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Structural controls of Ni-Cu-PGE ores and mobilization of metals at the Garson Mine, SudburyMukwakwami, Joshua 31 July 2013 (has links)
The Garson Ni-Cu-PGE deposit is located on the South Range of the 1850 Ma Sudbury
structure along the contact between the Sudbury Igneous Complex (SIC) and the
underlying metasedimentary and metavolcanic rocks of the Paleoproterozoic Huronian
Supergroup. It comprises four ore bodies that are hosted by E-W-trending shear zones
that dip steeply to the south. The shear zones formed as south-directed D1 thrusts in
response to flexural-slip during regional buckling of the SIC. They imbricated the ore
zones, the SIC norite, the underlying Huronian rocks and they emplaced slivers of
Huronian rocks and anatectic breccia into the overlying Main Mass norite. Coexisting
garnet-amphibole pairs yielded syn-D1 amphibolite facies metamorphic temperatures
ranging from ~550°C to 590°C. The shear zones were coeval with the moderately southdipping
South Range and Thayer Lindsley shear zones, which formed to accommodate
the strain in the hinge zone as the SIC tightened with progressive D1 shortening. The SE
limb of the SIC was overturned together with the D1 thrusts, which were then reactivated
as steeply south-dipping reverse shear zones during syn-D2 greenschist metamorphism.
Syn-D2 metamorphic titanite yield a U-Pb age of ca. 1849 ± 6 Ma, suggesting that D1 and
D2 are part of a single progressive deformation event that occurred immediately after
crystallization of the SIC during the Penokean Orogeny.
The ore bodies plunge steeply to the south parallel to the colinear L1 and L2 stretching
mineral lineations. Ore types consist mainly of pyrrhotite-pentlandite-chalcopyrite breccia
ores, but also include pyrrhotite-pentlandite-chalcopyrite disseminated sulfide
mineralization in norite, and syn-D2 quartz-calcite-chalcopyrite-pyrrhotite-pentlandite
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veins. In the breccia ores, matrix sulfides surround silicate rock fragments that have a
strong shape-preferred orientation defining a pervasive foliation. The fragments are
highly stretched parallel to the mineral lineations in wall rocks, suggesting that the ore
bodies are zones of high strain. Pyrrhotite and chalcopyrite occur in piercement
structures, in boudin necks between fragments, in fractures in wall rocks and in fold
hinges, suggesting that the sulfides were mobilized by ductile plastic flow. Despite
evidence of high strain in the ore zones, the sulfide matrix in D1 and D2 breccia ores show
little evidence of strain as they consist predominantly of polygonal pyrrhotite aggregates,
suggesting that they recrystallized during, or immediately after D1 and D2. However, rare
elongate pyrrhotite grains aligned parallel to S2 are locally preserved only in D2 breccia
ores. Exsolution of pentlandite loops along grain boundaries of elongate pyrrhotite
formed S2-parallel pentlandite-rich layers in D2 breccia ores, whereas the pentlandite
loops are multi-oriented in D1 contact breccia as they were exsolved along grain
boundaries polygonal pyrrhotite. Because exsolution of pentlandite post-date D1 and D2,
and that individual pentlandite grains neither have a shape-preferred orientation nor show
evidence for cataclastic flow, the sulfides reverted to, and were mobilized as a
homogeneous metamorphic monosulfide solid solution (mss) during D1 and possibly D2.
This is in agreement with predictions from phase equilibria as the average Garson
composition plots within the mss field in Fe-Ni-S ternary diagram at temperatures above
~400°C.
Disseminated and breccia ores at Garson have similar mantle-normalized multi-element
chalcophile patterns as undeformed contact-type disseminated and massive ore,
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respectively, at the well known Creighton mine in the South Range. This suggests that the
Garson ores are magmatic in origin and that their compositions were not significantly
altered by hydrothermal fluids and deformation. The lack of variations in Ni tenors
between the disseminated and breccias ores suggest that the R-factor was not the process
controlling metal tenors because the disseminated sulfides do not consistently have higher
metal tenors than the breccia ore. The breccia ores are enriched in Rh-Ru-Ir and are
depleted in Cu-Pd-Pt-Au, in contrast to footwall-type ore at the nearby Garson Ramp
mine which is enriched in the same metals. When Ni100, Rh100, Ir100, Pt100 and Pd100 are
plotted against Cu100, the breccia and footwall-type ore analyses plot along model mss
fractionation and sulfide melt model curves, suggesting that these two ore types are
related by mss fractionation.
In summary, the Garson breccia ores are mss cumulates that settled quickly at the base of
the SIC via a gravity filtration process, and were mobilized as a metamorphic mss by
ductile plastic flow during D1 and D2. Despite minor local hydrothermal mobilization of
some metals, the study confirms findings from other studies that highly deformed Ni-Cu-
PGE deposits, such as the Garson deposit, can provide important information on the
genesis of the deposits.
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Formation of Sulphides in the Canadian High Arctic Large Igneous Province; Testing the Influence of Sedimentary Rocks / Bildandet av sulfider i den kanadensiskahögarktiska magmatiska provinsen: prövning av sedimentära bergarters inflytandeHagerfors, Erika January 2018 (has links)
Large Igneous Provinces (LIPs) form during short-lived pulses of extensive magmatic activity. LIPs are known for their ability to affect global climate as well as for their Ni-Cu-PGE ore potential. A key factor that controls the intensity of the climate impact of a LIP and its ore potential is the assimilation of volatile-rich sedimentary host rocks. Magmas of the High Arctic Large Igneous Province (HALIP), exposed in the Arctic, intruded volatile-rich black shales, carbonates and evaporites in the Canadian Arctic Islands, offering a great opportunity for studying magma-sediment interaction. The purpose of this study is to test whether assimilation of sedimentary sulphide can promote sulphide immiscibility in magma and thus aid formation of Ni-Cu-PGE ore bodies. This is done by analysing sulphur isotopes in pyrite grains hosted in a HALIP dolerite sill, which was emplaced into black shale, by using Secondary Ion Mass Spectrometry (SIMS). Four dolerite samples are analysed; two coming from the lower contact margin of the sill, one from 60 cm into the sill and one sample from a basaltic vein at the upper contact margin of the sill. A total of 14 pyrite grains (n = 246 individual SIMS spot analyses) were analysed for their sulphur isotope ratios. The results of the SIMS analyses show that all analysed sulphides have highly negative δ34S values ranging from -19.5 to -5.7‰ (average δ34S = -8.2 ± 0.83‰, 2SD), which therefore differ largely from that of the primitive mantle (0 ± 1.8‰). In order to put our four analysed dolerite samples into a broader context, δ34S data of our sulphides are compared with whole-rock δ34S and δ18O data from Hare Fiord shale and dolerite samples. The δ34S values of the sulphide samples from the sill typically trend toward the negative sulphur isotope composition of the sulphides in the surrounding shale, and the shale surrounding the sill experiences a loss of 32S near the contact of the sill. This indicates that sedimentary light sulphur (32S) has been locally incorporated into the sill by the surrounding shale, resulting in negative δ34S values in the magmatic sulphides. Since sulphide immiscibility in the Hare Fiord sill was triggered by assimilation of sulphur from host rock shale, the igneous rocks of the HALIP may be prospective for Ni-Cu-PGE mineralization, though more studies are needed. Furthermore, our results suggest that incorporation of crustal sulphur increased the volatile budget of HALIP magmas, which therefore could have contributed to a deterioration of the environmental conditions during the emplacement of the HALIP. / Stora magmatiska provinser (på engelska Large Igneous Provinces, LIPs) är vulkaniska event då enorma mängder magma avsätts över en väldigt stor yta under ett, i ett geologiskt perspektiv, kort tidsspann. Dessa stora vulkaniska utbrott har väckt stort intresse då de är samtida med flera av de största massutdöendena i jordens historia, men också för att en viss typ av sulfidmalm rik på nickel, koppar och platinametaller (Ni-Cu-PGE malmer) ofta förekommer i provinsernas magmagångar och magmakammare. En viktig faktor som till stor del avgör en magmatisk provins påverkan på klimatet och potentiella malmförekomster är inkorporering av sedimentära bergarter till magman som, när de hettas upp, kan frigöra gaser rika på svavel och kol. I Kanadas arktiska öar trängde magma tillhörande den högarktiska magmatiska provinsen (HALIP) in i svart skiffer, karbonater och evaporiter, som är sedimentära bergarter rika på flyktiga ämnen. Denna magmatiska provins erbjuder därför stora möjligheter till att studera interaktionen mellan magma och sedimentära bergarter. Syftet med denna studie är att testa om inkorporering av sedimentärt svavel kan främja bildandet av sulfidsmälta i magma och därigenom bidra till bildandet av sulfidmalmer. Detta görs genom att analysera svavelisotoper i sulfidmineral i prover från en magmagång, som trängde in i en skifferformation, tillhörande den högarktiska magmatiska provinsen i norra Kanada. Genom att analysera svavelisotopkvoten (δ34S) i sulfidmineral kan man få information om huruvida svavlet i mineralen är av sedimentärt ursprung (där skiffer generellt har negativa δ34S värden) eller om svavlet har δ34S värden liknande de från manteln (som har δ34S värden runt 0‰), vilket i så fall skulle innebära att magman inte har inkorporerat sedimentärt svavel. Genom att använda masspektrometri av typen SIMS analyseras totalt 14 sulfidmineralkorn (n = 246 individuella SIMS punkter) för deras svavelisotopkvoter. Resultatet av studien visar att alla analyserade sulfidmineral har mycket negativa δ34S värden mellan -19.5 och -5.7‰ (med ett δ34S medelvärde på -8.2 ± 0.83‰, två standardavvikelser). Genom att jämföra våra δ34S värden med δ34S och δ18O värden för andra prover från både magmagången och den omgivande skiffern kunde vi se att δ34S värdena för sulfidmineralen i de yttre delarna av magmagången har liknande negativa värden som den omgivande skiffern, och att δ34S värdena för skiffern närmast magmagången är mer positiva. Detta tyder på att sedimentärt svavel i kontakten mellan magmagången och skiffern har blivit inkorporerat i magman från den omgivande skiffern. Våra resultat tyder därför på att sulfidmineralen i våra prover från magmagången bildades genom assimilering av svavel från den omgivande skiffern. Detta innebär i sin tur att den kanadensiska högarktiska magma provinsen potentiellt kan vara en källa för sulfidmalm, även om ytterligare studier behövs. Dessutom visar våra resultat att inkorporering av sedimentärt svavel förmodligen ökade de vulkaniska gaserna i magman, vilket kan ha bidragit till klimatförändringar relaterade till den vulkaniska aktiviteten av den högarktiska magmatiska provinsen.
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