The Makganyene Formation forms the base of the Postmasburg Group in the Transvaal Supergroup in the Griqualand West Basin. It consists of diamictites, sandstones, banded iron-formations (BIFs), shales, siltstones and carbonates. It is generally accepted that the Makganyene Formation rests on an erosive regional unconformity throughout the Northern Cape Province. However this study demonstrates that this stratigraphic relationship is not universal, and conformable contacts have been observed. One of the principal aims of this study is to identify the nature of the Makganyene basal contact throughout the Griqualand West Basin. Intensive fieldwork was carried out from Prieska in the south, to Danielskuil in the north. In the Sishen and Hotazel areas, only borehole material was available to assess the stratigraphy. The Griquatown Fault Zone delimits the boundary between the deep basin and platform facies. The Koegas Subgroup is only present south of the Griquatown Fault Zone, where it pinches out. However, the transition Griquatown BIFs-Koegas Subgroup occurs in lacustrine deposits on the Ghaap platform (Beukes, 1983). The Griquatown Fault Zone represents the edge of the basin, which corresponds to a hinge rather than a fault zone. The Makganyene Formation rests with a conformable contact on the Koegas Subgroup south of the Griquatown Hinge Zone, and north of it the Makganyene Formation lies unconformably on the Asbestos Hills Subgroup. The Makganyene Formation displays lateral facies changes that reflect the paleogeography of the Griqualand West Basin, and the development of ice sheets/shelves. The Ghaap platform is characterised by coarse immature sand interbedded with the diamictites. The clasts in this area contain local Asbestos Hills material and no dropstones are present. Such settings are typical of sediments that are being deposited below a grounded ice mass. At the Griquatown Hinge Zone, the sandstone lenses are smaller, and the clasts consist of chert, of which a great number are striated and faceted. In the Matsap area, the presence of dropstones is strong evidence for the presence of a floating ice shelf that released its material by basal melting. Further south, the Makganyene Formation contains stromatolitic bioherms that only form if clastic contamination is minimal and therefore the ice that transported the detritus to the basin did not extend far into open sea conditions. The base of the Hotazel Formation also contains diamictite levels. Dropstones have been identified, implying a glacial origin. The Hotazel diamictites are interbedded with hyaloclastites and BIFs. The Makganyene glacial event, therefore, was not restricted to the Makganyene Formation, but also included the Ongeluk Formation, through to the base of the Hotazel Formation. Petrographic studies of the Makganyene Formation and the base of the Hotazel Formation reveal mineral assemblages that are diagnostic of early to late diagenetic crystallisation and of low-grade metamorphism not exceeding the very low green-schist facies. The facies identified display the same sense of basin deepening, from shallow high-energy Hotazel area on the Ghaap platform, to the deep basin in the Matsap area. Whole-rock geochemical analyses reveal that the elemental composition of the Makganyene Formation is very similar to that of the Asbestos Hills BIFs, which were the most important source of clastic detritus for the Makganyene Formation. However, minor amounts of carbonates of the Campbellrand Subgroup, as well as a felsic crustal input from the Archean granitoid basement, made contributions. On the Ghaap platform, the Makganyene diamictite is enriched in iron, calcium, and magnesium, while in the deeper parts of the basin the diamictites are enriched in detrital elements, such as titanium and aluminium, which occur in the fine clay component. The Hotazel diamictite displays a distinct mafic volcanic input, related to the extrusion of the Ongeluk basaltic andesites, which was incorporated in the glacial sediments. Sequence stratigraphy is based on the recognition of contacts separating the different systems tracts that compose a depositional sequence. However, because the basal contact of the Makganyene Formation has not been properly identified in previous work, no correct model has been proposed so far. Therefore correlations between the Griqualand West and the Transvaal basins, based on lithostratigraphic similarities and extrapolations of unconformities, have to be reviewed, especially since the publication of new radiometric ages contradict all previously proposed correlations. It is proposed here that the Transvaal Supergroup in the Griqualand West Basin represents a continuous depositional event that lasted about 200 Ma. The Makganyene glacial event occurred during changing conditions in the chemistries of the atmosphere and ocean, and in the continental configuration. A Snowball Earth event has been proposed as the causative process of such paleoenvironmental changes. However, evidence presented here of less dramatic glacial conditions, with areas of ice-free waters, implies an alternative to the Snowball Earth event. The paleoenvironmental changes are thought to represent a transition from an anaerobic to aerobic atmosphere, that was responsible for the global cooling of the surface of the Earth, Such a glacial event may have aided in the large-scale precipitation of iron and manganese in areas of intense upwellings.

L'objectif de cette thèse est d'expliquer les avantages qu'offrent la reconstruction de l'architecture des unités géologiques, leurs déformations ainsi que leurs variations au cours du temps à l'exploration de ressources minérales, tout en appliquant des méthodes et outils de modélisation 3D et 4D. La modélisation et la restauration structurale sont utilisées ici pour estimer des attributs géologiques qui peuvent aider à la compréhension de la formation des gisements, et à l'identification des zones favorables aux minéralisations. Cette thèse est axée sur l'application de la modélisation 3D et 4D à des cas réels pour trouver le lien entre une minéralisation et des processus géologiques tel que l'exhumation des terrains, l'activité des failles et la fracturation résultant d'un évènement de déformation. Ce mémoire est organisé en trois parties : (i) la modélisation structurale ainsi que la restauration surfacique ont été appliquées au district minier de la Ceinture de Cuivre de Legnica-Glogów (sud-ouest de la Pologne), pour estimer les conditions favorables à la fracturation hydraulique. Cette fracturation est intervenue dans le nord de l'Europe lors d'une phase d'inversion à la fin du Crétacé et au début du Paléocène. Dans notre hypothèse de départ, la fracturation hydraulique développée au cours de cette période a joué un rôle important dans la distribution en cuivre observée aujourd'hui dans le district minier ; (ii) la courbure des surfaces triangulées, représentant les horizons de la région des Sudètes polonaises, permet de mettre en évidence les systèmes de failles dans le socle. En particulier, des méthodes de restauration surfaciques ont été utilisées pour évaluer l'activité de des failles au cours du temps, en se basant sur la courbure des surfaces obtenues à chaque étape de la restauration. Les zones de fortes activités sont ici associées aux processus de minéralisation cuprifère de la région ; (iii) la restauration mécanique de la région de Mount Pleasant (Australie occidentale), a permis de simuler un évènement de raccourcissement apparu dans l'Archéen et qui est lié à un processus de minéralisation aurifère. La restauration mécanique est appliquée pour estimer le champ des déformations de la région au moment du raccourcissement. Avec ce champ de déformation, il est possible de calculer les paramètres d'endommagement de la masse rocheuse qui semblent liés aux zones aurifères situées hors des systèmes principaux de failles. Cette thèse a ainsi permis de mettre en évidence l'aspect prometteur de la modélisation et de la restauration structurale pour identifier des zones potentiellement minéralisées, mettant en valeur leur utilisation pour l'exploration des gisements et des ressources minérales / The objective of this Ph.D. thesis is to apply 3D and 4D modeling methods to reconstruct the architecture and deformations over time of geological entities in a defined region. Structural restoration modeling is used here to estimate geological, physical and structural attributes for understanding the origin of ore-deposits, and for identifying potential mineralized areas. We focused this thesis on 3D and 4D modeling on real case studies with different geological contexts (e.g. uplifting, fault activity and shortening), demonstrating the advantages and drawbacks on their use for similar situations. This thesis is organized into three parts: (i) the application of structural modeling in the mining district of the Copper Belt of Legnica-Glogów (south-west Poland). A surface-restoration approach was applied to estimate favorable conditions for hydraulic fracturing during an inversion, occurred in the northern part of Europe at Late Cretaceous--Early Paleocene. In our hypothesis, hydraulic fracturing developed at that time played an important role in the distribution of copper content observed in present days in the mining district. (ii) The curvature calculated on triangulated surfaces that represent the stratigraphic horizons in the Fore-Sudetic region (Poland), are used to highlight the fault systems in the basement as well as their activity. High curvature values reveal the fault activity which is associated with the copper mineralization process in the region. (iii) Mechanical restoration of the Mount Pleasant, Western Australia, simulates an Archean shortening event which occurred in the area linked to the gold mineralization process. The mechanical restoration was used to estimate the strain field in the region at the time of shortening. This deformation field was used to estimate the damage parameters of the rock mass. They show new potential gold areas located in off-fault gold systems. In conclusion, it is shown that 3D modeling and structural restoration could be used to identify potential favorable zones for the presence of mineralization, and seem promising as a tool for the exploration of ore-deposits and mineral resources

No description available.

Alfred Stelzner, ein Geologe, Petrograph und Vertreter der Stratigraphie und Lagerstättenlehre, war ein Meister der mechanischen Trennung von Materialien.

In recent years nickel is mostly produced from lateritic ore deposits such as nontronite, limonite, etc. Resource estimation is difficult for laterite deposits as they have a weak and heterogeneous form. 3D modeling software are rather suitable for deposits having tabular or vein type ores. In this study the most appropriate estimation technique for resource estimation of nickel laterite deposits was investigated. One of the known nickel laterite deposits in Turkey is located at T&uuml / rkmen&ccedil / ardagi - G&ouml / rdes region. Since the nickel (Ni) grade recovered from drilling studies seem to be very low, a reconciliation pit having dimensions of 40 m x 40 m x 15 m in x-y-z directions was planned by Meta Nikel Kobalt Mining Company (META), the license owner of the mine, to produce nickel ore. 13 core drilling and 13 reverse circulation drilling (RC) and 26 column samplings adjacent to each drillholes were located in this area. Those three sampling results were compared to each other and as well as the actual production values obtained from reconciliation pit. On the other side 3D computer modeling was also used to model the nickel resource in T&uuml / rkmen&ccedil / ardagi - G&ouml / rdes laterites. The results obtained from both inverse distance weighting and kriging methods were compared to the results of actual production to find out the applicability of 3D modeling to laterite deposits. Modeling results showed that Ni grade of the reconciliation pit in T&uuml / rkmen&ccedil / ardagi - G&ouml / rdes, considering 0.5% Ni cut-off value, by using drillholes data, inverse distance weighting method estimates 622 tonnes with 0.553% Ni and kriging method estimates 749 tonnes with 0.527% Ni. The actual production pit results provided 4,882 tonnes of nickel ore with 0.649% Ni grade. These results show that grade values seem to be acceptable but in terms of tonnage, there are significant differences between theoretical estimated values and production values.

Processing of Bolu-Himmetoglu (Type I Kerogen) and Ankara-Beypazari (Type II Kerogen) oil shales by flotation techniques were investigated for achieving clean solid fuel substitutes. Materials characterization was done through mineralogical, XRD and FTIR analyses. Flotation responses of the samples were tested with non-ionizing and ionizing collectors of cationic and anionic types. The effects of the collector dosage and pulp pH on cleaning were determined. Other important flotation parameters, conditioning time, flotation time, pulp density, particle size and frother dosage were encountered using a statistical approach, through a full two level factorial experimental design. An advanced flotation procedure, assisted by ultrasonic application, was developed for further improvement in flotation performance. The effects of cleaning on thermal characterstics and combustion kinetics were evaluated with Differential Scanning Calorimetry and ASTM methods while the changes in the emission profiles were assessed using Effluent Gas Analysis. Himmetoglu sample was characterized as a carbonate and organic rich humic oil shale with XRD and FTIR analyses while Beypazari oil shale involved significant carbonate and clay minerals and exhibited a fulvic character with a poor organics content. Reverse flotation with amine acetates provided the most effective means of cleaning with Himmetoglu oil shale. Ash was decreased from 34.76 % to 23.52 % with a combustible recovery of 83.57 % using 800 g/ton Flotigam CA at natural pH and the calorific value increased from 4312 kcal/kg to 5010 kcal/kg. Direct flotation with amines was most effective for Beypazari oil shale cleaning. Using Armoflote 17, ash was reduced from 69.88 % to 53.10 % with 58.64 % combustible recovery using 800 g/ton Armoflote 17 at natural pulp pH and the calorific value of the sample increased from 876 kcal/kg to 2046 kcal/kg. Following optimization, ash of Himmetoglu oil shale decreased to 16.81 % with 84.10 % combustible recovery and calorific value increased to 5564 kcal/kg. For Beypazari oil shale ash decreased to % 48.42 with 59.17 % combustible recovery and the calorific value increased to 2364 kcal/kg. Ultrasonic pre-treatment before flotation further decreased the ash of Himmetoglu sample to 11.82 % with 82.66 % combustible recovery at 15 minutes pre-conditioning time and 50 % power level. For Beypazari oil shale, ash decreased to 34.76 % with 64.78 % combustible recovery after 15 minutes pre-treatment time at 70 % power level. Comparative XRD spectra and SEM analyses revealed that the extent of mineral matter removal relied on the flotation performance. The thermal indicators considerably improved after cleaning and the extent of improvement increased with a decrease in the ash of the concentrates. Kinetic analysis showed the favorable effect of inorganics removal on the effectiveness and easiness of combustion and activation energies decreased after cleaning for both oil shales. The contributions of cleaning on the effectiveness of combustion were also revealed by the increases in the emission rates and total CO2 and CO emission amounts. CO2 emissions due to mineral matter decomposition and harmful SO2 emissions apparently decreased as a consequence of the cleaning of the undesired inorganic contituents and potentially cleaning components. Results of the cleaning and thermal analysis sudies revealed that it was possible to achieve a clean energy source alternative from oil shales through flotation and a significant potential can be anticipated for future use of oil shales as a cost effective and environmental friendly solid fuel substitute in view of Turkey&amp / #8217 / s great oil shale reserves.

Thesis (MSc)--Stellenbosch University, 2005. / ENGLISH ABSTRACT: The availability of multispectral data from the satellite-borne ASTER (Advanced Space borne Thermal Emission Reflection Radiometer) sensor with 14 spectral bands, launched on 18 December 1999, ushers in a new dimension in large-scale mineral exploration. The ASTER bands are strategically positioned to map distinctive absorptive features for mapping alteration mineralogy, which has increased the potential to map hydrothermal alteration zones as compared to the conventional Landsat TM satellite and aerial photographs. This research tests the ability of ASTER to map hydrothermal alteration zones by applying various image enhancement techniques and comparing them. The study area is the Haib copper prospect in Namibia. The Crosta technique, standard colour composites, spectral band ratioing, the software defoliant technique, log residuals and spectral linear unmixing were applied and compared against results from the previous detailed geophysical and geochemical exploration. The results from all the techniques corresponded with published geological maps from previous work and indicated ASTER's ability to detect alteration zonations. Comparison of the methods applied showed that choice of technique is usually dependent of the level of detail which one seeks to achieve. Standard colour composite and log residuals are more useful for a generalized overview of the alteration mineralogy, whilst uniquely defining mineral end members is achieved by application of the Crosta technique, ratioing and spectral linear unmixing. Application of the software defoliant techniques involved ratioing results, which are affected by spectral interferences from other minerals. The presence of a highly fractured system has been established by application of Sobel filtering. A spatial association of the extracted fracture system with alteration areas suggest mineralization at the Haib is fracture controlled. The results support the presence of argillicphyllic and prophylitic alteration zones on a regional scale, a scenario which can be equated to the Lowell-Guilbert model. The potassic-phyllic zone boundary could not be spectrally detected which also supports previous studies which suggest the potassic zone is nondefinitive and is over-printed by the phyllic zone. The results demonstrate that ASTER is an effective tool to map hydrothermal alteration systems in arid areas. / AFRIKAANSE OPSOMMING: Multispektrale data van die ASTER (' Advanced Space Borne Thermal Emmission Reflection Radiometer') sensors bestaande uit 14 spektrale bande, afkomstig van 'n satelliet gelanseer op 18 Desember 1999 lui 'n nuwe era in vir grootskaalse minerale eksplorasie. Die ASTER bande is strategies sodanig op die spektrum geposisioneer om onderskeidende absorberende verskynsels van veranderde mineralisasie te identifiseer. Hierdie data het die potensiaal verhoog om hidrotermale veranderingstelsels meer suksesvol te karteer as met konvensionele Landsat TM beelde en lugfotos. Hierdie navorsing toets die vermoeëns van ASTER om hidrotermale veranderingstelsels te karteer deur 'n wye reeks beeldverrykings tegnieke toe te pas en te vergelyk. Die studiegebied IS die Haib koperafsetting in Namibië. Die Crosta tegniek, standaard kleursamestellings ('colour composites'), ratio-tegnieke, plantegroeistroping ('software defoiliant'), log residuele ('log residual '), en spektrale lineêre ontmenging ('spectral linear unmixing') is toegepas en die resultate met vorige gedetailleerde geofisiese en geo-chemiese veldopnames te vergelyk. Die verkreë resultate van al die verskillende tegnieke het grootliks met gepubliseerde geologiese kaarte van die gebied ooreengestem en bevestig dat ASTER data geskik is om sulke mineralogies veranderde gebiede te karteer. Vergelykings tussen die tegnieke het getoon dat die keuse van tegniek bepaal word deur die vlak en tipe detail wat verlang word. Standaard kleursamestellings en die log residuele tegnieke lewer goeie resultate om veralgemeende oorsigte van mineralogies veranderde sones te verskaf, terwyl die Crosta-, ratio- en spektrale lineêre ontmengingstegnieke meer suksesvol is om spesifieke minerale te identifiseer. Die plantegroei stropingtegniek is nodig in gevalle waar spektrale ratios deur plantegroeiresponse geaffekeer word. Die aanwesigheid van 'n intensief gefraktuurde sisteem is bepaal deur 'n Sobel filter toe te pas. Ruimtelike assosiasies tussen die voorkoms van die gefraktuurde sone met en die minealogies gewysigde sones dui aan dat mineralogiese wysiging in die Haib gebied deur frakturering beheer is. Die resultate steun die aanwesigheid van argillities-fillitiese enpropolities gewysigde sones op 'n streekskaal, 'n scenario wat deur die Lowell-Guilbertmodel voorgehou word. Die grense van die kalium-fillitiese sone kon nie spektraal waargeneem word nie. Dit steun ook vorige studies wat suggereer dat die kaliumsone nieafbakenbaar is en waarskynlik deur die fillitiese sone oorlê word. Die resultate bevestig onomwonde dat ASTER data benut kan word om hidrotermaal veranderde sones in semiariede gebiede effektief te karteer.

In the San Dimas district, on the western flank of the Sierra Madre Occidental, near the small town of Tayoltita, Durango, gold and silver epithermal ore deposits are mined from the complex Arana fault system. The structural relationships of the Tayoltita system are well-mapped, but their kinematic relationship to ore deposition is unclear. In plan view and in cross-section, the Arana system has a horsetail or wedge-shaped geometry. Subsurface mapping of slickenside striae as movement indicators suggest that the N13°W-striking Arana fault, forming the eastern boundary of the system, is a normal slip fault with at least 250 m of throw. Subsidiary system faults display normal separation with varying degrees of dextral horizontal separation (which is a function of fault orientation). Experimental modeling of the Arana system indicated that the system formed under simple shear as the σ₂ and σ₃ stress axes rotated in a subhorizontal plane about σ₁. Rotational strain caused the developing fault strands to rotate and to be captured by the Arana fault, forming the typical wedge-shaped geometry. Later, a more complex rotation of the three major stress axes enabled hydrothermal fluids to progressively mineralize faults, which had more northerly strikes, by a process similar to progressive strain. This is documented by mineral assemblages that record the instants of fault opening and by the lack of mineralization along the high-angle, northwest- striking faults.

PhDENV (Geology) / Department of Mining and Environmental Geology / The study focused on the geology, structural setting and mineralisation of copper-sulphide deposits in the Musina area, located in the Central Zone of the Limpopo Mobile Belt of South Africa. The Messina copper deposits are located in the eastern part of Limpopo Province near the border with Zimbambwe. The deposits stretch from northeastern to southwestern direction for about 15 km. Previous copper mining in the area took place at Artonvilla, Messina, Harper, Campbell and Lilly copper deposits. The current study, however, focused on two main deposits, Campbell and Artonvilla. The origin, nature and mode of formation of the Cu-sulphide deposits in the Musina area have not been established with certainty. Two principal hypotheses on the origin of the Messina copper sulphide deposits have been proposed, viz; a magmatic-hydrothermal model, and meteoric waters model. Consequently, the mode of formation and mineralisation style of the Messina Cu-sulphide deposits remain contentious. Therefore, the main objective of the study was to investigate the nature and mode of formation of Cu-sulphide deposits in the Musina area. Different research methods have been applied in the current study so as to unpack the contradictory positions on the genesis of the Messina copper deposits. This included fieldwork, remote sensing data acquisition, laboratory work, and data analysis and interpretation. Fieldwork involved soil geochemical survey as well as rock and ore sampling within the study area. A total of 295 soil samples, 33 rock specimens and 21 ore samples were collected for laboratory investigation. Laboratory work consisted of a range of methods that included; geochemical analysis, petrographic and cathodoluminescence microscopy, ore mineralogy and ore microscopy, fluid inclusion geothermometry and isotope geochemistry. The work was done in different laboratories including: Mining and Environmental Geology Laboratory, Unviersity of Venda; Department of Geology Laboratory, University of Johannesburg; MINTEK Laboratory in Johannesburg; Société Générale de Surveillance Laboratory in Johannesburg, South Africa; Department of Applied Geology, Geoscience Institute, Göttingen University, Germany and Department of Geology, University of Georgia, Athens, United States of America. Remote sensing data was acquired from Southern Mapping Company, Johannesburg, South Africa. Interpretation of Remote sensing data was done at the University of Applied Sciences, Oswestfalen-Lippe, Germany. Data analysis and interpretation of laboratory results involved the use of: Desktop ArcGIS 10.4.1 for geochemical data interpretation; ENVI 5.1 and ArcGIS 10.4.1 Softwares for remote sensing data; and Triplot version 4.1.2 software for ternary plot for compositional variation of rocks. Soil geochemical survey revealed geochemical anomalies for Pb, Zn, Cu, As and Ni over the known copper deposits in the area as well as over six other areas that have not been associated with any sulphide mineralisation. Such new anomalous areas have been identified as target areas for future exploration of sulphide ore mineralisation. Petrographic studies of the rocks confirmed the host rocks to be amphibolite-quartz granulite, biotite-garnet-quartz granulite, amphibolite, quartzite, hornblende gneiss, quartzo-feldspathic gneiss, potassium-feldspathic gneiss and cal-silicate gneiss. These rocks were subjected to hydrothermal alteration during ore mineralisation within the area. It was further noted that epidote alteration was quite intensive in ore samples, while in unmineralised rock samples it was less intensive. Remote sensing data interpretation revealed spatial distribution and intensity of epidote alteration within the study area and in places coincided either with the known copper deposits or structural features, thus led to the identification of target areas for future mineral exploration in the Musina area. The current study established that the process of ore mineralisation in the Messina copper deposits took place in two distinct phases: first the formation of garnet, graphite, magnetite and hematite during regional metamorphism of the Limpopo Mobile Belt; and secondly, sulphide ore mineralisation resulting in the formation of copper ore comprising, veined, disseminated and brecciated ores. Sulphide ore mineralisation consisted mainly of pyrite, chalcopyrite, sphalerite, bornite, chalcocite and minor pyrrhotite and galena as well as traces of pentlandite, tennantite, mollybdenite, cobaltite and tetrahedrite. This confirms that the Messina copper deposits had complex sulphide ore mineralisation that is typical of hydrothermal mode of ore mineralisation from a magmatic source. The study further establishes the paragenitic sequence of ore mineralisation, comprising four stages: Stage I (Garnet- graphite – Fe oxides); stage II (Quartz- pyrite); stage III (Pyrite- sphalerite - chalcopyrite); and stage IV (Carbonates). Stage III represented the main stage of sulphide ore mineralisation in the area, while Stage IV comprising calcite, dolomite and ankarite marked the final stage of hydrothermal ore mineralisation. Paragenetic sequence identified three generations of quartz; first generation being associated with garnet, graphite, magnetite and hematite, second generation with pyrite and third generation with pyrite, sphalerite and chalcopyrite. Previous studies, however, indicated that there was only one generation of quartz that formed at the temperature between 210o to 150°C, but the current study established that the entrapment temperature of first generation quartz ranges from 315o to 200°C; second generation quartz from 235o to 135°C and third generation quartz from 240o to 115°C. At the same time, sulphur isotope investigation of chalcopyrite-pyrite pair from Campbell deposit registered a temperature of 359°C. The study therefore concluded that the temperature of ore formation within the Messina copper deposits ranged between 359°C and 115°C. The presence of halite and calcite as daughter minerals within the fluid inclusions was noted and this apparently is indicative of high salinity of fluid inclusions, which is considered as a product of direct exolution of crystalizing magma. Raman spectroscopy revealed the composition of gases in the fluid inclusions to be CH4 and N2 with 80% and 20% composition respectively, however, some inclusions were gas-poor. The presence of gases in the fluid inclusions is an indication that there was boiling at the time of entrapment. A narrow range of 34S values of -0.5 to 0.5‰ obtained in this study further confirms the magmatic source of Sulphur as Sulphur from the host rock was found to have high 𝛿34S value of 8.2‰. A genetic model for copper ore mineralisation within Musina area is proposed. The deposits are of polymetallic vein type that are genetically associated with porphyry copper deposits. According to this model, copper ore bodies were formed from hydrothermal fluids originating from magma and were epigenetic in nature. Geological structures in the area acted as conduits for hydrothermal fluids that resulted in the alteration of the host rocks and mineralisation of copper sulphide ore. Thus, the Messina coper deposits are of magmatic hydrothermal origin although the apparent location of a batholith is still unknown and the study recommends further viii research work on the location of the batholith that is presumed to have been the magmatic source. The study further recommend dating of later rocks as well as orebody s it is essential for understanding the process of ore formation in this area. For further exploration, areas that have undergone “moderate” to “high” degree of epidote alteration and lie in close proximity to geological structures such as faults and thrust folds that could have acted as conduits for hydrothermal fluids and resulted in sulphide ore mineralisation and registered high geochemical anomalies for Pb, Zn, As and Ni should be targeted. In support of further mineral exploration within the study area, the study recommend a detailed geostatistical application for the purpose of delineating homogeneous areas based on the combination of lineaments, interpolated soil geochemical maps and thematic maps. / NRF

Das Element Cobalt gewinnt als Technologiemetall und kritischer Rohstoff zunehmend an Bedeutung. Weitgehend in Vergessenheit geraten ist hingegen die Bedeutung des Cobalts für den historischen Erzbergbau im Erzgebirge. Auch die Weiterverarbeitung der Kobalterze in den historischen Blaufarbenwerken ist ein nahezu vergessenes Kapitel der sächsischen Wirtschaftsgeschichte. Es existiert keine zusammenfassende Literatur, die sich mit allen Facetten des historischen Kobalterzbergbaus im Erzgebirge befasst. Das Ziel dieser Masterarbeit ist ein Desiderat, das einen zusammenfassenden und integrativen Überblick über den historischen sächsischen Kobalterzbergbau und der eng damit verknüpften Blaufarbenindustrie schafft. Es wird der Frage nachgegangen, in welchen Lagerstättentypen Kobalterze mineralisierten und wie sich deren räumliche Verbreitung im Erzgebirge beschreiben lässt. Durch Auswertung von Akten des Bergarchivs Freiberg und anderen historischen Quellen erfolgt eine qualitative als auch quantitative Beurteilung der historischen erzgebirgischen Kobaltlagerstätten. Unter Anwendung analytischer Methoden (XRD, REM-EDX) und weiterführenden Literaturauswertungen wurde unter Zuhilfenahme von Sammlungsproben des Museums für Mineralogie und Geologie in Dresden (MMGDD) die mineralogische Zusammensetzung des bedeutendsten Kobalterzes, dem Skutterudit, analysiert. Darauf aufbauend werden die Besonderheiten der Kobalterzverarbeitung in den Blaufarbenwerken dargestellt. Standortgeographische Voraussetzungen werden ebenso erläutert, wie regionale und überregionale Handelsbeziehungen. Des Weiteren wird die Bedeutung der Blaufarbenindustrie für das Glasmacher- und Keramikhandwerk aufgezeigt. Angedeutet wird ebenfalls, wie sich der historische Kobalterzbergbau und Wissenschaft und Technik gegenseitig beeinflussten und so die sächsischen Blaufarbenwerke trotz Erfindung des kostengünstigeren Ultramarins um 1828 noch bis zu Beginn des 20. Jhd. marktbeherrschend blieben. Darüber hinaus werden die heutigen global bedeutendsten Kobaltlagerstätten und die Relevanz dieses Technologiemetalls vorgestellt. / Cobalt is becoming increasingly important as a technology metal and critical raw material. Largely forgotten, however, is the important role of cobalt for the historical ore mining and the subsequent industrial processing in the historical cobalt blue industries in the Erzgebirge mountains of Saxony. In the absence of a comprehensive modern literature the aim of this Master thesis is a desideratum that provides an overview of the historic cobalt ore mining and the closely related cobalt blue industries in the Saxon Erzgebirge. It examines the question in which types of mineral deposits cobalt was mineralised and how their spatial distribution can be described. As a result of evaluating documents of the Bergarchiv Freiberg and other historical sources, a qualitative as well as quantitative assessment of the historical cobalt deposits in the Erzgebirge is carried out. The most important cobalt ore, Skutterudite, was analyzed by using analytical methods (XRD, REM-EDX) and further literature reviews. For this purpose, collection samples from the Museum of Mineralogy and Geology in Dresden (MMGDD) were available. In addition, the peculiarities of further industrial processing of cobalt ore in the cobalt blue industries are presented, as well as their specific geographic prerequisites. Furthermore, the importance of the cobalt blue industry for the old crafts of glassmaking and ceramics is shown, just as the mutual influence with science and technology. Last but not least, the todays world's most important cobalt deposits and the relevance of this technology metal are presented.