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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
11

Cooling liquid ³He below 1 mK by nuclear demagnetization /

Muething, Kevin Albert January 1979 (has links)
No description available.
12

Evaluation of the Reduction of the Nonadiabatic Hyperspherical Radial Equation to the First Order

Carbon, Steven L. 01 January 1987 (has links) (PDF)
In this paper we examine the effectiveness of reducing the second order radial equation, of the hyperspherical coordinate solution to the two-electron Schrodinger equation, into a set of coupled first order linear equations as suggested by Klar. All results have been obtained in a completely nonadiabatic formalism thereby ensuring accuracy. We arrive at the conclusion that our application of the reduction process is in some way inconsistent and suggest a possible resolution to this anomaly.
13

Trapping ultracold atoms in time-averaged adiabatic potentials

Gildemeister, Marcus January 2010 (has links)
This thesis describes the trapping and manipulation of ultracold atoms in time-averaged adiabatic potentials (TAAP). The time-averaged adiabatic potential, proposed in [Phys. Rev. Lett. 99, 083001 (2007)], uses resonant radio frequency (rf) radiation to couple the different magnetic substates of a hyperfine level manifold. The resultant dressed states are time-averaged and produce smooth and versatile trapping geometries. More specifically, we apply rf-radiation (MHz) to a quadrupole magnetic field, which results in an ellipsoidal trapping potential for rubidium-87 atoms in the F=1 manifold. This geometry is time-averaged with the help of oscillating (kHz) Helmholtz fields. We develop a convenient loading scheme for the TAAP which uses a standard TOP trap and suffers negligible atom losses and heating. Subsequently we characterize the TAAP trap itself and observe low heating rates and sufficient lifetimes (>3s). Furthermore it is possible to use a second, weaker rf-field to evaporatively cool the atoms to quantum degeneracy [Phys. Rev. A. 81, 031402 (2010)]. This opens up a route for further experiments in this potential: we show how atoms can be trapped in a double well potential and a ring trap geometry. Additionally a process to instigate rotation in these potentials by rotating the polarization of the rf-radiation is developed and implemented. This allows us to impart angular momentum onto the atomic cloud and spin it into a ring.
14

Theoretical studies of chemical dynamics on excited states, driven by non-adiabatic effects : Charge recombination reactions

Nkambule, Sifiso Musa January 2016 (has links)
This thesis is based on theoretical studies of molecular collisions occurring at relatively low to intermediate collision energies. The collisions are called dissociative recombination (DR) and mutual neutralization (MN). In a molecular quantum mechanical picture, both reactions involve many highly excited molecular electronic states that are interacting by non-adiabatic couplings with each other. The molecular complexes involved in the collisions are relatively (diatomic or triatomic systems) composed of relative light atoms. This allows for accurate quantum chemistry calculations and a quantum mechanical description of the nuclear motions. The reactions studied here are the MN reaction in collisions of H++ H-, Li++ F-, and He++ H- and the DR reaction of H2O+. Rotational couplings are investigated in the study of MN reaction for  He++ H . For some reactions, the electronic resonant states have to be considered. These are not bound states, but are states interacting with the ionization continuum. Electronic structure calculations are combined with electron scattering calculations to accurately compute potential energy curves for the resonant states involved in the DR of H2O+ and the MN of  He++ H. From these calculations, the autoionization widths of the resonant states are also obtained. Once the potential energy curves are computed for the systems, the nuclear dynamics are studied either semi-classically, using the Landau-Zener method or quantum mechanically, employing the time-independent and time-dependant Schrödinger equations. Reaction cross section and final states distribution are computed for all the reactions, showing significantly large cross section at low to intermediate collision energies. For the MN processes, studied here, not only total cross sections are calculated but differential cross sections as well. Where possible, comparisons with previous experimental and theoretical results are performed / <p>At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Manuscript.</p>
15

The magnetic properties, crystal and magnetic structures of Nd5SixGe4-x /

Wang, Huabin, 1969- January 2007 (has links)
No description available.
16

Computational and experimental study of film cooling performance including shallow trench configurations

Harrison, Katharine Lee 22 June 2015 (has links)
Film cooling computations and experiments were performed to study heat transfer and adiabatic effectiveness for several geometries. Various assumptions commonly made in film cooling experiments were computationally simulated to test the validity of using these assumptions to predict the heat flux into conducting walls. The validity of these assumptions was examined via computational simulations of film cooling on adiabatic, heated, and conducting flat plates using the commercial code FLUENT. The assumptions were found to be reasonable overall, but certain regions in the domain suffered from poor predictions. Film cooling adiabatic effectiveness and heat transfer coefficients for axial holes embedded in a 1 [hole diameter] transverse trench on the suction side of a simulated turbine vane were experimentally investigated as well to determine the net heat flux reduction. Heat transfer coefficients were determined with and without upstream heating both with and without a tripped boundary layer approach flow. The net heat flux reduction for the trench was found to be much higher than for the baseline row of holes. Two transverse trench geometries and a baseline row of holes geometry were also simulated using FLUENT and the results were compared to experiments by Waye and Bogard (2006). Trends between simulated trench configurations and baseline cylindrical holes without a trench were found to be largely in agreement with experimental trends, suggesting that FLUENT can be used as a tool for studying new trench configurations. / text
17

Adiabatic limits of the Hermitian Yang-Mills equations on slicewise stable bundles

Mandolesi, André Luís Godinho 28 August 2008 (has links)
Not available / text
18

Solvent effects on the molecular structures of crude gliadins as revealed by density and ultrasound velocity measurements

Zhang, Zhuo 22 June 2010 (has links)
Crude gliadins were extracted from Canada Western Red Spring (CWRS) wheat flour with 70% (v/v) aqueous ethanol solutions and then lyophilized. Lyophilized crude gliadins were dissolved in 70% (v/v) aqueous ethanol (EtOH) or 4 mM acetic acid (HAc) and the density and ultrasound properties were measured at 20 °C. Good linear relationships of density, ultrasound velocity and ultrasound attenuation with solution concentrations were found. Solvent and sonication effects on the crude gliadins were discussed in terms of the values of the partial specific volume and the partial specific adiabatic compressibility coefficient for crude gliadins. The ethanol soluble crude gliadins had a larger partial specific volume and larger partial specific adiabatic compressibility coefficient than those for acidic soluble crude gliadins. These large values for the physical properties of ethanol soluble crude gliadins were thought to be evidence for the existence of complexes formed by some proteins (ethanol soluble LMW-glutenins and gliadins) and lipids in ethanol solutions and it was also found that the protein-lipid complexes were not destroyed by sonication treatment. Besides, there was no evidence showing that gliadins change with different wheat flours and cause different volume and compressibility properties of crude gliadins.
19

The magnetic properties, crystal and magnetic structures of Nd5SixGe4-x /

Wang, Huabin, 1969- January 2007 (has links)
The magnetic properties, crystal and magnetic structures of Nd5 SixGe4-x were investigated by ac susceptibility and high resolution neutron powder diffraction. The magnetic and crystalline phase diagrams were derived. Four distinct structures exist in the Nd 5SixGe4-x system: Gd5Ge 4-type [O(II)], Gd5Si2Ge2-type (M), Gd5Si4-type [O(I)], and Zr5Si4-type (T). The refinements of the neutron powder diffraction patterns revealed that the Nd5SixGe4-x compounds exhibit mixed ferro-antiferromagnetic structures. The ac susceptibility measurements showed that the magnetic ordering temperature of Nd5SixGe 4-x increases slightly with increasing silicon content, except that it increases by a factor of 2 in the orthorhombic Gd5Si 4-type [O(I)] phase region. The abrupt change of the magnetic ordering temperature between x = 2.25 and x = 2.5, where the monoclinic Gd5Si 2Ge2-type (M) structure changes to the orthorhombic Gd 5Si4-type [O(I)] structure, suggested that a first order magnetostructural transition likely takes place in this narrow composition range (2.25 &lt; x &lt; 2.5). The investigation of Nd5Si2.335 Ge1.665 revealed that Nd5Si2.335Ge 1.665 adopts the Gd5Si2Ge2-type (M) structure and undergoes a first order magnetostructural transition from the paramagnetic-monoclinic Gd5Si2Ge2-type (M) structure to the orthorhombic Gd5Si4-type [O(I)] structure upon cooling. The T1-T1 bonds increases by &sim;1 A when the the Gd 5Si4-type [O(I)] structure (10 K) transforms to the Gd 5Si2Ge2-type (M) structure (140 K). The giant magnetocaloric effect is not observed in Nd5Si2.335Ge 1.665 probably due to the co-existence of the M phase and the O(I) phase. The maximum magnetic entropy change in Nd5Si2.335Ge 1.665 is 7.3 J/kg K for magnetic field change from 0 to 7 Tesla, which is similar to that obtained in Nd5Si1.5Ge2.5, the neighboring phase O(I).
20

Solvent effects on the molecular structures of crude gliadins as revealed by density and ultrasound velocity measurements

Zhang, Zhuo 22 June 2010 (has links)
Crude gliadins were extracted from Canada Western Red Spring (CWRS) wheat flour with 70% (v/v) aqueous ethanol solutions and then lyophilized. Lyophilized crude gliadins were dissolved in 70% (v/v) aqueous ethanol (EtOH) or 4 mM acetic acid (HAc) and the density and ultrasound properties were measured at 20 °C. Good linear relationships of density, ultrasound velocity and ultrasound attenuation with solution concentrations were found. Solvent and sonication effects on the crude gliadins were discussed in terms of the values of the partial specific volume and the partial specific adiabatic compressibility coefficient for crude gliadins. The ethanol soluble crude gliadins had a larger partial specific volume and larger partial specific adiabatic compressibility coefficient than those for acidic soluble crude gliadins. These large values for the physical properties of ethanol soluble crude gliadins were thought to be evidence for the existence of complexes formed by some proteins (ethanol soluble LMW-glutenins and gliadins) and lipids in ethanol solutions and it was also found that the protein-lipid complexes were not destroyed by sonication treatment. Besides, there was no evidence showing that gliadins change with different wheat flours and cause different volume and compressibility properties of crude gliadins.

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