the presence of tissue movements may hamper the effectiveness of this technique. In-vivo experimental results confirm that the tissue motion of the rat during the acquisition is an inevitable barrier of this technique.

Les travaux portent sur l’endommagement laser en régime nanoseconde aux longueurs d’onde 355 nm et 266 nm. L'objectif de cette étude est de comprendre et d'analyser les processus mis en jeu lors de l'endommagement laser en surface et en volume de matériaux optiques, massifs ou en couches minces, lors de tirs répétés. Dans ce contexte, un banc d'endommagement laser a été entièrement mis en place et automatisé. Il permet d'analyser la résistance et le vieillissement de ces composants sous irradiation UV à des fréquences de tir de 50Hz, pour un grand nombre de tirs et de relever de façon systématique les paramètres du test les plus importants (profiles spatiaux et énergies des impulsions, images du site avant et après dommage). Pour une meilleure compréhension des phénomènes physiques conduisant à la fatigue des matériaux en tirs laser répétés, un modèle a été développé afin de discriminer les effets statistiques (dus au grand nombre de tirs impliqués) de modifications du matériau sous flux UV. Ce modèle a été validé expérimentalement dans le cas de la silice synthétique étudiée en volume. En ce qui concerne les couches minces, une étude multi-paramètres de la tenue au flux UV de mixtures d'oxydes a été menée, en partenariat avec le Laser Zentrum Hannover (LZH, Allemagne). Ces matériaux ont en effet un comportement complexe et encore mal connu, en particulier en tirs répétés. Enfin, une partie du travail de thèse est consacrée à la caractérisation non-destructive de cristaux de KDP par photoluminescence pompée dans l'UV, réalisée dans le contexte du laser MégaJoule en collaboration avec le CEA Le Ripault (Monts). / The work is devoted to laser-induced damage in the nanosecond regime at the wavelengths of 266 nm and 355 nm. The goal of this study is to understand and to analyze the processes taking place during multi-pulse irradiation causing laser-damage, on the surface and in the bulk of massive or thin-films optical materials. To this end, a laser-damage experiment was entirely set up and automated. It allows analyzing the laser-damage resistance and the ageing of these components under UV irradiation at a pulse repetition rate of 50 Hz and for a high number of laser pulses and to record systematically the most important test parameters (spatial beam profiles, energies, images of the site before and after irradiation).To better understand the physical phenomena leading to fatigue effects in the materials under multiple pulse irradiation, a model was developed allowing the discrimination of statistical effects (due to the high number of shots) from material modifications under UV irradiation. This model was confirmed by testing synthetic fused silica irradiated in the bulk. Concerning thin-film coated components, oxide mixtures were studied in collaboration with the Laser Zentrum Hannover (LZH, Germany) using a multi-parameter approach. These materials show indeed a complex behavior and remain poorly known, in particular under multi-pulse irradiation. Finally, a part of the work is dedicated to the non-destructive characterization of KDP crystals by UV-pumped photoluminescence, realized in the framework of the MegaJoule project, in collaboration with CEA Le Ripault (Monts, France).

The future International Linear Collider (ILC) and Compact Linear Collider (CLIC) are intended for precision measurements of phenomena discovered at the Large Hadron Collider (LHC) and also for the discovery of new physics. In order to offer optimal conditions for such experiments, the new colliders must produce very-high-luminosity collisions at energies in the TeV regime. Emittance growth caused by imperfections in the main linacs is one of the factors limiting the luminosity of CLIC and ILC. In this thesis, various emittance preservation and luminosity tuning techniques have been tested and developed in order to meet the challenging luminosity requirements. Beam-based alignment was shown to be insufficient for reduction of emittance growth. Emittance tuning bumps provide an additional powerful preservation tool. After initial studies of tuning bumps designed to treat certain imperfections, a general strategy for design of optimised bumps was developed. The new bumps are optimal both in terms of emittance reduction performance and convergence speed. They were clearly faster than previous bumps and reduced emittance growth by nearly two orders of magnitude both for CLIC and ILC. Time-dependent imperfections such as ground motion and magnet vibrations also limit the performance of the colliders. This type of imperfections was studied in detail, and a new feedback system for optimal reduction of emittance growth was developed and shown to be approximately ten times more efficient than standard trajectory feedbacks. The emittance tuning bumps require fast and accurate diagnostics. The possibility of measuring emittance using a wide laserwire was introduced and simulated with promising results. While luminosity cannot be directly measured fast enough, it was shown that a beamstrahlung tuning signal could be used for efficient optimisation of a number of collision parameters using tuning bumps in the Final Focus System. Complete simulations of CLIC emittance tuning bumps, including static and dynamic imperfections and realistic tuning and emittance measurement procedures, showed that an emittance growth six times lower than that required may be obtained using these methods.

Cette thèse concerne l'étude de la dynamique des structures optiques dissipatives observées dans une cavité à gestion de dispersion utilisant l'évolution non linéaire de la polarisation comme technique de blocage de modes. Nous avons montré expérimentalement l'existence d'une transition graduelle entre le régime de fonctionnement continu et le régime de fonctionnement multi-impulsionnel. Nous nous sommes intéressés à l'état intermédiaire où il nous a été possible d'obtenir divers régimes inédits et d'étudier ainsi le comportement collectif des solitons dissipatifs en présence d'un fond continu. La dynamique de "la pluie de solitons" est une manifestation complexe et fascinante constituée de trois composantes de champ : le fond continu, les solitons de dérive et la phase condensée. Elle s'accompagne d'une circulation d'énergie à travers ces trois composantes. Le mouvement relatif des solitons de dérive ainsi que l'asymétrie temporelle présentent les caractéristiques majeures qui distinguent cette dynamique des autres. D'autres types d'auto-organisation ont été observés et étudiés, comme "le relargage des solitons de la phase condensée" ou bien encore "la vobulation du train de solitons". Nous nous sommes intéressés aussi à la propagation d'une seule impulsion dans la cavité. Pour la première fois, une importante dynamique de respiration spectrale a été prédite dans une cavité à gestion de la dispersion. Nous avons montré qu'une compression temporelle de l'impulsion est accompagnée d'un élargissement spectral d'une grande ampleur dans la partie passive de la cavité et que la largeur de l'impulsion peut dépasser la largeur de la bande passante du milieu amplificateur. Nous avons étudié la dynamique de la respiration spectrale, l'extraction et l'optimisation du signal laser en fonction des paramètres de la cavité et nous avons présenté les caractéristiques d'une cavité qui permet la génération d'une impulsion dont sa largeur spectrale est supérieure à la largeur de la bande passante de l'amplificateur d'un facteur de 2.4. Les dynamiques présentées dans cette thèse témoignent de la complexité et de la richesse de la dynamique dissipative des lasers à fibre fonctionnant en régime de blocage de modes passif par évolution non linéaire de la polarisation. / This thesis presents a study of the nonlinear dissipative dynamics of localized of self organized structures in passively mode-locked fiber laser through nonlinear polarization evolution. We reveal the existence of a gradual transition from the quasi-cw to mode locked dynamics in the multi-pulsing regime. We emphasize on the intermediate state, where various new dynamics are observed. We study collective behaviors of dissipative solitons in the presence of a continuous background. One of the complex and attractive dynamics presented is the "soliton rain", which composed of three field components : continuous modes of background, drifting of solitons and condensed phase solitons. This dynamic appears when the energy flows through the three components. The relative motion of the drifting solitons and the temporal asymmetry present the major characteristics that distinguish this dynamic. Other types of self-organizations of solitons were observed and studied as the "release of the solitons from the condensed phase" and the "chirped trains with condensed soliton phase". We were also interested in the single pulse propagation. For the first time, an important dynamics of spectral breathing was predicted in a dispersion-managed cavity. We showed that pulse compression dynamics in the passive anomalous fiber can be accompanied by a significant enhancement of the spectral width and that the width of the pulse can exceed the amplifier bandwidth. We studied, the extraction and the optimization of the signal laser according to the parameters of the cavity and we presented the characteristics of a cavity delivering ultra short pulses with a spectral width exceeding the amplifier bandwidth by a factor of 2.4. The dynamics presented in this thesis show the complexity and variety of the dissipative dispersion-managed dynamics in fiber laser mode locked through nonlinear polarization evolution.