OBJECTIVES: To evaluate various cements in vitro for adhesion to zirconia, light curing vs. self-curing, the effect of particle abrasion (APA) on the zirconia intaglio for maximizing retention, the effect of thermocycling, and the effect of cement space. METHODS: The tested cements included: Ceramir C&B (Doxa) Panavia F2.0 (Kuraray); Multilink Automix (Ivoclar); Theracem (Bisco); Duolink (Bisco); Bifix (Shofu); CemEZ (Zest Dental). For testing cements retention, custom made zirconia rings 12.5 mm outer diameter, 5.5 mm height and 6.147 mm inner diameter were used to emulate crowns. Round steel rods (McMaster) were manufactured to fit into the zirconia rings allowing a cement space of 50 Microns or 100 Microns. A cementing jig was used to keep the rods at the center of the zirconia rings. Cements were tested using light curing and self-curing (n=10 per each test). Groups of zirconia rings were air braded with 100 Microns aluminum oxide particles for 10 Sec. Half the specimens were stored in water for 24 hours at 37o C in dark environment or thermocycled for 5000 cycles. A ‘push-out’ test using an Instron universal machine at a crosshead speed of 0.5mm/min. Loads to failure were recorded to calculate cements retention. RESULTS: Statistical analysis was performed using JMP Pro 13 software. Data were analyzed using one way ANOVA, multiple t-test, and Tukey-Kramer HSD. For self curing method without APA, retention strength ranking for tested cements were: Ceramir C&B ≥ Theracem > Panavia F2.0 ≥ Duolink ≥ Multilink Automix ≥ Bifix. For light curing method without APA, retention strength ranking for tested cements were: CemEZ ≥ Theracem ≥ Multilink Automix ≥ Duolink ≥ Bifix ≥ Panavia F2.0. There was a significant influence in retention strength for light cured cements compared to self-curing method except for Theracem and Panavia F2.0. For the self-curing method with APA, retention strength ranking for tested cements were: Theracem > Duolink ≥ Panavia F2.0 ≥ Multilink Automix ≥ Bifix > Ceramir C&B. For the light curing method with APA, retention strength ranking for tested cements were: Theracem ≥ Multilink Automix ≥ CemEZ ≥ Duolink ≥ Panavia F.0 ≥ Bifix. A significant increase in retention strength with APA compared to self-curing method with APA. There was no significant effect of thermocycling treatment on retention strength of the cements tested. There was no significant effect of different cement spaces on retention strength except for Ceramir C&B without APA and Multilink Automix with and without APA (P < 0.0001). CONCLUSIONS: 1- There was a significant difference in retention strength to zirconia among tested cements in self and light curing methods. 2- Light curing resin cements influenced retention strength to zirconia for the tested cements. 3- APA influenced the retention strength to zirconia for tested cements except for Ceramir C&B. 4- Increasing the cement space from 50μm to 100μm had no significant difference in retention strength to zirconia except for Ceramir C&B without APA and Multilink Automix with and without APA. 5- Thermocycling had no significant effect of on retention strength to zirconia for the tested cements. / 2020-07-30T00:00:00Z

EFFECTS OF ETCHING DURATION ON THE SURFACE ROUGHNESS, SURFACE LOSS, FLEXURAL STRENGTH OF E.MAX CAD GLASS CERAMIC AND SHEAR BOND STRENGTH TO A RESIN CEMENT Background: Long-term retention of ceramic restorations is dependent on the bond strength of the luting resin to both the tooth and porcelain substrates. In order to achieve successful bonding, the surface of the porcelain substrate must be modified to increase the surface roughness, and this can be achieved chemically by hydrofluoric (HF) acid etching. However, prolonged HF acid etching has shown to have a weakening effect on the evaluated lithium disilicate glass-ceramics. Therefore, it is essential to quantify the required etching duration of HF acid to minimize the possible deleterious effects on ceramic strength while maximizing the bond strength to tooth structure. Objectives: To evaluate the effects of HF acid etching duration on the surface roughness, surface loss, flexural strength, and shear bond strength of IPS e.max CAD (Ivoclar Vivadent) lithium disilicate-based glass ceramic to a resin cement. Hypothesis: The differences in HF acid etching durations will not have a significant effect on the surface roughness, surface loss, flexural strength, or shear bond strength of IPS e.max CAD to a resin cement. Methods: 168 specimens were prepared from IPS e.max CAD blocks. All specimens were polished and sonically cleaned in distilled water. Specimens were fired in the vacuum pump furnace according to the manufacturer’s instructions. Specimens were then divided into 4 groups, according to etching durations, then further divided into 3 subgroups, according to the properties tested. Group A was not etched (control), Groups B, C and D were etched with 5-percent HF acid (IPS Ceramic Etching gel, Ivoclar Vivadent) for 20 s, 60 s and 90 s respectively. The morphologies of both etched and non-etched surfaces in specimens of subgroup 1 of each etching group (n = 16/group) were observed under scanning electron microscopy (SEM). In addition, non-contact surface profilometry (Proscan 2000) was used to calculate the surface loss and to examine the surface roughness of the etched ceramic surfaces and roughness values (Ra, Rq) were documented for each group. Furthermore, etched specimens of subgroup 2 (n = 16/group) were silanated (Monobond Plus, Ivoclar Vivadent) and cemented with a resin cement (Multilink Automix, Ivoclar Vivadent). The shear bond strength (SBS) was measured using a universal mechanical testing machine. For each etching group, subgroup 3 specimens (n = 10/group) were loaded to failure in a three-point bending test to measure their flexural strength values using a universal mechanical testing machine. Data for surface roughness, surface loss, and flexural strength were analyzed using one-way analysis of variance (ANOVA), to identify the significant effects of different HF acid etching durations. Data for shear bond strength test were analyzed using two-way ANOVA to test the effects of etching duration, storage for 24 hours/thermocycling, and their interaction. All pair-wise comparisons from ANOVA analysis were made using Fisher’s Protected Least Significant Differences to control the overall significance level at 5 percent. Results: Difference in HF etching durations did not have a significant effect on surface roughness values Ra or Rq (p = 0.3408; p = 0.3245) respectively, but had a significant effect on surface loss (p = 0.0006). SBS values were not significantly different between experimental groups (p = 0.4650); however, SBS values after 24-h storage were significantly higher than that found after thermocycling (p = 0.0166) among different etching durations. Finally, different HF etching durations did not have a significant effect on flexural strength values (p = 0.1260). Conclusion: Within the limitations of this study, different HF etching durations did not have a significant effect on surface roughness, flexural strength, or shear bond strength of IPS e.max CAD. However, the different etching durations significantly affected the surface loss of the lithium disilicate glass ceramics.

Indiana University-Purdue University Indianapolis (IUPUI) / Process induced dimensional changes in composite parts has been the topic of interest for many researchers. The residual stresses that are induced in composite laminates during curing process while the laminate is in contact with the process tool often lead to dimensional variations such as spring-in of angles and warpage of flat panels. The traditional trial-and-error approach can work for simple geometries, but composite parts with complex shapes require more sophisticated models. When composite laminates are subjected to thermal stresses, such as the heating and cooling processes during curing, they can become distorted as the in-plane and the throughthickness coeffcients of thermal expansion are di erent, as well as chemical shrinkage of the resin, usually cause spring-in. Deformed components can cause problems during assembly, which significantly increases production costs and affects performance. This thesis focuses on predicting these shape deformations using software simulation of composite manufacturing and curing. Various factors such as resin shrinkage, degrees of cure, difference between through thickness coeffcient of thermal expansion of the composite laminate are taken into the consideration. A cure kinetic model is presented which illustrates the matrix behavior during cure. The results obtained using the software then were compared with the experimental values of spring-in from the available literature. The accuracy of ACCS package was validated in this study. Analyzing the effects of various parameters of it was estimated that 3D part simulation is an effective and cost and time saving method to predict nal shape of the composite part.

京都大学 / 0048 / 新制・論文博士 / 博士(農学) / 乙第13104号 / 論農博第2850号 / 新制||農||1051(附属図書館) / 学位論文||H29||N5036(農学部図書室) / (主査)教授 森 直樹, 教授 宮川 恒, 教授 三芳 秀人 / 学位規則第4条第2項該当 / Doctor of Agricultural Science / Kyoto University / DFAM

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No description available.

OBJECTIVES: This in-vitro study aimed to evaluate the effect of hydrofluoric acid etching and airborne particle abrasion on zirconia bond strength, using three different types of cement. To assess the impact of hydrofluoric acid etching on zirconia surface roughness and investigate the effect of hydrofluoric acid etching on zirconia's surface topography, microstructure, and crystal structure. MATERIALS AND METHODS: Crown-abutment simulation systems were constructed, using a custom-made zirconia tapered ring model and tapered titanium pin-abutments. Twelve groups were included in the study and classified according to the surface treatment and type of cement used. Each group had 10 specimens for a total of 120 test specimens. The fully sintered zirconia ring was alumina particle abrasion (APA) treated with a 50-μm alumina and/or etched with 9.5% HF acid, solution for 1 minute. The Ti pin was APA treated with 125-μm alumina. Three different types of cement were used: one RMGIC (GC FujiCem Evolve) and two resin composite types of cement (Panavia SA Universal and Panavia V5). A cementing jig was used to standardize the cementation process of the titanium pins to the zirconia rings. An Instron was used to obtain the retention load values. The failure load between the zirconia ring and the titanium pin was determined using an axial pullout test and the values were statistically analyzed for the effects of etching treatment, APA treatment, and cement type using JMP Pro 16. Zirconia-disk specimens were constructed using a custom-made disk model. Thirteen groups were included in the study and classified according to the hydrofluoric acid etching concentrations, consistencies, and timing used. Each group had 3 specimens. The total specimen size was thirty-nine specimens. Disks were polished and etched using 5% HF, 9.5% HF, and 40% HF acid etching concentrations, gel, and solution consistencies, and for 1 and 15 minutes of etching time. Disks were examined with an SEM, X-Ray diffractometer, and a profilometer for microstructure, crystallography, and surface roughness, respectively. RESULTS: HF acid-etching treatment significantly increased retention load compared to non-etched groups. There was no significant difference in retention load between APA-treated and non-APA-treated groups. Groups cemented with Panavia V5 showed a higher retention load compared to GC FujiCem Evolve and Panavia SA Universal. There was no significant difference in the surface roughness among the etched groups and the control groups. Roughening of the crystal boundaries with irregularities and pits was observed under SEM. As etching time and concentration increased the surface became rougher and more irregular. There were no obvious crystal structure differences between the etched groups and non-etched groups. CONCLUSIONS: Significantly different retention loads were found among tested groups. Hydrofluoric acid etching increases the bond strength of zirconia and titanium, using resin composite cement. Using hydrofluoric acid etching to pre-treat the zirconia surface may be an alternative approach to obtain sufficient bonding strength.

Polyurethane resin injection is a treatment being considered as a replacement for traditional methods of ground improvement. It has been used to re-level foundations and concrete slabs that have settled over time. Additional claimed benefits of the treatment have been noted recently, including improved factors of safety against soil liquefaction and reduced earthquake-induced settlements. To investigate the capability of the polyurethane resin injection treatment to mitigate liquefaction, two full-scale blast liquefaction tests were performed; one test was conducted in an improved panel (IP), an 8 m circular area treated with the polyurethane resin in a 1.2 m triangular grid from a depth of 1 to 6 m, and another test in an untreated 8 m circular area, the natural panel (NP). Each blast test was severe enough to produce liquefaction (ru ≈1.0) in the respective panel, with blast-induced settlements in the range of 70 to 80 mm. Despite similar levels of ground-surface settlement in the IP and NP, settlement within the top 6 m of the IP was about half that of the NP. A CPT-based predicted settlement for each panel was employed using the Zhang et al. (2002) methodology. Good correlation was found between the observed settlements and predicted settlements in both panels. Differential settlements across the panels were calculated based on ground-based lidar surveys, with a reduction of 42 to 49% between the IP and NP. The measured total and differential settlements following resin injection were at the bottom of the range observed in blast tests on a variety of shallow ground improvement methods conducted by the New Zealand Earthquake Commission in 2013. The persistence of the polyurethane resin injection ground improvement three years following its installation was indicated by the lasting increase of fundamental in situ test parameters. The results of the study indicate that resin injection is a viable method of ground improvement to reduce liquefaction-induced settlements by creating a stiffer surficial crust.

Indiana University-Purdue University Indianapolis (IUPUI) / New products are frequently developed for bonding brackets. This continuum brings about incessant studies attempting to prove or disprove their value. The need to compare the results of bond failure studies is made difficult if not impossible by the variation of published testing methods. The purpose of this study is to compare the differential effects of thermocycling, as a lab protocol, on three debonding techniques, shear-peel, tension, and torsion when using a traditional orthodontic resin adhesive. A standard orthodontic resin, Transbond™ XT (3M Unitek, Monrovia, CA) was used to bond 102 flattened 0.018-inch stainless steel brackets (3M Unitek) to flattened bovine incisors. Two step acid etching and priming (37 % phosphoric acid gel and Transbond MIP Primer, 3M Unitek) was used to prepare the enamel for bonding. During bonding, the resin thickness was held consistent. The bonding was accomplished under controlled temperature and humidity. Half of the samples were thermocycled prior to debonding. The samples were debonded in shear-peel, tension, and torsion. The data showed no significant differences between thermocycling and nonthermocycling in shear-peel or torsion, but in tension the thermocycling group had a statistically significant higher failure load. Overall, was a trend toward increased bond strength in the thermocycled group. The increase is likely the result of continued polymerization during thermocycling. The statistical difference that is noted in tension is thought to be due to the location of the highest stress being in the center of the resin pad. This would be the location of the least initial polymerization. The use of thermocycling as a lab protocol during bracket failure studies in shear-peel and torsion is not necessary when using traditional orthodontic resin.

OBJECTIVES: This in vitro study aims to compare and evaluate the mechanical properties of different 3D-printed resin materials. Determine the impact of 3D printer type on the mechanical properties. Investigate the filler percentage by weight for each resin material. MATERIALS AND METHODS: Eight resin materials were tested for flexural strength, flexural modulus, microhardness, fracture toughness, and wear resistance. Resin materials: Rodin Sculpture (RS), BEGO VarseoSmile Crown Plus (BVS), Desktop Health Flexcera Smile Ultra Plus (DHF), SprintRay Crown (SRC), SprintRay Ceramic Crown (SCC), Saremco Crowntec (SC), Myerson Trusana (MT), PacDent Ceramic Nanohybrid (PAC). 3D printer Asiga Max and Ackuretta SOL were used to print 12 specimens from each material to compare three-point flexural strength in bar-shape, biaxial flexural strength in disc-shape, fracture toughness in single edge V-notched beam, wear resistance in pin-shape. Three discs shape specimens from each material were used to compare the Vickers microhardness. The filler percentage by weight of each material is determined by Ash burning and Solvent extraction. The microstructure of a polished disc from each material was examined under a scanning electron microscope (SEM), and the elemental composition was investigated by Energy Dispersive Spectrometry (EDS). Results were analyzed using ANOVA, regression of least square means (α = 0.05), Tukey HSD test, Pearson correlation coefficient, and Student’s t-test. RESULTS: The flexural strength test results, utilizing the three-point method, reveal significant differences among the materials tested. The highest average was recorded in SCC at 160 MPa, while the lowest was found in SRC at 84.4 MPa. The flexural modulus also exhibited significant differences, with the highest average observed in SCC, BVS, RS, SRC, DHF, SC, and MT, measuring 7.8, 6.2, 6.0, 5.8, 4.9, 4.5, and 3.0 GPa, respectively. The resin materials with the highest biaxial flexural strength were DHF 217 MPa and MT 200 MPa, with no significant distinction between them and different from the remaining materials. SCC demonstrated a notably higher average value in Vickers microhardness 44 HVN, while DHF exhibited a significantly lower value of 15.58. The Fracture toughness test presented no significant differences between DHF, MT, and SCC, with values of 2.28, 2.27, and 2.11 MPa.m0.5, respectively, exceeding the remaining materials. In the wear test, DHF and MT had a significantly higher weight loss rate of 29.25 and 27.18 mg/million cycle, respectively. In contrast, MT's height loss rate of 2.02 mm/million cycle was the only significantly higher difference from other materials. The data indicates that the printer type does not significantly affect biaxial flexural strength. At the same time, Asiga exhibited significantly higher values in three-point flexural strength, flexural modulus and hardness tests. In contrast, the SOL printer demonstrated higher values in fracture toughness than Asiga. The ash and solvent extraction methods revealed that SCC had the highest filler percentage by weight, while MT had the lowest. SEM imaging showed the existence of filler particles in all materials, with PAC containing the largest particles and MT containing the smallest. DHF was the only resin material that contained exclusively spherical shape filler particles. EDS analysis disclosed the elemental composition of each material with a higher percentage in Silica, Oxygen, Barium, Titanium, and Ytterbium. CONCLUSION: The results demonstrate significant differences in the tested materials' flexural strength, flexural modulus, biaxial flexural strength, Vickers microhardness, fracture toughness, and wear rates. Even though there are significant differences in some of the mechanical properties of the printer type, it is small and might not have an effect clinically. A strong correlation exists between filler percentage with flexural modulus r = 0.83, biaxial flexural strength r = 0.60, microhardness r = 0.73, and wear resistance r= 0.82. There is a low correlation between filler percentage with fracture toughness r= 0.41, with no correlation with flexural strength in the three-point test. Filler particle percentage highly affects the mechanical properties of 3D printed resin materials. These findings could be valuable in selecting appropriate materials for specific applications.