Despite ecological, anthropological, and archaeological debate surrounding their desirability as habitats for human occupation, tropical rainforests have received relatively little attention in discussions of Homo sapiens' Pleistocene dispersal. Sri Lanka has yielded some of the earliest dated fossil and material culture evidence (c. 38-35,000 cal. years BP) for our species in a modern rainforest context beyond Africa. Nevertheless, assertions in Sri Lanka, and elsewhere, regarding early human rainforest reliance have been largely based on coarse or 'off-site' palaeoenvironmental records, and the overall role of these environments in human subsistence strategies has remained uncertain. This study applies stable carbon and oxygen isotope analysis to Sri Lankan human fossil, and associated faunal, tooth enamel dated to between 36-29,000 and 3,000 cal. years BP, in order to directly test human rainforest resource reliance, reconstruct a stable isotope ecology, and develop 'on-site' palaeoenvironmental records for Late Pleistocene-Holocene Sri Lankan rainforest foragers. Stable carbon and oxygen isotope analysis of modern Sri Lankan primates, and stable carbon, oxygen, and nitrogen isotope analysis of modern plant samples from the Polonnaruwa Nature Sanctuary, are also performed to investigate the ecology of Sri Lankan primates on which Late Pleistocene-Holocene forager subsistence strategies were focused. The results demonstrate that Homo sapiens relied on rainforest resources in Sri Lanka from c. 36-29,000 cal. years BP until the Iron Age c. 3 cal. years BP, even when open environments, and their corresponding resources, were available. This remains the case through periods of evident environmental change at the Last Glacial Maximum and even upon the arrival of agriculture in the island's tropical forests. The primate stable isotope data prove difficult to interpret as ecological niche separation in the absence of observation data. Nonetheless, humans were evidently able to not only use but also rapidly specialise in the exploitation of South Asia's rainforests.

The biostratigraphy and isotope stratigraphy of the upper Aptian to lower Cenomanian interval including oceanic anoxic events OAE1b, 1c and 1d are investigated in ODP Site 763, drilled on the Exmouth Plateau offshore northwest Australia. Benthic foraminifera suggest that Site 763 was situated in outer neritic to upper bathyal water depths (~150-600 m). OAEs of the Atlantic basin and Tethys are typically associated with organic carbon-rich black shales and δ13C excursions. However, OAEs at this high latitude site correlate with ocean acidification and/or pyrite formation under anoxic conditions rather than black shales. Ocean acidification maybe responsible for sporadic low abundances of planktic foraminifera compared to radiolarians and benthic foraminifera associated with increased volcanogenic CO2 production during the formation of the Southern and Central Kerguelen Plateaus. Sea surface temperature may have cooled to 11°C in the late Aptian but increased gradually during the Albian. The Aptian/Albian boundary is placed at a negative carbon isotope excursion associated with the lowest occurrence of Microhedbergella renilaevis, typically found within the Niveau Kilian black shale of OAE1b. Third-order sea level cycles, particularly in the middle Albian, produced cyclic changes in the abundance of inoceramid prisms that increased during inferred times of falling sea level. The late Albian OAE1c and OAE1d coincide with horizons of intense pyritization and the absence of all biocomponents suggesting the development of euxinia. Warm Tethyan waters reached the Exmouth Plateau during the latest Albian based on the presence of thermocline dwelling keeled planktic foraminifera including Planomalina buxtorfi.

La vitesse de surrection du l’Himalaya et du plateau tibétain tout au long du Cénozoïque reste encore aujourd’hui largement débattue. L’analyse des isotopes stables de l’oxygène pour reconstruire les paléo-altitudes est considérée comme une technique très efficace et a été largement utilisée. Néanmoins, cette méthode a deux limites principales: 1) les relations entre δ18O et climat ne sont pas bien établies et 2) le climat Cénozoïque en Asie est mal contraint. Dans le cadre de cette thèse, nous avons étudié le lien entre la surrection des montagnes, les changements climatiques associés et le δ18O dans la paléo-précipitation. Nous utilisons le modèle de circulation générale atmosphérique isotopique LMDZ-iso. Nos simulations climatiques montrent que le retrait de la Paratéthys, le déplacement latitudinal de l’Inde et l’altitude du plateau tibétain contrôlent les précipitations et la variabilité de la mousson en Asie. Afin de comprendre où et comment ces changements climatiques liés à la surrection des montagnes affectent le δ18O, nous avons proposé une expression théorique de la composition isotopique des précipitations fondée sur la distillation de Rayleigh. Nous avons montré que seulement 40 % des sites échantillonnés de l’Himalaya et du plateau tibétain contiennent une signature isotopique représentant la topographie. Les résultats obtenus dans cette étude montrent que l’Himalaya pourrait avoir atteint son altitude actuelle plus tardivement que précédemment proposé. Des conditions aux limites réalistes nous permettent de reconstruire le δ18O des paléo-précipitations pour quatre époques du Cénozoïque (55, 42, 30 et 15 Ma). Dans la mesure où les reconstructions des paléo-altitudes sont particulièrement controversées pour les premières étapes de l’évolution du plateau tibétain, nous avons ensuite approfondi notre étude en nous focalisant sur l’Eocène (en utilisant une paléogéographie qui correspond à 42 Ma). Pour ce cas, nous montrons que le δ18O des précipitations est insensible à l’altitude en Asie, tandis que le δ18O dans les archives naturelles (carbonates) enregistre le signal de la paléo-élévation puisque le fractionnement entre la calcite et l’eau est sensible à la température, qui elle-même dépend en partie de l’altitude. La comparaison du δ18O simulé pour l’Eocène avec les données du δ18O mesuré dans les carbonates suggère que, pendant l’Eocène, l’Himalaya et le plateau tibétain n’avaient pas encore atteint leur élévation actuelle (> 3000 m). / The timing and rate of surface elevations of the Himalayas and the Tibetan Plateau remain controversial and their impact on Asian climate and the onset of monsoon systems in this area is highly debated. Stable oxygen paleoaltimetry is considered to be a very efficient and widely applied technique, but has limitations from two sides: 1) the link between stable oxygen composition of precipitation and climate is not well established, 2) Cenozoic climate over Asia is poorly reconstructed. With a purpose of filling the gap in our knowledge of climate variability over Asia during the Cenozoic, we use the isotope-enabled atmospheric general circulation model LMDZ-iso to understand the links between the growth of mountains, associated climate changes and δ18O in paleo-precipitation. Our results show a significant influence of the Paratethys retreat, the latitudinal displacement of India and the height of the Tibetan Plateau on Asian hydrological cycle. For the purpose of understanding where and how the climatic changes linked with the growth of mountains affect δ18O in precipitation, we develop a theoretical expression for the precipitation composition based on the Rayleigh distillation and show that only 40% of sampled sites for paleoaltimetry depict signal attributed to topography changes. We conclude that the Himalayas may have attained their current elevation later than expected. Realistic Cenozoic boundary conditions allow us reconstructing δ18O in paleoprecipitation for several periods during the Cenozoic (for 55 Ma, 42 Ma, 30 Ma and 15 Ma). The focus has been put on the Eocene (42 Ma), since paleoelevation reconstructions are particularly controversial for this time. We show that Eocene precipitation δ18O is rather insensitive to topographic height in Asia. However, carbonate δ18O still records paleo-elevation because the fractionation between calcite and water is sensitive to temperature, which partly depends on altitude. Comparison of simulated Eocene δ18O patterns with data from the carbonate archives suggest that the Himalayas and the Tibetan Plateau did not reach present-day (> 3000 m) elevations during the Eocene.

No description available.

The North American Wall mafic dikes and the diorite of the Rockslides mafic complex in the intrusive suite of Yosemite Valley show evidence of mixing with their host granites as well as with earlier components. Whole rock major element variation diagrams indicate the mafic rocks mixed with a more silicic component, but extrapolating to the silica end member does not yield the same result with each element. Trace element concentrations show a wide variation in concentration of Cr and Ni, with two samples showing enrichment in Cr (>300 ppm) and Ni (~44 ppm) compared to other samples (Cr =13-94 ppm; Ni = 5-26 ppm). These samples have the most primitive epsilon Nd values (-3.3, -3.5 at 100 Ma) analyzed thus far for the intrusive suite, indicating the suite has a larger range of isotopic values than previously thought. Delta 18 oxygen for Rockslides samples vary from 6.6 to 7.5 per mille (6 samples, average 7.03), higher than the 5.5 + 0.3 range for the mantle, indicating the presence of a crustal component in the system. Plagioclase phenocrysts within each unit display bimodal compositional populations. Subhedral to euhedral partially resorbed calcic cores (mode = An84-88) are reminiscent of a mafic magma, while sodic rims (mode = An48-50) are the product of a more silicic component. Very little to no intermediate zoning is present between cores and rims. Mineral-scale 87Sr/86Sr analysis of plagioclase cores and rims are consistent with previously published enriched bulk-rock ratios for the suite (0.7065-0.7078), but are unable to distinguish between mixing components. The plagioclase isotopic data show no direct evidence for a depleted mantle melt component contaminated by crustal assimilation. However, the mafic rocks are comparable to high-alumina basalts, whose generation involves crystal fractionation and magma mixing/crustal assimilation. The evolution of these high-alumina basalts provides an opportunity for magma contamination to take place before plagioclase crystallization, thus explaining why plagioclase core-rim analysis could not distinguish between mixing components. Therefore, it is possible but not necessary to derive the rocks from an enriched mantle source, especially since the bulk-rock oxygen isotopic values indicate a significant crustal component is present.

No description available.

No description available.

No / Pottery was a hunter-gatherer innovation that first emerged in East Asia between 20,000 and 12,000 calibrated years before present (cal bp), towards the end of the Late Pleistocene epoch, a period of time when humans were adjusting to changing climates and new environments. Ceramic container technologies were one of a range of late glacial adaptations that were pivotal to structuring subsequent cultural trajectories in different regions of the world, but the reasons for their emergence and widespread uptake are poorly understood. The first ceramic containers must have provided prehistoric hunter-gatherers with attractive new strategies for processing and consuming foodstuffs, but virtually nothing is known of how early pots were used. Here we report the chemical analysis of food residues associated with Late Pleistocene pottery, focusing on one of the best-studied prehistoric ceramic sequences in the world, the Japanese Jomon. We demonstrate that lipids can be recovered reliably from charred surface deposits adhering to pottery dating from about 15,000 to 11,800 cal bp (the Incipient Jomon period), the oldest pottery so far investigated, and that in most cases these organic compounds are unequivocally derived from processing freshwater and marine organisms. Stable isotope data support the lipid evidence and suggest that most of the 101 charred deposits analysed, from across the major islands of Japan, were derived from high-trophic-level aquatic food. Productive aquatic ecotones were heavily exploited by late glacial foragers, perhaps providing an initial impetus for investment in ceramic container technology, and paving the way for further intensification of pottery use by hunter-gatherers in the early Holocene epoch. Now that we have shown that it is possible to analyse organic residues from some of the world's earliest ceramic vessels, the subsequent development of this critical technology can be clarified through further widespread testing of hunter-gatherer pottery from later periods.

The origin of silicic magma in basalt-dominated oceanic settings is fundamental to our understanding of magmatic processes and formation of the earliest continental crust. Particularly significant is magma-crust interaction that can modify the composition of magma and the dynamics of volcanism. This thesis investigates silicic magma genesis on different scales in two ocean island settings. First, volcanic products from a series of voluminous Neogene silicic centres in northeast Iceland are investigated using rock and mineral geochemistry, U-Pb geochronology, and oxygen isotope analysis. Second, interfacial processes of magma-crust interaction are investigated using geochemistry and 3D X-ray computed microtomography on crustal xenoliths from the 2011-12 El Hierro eruption, Canary Islands. The results from northeast Iceland constrain a rapid outburst of silicic magmatism driven by a flare of the Iceland plume and/or by formation of a new rift zone, causing large volume injection of basaltic magma into hydrated basaltic crust. This promoted crustal recycling by partial melting of the hydrothermally altered Icelandic crust, thereby producing mixed-origin silicic melt pockets that reflect the heterogeneous nature of the crustal protolith with respect to oxygen isotopes. In particular, a previously unrecognised high-δ18O end-member on Iceland was documented, which implies potentially complex multi-component assimilation histories for magmas ascending through the Icelandic crust. Common geochemical traits between Icelandic and Hadean zircon populations strengthen the concept of Iceland as an analogue for early Earth, implying that crustal recycling in emergent rifts was pivotal in generating Earth’s earliest continental silicic crust. Crustal xenoliths from the El Hierro 2011-2012 eruption underline the role of partial melting and assimilation of pre-island sedimentary layers in the early shield-building phase of ocean islands. This phenomenon may contribute to the formation of evolved magmas, and importantly, the release of volatiles from the xenoliths may be sufficient to increase the volatile load of the magma and temporarily alter the character and intensity of an eruption. This thesis sheds new light on the generation of silicic magma in basalt-dominated oceanic settings and emphasises the relevance of magma-crust interaction for magma evolution, silicic crust formation, and eruption style from early Earth to present.

Les cherts, roches siliceuses, sont souvent considérés comme des marqueurs des conditions environnementales de la Terre primitive. Ces roches sont constituées de quartz sous différentes formes dont le quartz microcristallin ou microquartz est la forme majoritaire. Le but de cette thèse est d'étudier à l'échelle micrométrique les compositions isotopiques de l'oxygène et du silicium des différentes formes de silice dans des cherts d'âges variés, allant de 3,5 à 1,9 Ga afin de mieux comprendre l'origine et le mode de formation de ces roches et d'essayer d'améliorer les reconstructions des températures océaniques du Précambrien. Les mesures isotopiques, réalisées à la sonde ionique ims 1270, ont une précision meilleure que 0,2 ‰ pour le [delta]18O et de l'ordre de 0,3 ‰ pour le [delta]30Si. Ces analyses isotopiques ont été combinées avec l'analyse des éléments traces (B, Na, Mg, Al, K, Ca, Ti, Fe) avec la sonde ionique 3f, avec une étude pétrographique détaillée du microquartz et avec l'analyse des inclusions fluides des veines de quartz. Le résultat principal est la mise en évidence de grandes gammes de variation du [delta]18O (entre 1 ‰ et 14?‰) et du [delta]30Si (entre 2 ‰ et 5 ‰) à l'échelle micrométrique dans le microquartz. La gamme de variation du [delta]18O a pu être interprétée dans les échantillons datés de 1,9 Ga comme témoignant de l'histoire diagenètique de ces roches. Cette gamme permet, en corrigeant de l'effet de la diagenèse, de reconstruire des températures océaniques à 1,9 Ga entre 37 et 52°C, ce qui laisse suggérer un océan assez chaud au Précambrien si ces échantillons sont représentatifs de conditions globales. Dans le cas des échantillons datés à 3,5 Ga, les variations de [delta]30Si et de concentrations en éléments traces apportent des informations sur les origines variées des cherts. Enfin, l'effet des circulations fluides sur les compositions isotopiques du microquartz a été caractérisé par l'analyse isotopique du [delta]18O et du [delta]30Si et par l'étude des inclusions fluides. Il est démontré que dans certains cas le [delta]18O du microquartz peut être entièrement rééquilibré avec les fluides hydrothermaux ou métamorphiques. L'approche développée dans cette thèse devra dans le futur être appliquée systématiquement à l'étude des cherts aux fins de reconstructions paléo-environnemantales / Cherts, which are siliceous rocks, are considered as possible proxies of paleo-environmental conditions of the Early Earth. These rocks contain various forms of quartz, microquartz being the predominant one. The study of oxygen and silicon isotopic composition in the various forms of silica in cherts of different ages, from 3,5 Ga to 1,9 Ga, allowed to better understand the origin and the formation of these rocks and allowed to try to reconstruct paleo-temperatures for Precambrian seawater. Isotopic measurements were obtained with the ims 1270 multicollector ion microprobe with a precision better than 0,2 ‰ for [delta]18O and of ˜ 0,3 ‰ for [delta]30Si. These analyses were combined with the measurement of traces elements concentrations (B, Na, Mg, Al, K, Ca, Ti, Fe) with the ims 3f ion microprobe, with a petrographical study of microquartz and with the study of fluid inclusions in quartz veins. The major result is the existence at a micrometer scale of a large range of variations for [delta]18O (between 1 ‰ to 14?‰) and [delta]30Si (between 2‰ to 5‰). In the Gunflint cherts, the range of [delta]18O variation has been interpreted as due to diagenesis and has been used to reconstruct oceanic paleo-temperatures. The calculated temperatures range from +37°C to +52°C, suggesting an hot ocean during the Precambrian era if Gunflint cherts are representative of global environmental conditions. The [delta]30Si variations associated with that of trace elements concentrations allow to constrain the various origins of these cherts. The effect of fluid circulations on the isotopic compositions has been characterized by [delta]18O and [delta]30Si analyses and by fluid inclusions study. It is shown that in some cases the [delta]18O value of microquartz can be totally re-equilibrated with the hydrothermal or metamorphic fluids. The approach developed in this thesis will be decisive in future studies of Archean cherts for paleotemperature reconstructions