The diploma thesis is focused on the design of planar filters combining fractal layouts and defected ground substrates. The diploma thesis can be divided into three main parts. First, basic knowledge about fractals is presented (creation of Minkowski Island and Koch loop, e.g.). Then, the principle of defected ground structure is described, and a combination of fractal motives with a defected ground structure is briefly introduced. Properties of investigated structures are verified by CST Microwave Studio and Ansoft HFSS. Second, different defected ground structures under the 50 transmission line are designed, and conventional equivalent filters are created. Filters are simulated and compared. In final, the investigated filters are recalculated for the substrate Arlon 25N, simulated, manufactured, measured and confronted with a conventional filter on the defected ground substrate.

This master’s thesis is focused on the properties and types of helical antennas. The helical antenna work in the different modes. These modes are described in this thesis. There are also discussed possibility for design a dual-band helical antennas. The main aim of this work is the selection of a suitable solution and design a dual-band helical antenna for the WiFi band working at resonance frequencies of 2,4 GHz and 5 GHz. The simulation of this antenna was performed in the program CST Microwave studio.

The design which was work out in college plan M2I-K is setting up a production technology for an wall clamp from a steel plate 11 321.1. Based on the literature search it was chosen optimal technology of cutting and forming. Structural and technological calculations were implemented for these methods and the composite machine tool was projected. The eccentric bending press CDCH 3000P was chosen because of its working power. Working parts of the tool are made from steel 19 436.3. Price of the component is 36 Czech crowns which is result

The diploma thesis is aimed to design, optimize, produce and subsequently measure the properties of the reflector with the electronic steering direction for the frequency of the 24,125 GHz band ISM. The problem chosen is solved by a group of voltage-controlled varicaps. The reflector consists of a matrix of two rows, each containing 3 cells. The reflector was designed by full-wave software CST Microwave Studio 2015.

Les réactions de cycloisomérisation sont des outils puissant pour la synthèse d’hétérocycles et de carbocycles, tant sous leur forme racémique qu’énantioenrichie. La cyclisation directe de substrats énynes, afin de former des nouvelles liaisons carbone-carbone ou carbone-hétéroatome s’est révélée être une approche efficace, tant en économie d’atomes qu’en nombres d’étapes de synthèse, pour l’obtention de composés bicycliques ou tricycliques. Les réactions de cyclisation des substrats énynes-1,5 et 1,6 sont certainement les exemples les plus marquants. Dans notre équipe de recherche, depuis quelques années, nous avons developpé avec succés des nouveaux catalyseurs chiraux d’or(I) et de platine. Ces derniers nous ont permis d’obtenir dans les reactions de cyclisation d’énynes les produits correspondants avec de très bons rendements et énantiosélectivités. Cependant à notre connaissance, et jusqu’à present, les meilleurs catalyseurs d’or(I) chiraux possédaient soit une chiralité axiale, centrale ou hélicoïdale. En effet, concernant les complexes d’or(I) possédant une chiralité planaire, à part quelques résultats préliminaires modestes, cette source de chiralité a plutôt été négligée jusqu’à présent.Afin de combler ce vide, nous proposons dans cette thèse le développement de deux nouvelles familles de catalyseurs à chiralité planaire, et de les appliquer dans des réactions de cycloisomérisation d’énynes. Dans la dernière partie de cette thèse, nous avons développé une nouvelle réaction énantiosélective pour la formation de composés polycycliques.Cette thèse regroupe l’ensemble de ces résultats en cinq chapitres distincts : i) Une introduction générale sur la catalyse à l’or et sur les différentes réactions et applications envisageables. ii) La préparation d’une nouvelles famille de ligands phosphorés ferrocéniques possédant une chiralité planaire, et des complexes d’or(I) correspondants. Ces complexes se sont révélés être particulièrement actifs dans la formation de bicyclo[3.1.0]hexanones par cycloisomérisation d’énynes 1,5. iii) Dans le troisième chapitre sera détaillé mon travail concernant le développement d’une nouvelle famille de phosphoramidites à chiralité planaire. Les complexes d’or correspondant se sont révélé être très actifs dans des réactions de cyclotrimérisation de diénynes 1,6 azotés. Les produits correspondants ont été obtenus avec de bons rendements, diastéréosélectivités et énantiosélectivités (jusqu’à 95% ee). iv) Enfin, nous avons mis au point une nouvelle réaction énantiosélective de formation de dérivés polycycliques, en utilisant tous les catalyseurs d’or préalablement synthétisés, ainsi que ceux décrits dans la littérature. De nombreux substrats cyclopropylénynes diversement substitués ont pu donner accès aux produits correspondants avec de très bons rendements et énantiosélectivités (jusqu’à 99% ee). La post-fonctionnalisation des produits ainsi obtenus a permis l’obtention de produits analogues de composés naturels complexes. v) Après la conclusion et les perspectives à ce travail, une partie expérimentale regroupant les modes opératoires et toutes les analyses physico-chimiques des produits synthétisés est présentée. / The gold(I)-catalyzed cycloisomerization reactions provide powerful tools for the synthesis of heterocycles and carbocycles in both racemic and enantiomerically enriched forms. The direct cyclization of enyne substrates to form new C-C or C-heteroatom bonds proved to be an efficient atom and step economy approach for the synthesis of bicyclic or tricyclic compounds. The well-known cyclizations of 1,6- and 1,5-enynes into bicyclic compounds are one of the most powerful examples. Moreover, during the last few years, our group developed several series of chiral platinum or gold pre-catalysts which exhibit excellent catalytic activity, diastereoselectivity and enantioselectivity in the cyclization of enyne substrates.As far as we know, gold complexes with central, axial and helical chirality exhibited excellent results both in terms of catalytic activity and enantioselectivity. However, the planar chirality has been rather neglected so far in the gold promoted enantioselective cyclizations. Although some planar chiral gold complexes (mainly based on the ferrocene structure) have been reported in recent years, high enantioselectivity proved particularly difficult to obtain. In order to extend the potential applications of the planar chiral gold complexes, we have synthesized two new family of gold complexes with planar chirality and applied them in the cycloisomerization of 1,5-enynes and 1,6-dienynes. Finally, with several families of chiral gold complexes (with axial, planar or helical chirality) in hand, we developed a new type of cycloaddition reaction, with excellent catalytic activity and enantioselectivity.This thesis summarizes these studies: i) The chiral monodentate phosphines based on ortho-disubstituted ferrocene units have been prepared and used for the synthesis of gold(I) complexes. These complexes proved to be very active catalysts for the cycloisomerization of 3-hydroxy-1,5-enynes into bicyclo[3.1.0]hexanones. Their high catalytic activity is ascribed to their structural analogy to the biaryl-based Buchwald phosphines. ii) We have also synthesized and characterized new chiral phosphoramidites and demonstrated for the first time the ability of planar-chiral gold(I) complexes to obtain high enantioselectivities in cycloisomerisation reactions. Furthermore, starting from N-tethered prochiral dienynes, the corresponding bicyclo[4.1.0]heptane derivatives, containing three contiguous stereocenters, were obtained in good yields, with a total diastereoselectivity and up to 95% ee. iii) With a number of chiral gold complexes (with axial, planar or helical chirality), an efficient approach for the cycloaddition of cyclopropylenynes has been developed, based on the enantioselective gold catalyzed cycloaddition reaction. This novel method provides an easy access to the enantioselective synthesis of cyclobutanones and the further preparation of chiral tricyclic compounds possessing the skeleton of natural products. We have highlighted axial bis(phosphine)digold(I) complexes which afforded the cyclobutanones with up to 99% enantiomeric excesses in these cyclization reactions.

This report presents a project that has been made to present the design of a planar transformer as a part of a series loaded resonant DC/DC converter in a power unit. The design is based on an existing transformer that is not planar and so the characteristics of the transformer is translated into a planar version. A multilayer printed circuit board (PCB) design was made to fit a chosen magnetic ferrite core that was chosen based on the magnetic characteristics of the old core. Calculations were made for the loss of both core and windings and the final results show that it is possible to design a planar transformer from a traditional transformer.

Finding bottlenecks and eliminating them to increase the overall flow of a network often appears in real world applications, such as production planning, factory layout, flow related physical approaches, and even cyber security. In many cases, several edges can form a bottleneck (cascaded bottlenecks). This work presents a visual analytics methodology to analyze these cascaded bottlenecks. The methodology consists of multiple steps: identification of bottlenecks, identification of potential improvements, communication of bottlenecks, interactive adaption of bottlenecks, and a feedback loop that allows users to adapt flow networks and their resulting bottlenecks until they are satisfied with the flow network configuration. To achieve this, the definition of a minimal cut is extended to identify network edges that form a (cascaded) bottleneck. To show the effectiveness of the presented approach, we applied the methodology to two flow network setups and show how the overall flow of these networks can be improved.

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第19406号 / 工博第4122号 / 新制||工||1635(附属図書館) / 32431 / 京都大学大学院工学研究科高分子化学専攻 / (主査)教授 中條 善樹, 教授 澤本 光男, 教授 赤木 和夫 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

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Planar graphs have a rich history that dates back to the 18th Century. They form one of the core concepts of graph theory. In computational graph theory, they offer broad advantages to algorithm design and many groundbreaking results are based on them. Formally, a given graph is either planar or non-planar. However, there exists a diverse set of established measures to estimate how far away from being planar any given graph is. In this thesis, we aim at evaluating and improving algorithms to compute these measures of non-planarity. Particularly, we study (1) the problem of finding a maximum planar subgraph, i.e., a planar subgraph with the least number of edges removed; (2) the problem of embedding a graph on a lowest possible genus surface; and finally (3) the problem of drawing a graph such that there are as few edge crossings as possible. These problems constitute classical questions studied in graph drawing and each of them is NP-hard. Still, exact (exponential time) algorithms for them are of high interest and have been subject to study for decades. We propose novel mathematical programming models, based on different planarity criteria, to compute maximum planar subgraphs and low-genus embeddings. The key aspect of our most successful new models is that they carefully describe also the relation between embedded (sub-)graphs and their duals. Based on these models, we design algorithms that beat the respective state-of-the-art by orders of magnitude. We back these claims by extensive computational studies and rigorously show the theoretical advantages of our new models. Besides exact algorithms, we consider heuristic and approximate approaches to the maximum planar subgraph problem. Furthermore, in the realm of crossing numbers, we present an automated proof extraction to easily verify the crossing number of any given graph; a new hardness result for a subproblem that arises, e.g., when enumerating simple drawings; and resolve a conjecture regarding high node degree in minimal obstructions for low crossing number.